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By V. Nudo, R. del Villar, A. R. Laplante

"Fine iron ore recovery from the tails of Les Mines Quebec Cartier was investigated using Reichert trays and spirals. The effect of feed rate, density and splitter setting on the performance of rougher, cleaner and recleaner stages of a 2DS tray assembly was determined using 2- and 3- factorial experimental designs. The tray concentrate, assaying 27% Fe, was further upgraded by spiral to yield a concentrate assaying 55% Fe. Further laboratory scale testing showed this material to be easily upgraded to 65-66% Fe with high Fe recoveries.This paper presents the metallurgical results of the three tray stages. The model used to predict the performance of a full recovery circuit is then described. Simulation results are presented and their reliability assessed. Finally, an economic evaluation of the proposed scavenging circuit is summarized.INTRODUCTIONThe Mount Wright plant (UWP), located near Fermont, Quebec, processes daily 130,000-150,000 tonnes of iron ore assaying between 27 and 33% Fe, to upgrade it with three stages of 44.5 cm pitch GEC spirals to 66% Fe, while rejecting approximately 80,000 tonnes assaying between 6 and 11% Fe (1-3). Heavy liquid separation (at 3. 3 g/mL) of the plus 37 µm fraction (+400 mesh) of the tails reveals that a significant fraction of the iron is in the sink product, below 150 pm (100 mesh), as shown in Table 1. Also shown is the iron grade of the sink and float fractions. The high grade of the fine sink indicates that hematite ls well liberated below 105 µm (150 mesh), as previous studies have shown (4,5). The iron grade of the floats is very low in the fine size range, but increases with increasing size above 105 pm, because of incomplete liberation. Overall, two thirds of the plus 37 µm iron ls in the sink product, which constitutes less than 10% of the total tail."

Jan 1, 1987

By Egon Berger

"In recent years the trend in underground metal mining has been toward ever increasing blasts (often in excess of 100 000 tonnes per blast). The Canadian mining industry has been in the forefront of these developments (VRM, LBHand cable bolting to stabilize the surrounding rock /avoid dilution).In order to move these large tonnages, efficient loading systems have to be developed. This paper shows the technical and economic implications of various loading scenarios based on a predefined (however typical) stoping layout by:1 . discontinuous loading using scoop trams;2. discontinuous loading using scoop trams in combination with low profile dump trucks;3. continuous loading (based on loading performance/operating costs of the AL-60) in combination with low profile dumptrucks.The cost advantages of production concentration (loading large tonnages from one drawpoint}, made possible by continuous loading as opposed to sea tiered mining (small tonnages), using discontinuous loading in tunnelling will be presented, based on actual results obtained in a decline development project using the A L-60 continuous loader. At as pacing oj150m between turning bays, it was found that continuous loading was out performing discontinuous loading in approximately80% of the overall decline development.Fuel consumption and total cycle times are compared, and a cost assessment is presented.INTRODUCTIONThe subject of this paper deals with the introduction of continuous loading in underground metal mining and single heading tunnelingContinous mining has been widely introduced both in underground and surface coal mining. Mechanized longwall mining, utilizing moveable shield supports in combination with double drum- shearers, has resulted in a tremendous increase of coal production per working face.This has led to very concentrated mining operations. In a typical German coal mine two mechanized longwalls nowadays would produce the same amount of coal as 12 to 15 longwalls in the 1950s. One longwall in a South African coal mine has recently set a world record with 120 000 tonnes of coal in a single month.In underground metal mines-often due to the irregular nature of the ore body and the mining methods used-mining is far less concent rated. Ore is often produced from a large number of stopes and production sections. Sometimes, a substantial amount of ore may be obtained from development in the orebody (40070 at a German base metal mine)."

