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By Todd Kennedy, Kurt Tischler

"This paper presents the field experience of Siemens with regard to Gearless Drives in the mining industry … We consider the elapsed production hours of Siemens Gearless Drives to be extensive enough to provide a reliable estimation of availability calculated on the basis of data representing repair time, downtime, and operating time. The users of Siemens Gearless Drives confirm an availability of more than 98% after exclusion of some major issues. The paper addresses all of these major issues of Siemens Gearless Drives, describes successfully applied corrective measures, explains the influences on the design of the drives, and lists the downtimes associated with each of these issues. INTRODUCTIONThe first Siemens Gearless Drive in mining began operation in 1980 and was installed on an iron ore grinding mill. As of September 2011, 40 Siemens Gearless Drives will have accumulated 136,000 machine days of operating time. According to pure rules of statistical analysis, this accumulated operating time may be too low to be used for a sample of field data to provide precise statistical values of availability, however we consider it large enough to provide indicative values of worthwhile consideration. This paper deduces the availability statistics of Siemens Gearless Drives in the mining industry from information received from end users and factors in all major issues that Siemens has experienced with our Gearless Mill drives. This paper does not consider Gearless Drives in other industries such as the cement industry. The cement plants, especially in the northern hemisphere, interrupt production for several months in the winter. This lengthy downtime is used to maintain the complete plant including the mills, their motors and their drives. The mining industry has more stringent and higher production requirements. In the mining industry, production must run 24 hours per day, 365 days a year."

Jan 1, 2012

By John Rowson, Caitlin Brown, Kebbi Hughes, Joseph Esslifie-Dughan

The McClean Lake mill in northern Saskatchewan, Canada, is operated by Orano Canada Inc. and has been in production for the last 20 years. The tailings preparation process at the mill has been designed with decommissioning in mind, to produce tailings that are geochemically stable over the long-term within the site’s tailings management facility. Twenty years of study have contributed to a detailed understanding of geochemical and geotechnical properties of the McClean Lake tailings. Validation of the tailings properties has occurred through in-situ sampling campaigns conducted initially every year, and later every five years. Each sampling campaign has applied the same rigorous sampling procedure to provide data with useful correlations year over year. Each campaign result compares elements such as the inherent variability of the tailings, consolidation of the tailings and variations in the tailings placement methods. We will discuss lessons learned from seven sampling campaigns over 20 years and present data to show the reliable tracking of geochemical evolution of the in-situ tailings over time; providing opportunities for continuous improvements.

Jan 1, 2020

By Yongjie Bu, Wei Sun, Zhiyong Gao, Yuehua Hu, Hongbiao Tao, Runqing Liu, Central South University

"The flotation behavior of O-isopropyl-N-ethyl thionocarbamate (IPETC) and pH for chalcopyrite and galena was studied through pure mineral test, adsorption quantity determination, solution chemistry calculation and Materials Studio simulation. The results show that the recovery differential value of chalcopyrite and galena is about 20% when pH of the pulp 9.5 and IPETC is 7×10-4 mol/L, the flotability differences of the two minerals is significant. There is competitive adsorption between OH? and IPETC on mineral surfaces, it lead to galena flotability is lower than chalcopyrite flotability. IPETC can remove the hydration layer on mineral surface and adsorb on active sites for collector adsorption, minerals have a better hydrophobicity.INTRODUCTIONCopper and lead are two of the most widely used metals in industrial and living, their applications include building construction, various metal alloys, heat and electricity, machine manufacturing (Zhang et al., 2014). Chalcopyrite and galena are the major source of copper and lead, normally they associated with each other. With the growing use of these resources, high grade and dissemination large particle sizes minerals are less and less, the use of low grade and complex dissemination minerals have to be paid more attention (Chen, Ye, & Li, 2010; Liu, Sun, Hu, & Wang, 2009). As the special properties and complex composition of copper-lead sulfide ore, flotation separation of chalcopyrite from galena effective is a research emphasis and difficulty point in mineral processing (Bruckard, Sparrow, & Woodcock, 2011).In the separation process of chalcopyrite and galena, it is rather important to choose effective collector (Huang, Wang, & Liu, 2014). Enlarging and using the two mineral flotability will be a good basis and start in flotation (Reyes-Bozo et al., 2014). Qin et al. (2013) made a great deal of research on flotation separation of copper/lead concentrate, collector O-isopropyl-N-ethyl thionocarbamate (IPETC), butyl xanthate (BX) and ammonium dibutyl dithiophosphate (ADTP) were investigated, BX and ADTP floated both chalcopyrite and galena well, specific adsorption appeared in the surface of mineral, the problem was the collectors were not selective enough, however IPETC showed better selective."

