Search Documents

By Ahmad Ghahreman, Lin Li

"In this study, the Fe(II)/Fe(III) redox reaction kinetics on the surface of pyrite, have been investigated in a 0.5 mol L-1 sulfuric acid solution for a temperature range of 22 to 65°C. Based on mixed potential theory, chronoamperometry is introduced to study the Fe(II)/Fe(III) kinetics by subtracting the current density of pyrite oxidation in an iron-free acidic solution from that in an iron-containing solution at the same applied polarized potential. Tafel behavior was established by this method to analyze the kinetics of the Fe(II)/Fe(III) redox reactions. The results showed that exchange current densities increased slightly with temperature, however remained on the order of 10-5 A cm-2. The activation energy for Fe(II) oxidation and Fe(III) reduction on the pyrite surfaces was calculated to be 102.0 and 32.7 kJ mol-1, respectively. Anodic transfer coefficients also increased, from 0.24 to 0.39, with increasing temperature, which indicates a weakened n-type semiconductor property at higher temperatures. Electrochemical impedance spectroscopy measurements have indicated that at lower anodic over potentials the charge transfer is the rate determining step of pyrite oxidative dissolution in sulfuric acid solution. In the presence of Fe ions, the major contribution of the total current density comes from the Fe(II)/Fe(III) redox reaction. INTRODUCTION Pyrite, an abundant sulfides mineral in the nature, is commonly considered a valueless gangue mineral frequently associated with other valuable sulfide minerals such as chalcopyrite, or metals such as gold, or coal (Lin & Say, 1999). Pyrite oxidation has been the subject of extensive research in view of gold metallurgy, as oxidation of pyrite is the initial step to break down the pyrite lattice and expose the encapsulated fine gold particles (Gasparrini, 1983). Fe(III) ion and dissolved oxygen (DO) have generally been considered as the two most important oxidants with respect to pyrite oxidation, having been studied extensively in previous research (Zheng, Allen, & Bautista, 1986; King Jr & Lewis, 1980). The process of pyrite oxidation can be viewed as a series of reactions amongst pyrite, ferrous, ferric and oxygen in which pyrite is initially oxidized by the dissolved oxygen in water forming ferrous (Eq. 1), and then the ferrous also is oxidized by he dissolved oxygen to form ferric (Eq. 2). The ferric, produced by reaction 2, then could potentially oxidize pyrite (Eq. 3) and convert to ferrous."

Jan 1, 2017

By Forrest A. Kerr

Introduction During recent years the work of the Geological Survey in northwestern British Columbia has been in the nature of reconnaissance and exploratory mapping, largely for the purpose of gaining knowledge of the potential mineral-producing zones known to occur along the eastern side of the Coast range, and also to gather such data as might facilitate their exploitation. Commencing with fairly detailed mapping in the more accessible parts, the work has been continued and expanded until now an understanding has been gained of the more general features of a continuous section along the range for a distance of about two hundred miles. Geographically, northern British Columbia is more or less isolated. It is cut off from the central part of the Province by a rugged and mountainous country which, except for the telegraph line and a rarely travelled trail along it, is not penetrated by any developed routes or lines of communication. To the west, it is cut off from the Pacific by the Coast range, an extremely rugged area sixty to eighty miles in width which, except along the few navigable rivers cutting across it, cannot be readily traversed. Politically, it is further isolated in this direction by the narrow strip of south-eastern Alaska which borders the coast and extends inland to the axis of the range.

Jan 1, 1931

By R. P. Kofluk

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Significant economic implications are associated with the refining of precipitated sulphides containing elevated iron contents. The Moa Nickel S.A. operations encompass laterite mining, high pressure acid leaching (H PAL), and ultimately, precipitation of a mixed sulphide product. These processes are reviewed as they pertain to the control of iron and the formation of a mixed sulphide containing nominally 55% Ni, 5% Co and 1% Fe. The contributors to the iron content of the mixed sulphide product are reviewed; the major contributors are the HPAL operation and sulphide precipitation. The precipitation of iron during sulphide precipitation is influenced by the solution acidity, the iron and copper concentrations in the feed solution, and the presence of laterite leach solids. The significance of the copper concentration of the sulphide precipitation solutions is manifested by both physical and chemical modifications of the sulphide precipitates, presumably through the formation of fine copper sulfide seed particles.

