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By M. C. Harris

"Excess Gibbs energy is a thermodynamic parameter which quantifies the difference between the value of the Gibbs energy for a real mixture and that for an ideal mixture. More specifically the partial molar excess Gibbs energy of a species (i) in a mixture is indicated by the change in the overall excess Gibbs energy of the solution as the number of moles of species (i) changes while keeping temperature, pressure and the number of moles of all other species in the solution constant. Generally it is obtained from the activity coefficient which in turn can be obtained for a species in a mixture using a variety of models. The most widely used method is to use UNIFAC. Flotation is probably the most important process in the concentration of minerals and requires the use of reagents such as collectors and frothers. There is abundant experimental data which illustrates that collectors of different alkyl chain lengths will change the contact angle and that frothers of different structures and molecular weights will result in changes in key flotation properties such as froth behavior, surface tension and critical coalescence concentration. In this paper it is shown that there is a strong linear relationship between measured parameters such as froth volume/height, surface tension, critical coalescence concentration and contact angle and the partial molar excess Gibbs energy of the molecules used. Proposals are made to explain these correlations.INTRODUCTIONAs is well known froth flotation is arguably the most widely used process in the separation of minerals. In broad terms the process relies on the use of reagents known as collectors to adsorb onto a mineral surface and thus render the mineral particle hydrophobic. Alkyl thiolates are very commonly used for this purpose. The hydrophobicity is induced as a result of the alkyl group’s molecular structural properties which results in it forming a non-ideal mixture with the process water. Surfactants (or frothers) are typically alcohols and are known to lower the surface tension of the system and also inhibit bubble coalescence and reduce bubble size. Since alcohols are polar they will also form a non-ideal mixture with water. The hydrophobic mineral attaches to the bubble and rises to the froth phase where the valuable mineral is recovered as a concentrate. Frothers have often been characterized using the so-called HLB (hydrophobic-lipophilic balance) number but recently it was shown that the use of activity coefficients (?) or excess Gibbs energy (G ex ), which is calculated using equation (1) is a much more appropriate way to describe the behavior of these reagents in non-ideal mixtures with water (Corin and O’Connor, 2014)."

Jan 1, 2016

By E. C. Sanford

A laboratory-scale batch extraction unit and operating procedure for studying the hot-water separation of bitumen from Athabasca tar sands are described. The extractor evolved from earlier units and has been in use by Syncrude Research for the past 10 years. By using a unit such as this, it is possible to study tar sand feed quality and the effects of chemicals on the hot-water extraction process, while process variables are held constant. Data are presented to demonstrate the importance of surfactants to the process and the interrelated role of inorganic bases and surfactants.

Jan 1, 1979

By Y. Champoux, N. Atalla, R. Oddo, C. Lesage

"Percussion drills are the source of the most serious noise problems in mining activities, due to their extremely high noise levels(114-122 dB(A)) and widespread use(Bartholomae and Stein, 1988). Percussion drills will continue to be widely used to drill small diameter holes in hard rock because no other method seems to be economically avail-able to replace them (Boillat et al., 1993).Many studies (Danière, 1991; Hawkes etal., 1977a; Jensen and Visnapuu, 1972;Leblond et al., 1976; Milette, 1989) were con-ducted to determine the major noise sources of percussion drills. The exhaust air of pneumatic drills, the hammer, the bit in contact with the rock and the drill rod have been identified as the major noise sources. A muffer can be used to reduce the exhaust noise and the hammer can be enclosed. The bit noise is considered to be of concern only at the beginning of holes. When all the available methods are used to reduce the noise of a percussion drill, the drill rod vibrations become the dominant noise source (Hawkes and Burks, 1979). However, the noise levels generated by this source remain high and future efforts should concentrate on reducing its radiation.Works by Hawkes and Burks (1979) and Hawkes et al. (1977b) for the U.S. Bureau of Mines provide the most complete description on the noise and vibration of percussion drill rods.The longitudinal and bending waves are the two most important types of elastic waves generated in drill rods. Among these, only the longitudinal waves contribute to the drilling rate. The bending waves are caused by non-centralized impacts, drill rod curvature and non-uniform bit/rock interface. Drill rod noise is generated by Poisson’s ratio expansions and contractions of the rod as the longitudinal waves travel up and down it and by transverse rod motions induced by bending waves. The radiation efficiency is much higher for bending waves than for longitudinal waves. Most of the impact energy is transformed into longitudinal waves, as expected for axial impacts. The evaluation of the relative contribution of longitudinal and bending waves to noise generation poses a very difficult problem for experimental, analytical and numerical approaches. It is, however, an important issue because the relative contribution of these two waves will guide future noise reduction efforts. It seems that very little can be done to reduce the noise radiation of the axial waves without affecting the drilling rate. The main difficulty that analytical and numerical approach-es face, in the evaluation of the relative contribution of the two waves, is that there is no adequate theory for predicting the bending vibrations from the factors that cause them. The experimental approach has, thus, been limited to test fixtures that do not adequately represent the boundary conditions, as well as by measurements obtained under real operating conditions from which it is difficult to establish the relative contribution of the two types of waves. For example, Hawkes and Burks (1979) and Hawkes et al. (1977b) used a test fixture with free-free boundary conditions and made no clear link with measurement under real operating conditions. Rather, they have based their discussion on a simple model. Many authors assume that fexural waves are the main noise source on drill rods. However, measurements have been somewhat contradictory and researchers are still unable to state with certainty that this is indeed the case (Lednik et al., 1988)."