Jan 1, 2016

By J. A. Herbst

Professor Klaus Schönert and his students used fundamental physics to develop many of the principles required for the design and scale-up of "Gutt Bett Zerkleinern" devices such as the high pressure grinding roll (HPGR) or the high pressure roll crusher (HPRC). As the equipment evolved so have the tools used for its selection and analysis. In the current paper discrete element modeling (DEM), Metso's proprietary Fast Breakage simulations, and Schönert's packed bed piston test are combined with energy based population balance models (PBM) to yield an alternative to ore characterization and equipment selection by pilot plant testing. The resulting methodology is used to take the next step in understanding these devices with a view toward predicting plant performance. This paper describes a journey beginning with precise modeling of a small HPGR including stud geometry and system hydraulics. A key to predicting performance is the accurate modeling of individual particles, their motion in the machine, the probability of breakage and redistribution of fragments, and the inter-particle breakage events that occur between the rolls at different pressures, speeds and moisture levels. Advanced DEM simulations and particle breakage characterization methods provide the necessary technology. The resulting combined models were validated using a small diameter laboratory scale unit. The validated physics based model was used then used to predict the performance of plant scale units using a specific energy based scale-up method. Scale-up results are analyzed in terms of power draw, throughput, and discharge product size distribution.

Jan 1, 2012

By S. Banisi, J. A. Finch, A. R. Laplante

"A technique for on-line simultaneous estimation of gas and solids holdup (volume fraction), based on a combination of conductivity and pressure difference measurements, is proposed and tested in a laboratory flotation column (10cm in diameter and 447cm in height). Fundamental concepts underlying this technique and the effect of relevant parameters are discussed. In the studied range, 3-30 %v/v gas holdup and 2-18 % v/v solids holdup, experimental results showed good agreement between the estimated and actual holdup values (as determined by an isolating technique). The relative accuracy of the solids holdup estimation increased when solids density or solids concentration increased. Frequent re-calibration of pressure transducers was found necessary for accurate phase holdup estimation.IntroductionGas holdup is a key parameter in controlling the performance of flotation columns. For example, flotation rate is affected by bubble size and gas rate both of which, in turn, affect gas holdup. Moreover, gas holdup also determines the slurry residence time which indicates a direct influence of gas holdup on recovery.Gas holdup determination has been the focus of many studies (e.g., Castillejos, 1986; Marchese et al., 1992). Some of the techniques which have been used are given in Table 1."

Jan 1, 1994

By D. M. Baird

"THE Island of Newfoundland lies on the extreme eastern edge of the continent of North America and at the extreme northeastern end of the Appalachian geological province. Its belonging to the Appalachian province is shown in the geological history of the region and in the rock types and structures.Geosynclinal sedimentation in early and middle Palaeozoic times was interrupted by Taconic and, more profoundly, by Acadian, mountain building activity. Mid-Palaeo-zoic intrusions range from masses of serpentinized ultrabasic rocks to granite batholiths. A Carboniferous overlay of continental and shallow, drying sea types covers the earlier developed complex. Local basins in these times were filled with products of the erosion of tl1e earlier rocks, and, locally, grew the right kind of vegetation to make thin, discontinuons seams and pockets of coal. Post-early Pennsylvanian history is one of erosion and pene-planation with renewal of movement along many of the older fault systems."