Jan 1, 2006

By Mehmet F. Taner

"Abstract - "Les Mines Selbaie" is a large, generally low-grade, polymetallic (Zn, Cu, Ag, Au) "giant" volcanic-associated ore deposit in the Harricana-Turgeon belt, which is part of the northern Abitibi Subprovince of Quebec. Economically recoverable mineralization occurred in three zones: the A1 (open pit), A2, and B Zones (underground). The pre-mining resource was 54.9 Mt, including 8 Mt of sub-economic, locally silver-rich massive pyrite. In the Selbaie region, calc-alkaline andesitic volcanics form the "basement." The Brouillan Volcanic Complex formed within an islandarc setting on this regional basement. Evolution of this complex involved the formation of a felsic magma chamber and the development of a large caldera structure over the Brouillan batholith. Second- order linear and sub-parallel faults and rifts developed as a result of back-arc rifting/extension. The edges of these rifts were feeders for linear felsic volcanism (similar to fissural volcanism). During felsic volcanism, the feeder zones acted as conduits for hydrothermal fluids with associated pervasive potassic alteration. The alteration is characterized both vertically and laterally by well-defined quartz, sericite, K-feldspar and/or, locally, biotite halos, to produce a mushroom-shaped morphology. This K-feldspar alteration is not common in most other volcanic-associated ore deposits. Mafic dikes cut all of the geological units and appear to occupy earlier synvolcanic structures. Regional greenschist- assemblage metamorphism and pervasive deformation affect all units. Thrust faults moved part of the Brouillan batholith and basement units over the Mine Sequence. Although there is no relationship between the earlier mineralizing events and these late thrust faults, the thrust faults probably played an important role in location of ore lenses. Three types of mineralization are present: 1) copper-rich veins and hydraulic breccias; 2) disseminated and stringer, low-grade and high volume zinc-copper mineralization; and 3) finely laminated, massive, locally silver-rich pyrite mineralization within structural basins. At the bottom of these basins and at the contact of welded acid tuff (WAT) units, massive pyrite zones are locally enriched in zinc, and contain the possible vestiges of black smoker-like material. The ore metals were probably derived from leached basement andesitic volcanics in a hydrothermal system powered by one or more heat sources within the Brouillan Volcanic Complex. The Selbaie deposits are mainly characterized by: (1) the presence of small volcano-tectonic subsidence basins, which host chemical sediments and volcaniclastic materials; (2) pervasive potassic alteration; (3) locally high-grade silver mineralization (up to 1-2 kg/t Ag); and (4) the presence of random zones of Pb mineralization. The Selbaie deposits can be closely compared with the copper-rich Murgul deposits, which belong to the eastern Pontides metallogenetic province in Turkey. If conventional classification criteria for the volcanogenic massive sulfide deposits (e.g., Noranda, Mattabi types, and recent subsea floor deposits) are taken into account, the Selbaie deposits still exhibit many differences in terms of alteration assemblages, physical volcanology and some styles of mineralization (low-grade and large volume). Consequently, the "Selbaie" deposits belong to a new sub-type of volcanic-associated sulfide deposit, which may be used in future exploration programs."