Jan 1, 1997

By P. Nayak

"Comminution is an energy intensive and expensive process consuming approximately 40-50% of the total processing costs in a mining operation. This process poses an even greater challenge with gold ores due to their low elemental concentration and small particle size. Over 99.9% of the ore fed to the mill is waste which must be removed during the ore processing stage. Preconcentrating the Run of Mine (ROM) ore before feeding the mill will result in significant cost savings. In partnership with Sacré-Davey Engineering, Agnico Eagle Mines Limited identified this opportunity and is currently evaluating the implementation of sorting technology to preconcentrate the ore or upgrade the waste material at its operations. This paper will discuss the steps adopted by Agnico Eagle in the evaluation and installation of sorting technology at its operations. Since the Company has a large portfolio of operations, the first step in the project was to shortlist the operations that had the highest probability for successful application of the technology. Following this, the top three operations were selected for bench scale evaluation. The projects which showed the most economic potential were then considered for detailed evaluation and pilot plant installations. This paper provides an insight into the methodology followed by Agnico Eagle and Sacré-Davey in the evaluation of the technology.INTRODUCTION The benefits of ore sorting technology are being increasingly understood by the mining industry today. The application of ore sorting in gold mining is attractive due to the nature of the mineral distribution. The presence of high value minerals distributed in an extremely small mass of the ROM ore creates a tremendous opportunity for preconcentration with ore sorting. Since Agnico Eagle currently has a portfolio of eight operating mines and numerous development projects and exploration properties, the challenge was to identify the deposits which had the most favourable mineralogy and grade distribution for successful ore sorting. The success of ore sorting is mostly based on the minerals present in the deposit and the grade distribution. The minerals signify the amenability of the deposit for ore sorting and the kind of sensing technology to be used. On the other hand, the grade distribution demonstrates the amount of material that can be rejected without losing value. In order to understand a deposit’s characteristics, it is important to examine the sample’s behaviour with various sensors and then assay it to know its actual value. It is a common practice in the mining industry to document assay value of drill cores and/or material feeding in and out of the mill. However, those VALUES (are insufficient to understand the grade variability on a granular basis. To capture the ore variability in very high resolution and significantly improve the selectivity of the material feeding the mill, it is vital to assay the samples on a rock-by-rock basis, as this is the level of resolution which will be examined by the ore sorter during sorting. A careful and elaborate procedure was followed in evaluating the technology at Agnico Eagle’s operations which is discussed in this paper."