Jan 1, 1960

By Ausenco Engineering Canada

"This paper demonstrates the selection of grinding circuit technology for a number of recent projects including discussion of the key drivers and the role of energy efficiency. Decreasing head grades combined with a strong and sustained increase in operating costs has forced miners to examine increased project size, increased equipment capacity and efficiency improvements in order to reduce their unit operating costs and improve overall project economics. Comminution energy consumption, safety and capital cost considerations play a critical role in the success of projects. This paper presents some key guidelines for a successful and cost effective comminution circuit design and includes a case study on three projects, outlining the issues and the drivers which led to the ultimate circuit selection and the critical role that energy efficiency played.INTRODUCTIONComminution circuits for minerals processing are selected based on their suitability and efficiency in reducing run-of-mine ore to the desired feed size for the downstream process. The input material (ore) properties and downstream process requirements are the key determinants and there are standard approaches for each circumstance.The minerals processing industry has been a fast adaptor of efficiency improvements based on increasing capacity of equipment (e.g. trucks, crushers, mills, pumps) but less successful in adapting radically new technologies that disrupt incumbent flowsheets or processes.The installed power of grinding mills has increased linearly over the past 25 years (Meka & Lane, 2010) and pumps and classification equipment have kept pace. The autogenous grinding (AG) and semiautogenous grinding (SAG) mills displaced stage crushing as a dominant method of coarse rock breakage in many applications causing crusher manufactures to increase the capacity of cone crushers to meet the competitive demand.Examples of new comminution technology in the 20th and 21st centuries are the development and adoption of cyclone classification in the 1940s (Newtech, 2016), AG milling in the late 1950s, vertical grinding mills in the 1980s, high pressure grinding rolls (HPGRs) also in the 1980s and ultrafine milling technology in the 1990s (Meka & Lane, 2010)."

Jan 1, 2016

By Lisa L. Van Loon, Neil R. Banerjee

Canada is a world leader in uranium exploration, but many deposits are located in remote regions making exploration targeting challenging. Novel approaches are needed to detect the presence of large-scale ore-forming systems and to vector toward mineralization. Boron is commonly used as a key pathfinder element associated with sandstone/unconformity-hosted and basement-hosted uranium deposits in the Athabasca Basin, but the genetic relationship remains uncertain. Alteration assemblages containing boron geochemical anomalies are commonly spatially-associated with – and possibly coeval with – uranium mineralization. Boron is commonly found in tourmaline minerals but in some portions of ore deposits the host mineral for the anomalous boron remains cryptic. Boron coordination chemistry within alteration haloes can better constrain boron host mineralogy, provide insight into the nature of the boron-uranium relationship, and thus has the potential to better constrain targets for exploration. Synchrotron-source X-ray absorption near-edge structure (XANES) spectroscopy is a direct, element-specific analysis that identifies boron coordinated in both trigonally- (BO3) and tetrahedrally-coordinated (BO4) forms. This makes XANES uniquely suited for identifying the geochemical hosts for boron that may be related to hydrothermal ore forming processes. XANES spectroscopy was conducted on whole-rock assay powders from uranium deposits across the Athabasca basin containing boron concentrations ranging from <10 ppm to >10,000 ppm. XANES directly identifies the relative amount of trigonally- (BO3) and tetrahedrally-coordinated (BO4) boron in these complex mineralogical mixtures. Our work suggests a link between boron and uranium that is likely related to the unique physiochemical characteristics of ore bearing fluids that may provide a unique vector to mineralization.

Jan 1, 2020

By E. Pallumbo, N. Szwedska, R. Asselin

"This paper highlights the results of collaboration between geology, mining and mineral processing teams during the restart of the North American Lithium Project, located near La Corne, Quebec, Canada. This collaboration was central in ensuring a cross discipline harmonization of design parameters and key inputs, all of which allowed for the development of an optimized life of mine plan suited to the particular needs of the operation.INTRODUCTION In July 2016, North American Lithium Inc. (NAL) began the process of restarting operations at the former Quebec Lithium Mine, located in the municipality of La Corne, Quebec, Canada. The North American Lithium Project (the Project) as it is known today, is the latest chapter in the history of this property. In order to provide a robust foundation for the project, multidisciplinary collaboration was instituted between the geology, mining and metallurgy teams. Despite the intrinsic link between these departments, in many instances their work is completed separate from one another; in silos. This collaboration highlighted specific drivers in the mining value chain that could be exploited to ensure that a saleable product could be produced effectively. This paper explores some of the concepts and strategies that were developed during the feasibility study that supported the project restart (excerpts from the study technical report have been used throughout this paper). PROJECT HISTORY In 1942, prospectors identified the presence of numerous spodumene-bearing pegmatite dykes on the Property. This led to additional interest and exploration drilling campaigns. In 1955, Quebec Lithium Corp. (QLC), who had acquired the property, began construction of an underground mine with mill facilities located on the surface. Operations began the following year at a production rate of 1,100 tonnes per day. A historical cross-section view of the underground mine is shown in Figure 1. In 1959, QLC began the construction of an on-site lithium refinery to produce lithium hydroxide. The refinery was finally operational by 1963. Mining and processing operations continued until 1966 when activities were halted due to a labour dispute. The property was sold and a few years later attempts to resume production were unsuccessful. Property ownership changed several times again until being acquired by Cambior in 1987. In the early 1990’s the existing mine and mill facilities were sold and the mine site rehabilitated"