Jan 1, 2000

By D. E. Barnett

"Paramount to sound aggregate resource management is an awareness of what resources exist. For the past six years, New Brunswick has been conducting granular aggregate resource inventories in and around urban centres as a means of documenting, both qualitatively and quantitatively, these resources.These aggregate studies require extensive ground truthing due to the often small nature of the surficial feature s as well as extensive foliage. Approximately 35% of the province's land mass has been mapped at a 1:50,000 scale as part of this on-going program. Reports are published annually and include data on size analysis, lithology soundness, abrasion and absorption.Aggregate deposits in New Brunswick frequently reflect the local bedrock lithology and, whereas much of New Brunswick is underlain by soft, friable sandstone of Pennsylvanian age, it is necessary to transport aggregate for higher-specification use considerable distances. Alternatively, the construction industry must turn to crushed stone as a source of asphaltic or concrete aggregate.Over 40% of New Brunswick's land mass is owned by the Crown, and aggregate resources are managed under the Quarriable Substances Act. Under this legislation, permit applications are reviewed by a Land Management Advisory Committee which consists of representatives from the various government departments involved.IntroductionSurficial materials either directly or indirectly form the basis of much of our economic activity, whether it is the field of agriculture, forestry, manufacturing, construction or other. Although sand and gravel have been produced and used since the day s of early settlement, the economic significance attached to such materials has only recently been recognized by both government and the general public."

Jan 1, 1982

By F. E. Lathe

The method of feeding blast-furnaces to be described below is simply the application of well-known principles, and an attempt to carry that application to its logical conclusion. It does not involve radical changes in equipment, nor does it require unusual skill on the part of the furnaceman. In fact, much of its value lies in its very simplicity. Before giving details of the method it will be well to consider briefly the conditions under which it was used at the Nickelton plant of the British America Nickel Corporation, in the Sudbury district, before that plant closed down. The Sudbury nickel ore consists chiefly of pentlandite, chalcopyrite and pyrrhotite in a gangue of norite or greenstone. The proportions of sulphide and gangue vary widely in different mines, the former constituting about 45 per cent of the total in the British America sorted ore. The gangue is fairly uniform in analysis, carrying about 55 per cent Si02, 18 per cent A120 3, 13 per cent FeO and smaller quantities of CaO, MgO, Na20 and K20. The ore has been frequently described as refractory, a word which seems suitable when one considers the many unsuccessful attempts to smelt it pyritically, as well as the high percentage of coke normally used at all the plants in the district.

Jan 1, 1925

By A. J. Hargraves

"It is difficult to quantify comparatively the gassiness of a property. The most common index to gassiness, cubic feet of gas per ton of coal mined, is very arbitrary and does not take into account the geological setting nor the mining operation. The gassiness of a virgin coal in situ can be assessed, but no method is precise and the most accurate methods involve prolonged field and laboratory experiments. In general, gassiness increases with depth. Whereas 'gas' normally implies methane, other gases such as nitrogen, carbon dioxide, etc. may be present in seam gas also. The inflammability of methane is a problem, particularly the explosibility of a methane-air mixture; also oxygen dilution is involved in high gas concentrations and some gases are poisonous even in low concentrations. Cross measuring into a virgin seam is usually not as troublesome as development in the seam, where narrow openings may require strong ventilation to dilute gases exuding from the face and sides. Total extraction presents problems of gas from the working seam, or from adjacent seams, particularly at the return side, or of gas-laden air from the goaf streaming out or sometimes surging out intermittently, again on the return side. In pillar extraction or longwall retreating special roadways may be required to allow the side-to-side and end-to-end flushing of the goaf which is somewhat inherent in longwall advancing. Layering may occur, particularly where ventilation conditions are not brisk. Outbursts of gas from adjoining seams may be induced by sudden rupture of roof or floor in caving workings. Outbursts of coal and gas from the working seam may occur, mostly in development work, under special environmental circumstances. Gas problems may be reduced or eliminated by predrainage of gas ....:. rarely successful from the working seam - usually undertaken from adjoining seams prior to escape of gas released by caving. The ideal solution - general predrainage of gas to the surface from measures prior to mining - has yet to be accomplished. • In the planning of gassy mines it is possible to make an assessment of gas contained in the seams and to estimate what proportion will be released into the mine air, but emission of gas into mine workings is never steady and at present there is no better planning criterion than experience at the mine next door!"