Jan 1, 1989

By Chr. Krause

Within the scope the collaborative research centre 599 (Medical University of Hanover, University of Veterinary Medicine Hanover, University of Hanover) the behaviour of the degradation of magnesium materials as implants are investigated by using animal experiments (rabbits). Thus extruded cylindrical pins from the magnesium alloys MgCa0.8%, WE43 and LAE 442 were implanted intramedullary in the tibiadiaphyses. The implantation duration was 3 and 6 month. After the explantation 3 point bending tests were carried out to investigate the possible changes of the mechanical properties. Clearly changes in dependence of the implantation duration could be determined. The three magnesium alloys show a decrease of the mechanical resistance with an increasing implantation time. To evaluate the degradation process, wich is the reason for the changes, micrographs and element analyses (EDX) have been accomplished after the 3 point bending tests. The micrographs show for all used magnesium alloys corroded surfaces but no preferred corrosion on the grain boundarys. The element analyses show beside a layer which is rich in calcium and phosphorus an agglomeration of rare earth elements in this layer. With these results a using of magnesium alloys as a material for implants can be announced.

Jan 1, 2006

By A. Bouajila

To stay competitive in an open market, mineral industries have to optimise their processes, lower their production costs and improve the commercial value of their products. Up to a recent past, they were impaired in this attempt by a lack of adequate devices allowing reliable on-line and real-time process monitoring (detection or measurement). Process monitoring for process control and the product characterisation for quality control are quite different tasks. Planners and researchers should be fully aware of this when evaluating or developing monitoring equipment for on-line process control. This paper will comment on some aspects of sensor specifications, during the design and the evaluation steps, related to sampling, measurement (accuracy, sensitivity, delay and correlation to the process) and suitability to the exploitation environment. Examples of R&D projects promoted by COREM for various industrial applications will be presented.

May 1, 2001

By Harry Wilton-Clark

Introduction Coal cleaning may be taken as meaning the separation of coal-as-mined into two or more fractions. Coal cleaning includes coal washing, together with any other means used in the ultimate preparation of coal prior to shipment (as coal) . The method of coal cleaning devised for any given mine must be one which is based entirely on the economic results obtainable. The installation of a high-cost and complex washing plant, designed to produce a low-ash dean coal, at the highest possible recovery, may be unsound practice. A crude 'roughing' washer may be the best result of sound engineering and operating consideration, and in some cases coal cleaning should be confined entirely to preparation at the face. Consideration of complete costs, to the point where the coal is actually sold, may show that certain seams are workable or not workable. Of the seams found workable, extraction of the whole or parts of the seam may be decided on. The portion to be extracted may contain rock or bone partings, which must be removed. It may be good practice to mine the extra portion and remove the objectionable materials by surface washing; or it may be that such materials should be removed underground, even at an increased mining cost. For instance, in some of the steeply pitching seams of the Alberta Crow's Nest Pass district, the removal of bone and rock at the face may be almost impossible under the usual 'up the pitch' or 'angle' mining methods, but possible by mining across the pitch so that the material to be rejected can be removed and gobbed. Again, if a complete seam is being extracted, investigation may show marked differences between top coal and bench coal, and if sufficient mine cars are being loaded from a chute at one time, the fact that such a place is working top or bench coal at the time may be reflected by peaks in ash content or size proportions at the ripple. It may be very effective coal preparation to smooth out such peaks.

Jan 1, 1934

By James H. C. Martens

Among the many interesting problems of the pre-Cambrian of the Canadian Shield is that of the origin of certain types of gneisses which are intimately associated with the granites on the one hand and with the metamorphic rocks of known sedimentary origin on the other. The observations recorded in this paper on the structure and composition of these ancient rocks found in a small part of northern Quebec may help to lead to a clearer understanding of the way in which they were formed and also constitute a contribution to the regional geology and petrography of a district for which little detailed information is available. The area considered is located near the Ashuapmuchuan, or Chamuchuan, river about 180 miles north-northwest of the city of Quebec, and therefore well within the Canadian Shield. Although most attention was devoted to the rocks along this river from the 57th to the 70th mile above its entrance into Lake St. John, a few observations on other localities to the north and northwest of that lake will be included. The field work was done in the summer of 1924 in cooperation with L. W. MacNaughton, E. S. Roberts, and B. M. Shaub, all of Cornell University. The party ascended the Ashuapmuchuan river by canoe and spent about a month near the mouth of Stacker, or Brochet, river, the outlet of the lake of the same name, returning by way of Mikoasas river. The writer wishes to express his obligation to his associates for their co-operation in the field and for their permission to publish the results. He is especially indebted to B. M. Shaub for the photographs of rock outcrops. Professor A. C. Gill g:ive many suggestions which were helpful in the laboratory study of specimens and in the preparation of this paper.