Jan 1, 2019

By S. Kelebek

Efficient separation of minerals is the essence of mineral processing. Separation of hexagonal pyrrhotite in processing of Ni-Cu sulphide ores was investigated together with particle size effects with respect to selective flotation recovery of pentlandite and nickel. The recovery by size response was compared for sodium metabisulphite (SMBS), triethylenetetramine (TETA) and their combinations with amyl xanthate as a collector. The pyrrhotite recovery for all sizes was lower than that of pentlandite for the blank case as well as individual cases with SMBS and TETA. For pyrrhotite, the recovery by size relations in the case of individual uses of reagents were mainly determined by recovery losses at coarser size range (>74 um), which occurs at a coarser size for pentlandite (>212 um). The combined use of SMBS and TETA, and the associated synergistic effect very significantly knocked down the pyrrhotite recovery to less than 7% that was a maximum for the –10 um (attributable to hydraulic entrainment). High recovery of pentlandite in a wide range of intermediate sizes and drastically low recovery of pyrrhotite resulted in a very efficient separation of pentlandite from pyrrhotite in all sizes. Separation of this mineral is discussed in relation to fundamental functionality of the reagents used.

Jan 1, 2017

By G. A. Sutton

"At the San Manuel mine (Arizona, USA), in-situ copper leaching of a copper porphyry deposit was carried out from 1986 to 1999 during underground and open-pit mining. In 1993–1994, well¬field testing of the supergene zone, composed primarily of chrysocolla and copper-rich clay minerals, led to estimates that 52% of the acid-soluble copper (ASCu) could be recovered during in-situ leaching; however, the actual recovery from zone 6, which had the longest leach history, was approximately 42%. Comparing drillcore assay data from holes drilled before and after leaching also indicated an approximate recovery of 42%. The discrepancy between the predicted (52%) and actual (42%) recovery is probably related to several factors, including difficulty maintaining fluid saturation, channelling effects, and gypsum precipitation. ¦ KEYWORDS Copper oxides, in-situ leaching, Modelling, Porphyry, Solvent extraction and electrowinning (SXEW), Well-to-well RÉSUMÉ À la mine San Manuel (Arizona, États-Unis), on a procédé de 1986 à 1999 à la lixiviation in-situ de cuivre d’un gisement porphyre cuprifère pendant l’exploitation minière souterraine et à ciel ouvert. En 1993 et 1994, des essais effectués dans des champs de captage de la zone supergène, composée principalement de chrysocolle et de minéraux argileux cuprifères, ont abouti à des estimations selon lesquelles on peut récupérer 52 % de cuivre soluble dans l’acide (ASCu) pendant la lixiviation in-situ ; toutefois, la récupération réelle dans la zone 6, qui affiche l’histoire la plus ancienne en matière de lixiviation, était d’environ 42 %. La comparaison des données d’analyses de forage obtenues à partir de trous forés avant et après la lixiviation indiquait également une récupération approximative de 42 %. La différence entre la récupération prévue (52 %) et réelle (42 %) réside probablement dans plusieurs facteurs, notamment la difficulté à maintenir la saturation des fluides, les effets de canalisation et la précipitation du gypse. ¦ MOTS CLÉS d’un puits à l’autre, extraction par solvant et extraction électrolytique (SXEW), lixiviation in-situ, modélisation, oxydes de cuivre, porphyreINTRODUCTION in-situ copper leaching at the San Manuel mine, Arizona, USA (Figure 1), began in 1986. It was recognized that some of the copper oxide resource was not economically recoverable by conventional open-pit and heap leach methods using solvent extraction and electrowinning (SXEW) and a high stripping ratio would be required to access part of the resource. At the time, in-situ leaching was becoming popular in the uranium industry, but the approach was virtually unknown in the copper industry, especially at a large scale."