Jan 1, 2019

By Claude Hubert, Alex C. Brown, Michel Richard, Rejean Sirois

"The Pierre Beauchemin gold deposit, situated 15 km NW of Rouyn-Noranda, produces an average of 1050 tonnes of ore a day. Reserves are 1.2 Mt grading 5.6 g/t Au. The deposit, located in a shear zone within the Flavrianpluton, in the Blake River Group, is hosted by four major rock types: meta-trondhjemite, meta-tonalite, hybrid rocks and meta-diorite (the prefu; ""meta-"" is omitted thereafter). The trondhjemite, tonalite, and metamorphic hybrid rocks are spatially distributed as a series of sub-horizontal tabular sills that form a genetically related group. Early fractures that permitted either the emplacement of pre-diorite felsic dikes or the formation of a visible alteration caused by early fluid circulation might have been developed in response to initial strain created during regional deformation. These fractures were precursors to the emplacement of diorite and the development of major shear planes. Sub-horizontal north-trending en échelon diorite lenses are observed at the mine. Together, these diorite lenses constitute larger scale diorite zones which are observed at the scale of the pluton. The diorite zones are interpreted as evidence of an episode of sub-vertical extension sustained by the layered trondhjemite, tonalite and hybrid system. The anisotropy created by the less competent sub-horizontal en échelon diorite was an important factor. In shear zone development and subsequent mineralization. The tonalite and diorite accommodated further defomation and developed the main N030°/40° ESE shears along with the spatially associated N060°/50°-60° SSE, and the N000°/10°-40° E shear zones. The N000° shears are interpreted as refracted or deflected equivalents of the N030° shears. The combined shears compose the Eldrich shear system which trends approximately N030°/40° ESE and has had a general reverse movement with a minor sinistral component.Gold mineralization occurs in all four major rock types as en échelon sigmoidal shaped lenses associated with the major N030° deformation system. The distribution of ore lenses can be divided into two categories: The first category occupies sub-horizontal diorite zones. The lenses trend N-S, dip 100 40° E, and are associated with shear zones, sub-horizontal fractures or tonalite-diorite contact planes. The second category of lenses is found in felsic granitic rocks; the lenses trend either N0300!40°ESE or N060°/50°-60° SSE. Local hydraulic breccia zones are observed near ore zones occupying felsic granitic rocks. These breccias may have resulted from high fluid pressures brought upon by confinement as a result of impermeable zones in an anisotropic tonalite-diorite system."

Jan 1, 1990

By J. M. Carr

The history, geological setting and local geology of the Magnum vein system, 100 miles west of Fort Nelson in northeastern British Columbia, are described. The system comprises a number of quartz-ankerite veins, mineralized with chalcopyrite and lesser pyrite, occurring in a steep northeastly zone of deformation and subsequent dike intrusion within otherwise little-deformed Precambrian sedimentary rocks. In April of 1970, Churchill Copper Corporation began producing copper concentrates in a 750-tpd mill fed from the Magnum mine.

Jan 1, 1971

By P. Personnet, D. Wheaton, E. Couzinie, V. Demetriou, Brooks. W., G. Girault, M. Meyer, L. Charbonnel

A common problem in Gas Treatment Centers (GTC) from primary aluminium smelters is the temperature of the gas to be treated : above a threshold, filtering media are irreversibly damaged. The traditional way of dealing with high gas temperature is to dilute with fresh air, which implies over sizing - and therefore higher cost for - the GTC in order to have the capacity to treat this dilution air without compromising on pot suction. A system was developed which decreases gas temperature without having to use dilution air. This system is based on water pulverization in gas collectors. The water vaporization leads to a temperature decrease of the gas. A pilot system was trialed in our R&D unit. Satisfactory results led to the development of an industrial system based on Envirocare equipment (partnership), which was trialed in our production plant in Tomago (NSW, Australia). This patented system was then generalized in this plant, which is now using it with success during austral summer.

Jan 1, 2006

By A. Banerjee, J. P. Weiler, J. Jekl, J. T. Wood, R. Berkmortel

"The work presented here is part of an ongoing project designed to develop predictive capabilities of the local mechanical properties, and thus, structural behaviour of a thin-walled high-pressure die-cast AM60B magnesium alloy component. This work focuses on developing correlations between process parameters and local microstructure. Numerical simulations of the die filling and solidification behaviour of the AM60B component were used to estimate local process parameters such as solidification rate, temperature gradient, filling velocity, etc. These estimated parameters were used to establish semiempirical correlations with measured VALUES (of the local microstructure measured in regions throughout the component of different solidification conditions. INTRODUCTIONHigh-pressure die-cast magnesium alloys are experiencing increasing use in structural automotive components. A strength-to-weight ratio comparable to steels and its ease of castability allow for these alloys to be utilized in such capacities as instrument panel beams, seat and door frames, and engine cradles, among others (Gjestland and Westengen, 2007). However, the current use of these alloys is limited due to variations in local mechanical properties. These local property variations restrict part designers to assume lower than actual properties, resulting in larger sections, thus diminishing the light-weighting advantages of magnesium alloys. If these local property variations could be predicted, part designers would be able to optimize die-cast magnesium alloy components and fully take advantage of the light-weighting capacity of these materials.The work presented here is part of an ongoing project aimed at developing predictive capabilities of the local mechanical properties, and bulk mechanical performance, from variations in local microstructure, and ultimately from local process parameters in die-cast magnesium alloys. This project, unique in its nature, is based upon the results determined from fifty sequentially cast AM60B magnesium alloy instrument panel beams provided by Meridian Lightweight Technologies (shown in Figure 1)."