Jan 1, 1927

By G. W. Brooks

This short article is quite different to the general run of papers that are presented to the Institute, but no apology is offered because I consider that first-aid and mine-rescue work are of equal importance to many other subjects that are dealt with in our Transactions. Members of the Institute should be as much interested in the safety of persons engaged in the mining industry as they are in the practical methods of modern mining. We must not only do our best to conserve life and property by adopting every known device to that end, but we must also prepare ourselves so that we may take prompt and effective action when life is in danger, or when property is subject to loss. The need for such preparation in Alberta is perhaps greater than in most places where mining is carried on, and we must spare no effort to assemble at every mine men who are well trained in first-aid and mine-rescue work. The large area over which the mines are distributed renders central training stations out of the question, hence the need for local rescue-teams. Hospitals with skilled staffs, close enough to the mines to be convenient, also seem to be out of the question; therefore the greater need of a high standard of first-aid training for the people in our mining camps. The Government mine-rescue cars are supplied with the equipment necessary for training persons in this essential work and also for dealing with disasters should they occur. The question then arises: are there a sufficient number of men who are trained ? If so we can rest assured that what is possible to be done will be done. But if a sufficient number of trained men are not available much loss of life and damage to property is likely to result.

Jan 1, 1925

By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25' C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By Daniel B. Leznoff

The cyanoaurate anions [Au(CN)2]- and [Au(CN)4]- are shown to be useful building blocks for synthesizing supramolecular coordination polymers. For the gold(I) unit, aurophilic interactions often increase the structural dimensionality of the system and can impart increased thermal stability to the metal-polymers produced. A series of polymers of the form M[Au(CN)2]2(Ligand)x have also been prepared and show large colour changes upon changing the ligand, thus illustrating a sensor-type application. Both building blocks can mediate significant antiferromagnetic and ferromagnetic interactions between transition-metal centres in the polymers. For the gold(III) unit, no metal-metal interactions are observed, although weak Au-N(cyano) interactions control the intermolecular packing. Several structural examples of cyanoaurate-based coordination polymers are presented, including 2-D and 3-D arrays and a supramolecular square.

Oct 1, 2003

By Fred W. Snow

THE mines of the Consolidated Copper and Sulphur Company, consisting of the Eust1s, the Albert, and the Capel mines, are situated w Ascot township, Quebec, about ten miles southeast of Sherbrooke, on the main line of the Quebec Central railway. Of these mines, only the Eustis is now producing, and it has been operated almost continuously for the past seventy years. Mining methods have been improved in recent years but are still old fashioned when compared with those employed in more modern and up-to-date mines. The ore is of milling grade and is mined for its copper and sulphur con-tent. Silver is present in small quantity, together with a trace of gold. The ore is mined by the shrinkage stope method. Pillars are frequently left as supports for the hanging-wall to prevent serious dilution of the ore and are sometimes recovered after the ore is drawn from the stope. Occasionally, small blacks of ore in close proximity to the shaft are mined by a cut-and-fill method. HISTORY ALBERT AND CAPEL MINES: The Albert and the Capel mines, originally known as the Capelton mine, were discovered in 1863 by George Capel (1). By the end of 1866 the Albert shaft had been sunk to a depth of 121 feet on an incline of about 30 degrees where a vein five feet thick was encountered. In 1879, these mines passed into the hands of G. H. Nichols and Company, by whom they were operated practically continuously until 1907. When mining operations ceased in that year, the shafts had reached depths on the incline of approximately 2,300 feet and 1,000 feet, respectively. These mines have been allowed to cave and fill with water and have been inaccessible for many years.

Jan 1, 1936

By K. D. Peaslee

Slag splashing is an important development that has dramatically improved BOF vessel campaign life and reduced operating costs. This paper highlights research from physical modeling work using a 1/8-scale room temperature model BOF and slag characterization studies from several plants in North America and China. In the model studies, gas flow rate during blow and viscosity of the liquid were found to be two of the most important factors to changing the overall rate of liquid splashed onto the vessel sidewalls. When the flow rate was increased or viscosity decreased, the lower regions of the walls were splashed at a much greater rate. It was also shown that by changing the lance height, more liquid was deposited in the upper regions of the vessel at the expense of lower regions. Reducing the number of nozzles was found to be the most effective method of selectively coating a particular vertical section of the wall. Studies of BOF's using slag splashing in North America and China showed a difference in the melting characteristics of the final slag. Generally, slag splashing is successful when the melting point of the slag is 220-270°C below the tap temperature to maintain a balance between fluidity and refractoriness.