Jan 1, 2019

By A. Warczok

Chalcocite concentrate obtained by magnetic separation and flotation of Bessemer matte is processed in the Inca top blowing bottom stirring MK reactor into semi-blister copper. The semi-blister is then converted into blister copper in the multi-purpose vessels (MPV) by oxidation of iron, nickel and sulphur. High melting point NiO and Fe30 4 are formed inside the MPV s, which together with Cu20 and smaller amount of fayalite are the major constituents of the solid mush. The accumulation of solid mush and buildup requires periodic MPV cleaning by adding reductant and copper-nickel matte, a unique process called "washout". Various reductants and their combinations, such as pig-iron, 15%Si Ferro-silicon and 50%Si Ferro-silicon, have been used for the reduction of solid mush and buildup. The possibilities of using calcium carbide as a reductant and slagging flux were examined experimentally at the crucible scale. The rate of reduction of MPV buildup was determined by continuous measurement of CO and C02 contents in the offgas and the flowrate of argon carrier gas. The rate of the buildup reduction with calcium carbide was approximately five times faster than the rate of reduction with coke. Additionally, the formation of CaO results in the melting of reduced buildup and formation of a slag at 1300°C and higher temperatures. It was found that simultaneous silica addition enhanced the melting and slag formation. The results showed the strong dependence of the reduction rate on temperature. Activation energy is approximately 225 kJ/mol. Expected benefits of using calcium carbide are related to cost saving on reductant, significant acceleration of solid mush reduction, and reduced amount iron input from reductant.

Jan 1, 2007

By Frank D. Adams

The Island of Ceylon, which is one of the most beautiful possessions of the British Empire, has been an abode of man from the very earliest times. The Veddhas, a wild tribe of some 4500 people still living in the fastnesses of the jungle in east central portion of the island, are believed to represent a remnant of the oldest inhabitants of which we have any actual knowledge, but in the caves in which they live there are found the stone axes and other implements of Palaeolithic people who represent the first race of men who inhabited our globe, and of whom they may be, for all that is known, the direct descendants. About the fifth century before Christ there came the Aryan invaders, apparently from the north of India, who drove the Veddhas into the remote fastnesses of the jungle and developed the remarkable Singhalese civilization whose high character is demonstrated by the remarkable and very extensive system of irrigation works which they built up, and through which they made the island wonderfully productive. Great cities arose, some of which are believed to have had a population of over a million souls and whose temples and public buildings show that the people were accomplished architects and sculptors.

Jan 1, 1926

By K. Harris, J. B. Wahl

Ni-base superalloy cast materials provide an outstanding balance of high temperature strength, fatigue resistance, oxidation resistance and coating performance and can be produced to very tight tolerances in extremely complex configurations, such as axial and centrifugal integral cast turbine wheels. As a result, cast superalloys are used in the most demanding applications of aero and industrial gas turbine engines. Use of these materials is expanding to smaller microturbine, turbojet, turbocharger and missile engine applications due to this unique combination of desirable properties. This paper will present an overview of the application of investment cast Ni-base superalloys and process capability to small turbine and missile engines.

Jan 1, 2010

By A. G. Eccles

Western Mines&apos; milling circuit produces three concentrates (copper, lead and zinc), with the tailings being disposed of at the bottom of Buttle Lake. In view of the mine&apos;s location and the method of tailing disposal, a comprehensive pollution control program has been in effect since start-up. Changes -in the ore over the past few years have required the use of increasing quantities of sodium cyanide in order to effect a good copper-lead separation. This led to the use of alkaline chlorination for destruction of ?residual cyanide and precipitation of dissolved copper contained in the tailing effluent. The development of Western Mines&apos; alkaline chlorination plant is discussed in detail, including initial test work and the evolution of procedures leading to the present operation. The current monitoring program is also reviewed.

