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By K. Lambrych

Hydrometallurgical equipment used to extract and refine copper and other metals is exposed to extremely corrosive chemical environments. These systems must be fabricated from materials that are durable against corrosion, meet exacting mechanical requirements, and perform economically over the life of the mineral processing plant. In several recent large hydromet projects, fiber reinforced plastic (FRP) has been shown to provide equal if not superior durability relative to alternative materials of construction. This paper will compare corrosion performance and cost of plant equipment fabricated with corrosion resistant alloys, rubber lined steel, and FRP made with Epoxy Vinyl Ester thermoset resins. Case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory-based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment. Specific examples from projects such as El Boleo, Long Harbour and others will be used to demonstrate how the versatility of FRP allows for remote fabrication of durable corrosion-resistant large-scale equipment for hydrometallurgical refinement of copper and other metals. INTRODUCTION Fiber reinforced plastic (FRP) began to emerge as a material of construction for corrosion service in many industrial processes in the late 1950s because of its ease of use and overall performance. Corrosion resistant (CR) FRP, as an alternative construction material to alloys, rubber and tile linings, grew steadily in following decades. The aggressive operating conditions associated with hydrometallurgical processes typically require materials of construction that can withstand acids and acid chlorides at temperatures up to 90°C, sometimes higher. Common metallic materials of construction, such as carbon steel, are not compatible with these conditions. High nickel alloys are capable of meeting performance requirements, but often at a high cost. In many cases FRP mining equipment based on epoxy vinyl ester resin (EVER) offers durability, long service life and lower maintenance costs. Through demonstrated performance and decades of case histories, more and more design engineers are confidently specifying FRP as the material of construction for new mineral processing equipment.

Jan 1, 2019

By L. Bratek, K. Jaworek, M. Czaplicka

Methods for arsenic compound removal from aqueous solutions include processes such as: coagulation, adsorption, membrane techniques, electrochemical and biotechnology techniques. Advanced oxidation using both UV radiation and strong oxidizing agents such as ozone and hydrogen peroxide may also decompose these compounds. It is known that effluents from metallurgical processes contain inorganic arsenic compounds in addition to the organic compounds such as: dimethylarsinic acid and phenylarsonic acid. This paper presents the conditions that lead to the formation of deposits containing mainly arsenic, such as pH, the wavelength of the radiation and the type of oxidant, for this type of effluent.

Jan 1, 2014

By H. Nakano

The codeposition behavior of impurities such as Ag, Bi, Fe, Ni, Pb and Sb with Cu was investigated galvanostatically at 5-3000 A/m2 using a Pt cathode at 60 °C in acidic copper (I) chloride (cuprous chloride) solution at pH1-2 containing 1.0 mol/L of Cu+ and 4.9 mol/L of Cl-. The impurities were classified into two groups: Group I (Ag, Bi) which codeposits with Cu as a metal, and Group II (Fe, Ni, Pb, Sb) which is slightly involved in the deposited Cu in nonmetal form from the electrolyte. Silver and Bi in Group I behaved as more noble metals than Cu, and significantly codeposited with Cu, showing typical features of regular-type codeposition. When Cu was deposited dendritically, the Ag and Bi content in the deposit increased with increased duration of electrolysis as a result of decreased net current density caused by increased cathode area. The current efficiency for Cu deposition in impurity-free solution was 95-100% over 100-1000 A/m2, but it abruptly decreased at above 1000 A/m2 when the limiting current density of Cu was attained. Although Fe, Ni, Pb and Sb in Group II were involved to 0.01-0.02 mass% in the deposit, they had no influence on the current efficiency or morphology of Cu.

Jan 1, 2007

By J. I. Gazzarri

A model of solid oxide fuel cell AC impedance behaviour has been developed and is used to simulate the frequency response of a single cell with and without mechanical damage. The results indicate that the presence of mechanically induced damage within the components of a solid oxide fuel cell can be detected by comparing the frequency response of the undamaged cell with that of a cell in which in-plane cracking or delamination has occurred. The presence of such defects manifests itself as a new semicircle in the Nyquist impedance diagram of the full cell. A parametric study reveals the resolution capabilities of the method in terms of the geometrical characteristics of the defects.