Jan 1, 2004

By S. Afshar, C. Allaire

Several studied have recently shown that the use of non-wetting additives is not always a sufficient solution to improve the corrosion resistance of refractories against molten aluminum. Once in contact with liquid aluminum, the coarse aluminosilicate aggregates, which do not benefit from the protective effect of non-wetting additives in the matrix, may be corroded. In some cases, the corrosion of aggregates, especially those containing a significant amount of free silica and/or alkalis, promotes corrosion in the surrounding matrix. The present work explores the possibility to protect the poor corrosion resistant aggregates via a lining procedure. A slip casting method, using either alumina or celsian-like composition based slurries, has been applied for lining of a series of aggregates. The results from this study show that such linings may prevent efficiently the corrosion of aluminosilicate aggregates. This work also analyzes the effects of firing temperature and lining quality on the corrosion behavior of aggregates

Jan 1, 2004

By M. D. Everell

Le Centre de Recherches minérales (CRM), qui est un organisme de recherche appliquée du ministère de l'Energie et des Ressources du Québec, a été créé en 1969, dans le but de procurer un support scientifique et technique à l'industrie dans le domaine des mines et de la métallurgie. Pour atteindre ses objectifs, le CRM met à la disposition de l'industrie un personnel spécialisé et compétent dont une quarantaine d'ingénieurs et de scientifiques. Etant donné la nature même de l'industrie minérale, ce personnel est très versé dans l'étude des problèmes diversifiés des domaines de la technologie minière, du traitement des minerais, de la métallurgie extractive et de l'analyse minérale. Ce Centre de recherches met également à la disposition de l'industrie une usine-pilote permettant de reproduire les résultats du laboratoire au moyen d'un appareillage de type industriel, d'obtenir des échantillons en quantité suffisante pour une exploration du marché et de familiariser du personnel avec les opérations normales de l'industrie. Certaines de ses contributions récentes au développement de l'industrie minérale du Québec seront présentées.

Jan 1, 1985

By E. A. Hart, J. E. Gill

"The property of Arntfield Mining Corporation, formerly Arntfield Gold Mines, Limited, covers an area of 2,110 acres and lies in Beauchastel township, western Quebec. The Francoeur mine lies to the west, and to the east are the West Wasa and Wasa Lake properties.The property was staked in September, 1923, by the late F. S. Arntfield. The early surface work was concentrated in the west part of the property along the Francoeur-Arntfield shear zone. The zone was opened by No. 1 shaft, which was sunk for an inclined depth of 250 feet. A series of silicified lenses were discovered farther east, where No. 2 shaft was later raised to the surface. A third shaft explored a shear zone about 1,900 feet to the east, where No. 3 shaft orebodies were developed.The mill was built at No. 3 shaft and production commenced in July, 1935, at 125 tons a day. This was increased to 280 tons by 1938, and later to 350 tons. The mine continued operations on this scale until April, 1942, when the exigencies of war necessitated closing. The Company was reorganized in 1944 and underground development was resumed in June, 1945. The total value of gold and silver produced to April, 1942, was $2,011, 755 from 529,987 tons of ore.ROCK TYPESThe area is underlain by highly deformed and altered Keewatin volcanics overlain by little deformed Cobalt sediments along the south boundary. The lavas in the vicinity of the mine workings are rhyolite, trachyte, andesite, and a flow breccia of intermediate composition. The fragmentals range from fine, well-bedded tuffs to coarse agglomerate in which acidic and basic horizons can be distinguished.The intrusive rocks are diorite and quartz-feldspar porphyry in the form of stock and sills, and narrow dykes of mica lamprophyre and syenite porphyry."