Jan 1, 1973

By K. Miao, W. Mu, M. Sharma, A. Haas, N. Dogan

"The ever increasing demand for cleaner steels with low inclusion content has highlighted the limits of our current knowledge for controlling and predicting inclusion agglomeration and removal during liquid steel processing. Key knowledge gaps in this area result from the complex nature of the problems associated with measuring and visualizing the phenomena studied. Confocal scanning laser microscope (CSLM) allows for continuous in situ observation of micron-size samples in real time, at high resolution, under conditions relevant to the steelmaking process. This paper summarizes some of recent CSLM applications in our laboratory to illustrate the methods of analyzing transient behavior. The reaction between inclusions and slag is given as an example. The dissolution rate of calcium aluminate inclusions in CaO-SiO2-Al2O3 slags has been studied at elevated temperatures: 1500, 1550 and 1600°C as well as thermodynamic/kinetic analysis. It is found that total dissolution time decreased with increasing temperature. The rate limiting steps are discussed. It is shown that the diffusion through a product layer is responsible for dissolution at 1500°C. At higher temperature, dissolution is most likely controlled by both boundary layer diffusion and chemical reaction at the slag-inclusion interface. In this paper, the evidence for and against the theory will be critically examined and repercussions of the theory to steel refining processes will be discussed.INTRODUCTION Inclusion formation during liquid steel refining is an unavoidable consequence of current ladle steelmaking processes. The nature and quantity of the inclusions formed in steel is critical in steelmaking, as it affects both productivity through clogging, and downstream physical properties of the steel. It is therefore crucial to better understand and control the formation, agglomeration and dissolution behaviour of inclusions in a slag in order to improve the removability of inclusions from liquid steel. Most research (Sandhage & Yurek, 1988; Sandhage & Yurek, 1990a; Sandhuge & Yurek, 1990b; Sandhuge, 1991) relevant to the kinetics of inclusion removal has been obtained by using a technique where simulated inclusion material (ceramic rods) is dipped in slag and the dissolution rate is measured. While much has been learned using this approach, the difference in scale from bulk materials to inclusions is likely to have a significant bearing on the dissolution kinetics of inclusions in a slag and will certainly result in a very different influence of capillary effects. Further, the data obtained using an indirect (dip test) procedure relies on a comparison of the initial and final conditions of a sample rather than in-situ observation which can be achieved in a confocal microscope in real time."

Jan 1, 2017

By G. A. Maki, P. J. Fullman, R. G. Roden

"In October 1984, Rocanville Division began using a stacking system to handle potash mill tailings. Previous to this date, mill tailings were slurried to the top of the tailings pile and allowed to debrine while flowing down the pile. With the new stacking system, slurried tailings are fed to mobile stackers. The stackers consist of cyclone packs to debrine the tailings and drag conveyors with screw discharges to deposit the tailings onto the existing pile. This paper deals with the various aspects of the project from conception to its present state.IntroductionPrevious to 1984, when the stacking project was first implemented, potash mill tailings were handled as follows. Mill tailings were first debrined to approximately 65010 solids using a cyclone cluster. The cyclone underflows were then introduced onto a vacuum scroll filter table. Here the tailings were further debrined and discharged into the disposal tank where the tailings were reslurried with reclaim brine and pumped to the tailings disposal site. At the disposal site the slurry was discharged onto the tailings pile and by a natural settling process the tailings were debrined with the brine ultimately collected in the reclaim brine ponds. The shape and profile of the tailings pile was controlled by building salt dykes to control the flow of the discharged tailings slurry. As the tailings pile grew in height, booster pumps were added to the disposal system."