Jan 1, 2005

By Pierre Laliberté

L?utilisation de plusieurs nouvelles technologies et systèmes de contrôle visant des économies d?énergie dans une exploitation minière pourrait laisser croire qu?il suffit d?additionner les économies potentielles de chacune de ces technologies pour en évaluer l?économie totale. Une addition simpliste des pourcentages d?économie pourrait, dans certains cas, dépasser 100%, ce qui est évidemment totalement incohérent. Les LMSM-CANMET sont à réaliser une étude dont les résultats serviront à estimer l?influence de certaines technologies et systèmes de contrôle visant des économies d?énergie et à évaluer l?impact des unes sur les autres. En outre, un modèle de simulation est en cours de création afin d?évaluer les gains incrémentaux liés à l?application d?une série d?innovations dans une exploitation minière. La présentation fera le point sur l'état d'avancement du projet en plus de soumettre quelques exemples.

May 1, 2007

By Robert Boutilier

For more information on what the social licence means, see the following: Joyce, S. and Thomson, I. 2000. Earning a social licence to operate: Social acceptability and resource development in Latin America. The Canadian Mining and Metallurgical Bulletin, 93(1037) Nelson, J. and Scoble, M. 2006. Social License to Operate: Issues of Situational Analysis and Process. Vancouver, BC: Department of Mining Engineering, University of British Colombia. Thomson, I. and Boutilier, R.G. 2010. The Social License to Operate In P.Darling, (Ed.), SME Mining Engineering Handbook: Littleton, CO: Society for Mining, Metallurgy and Exploration. Much of what has been written and said about the social license to operate focuses on what the company has to do or not do. But the social license is a two-sided relationship. We also need to look at what the community has to do, or not do, in order to be capable of issuing a social license that is meaningful.

May 1, 2010

By B. A. Zaharov, J. M. Shneerson, L. V. Chugaev, M. T. Zhunusov, A. M. Markelov, S. V. Drozdov

The main direction of research was the application of autoclave technology for the flotation concentrates or biooxidation feedstocks. The industry modernization also expects the possibility of increasing the yield of the flotation concentrate, to allow an increase in gold extraction in flotation circuit. This paper provides brief description of results obtained for concentrates with the yield of 4 and 8%, as well as corresponding biooxidation feedstocks. Technological efficiency of autoclave oxidation is shown for both concentrates and biooxidation feedstocks. The process has been evaluated on a laboratory and a continuous pilot plant scale. Gold extractions from POX discharge are ranging from 94-97% for each product, with only 5-7 kg/t cyanide consumed.

Jan 1, 2014

By Fred A. Webber

STEEL ROPE WIRE is one of the more specialized commodities among the many grades of highcarbon steel wires. In its production there are many metallurgical aspects of interest from the steelmaking on through the final stages of wire drawing. We produce rope wire in an integrated mill com prising all the operations from the blast furnaces to finished wire drawing in the wire mills. Steelmaking is carried out with close control on hot metal, selection of scrap, and fluxing materials. The basic open hearths are of 170 tons capacity. Steel is teemed into 19 1/2 in by 19 1/2 in big-end-down molds and is hot-topped with the use of clay refractory hot-tops. The weight of this ingot is 6,900 pounds. All high -carbon steel ingots are charged hot into the soaking pits and are then rolled through the blooming mill in 16 p asses to a bloom ax~ in. by 41/2 in. and approximately 65 feet long. Necessary bottom and top crops are taken on the bloom as it passes from the blooming? mill to the billet mill. The still hot bloom is continuously rolled through the billet mill in . 5 passes to a 2 3/8 in. square. Billets are cut to 32 feet in length by a flying shear and then allowed to cool on the hot bed.

Jan 1, 1957

By Mike McKevitt

We are trying to promote a concept and a change in management?s approach to the iterative process of grade control. This is important as grade control must routinely try and achieve the long term objectives set by the mine plan ??BackgroundBackground ??Factors contributing to variation from planFactors plan ??Basis of OptimisationBasis Optimisation ??Ore Block Optimisation processOre process ??Operating mine examplesOperating examples ??Chain of Mining. ??Intention is to highlight the need for repeatable and consistent materialand material-type classification to remain consistent with the Life of Mine Plan ??We can drill another hole or reWe re-optimise a plan, but once excavated, the final decision has been made ??The grade control decision is the last decision made in the resource exploitation sequence.