Jan 1, 1954

By S. Banisi, M. Pourkani, A. R. Laplante, A. Partoazar

"Canadian experience in industrial modeling of grinding, classification, and flotation kinetics was applied at the Sarcheshmeh copper mine, which processes 40,000 t/d of ore at 0.9 % Cu, in an effort to improve capacity and metallurgical performance. Mcivor's functional performance analysis was applied to ball mill cyclone circuits to maximize circuit capacity. Plitt's cyclone model was applied to predict how apex wear would affect classification performance, as part of a predictive maintenance program whereby the optimum wear period is determined for cast iron apexes. The flotation flowsheet was improved using Agar's optimization criteria. The impact of these technologies has been nothing short of spectacular, with an improved capacity of 1 S to 20""/o, and increased recoveries.1-IntroductionThe Sarcheshmeh copper ore body, which may rank as third or fourth largest in the world, contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and has been processing 40,000 t/d of ore since 1982. The mine produces 100,000 tonnes of copper and 2,200 tonnes of molybdenum concentrate per year. After three stages of crushing, the ore with a Fso of 12. 7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70""/o finer than 7 S microns. The concentrate of the first stage of flotation is reground and the tailings constitute the main component of the plant final tailings. A concentrate with an average grade of 31 % Cu is obtained after cleaning and re-cleaning stages. Total recovery of the plant varies between 83 and 87 % depending on the operating conditions and ore type.To improve the overall performance of the plant, it was first decided to evaluate the performance of grinding, classification and flotation. Measures were then taken to improve performance using the following criteria: (i) The improvements should be of the types that have resulted in significant improvements in other plants (e.g. Shannon et al, 1993); and (ii) The proposed improvements must be achievable with the manual operation presently used at Sarcheshmeh. The outcome of this study could also help in making decisions on the implementation of automatic control systems in the Sarcheshmeh copper mine."

Jan 1, 1998

By Thom Sedun

No sector of the mining industry is more closely tied to local communities than aggregates. Noise, dust, traffic, visuals aesthetics and environmental impacts all fall under the purview of neighbours, local governments and nongovernment organizations. It is no surprise that aggregate operations may not be welcome neighbors in many communities. In British Columbia (BC), the regulatory environment for aggregate operations includes a local component of municipal bylaws and land use-planning in addition to the usual suite of federal and provincial statutes that apply to its sister mining sectors. Additionally, under common law aggregate extraction is not considered to be a land use subject to land use zoning, and some aggregate processing activities can be regulated by zoning. Often traversing multiple local government jurisdictions, aggregate producers find themselves negotiating not only local traffic, but also a mosaic of regulatory environments. There is an opportunity in this present situation to facilitate the application of current technology and practices in the mitigation of many community and environmental concerns associated with aggregate operations. Moving a bulk commodity is a volume-based business, and operators often don?t have time for matters that don?t directly or obviously affect the bottom line. Regulatory agencies often play multiple and complex roles with respect to their industry, not the least of which is the fiduciary role. Balancing how and when to assist an industry is often a difficult decision. For the aggregate industry in BC, the Ministry of Energy and Mines saw an opportunity to assist not only aggregate operators, but also regulatory agencies, local governments, and the general public. Through investing in the Aggregate Operators Best Management Practices Handbook (handbook) project, the Ministry of Energy and Mines (MEM) believes that it will realize a return of upheld community values, enhanced environmental protection, improved regulatory compliance, reduce disputes and a stronger provincial aggregate industry. It is the intent to publish the handbook electronically through the MEM website later this year.