Jan 1, 1990

By R. L. Bruening, R. M. Izatt, N. E. Izatt, S. R. Izatt

"Molecular Recognition Technology (MRT) is a simplified, green chemistry process with applications in selective separations of Ni(II), Co(II), and platinum group metals in primary ore beneficiation processes and secondary recovery operations from spent products, scrap, and environmental waste solutions. Simplification in MRT processes is achieved by non-use of solvents, reduced space requirements, and a simple separation system involving columns packed with metal-selective SuperLig® resins. Minimal waste is generated and metal recovery is achieved at 99% levels from g L-1 to <mg L-1 concentrations. MRT systems are attractive technologically and economically compared with solvent extraction, ion exchange, and precipitation separation processes. Commercial examples of MRT use include removal of impurity metals Cd, Cu, Ni. Fe, and Pb to mg L-1 or lower concentration levels from Co streams to produce battery-grade Co. Highly purified Co is required for optimal function of lithium ion rechargeable batteries and superalloys associated with aerospace and gas turbine operations. Impurity metals are recovered for reuse or proper disposal rather than being discarded to landfill. Green chemistry processes, such as MRT, are needed in metal separations going forward into the 21st century to achieve global metal sustainability in processing of native ore and treatment of secondary sources.INTRODUCTION Maximizing efficiencies of metal separations and optimizing metal recovery rates during separation processes are important goals on the road to achieving metal sustainability. Achievement of these goals is consistent with stated principles of green engineering (O'Connor, Zimmerman, Anastas, & Plata, 2016) and green chemistry (Anastas & Eghbali, 2010). Molecular Recognition Technology (MRT) separation processes using SuperLig® resins have a 25-year record of performing competitive, commercial metal separations with metal recovery rates approaching 100% (Izatt, Izatt, Izatt, Krakowiak, & Bruening, 2017). SuperLig® resins are characterized by high selectivities for specific metals over concentration ranges from g L-1 to mg L-1 or lower. MRT systems use no solvents and are simple in design and operation resulting in reduced capital and operating expenses."

Jan 1, 2017

By P. Hubert, J. P. Ildefonse, F. Qafssaoui, J. Poirier

Corrosion tests by corrosive alumina-lime slags were carried out on commercial high alumina bricks used in steel ladle linings and model refractories (with different raw materials : bauxite, andalusite, and different microstructures). Using (SEM) scanning electron microscope and (EDS) energy dispersive spectroscopy, microstructures of slag-corroded refractory interfaces were studied in detail. The monomineral and glassy phases, the composition of reaction products and chemical profiles were determined. A thermochemical analysis based on phase equilibrium diagrams has permitted to estimate the proportion and the composition of the high temperature intergranular liquid phase. These data were compared to the experimental microanalysis results. The viscosity of the high temperature liquids were calculated according to Urbain &apos;s model and the relationship between the viscosity and the penetration of liquid phases were discussed. These theorical and experimental results were used to understand the complex phenomena of slag penetration and corrosion of andalusite and bauxite refractories at high temperature and to propose new ways of improvements for the formulation of high alumina refractories.

Jan 1, 2004

By Virginia Lawson, Adam Price

The rougher flotation stage is used to reject liberated gangue at a coarse size. Base and precious metals due to their high specific gravity tend to recycle in the grinding circuit and report to the flotation circuit at a finer size than the gangue from which it is being separated. Generally liberation levels of greater than 50% are achieved in roughing and thus a portion of the feed can be immediately upgraded to final concentrate. The proportion increasing as the amount of liberated mineral in the feed increases. Scalping out concentrate from the rougher can reduce the size of the subsequent regrind and cleaner circuits. Examples of alternative process design for circuits demonstrates that you don’t need large volumes to effectively recover all of the minerals – you need smart flotation. Several case studies will be presented where circuits can be significantly reduced in size by designing smarter – not larger. This paper describes case studies to test the amenability of the Jameson Cell to produce final concentrate from rougher feed. Metallurgical performance and plant design implications are discussed. Froth flotation has been used extensively for mineral concentration for over 100 years. Although the flotation cell design has changed, it has generally simply increased in capacity rather than increase in efficiency. Cell capacities of over 600 m3 are now being used in rougher flotation particularly for the lower grade ores where the amount of surface area for flotation is deemed less significant than the required volume. The plant design volume in rougher flotation comes from laboratory batch flotation tests and/or pilot plants. The volume required for the plant is calculated based on the laboratory residence time multiplied by a scale- up factor. Examples of laboratory to plant scale-up design are given in Dunne et al. (2010 part 2). The factors are usually between 2 and 3. A laboratory residence time of 10 minutes would equate to a plant design residence time of 25 minutes using a 2.5 factor. The volume of the required flotation cells can then be calculated using the design tonnage and volumetric throughput. This scale-up factor takes into account the differences in performance between batch flotation efficiency and full scale plant. The differences are likely related to inefficiencies of bubble particle contact in large cells as well as froth recovery, which is essentially complete in a batch cell. Flotation cells, such as the Jameson Cells, are smarter designs that improve bubble/particle collection, bubble/pulp separation efficiency and operate with high froth recovery rather than simply getting bigger. The Jameson Cell was designed on the principal of improving the collection efficiency of fine particles by separating the contact zone from the separation zone and having the bubbles generated by the plunging jet shearing and entraining air. This means the method of bubble generation is not impacted by the wear of mechanical equipment as it the case in other flotation devices. Jameson Cells make bubbles less than 600 micron in size under most operating conditions (Ding, 2016).