May 1, 2009

By A. Longval, Q. Jiao, T. Shannon

In 2000, Xstrata Zinc (former Falconbridge Ltd.) Brunswick Smelter commissioned a modified lead blast furnace. Since then, efforts have been made to improve its operation in order to achieve optimal operation in terms of coke consumption, lead loss to slag, and improved environmental and hygiene conditions. This paper will review the important step changes in operational philosophy, undertaken since 2004, for the control of the blast rate, oxygen enrichment in blast, slag chemistry and charge level. Furthermore, a review of the improvements made in secondary materials consumed at the blast furnace will be made. This paper will also discuss the significant reduction of the frequency of accretion removal as a result of improved furnace operation.

Jan 1, 2008

By Randy Settgast, Daniel Moos, Hyunil Jo, Ghazal Izadi, Christine Baba

"Analyses of production logs of multiply fractured horizontal wells in unconventional plays show that only a small percent (~30%) of perforation clusters contribute to production. We present in this paper one possible approach to mitigating this problem, based on use of a fully 3-D numerical model of fracture propagation through a heterogeneous medium, by studying the influence both of spacing and of perforation friction on the initiation and propagation of simultaneous hydraulic fractures from a horizontal wellbore. The results indicate that while limited-entry perforating can help to equalize the lengths of fractures simultaneously growing from multiple clusters, it cannot equalize their widths. Both fracture width and fracture length can be equilibrated by combining non-even cluster spacing with limited-entry perforating. This has obvious benefits as it allows equalized placement of proppant across the entire series of perforation clusters, resulting in similar fracture widths and conductivities which enhances the likelihood that all clusters will contribute equally to production.INTRODUCTIONThere is substantial evidence from production logs and other information that during the hydraulic stimulation of horizontal wells, not all perforation clusters within a given stage will produce. One possible cause is the interaction between the hydraulic fractures emanating from each perforation cluster. Typically fractures created at the outer perforation clusters create “stress shadows”, i.e. increases in compressive stress in the minimum principal stress direction, which limit the growth of fractures growing from interior clusters; this is confirmed by modelling [1, 2, 3]. An example of this can be seen in Figure 1 which shows the final configuration of simultaneously propagating fractures from multiple, evenly spaced clusters when there is no perforation friction. The inner fractures are substantially shorter, reproducing the results by Bunger and Peirce [3]. The inner fractures also have substantially smaller widths.One approach to equalize the growth of simultaneously propagating fractures from a horizontal wellbore is by using limited-entry perforating as a method to equilibrate the flow rates into each of the different perforation clusters. Perforation friction is caused by the finite diameter of the entry points into the formation, and leads to a pressure drop across each perforation which is proportional to the flow rate squared. Fractures that take more fluid have a higher fluid velocity through the perforations than fractures receiving less fluid. This causes a larger pressure drop between the wellbore and more rapidly growing fractures, compared to the same pressure drop between the wellbore and the fractures that grow more slowly. Because pressure within the wellbore is approximately the same at each entry point, the larger pressure drop leads to less pressure being delivered to rapidly growing fractures, thereby decreasing their ability to propagate and reducing the amount of fluid they are able to receive. Because the mass rate of injection into the wellbore is constant, this forces more fluid into the fractures that were propagating more slowly, increasing their growth rate. It also increases the pressure required to drive fluid injection. The balance of these effects makes the system largely self-regulating and delivers more balanced fracture growth. While this effect is well known, it is often neglected in current numerical models."

Jan 1, 2015

By Stefan Boshkov

THE ADVENT of mining at great depth has brought to the fore the question of stresses around mine openings. The many-pronged attack on this problem is certified by the accelerated appearance, in the mining literature, of articles on various topics related to this subject (1). Whereas it may be agreed that we, of the mining profession, have fallen woefully behind in research and the development of an understanding of this important facet of the general problem of mining, it must also be accepted that the analysis of the stresses in a mine structure is usually more complex than is the case in the majority of structures encountered and dealt with in civil engineering. Whereas homogeneity and isotropy are readily acceptable for most metals, such properties are but crudely approximated in rocks. Whereas the external loads on a structure in civil engineering may be readily determined, those on a mining structure are subject to ?conjecture. Whereas the limits of the structure may readily be defined in civil engineering, the boundaries of the mining structure are, in most cases, indeterminate, and subject to intelligent guesswork, at best.