Jan 1, 1977

By C. S. Chen, Y. J. Luo, M. W. Gao, B. Li, Z. F. Zhang

"To obtain large-sized billets with fine grains and homogeneous elements distribution, uniform direct chill (UDC) casting process, based on annular electromagnetic stirring coupling with intercooling, was employed to produce 7055 alloy billets with a size of F584 mm in this study. The results indicated that there were the coupled effects of annular electromagnetic stirring and intercooling on grain refinement and element homogenization, and also the billets produced by the UDC casting process showed excellent hot workability in comparison to the normal direct chill casting process.INTRODUCTION The high solute 7055 aluminium alloy has a wonderful combination of high specific strength and hardness, good resistance to stress corrosion cracking and high fracture toughness, which is very useful in aerospace application (Yan et al., 2013; Mondal & Mukhopadhyay, 2005). The production of large-sized 7055 alloy billets with high quality is the basic condition for the subsequent application of 7055 alloy to the aircraft. Inhomogeneous microstructures and performances of 7055 billets result from the high alloying element content and the inhomogeneous cooling condition in different regions of billets during the conventional direct chill casting (Paramatmuni et al., 2004; Lalpoor et al., 2011), which will bring bad influence to processing property, functional performance and utilization rate of materials. To alleviate segregation and obtain fine and uniform grains, some effective treatment methods were proposed including electromagnetic stirring (EMS) (Vives, 1989), ultrasonic vibrating (Zhang et al., 2011) and melt conditioning (Fan et al., 2013), on the melt to obtain fine and uniform grains. However, these methods could not effectively decrease the large temperature difference between central and periphery parts of the billet, because the solidification mainly depends on outside cooling including mould cooling and water spraying cooling. To change the heat extraction pattern of the billet functioned solely from the outer surface, based on annular electromagnetic stirring (A-EMS) invented by Xu et al. (2010), Luo et al. (2017) proposed uniform direct chill (UDC) casting coupling A-EMS with intercooling in the direct chill (DC) casting process. An in-mold cooler was inserted to the melt sump, and thus the alloy melt temperature and concentration at solidification front become more uniform."

Jan 1, 2018

By C. A. Sosa-Blanco

Minera Sabinas in central Mexico treats a complex sulfide ore containing galena, chalcopyrite, sphalerite and argentite as valuable minerals, and in some cases important amounts of non-magnetic pyrrhotite. For high pyrrhotite ores, results obtained by selective flotation showed good grades and recoveries in the lead-copper circuit, but a commercial zinc concentrate could not be produced due to the high floatability of pyrrhotite. When this is the case, an alternative method was proposed to produce a bulk concentrate by flotation which is then leached to recover copper and zinc from liquor in a SX-EW circuit. Leaching was conducted in an autoclave in order to study the effect of temperature and pressure, but bioleaching tests were also conducted. Leaching lead-silver residues were treated by cyanidation in order to recover silver values. The results obtained by selective flotation and by bulk flotation with leaching of the bulk concentrate showed that the latter alternative increased zinc recovery by 30 % with similar recoveries of the other metals.

Jan 1, 2007

By M. E. Holter

"Five main lignite seams occur in the Tertiary Ravenscrag Formation in the Eastevan area, at depths of 100 feet or less. They are named, in ascending order: the Boundary, Estevan, Souris, Roche Percee and Short Creek seams. A total sequence of approximately 250 feet is represented by the coal beds and interstratified clays, silts and sands. Strata dip to the southeast at 25 feet per mile or less and trike northeast. Large areas underlain by coal seams at shallow depths are delineated. Reserve calculations are dependent on detailed information on seam thicknesses and feasible stripmining depths. The stratigraphically higher seams are thinner on the average than lower seams and this, together with the increase in elastic size fractions in higher strata, suggests a retreat of a Tertiary marine margin to the south during the closing depositional history of coal seams and associated strata."

Jan 1, 1972

By François Charette

High stress conditions in weak rock masses lead to large deformation and breakdown of the rock material, while stress release events in hard rock mines can lead to sudden and usually violent rock failure. Typical support systems combine various reinforcement and support mechanisms to provide the required convergence control and retainment, but results are often mitigated by failure of surface liners, shotcrete and tendons. The paper reviews differing requirements of support and reinforcement for different failure types. In addition, the mechanical performance of a new reinforcing tendon is presented and analysed in view of the field requirements. Field tests results are presented.

May 1, 2011

By M. B. Mansur, A. S. Guimarães, A. J. M. Santanilla, D. C. R. Espinosa, J. A. S. Tenório, R. A. Pini

The separation of Ni and Co from sulphate medium containing Mn, Mg, Cu and Ca was carried out by solvent extraction. The object of this study was to investigate the synergistic effect using phosphinic acid (Cyanex 272) and carboxylic acid (Versatic 10) and their mixtures in kerosene. The extraction percent of each metal ion was found to increase with increasing pH and extractant concentration. Co was preferentially extracted over Ni under the same extraction conditions. The separation factors of Ni/Co increased with the use of the synergistic systems investigated.

Jan 1, 2014