Jan 1, 2019

By W J. Riva

This paper reviews the coal mining operations of The Canmore Mines, Limited, at Canmore, Alberta, paying particular attention to the use of this coal by the metallurgical and chemical industries. The characteristics of the deposits are outlined, and the mining and processing methods used are discussed. Introduction M INING in the Cascade coal area of Alberta began form-ally in 1886 when the Canadian Anthracite Coal Company was granted its charter. Earlier operations had been confined to prospecting and family-type enterprises serving the market area within barging distance on the Bow river. From 1886 to 1964, seven mines were opened between Banff and Ribbon Creek; six of these have since been abandoned, leaving the B c 0 L. original tenant, under the name of The Canmore Mines, Limited, as the sole survivor. The town of Canmore, hub of the mining ventures, is located on the main line of the C.P.R. and on the Trans-Canada Highway, 67 rail miles west of Calgary and 57 4 miles east of Vancouver, as shown in Figure 1.

Jan 1, 1965

By T. Shellhammer, A. Park

Among all pure metals, copper has the second highest thermal and electrical conductivity, next to silver. These properties coupled with a reasonable cost, make copper ideal for use in metallurgical vessels as a conductor of electrical current, as well as a lining material and protector of refractories and steel superstructures. Treatments of copper to address it’s softness and low melting point, specifically hard surfacing and calorizing, will be discussed. This paper will cover the evolution of copper to its current form, offer comparisons to other materials, and theoretical and empirical evidence on its superior performance in metallurgical vessels such as blast furnaces, basic oxygen converters and electric arc furnaces. Some case studies will be provided and finally a brief summary.

Jan 1, 2015

By P. W. A. Mayer

"As the push toward the northern regions of Canada steadily increases to exploit the rich mineral reserves, interest is steadily rising in respect to accessibility and climatic conditions and the problems posed thereby. In twelve years of operation, the Iron Ore Company of Canada, and associated companies, have found, through advanced technology, ingenuity and, most of all. need, some of the answers to the running of a profitable year-round open-pit mining operation."

Jan 1, 1966

By Garth D. Kirkham

The Problem The Don deposit is a series of two sub-vertical zones that pose a number of challenges with respect to modeling and interpolation. The first challenge is that, based on data and observations, the mineralization and, more importantly, the grade is layered or banded and is stratigraphically controlled. The second challenge is that, due to the undulations of the deposit and extreme changes in dip, using a standard oriented ellipse to guide the estimation process is not appropriate and does not result in an estimate that is representative on a local scale. In order to solve this problem an adapted methodology of relative elevation modelling, has been devised to effectively model and estimate deposits faced with these challenges. Relative Elevation Designed for bedded seam and gridded surface With variable dip and vertical grade variability