Jan 1, 1956

By S. Kelebek, B. Ingram, C. Gibson, T. MacNeil, M. Aghamirian

"The beneficiation and upgrading of pyrochlore from its ores is carried out through flotation. In industrial practice, upgrading is conducted in a two-stage flotation process in which pyrochlore flotation is carried out after gangue mineral pre-flotation (carbonate, silicate, sulphide or phosphate reverse flotation). In this study, the flotation of pyrochlore from a low grade carbonatite ore was performed at the laboratory scale following a two-stage flotation process in which carbonate minerals were floated in advance of niobium minerals. In parallel, a simplified flotation process was developed in which pyrochlore was floated directly from gangue minerals at increasingly acidic pH. Laboratory results indicated that both two-stage and direct flotation provided similar results in terms of niobium grade-recovery. Based on these results, a large scale, integrated pilot plant was conducted using a direct flotation flowsheet. While the elimination of reverse gangue flotation resulted in flowsheet simplification, the dissolution of carbonate minerals and the subsequent effect of dissolved cations on the floatability of pyrochlore added an element of complexity. A comparison of results from locked-cycle laboratory testing and pilot plant testing highlights the challenges of scaling up a complex flowsheet. A case is made for the direct flotation process and the key parameters to achieving success in large scale direct flotation of pyrochlore are discussed.INTRODUCTIONPyrochlore (Ca,Na)2Nb2O6(OH,F) is a niobium bearing mineral which has been the primary global source of niobium since the first pyrochlore mine commenced operations in the late 1960s (Gibson et al., 2015a). Preceding the discovery and development of high grade pyrochlore deposits in North and South America, the majority of global niobium supply came from gravity concentration operations of columbite (Fe,Mn)Nb2O6, across Africa (Perrault and Manker, 1981)."

Jan 1, 2016

By K. C. Lahiri, H. P. Das, G. G. Sarkar

"The petrographic components of any particular rank of coal often show some distinct physical and chemical characteristics. Therefore, their pro-portionate distribution in a coal greatly influences the technological behaviour of the coal.In any size or gravity separation of a coal, the petrographic constituents become segregated to different degrees in some preferred size or specific gravity range. Therefore, a knowledge of the petrographic nature of the washed and/or screened fractions is often considered essential in selecting the most efficient method for coal preparation and in exploring the proper evenues for its utilization.A graphical method is described in this paper to indicate the mineral-matter content and the petrographic components of the washed fractions of a coal at different ash levels of separation in the form of a new washability diagram. This diagram can be conveniently used to assess or predict the petrographic composition of clean coal or sinks corresponding to any desired ash level in the cleans. With the help of this diagram, it is also possible to locate the yield level of cleans at which maximum enrichment of vitrinites and exinites occurs with the least amount of mineral-matter content."

Jan 1, 1971

By Mark W. Bartlett

Program Objectives ??Identify and implement a tool for haul truck drivers that: -Reduces or eliminates fatigue-related injuries and fatalities -Reduces accidents and equipment damage ??Following evaluation period, apply tool where most effective Why do We Need a Fatigue Monitoring Tool? ??Everyone has probably fallen asleep while driving ??Driver fatigue is a major source of property damage and serious haul truck serious incidents ??To protect ourselves from the other ?tired?driver ??To know when to ask for relief ??To know when we are seriously distracted from driving ??To measure improvements in sleep incidents based on shift changes and intervention ??To help prevent incidents like the following:

May 1, 2011

By B. Daniels, A. Tieu, W. Yan, B. Ren, M. Vijay

"Plasma or thermal sprayed coatings are becoming more widely used in a wide range of industrial applications. The preference to use thermal sprayed coatings is mainly attributed to its superior wear, and corrosion resistant properties akin to hard chrome but without the harmful health implications of chrome in the coating process. Specifically, High Velocity Oxygen Fuel (HVOF) plasma sprayed Tungsten Carbide & Cobalt (WC/Co) coatings are presently being tested on aircraft landing gear. This coating can be efficiently applied and is highly resistant to corrosion and wear. However, HVOF coating's durability also makes it difficult to be stripped for inspection and overhaul. Current coating removal methods usually involve a multi-step process whereby the coating must undergo diamond wheel grinding, chemical dipping, grit blasting, ultrahigh pressure (UHP) 380 MPa (55 Kpsi) water blasting, and subsequent chemical dipping, depending on the type and thickness of the coating. As explained by Yan, et al [l]"" a unique method has been developed for removing HVOF coatings with the use of only water. The method consists of modulating a stream of water at a pressure of only 69 MPa (10 Kpsi) with ultrasonic waves to generate a forced pulsed waterjet. The resulting cyclic loading of the hard coating due to the impact of the water pulses easily causes it to flake off the substrate. This paper will briefly describe the fundamentals of the forced pulsed waterjet technique with an emphasis on insitu applications of the removal of various plasma and HVOF coatings."