May 1, 2002

By M. Romana

"RMR geomechanics classification is being used all over the World as a useful tool for tunnel predesign and construction. Bieniawski (1989) provided guidelines for tunnel excavation and support, according RMR numerical values; guidelines which are now included in almost all tunnelling books, regulations, and Internet portals. But in the last 25 years tunnelling techniques have changed and some of the guidelines have become obsolete.. The conditions of tunnels for the 1989 guidelines application were: horseshoe shape; 10 m width; vertical stress < 25MPa; construction by drilling and blasting. Actually a substantial number of tunnels are mechanically excavated. The tunnel themselves are now bigger: a span of 14 m. is very common for transportation tunnels. The guidelines included the following concepts: excavation method, rock bolts (20 mm diameter, fully grouted), shotcrete, steel sets. There is an increasing gap between the 1989 guidelines and the practice: in many tunnels different to-the-case excavation and support requirements are established. Bieniawski himself has published a paper (Lowson & Bieniawski, 2013) with different guidelines based in Lowson’s practice, with no explanations and/or justification.In this paper a new set of RMR tunnelling guidelines is proposed taking account of the actual industry conditions, and increased safety regulations. The 5 classes’ limit RMR:values (80,60,40,20) are no more useful actually: Values of RMR (70, 50, 30) are used in practice to define quite different tunnelling techniques. Consequently a 10 subclasses system is proposed. Each subclass covers a span of 10 RMR points. As the number of mechanically excavated tunnels has increased a new correction factor is necessary, according the excavation method.The proposed 2014 RMR guidelines are for tunnels 10 to 14 meters wide, the world practice for new roads/railways tunnels. Many tunnels for water/ services are smaller with smaller support needs. Wider than 16 m caverns are out of the RMR system.It is not possible, nor desirable, to propose only a value for support in each subclass. The new guidelines propose an interval of values for certain types of support. More pessimistic values must be chosen for wider tunnels, tunnels with lower RMR values in each class and cases when a higher safety factor is asked for. More optimist ones are chosen for narrower tunnels, and higher RMR values. Some alternatives are almost complementary, others are contradictory. Sometimes several different techniques are proposed Guidelines are not automatic options. Good engineering judgment must be used when choosing between the different alternatives. Guidelines are not mandatory suggestions."

Jan 1, 2015

By D. Song

In this paper, the differential equations governing the mass transport and the electrochemical reaction in a cathode catalyst layer of polymer electrolyte membrane fuel cells are solved based on the polynomial series expansion method. Explicit expressions for the polarization curve as well as for the distributions of oxygen, current density and overpotential are obtained when a quadratic, cubic or quartic polynomial is employed to approximate the oxygen concentration distribution. These kinds of explicit solutions are desirable for MEA design and diagnosis purposes. The comparison between the conventional numerical approach and the explicit solution approach proposed here shows that satisfactory accuracy can be reached by the first four terms of the polynomial series. The effect of the catalyst layer thickness on the accuracy of the obtained explicit polynomial solutions is also discussed.

Jan 1, 2005

By S. C. Ellis

THE bituminous sand of northern Alberta has already an extensive literature, and most of the reports dealing with the subject are still available (see Selected Bibliography at end of paper). A phenomenon so striking and, as regards its extent, so unique, as the deposit in the vicinity of McMurray settlement could not fail to attract the notice of the early explorers, and we find references to it as far back as the latter part of the eighteenth century. However, scarcely a thought had been bestowed upon the possible economic value of minerals in the the remote northern parts of Canada before the second decade of the present century, and practically no detailed mapping had been done north of the town of Athabaska. The late Wm. Ogilvie made a track survey of Athabaska river in 1884, and surveys of certain lines-including the 23rd base line-had been completed by 1911. Between this base line and lake Athabaska, nothing had been attempted. Actually, no definite information at all was available regarding the character and extent of the bituminous sand when, in the earl y summer of 1913, a reconnaissance party set out from Athabaska for McMurray. At that period, the journey was made in summer by scow or canoe. No telegraph line had been laid, and a casual mail service by canoe or dog team once in three months formed the only means of communication with the outside world. The investigation has begun by the Mines Branch was continued during several subsequent years. The sand deposits were studied and sampled, the bi rumen was extracted from the sand and studied chemically and physically, and the economic significance of the deposit was given exhaustive study.

Jan 1, 1937

By I Wilkomirsky

The neutralization of S02 from copper smelter gases to produce calcium sulphate (anhydrite) is considered an attractive alternative to sulphuric acid production. To develop the required technology for the process, a three-stages fluidized bed reactor prototype was designed and operated using both high and low grade limestone and gases with 2, 8 and 12 vol -% S02. The results obtained shows that at 800°C and up to 8 vol-% S02 in the gases, the capture of S02 reaches near 99% with limestone conversion to anhydrite of 45 to 48%. A larger pilot plant is presently being built at the Codelco El Teniente-Caletones Smelter to demostrate the technology and to evaluate the economics of the process. Cu2007

Jan 1, 2007