May 1, 2013

By W. Holyk

"Although lead, zinc, copper, and iron sulphides have been known for many years in the Bathurst region, the existence of large massive deposits was not known until the discovery of the Brunswick orebody in 1952. This was followed by the discoveries of the Anacon orebody in 1953 and the American Metals orebodies in 1954. There is no question as to the great importance of these large massive sulphide deposits, and no doubt that other sulphide deposits are to be found. The problem, of course, is where and how to find them.The discovery of the Brunswick and Anacon orebodies is attributed to geophysical work. The original discovery of the American Metals deposit is generally attributed to a regional airborne electromagnetic survey.It is generally stated that the Bathurst area is a geophysical camp, and this is essentially true, but in this highly competitive search for orebodies it is obviously impossible for an individual company to cover the entire area by a comprehensive geophysical survey. Some means other than geophysics must be used to narrow the target. The quickest, cheapest, and simplest method is geological investigations.It has been stated that nothing can be accomplished by geology in the Bathurst region, since the camp is largely covered with overburden. This is true only insofar as detailed work on certain properties is concerned. It is not true of the larger regional picture. Outcrops are scarce, but angular float is abundant, and precedent shows that angular float has moved but a short distance from its source.GeologyAeromagnetic maps published by the Department of Mines and Technical Surveys are the best guides to the geology and structure of the area. These maps supply factual information concerning the underlying rocks. When coupled with field investigations, they are very useful in the interpretation of regional geology and the selection of favourable areas. The discussion of the geology is accordingly centred upon the aeromagnetic maps. The following is essentially a working theory, based on geological facts as best reconciled with all other available information,"

Jan 1, 1949

By K. C. Sole

In most copper solvent-extraction operations, an important consideration in choice of extractant is the requirement for high selectivity of copper over iron. Ester-modified aldoxime extractants presently offer the best Cu:Fe selectivity. In some plants, however, the process feed liquors contain significant amounts of manganese but little iron. Although manganese is not chemically extracted by oximes, trace amounts are carried over to the electrowinning circuit by physical entrainment. This may result in anodic oxidation of manganese which, in turn, can cause oxidative degradation of the organic phase when returned to the solvent-extraction circuit in the spent electrolyte. Many of these operations prefer to operate with higher levels of iron reporting to the advance electrolyte, as appropriate control of the Fe(II)/Fe(III) couple will ensure that manganese remains in the benign Mn(II) form. A new reagent, LS 4202, designed by Cytec, now offers the possibility of tailoring the iron co-extraction, so that appropriate Cu:Fe selectivity can be achieved in the solvent-extraction operation to maintain an electrolyte Fe:Mn mass ratio of >10:1, while retaining the other benefits offered by ester-modified aldoximes. The results of an integrated solvent extraction-electrowinning pilot-plant trial are presented, in which the performances of the conventional extractants ACORGA® M.5774 and LIX® 984N are compared with LS 4202. The Cu:Fe selectivity is demonstrated, along with results on the transfer of other impurities to the advance electrolyte.

Jan 1, 2007

By Charlie Jefferson

Main Goal: Resource Assessment 1. Incorporate existing data & results, old process. 2. NEW Quantitative Analysis (Chung and Chen) 3. Try mass balance of U and geochemical tracers 4. Use holistic process approach ?with key foci ?Targeted basin / belt assessments ?Is there as much in the Athabascaas they say? ?Athabasca reference for other basins (Thelon, etc) ?Compare sandstone & volcanic with USA, Kazakhstan etc: do their models apply here? ?Which IOCG systems are prospective for uranium? 5.Consider Groundwater, Environment; 6.Communicate

May 1, 2006

By M. Kawahara, H. Sunayama

Oxidation rates of the cubic specimens, which were prepared by cutting the shaped magnesia-carbon bricks, were measured continuously with a thermo balance in the temperature range from 1273 to 1 823 K in N2-02 and Ar-02 mixed gas with 2.1 x 104 and 3.7x 102 Pa of oxygen partial pressure respectively. The effect of the graphite content, the maximum grain size of magnesia clinker and the oxygen concentration in the atmospheric gas on the oxidation rate for the MgO-C refractory has been investigated. The value of effective diffusion coefficient of O2, which diffuses through the porous decarburized layer, decreased with the decreasing of the porosity and the oxygen concentration in the external gas phase. It was speculated that the dense layer formed easily due to the high tortuosity of pores and the low recession speed of the carbon interface in the MgO-C bricks.

Jan 1, 2004