Jan 1, 2006

By W. A. Jones

Purpose of Paper Geophysics is a highly developed science which has found a wide use in industry. Perhaps the most spectacular application has been in the field of oil exploration. It has been estimated that, up to the end of 1939, geophysics was responsible for the discovery of five billion barrels of oil. In 1944, the sum o $40,000,000 was expended for geophysical work in the search for new oil deposits. Although the metal mining industry has so far made comparatively little use of the science, it is becoming increasingly common for the exploration engineer or geologist to be required to co-operate with the geophysicist. Many papers dealing with applied geophysics have been published but in most of them advanced training in physics and mathematics on the part of the reader has been assumed. It is difficult for the average engineer to obtain a ready understanding of the equipment, field procedure, and scope and limitations of the science from the literature. The present paper attempts to describe briefly and in simple terms the principles underlying magnetic, self-potential, and electrical resistivity methods and their application to a field problem. Introduction Geophysics is concerned with the study of gravity, magnetism, natural earth currents, earthquakes, vulcanism, and many other natural phenomena. The methods, originally devised for the measurement, for scientific purposes, of the forces associated with such phenomena have been adapted to the search for buried deposits of economic value. If the body sought has large dimensions and distinctive physical properties, geophysical measurements may reveal associated, and in some cases quite characteristic, anomalous features. However, in many instances the mass cannot be indicated directly but has a common association with geological features which can be defined by physical measurements. Although such surveys cannot specifically identify oil, metalliferous minerals, or other commercially valuable substances, it is possible to delineate anomalous sub-surface physical features which, with the help of geological information, can be assessed as possible or probable indications of the body or structure sought. The nature and extent of the material causing an anomaly, and its economic importance, can only be determined by further exploration, such as drilling.

Jan 1, 1947

By T. Grammatikopoulos, SGS Canada Inc.

"The Nechalacho rare metal deposit, located in the Northwest Territories, Canada, is currently being taken through Feasibility Study by Avalon Rare Metals Inc. QEMSCAN analysis and supplementary electron microprobe analysis were utilized to identify and quantify the mineralogy of the deposit, and determine REE distribution among the minerals. QEMSCAN mineralogy was performed to provide textural information on the mineralization, determine the variability of the ore and identify REE domains, and the liberation and association of the REE minerals. The sample matrix consists predominantly of silicate minerals. The REE minerals include allanite, monazite, synchysite, columbite, fergusonite, and bastnaesite. Zircon is present in considerable amounts and is a REE carrier. Fergusonite and zircon account for most of the HREE, and monazite, allanite, synchysite and bastnaesite the LREE. QEMSCAN mineralogical data is extremely valuable in assessing the mineralogy of the ore. The data are implemented to define the mineralogy of the ore body, support metallurgical test work, and predict recoveries and grades.INTRODUCTIONThe term rare earth elements (REE) is used to describe the 15 lanthanide elements or metals and, more recently, the metals yttrium and scandium, which display similar physical and chemical properties.Economic and potentially economic REE deposits form two main groups, a more commonly occurring “light rare earth element” (LREE) group containing lanthanum, cerium, praseodymium, neodymium, and samarium and a less commonly occurring “heavy rare earth element” (HREE) group which, in addition to the LREE, contains elevated concentrations of the more valuable REE, europium, gadolinium, terbium, dysprosium, holmium, yttrium, erbium, thulium, ytterbium, lutetium and scandium. The first group is hosted primarily by carbonatites and the second by highly alkaline (Na + K > Al) silicate igneous rocks. The LREE are produced mainly from bastnaesite, monazite, etc., while HREE are produced almost exclusively from low-grade secondary ion adsorption clay deposits in which the REE are adsorbed onto the surfaces of kaolinite and halloysite, clay minerals produced by the weathering of granite and sediments. HREE are also found in fegusonite, zircon, xenotime, etc but are not produced presently from these minerals. China is responsible for 97% of the World’s production of the REE, mainly from the giant Bayan Obo, carbonatite-related deposit and from the clay deposits mentioned above.Quantitative automated mineralogy is increasingly being applied to ore deposits. It helps users to understand and improve mineralogical parameters for geological and metallurgical purposes. Data include textural characterization, to quantification and distribution of ore and gangue minerals, liberation and association of the REE minerals. The data can be used to define mineralogical domains and predict the metallurgical response of the ore (Gunning, de Souza, & Grammatikopoulos, 2009)."

Jan 1, 2012

By Will S. Pettitt

Fracture Network Engineering (FNE) is the engineering design of rock mass disturbance through the use of advanced techniques to model fractured rock masses numerically, and then correlate field observations with simulated fractures generated within the models. Microseismic (MS) monitoring is a standard tool for evaluating the geometry and evolution of the fracture network induced during a hydraulic treatment, principally by source locating MS hypocenters and visualizing these with respect to the treatment volume and infrastructure (Figure 1). The integrated use of Synthetic Rock Mass (SRM) modeling of the hydrofracturing with Enhanced Microseismic Analysis (EMA) provides a feedback loop in which the SRM is constrained by the information provided by the MS data and the in-situ behavior of the fracture network is better understood, leading to informed decisions on future field operations. This paper discusses the technologies used in FNE and some of the developmental challenges we face in order to provide a more efficient and robust application of the approach. One particular challenge is the accurate representation of MS source data within the models (locations, magnitudes and mechanisms), and the ability to correlate these data effectively with field results. This challenge is being overcome by the development of more efficient numerical modeling algorithms, providing simulations in three dimensions at reservoir scale, combined with validation of these algorithms using laboratory and field case studies.

Jun 1, 2012

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama, Ryuji Oinuma

"Recently, the arsenic grade in copper ores has been increasing year by year. Arsenic bearing minerals (enargite (Cu3AsS4) and tennantite (Cu12As4S13)) coexist with typical copper minerals such as chalcopyrite (CuFeS2). The removal of arsenic from copper ores that contain relatively high arsenic content is essential due to its adverse impact on the environment and the resulting economic consequences. In this study, arsenic removal and dissolution behaviour of Cu and As from enargite (Cu3AsS4) were investigated using ferric sulphate (Fe2(SO4)3) solutions containing sodium chloride under high pressure oxidation conditions. The effects of numerous parameters including the concentration of Fe2(SO4)3 and NaCl, temperature, total pressure, leaching time and particle size were studied while other variables such as pulp density and stirring speed were fixed at 100 g/L and 750 rpm. The results showed that more than 60% of the copper was dissolved in a 0.1 M ferric sulphate solution under the high pressure oxidative conditions, whereas the leaching rate of arsenic was less than 20%. SEM observation revealed that elemental sulphur was deposited on the surface of enargite forming a passivation layer and the residue was agglomerated. Those phenomena may cause a decrease in the copper leaching rate. It was found that more than 80% of copper was dissolved in the ferric sulphate solution in the presence of 0.34 M sodium chloride under the conditions optimized, whereas the dissolution of arsenic in the mixture did not exceed 2%. XRD analysis of the solid residues from the leaching experiments used ferric sulphate and mixtures of ferric sulphate and sodium chloride showed arsenic to be present as scorodite (FeAsO4).INTRODUCTION In recent years, there has been an increase of the arsenic (As) content of copper ores due to the gradual depletion of high grade copper ores. In some copper deposits, arsenic occurs in the form of minerals such as enargite and tennantite. The removal of arsenic in ores containing copper is critical to the production of pure copper and the management of the environmental challenges caused by the smelting process. Due to the environmental risk caused by arsenic emission and the deteriorated quality of the copper product, smelting of enargite concentrates is not an effective method for the extraction of copper (Padilla et al., 2010; Safarzadeh et al., 2014; Long et al., 2012). Therefore, a number of studies have been carried out to develop arsenic removal technologies from copper ores using various methods such as hydrometallurgy (Curreli et al., 2009; Tongamp et al. 2010), pyrometallurgy (Dalewski., 1999; Padilla. et al, 2012) and bio-oxidation (Ehrlich, 1964; Sasaki et al., 2010). Several hydrometallurgical leaching processes like sulphuric acid, alkaline sodium sulphide and sodium sulphate and ferric sulphate leaching have been developed to treat enargite ores and concentrates. The alkaline sodium sulphide leaching process has been developed for the removal of arsenic from enargite (Anderson, & Twidwell, 2008; Parada et al., 2014). The mechanism of the dissolution of arsenic from enargite in sodium sulphite solution is"

Jan 1, 2016