Jan 1, 2012

By F. Richards

"The property of the Cariboo Gold Quartz Mining Company; Limited; is in the Wells-Barkerville district of Cariboo mining division. It consists of a group of 106 Crown granted mineral claims and fractions; and extends for over 6 miles along what is termed the Barkerville gold belt. The main portal and mine camp are half a mile south of Wells; which lies at the northeast end of Jack of Clubs lake and is reached by a 55-mile motor road from Quesnel; the northern terminus of the Pacific Great Eastern railway.Gold-bearing quartz veins were discovered on the surface in various parts of the property by different prospectors as far back as 1877, but the work that led to the formation of the present company was performed by Al Sanders in the year 1926. Sanders dug trenches and drove small adits on quartz veins containing gold above what is now known as the Sanders zone. Very little underground work has been done beneath the earliest known discovery-the B.C. vein. The Cariboo Gold Quartz Mining Company was formed in the autumn of 1926. The total production of gold from its beginning in 1933 to the end of 1944 has been as follows:"

Jan 1, 1954

By O. Babak, J. G. Manchuk

ABSTRACT A significant factor in evaluating bitumen recovery from an oil sands mine is the particle size distribution (PSD). Increased understanding of mined ore quality and improvement in predictions of recovery can be achieved through PSD modeling. This paper addresses PSD modeling using geostatistics. PSDs may be described using many discrete particle sizes, making this a challenge. The approach parameterizes PSDs with a few statistics. A lookup table is used to reconstruct the PSDs based on models of the statistics. The workflow is applied to Total E&P Canada’s Joslyn Lease and yields good results that reproduce input statistics without introducing artifacts.

Jan 1, 2013

By K. Sawamukai, S. Ogasawara, D. Umenai, T. Tsuruta

"Removal of cobalt, strontium or cesium ion from the aqueous solution containing each metal ion only using microorganism was examined. Arthrobacter nicotianae which had a high ability to remove cationic metal ion was used for the removal of each metal. The removal of cobalt, strontium or cesium using A. nicotianae cells was affected by the solution pH, concentration of metal ion, and cell amount. The effects of above mentioned factors on the removal of each metal and time course of strontium from the solution containing each metal only using A. nicotianae cells were reported in this paper. INTRODUCTIONRadioactive elements, such as cesium, iodine, strontium, plutonium, barium, cobalt, lanthanum, yttrium, and tellurium, were detected around Fukushima Daiichi nuclear power plant, which was damaged by the magnitude 9.0 earthquake and the tsunami followed.The removal of radioactive elements from contaminated sources is a worthwhile subject to investigatein terms of environmental control. Research efforts have been especially concentrated on studying microorganisms that remove uranium including bacteria (Andres et al, 1993, Hu et al, 1996, Marques et al, 1991, Strandberg et al, 1981), actinomycetes (Byerley et al, 1987, Friiss and Myers-Keith, 1986, Golab et al, 1991), fungi (Byerley et al, 1987, Galun et al, 1983a, Galun et al, 1983b,Tsezos and Volesky, 1981, White and Gadds, 1990) and yeasts (Strandberg et al, 1981, Schmate II et al, 1978).We have investigated removal and recovery of uranium from aqueous systems using microorganisms isolated from uranium mines. We identified some strains of bacteria with extremely high uranium removing abilities (Sakaguchi et al, 1996), and thus, the microbial biomass may be considered as an adsorbing agent for the removal and recovery of uranium and heavy metals present in aqueous systems around Fukushima Daiichi nuclear power plant.In the present study, we screened various species and strains of bacteria, actinomycetes, fungi, and yeasts for their ability to adsorb uranium (Tsuruta, 2002). Basic features affecting uranium adsorption?co-existing cations and anions, cell amounts, pH, and the adsorption time course?by Arthrobacter nicotianae cells, which adsorbed the largest amount of uranium, were also investigated. In addition, we examined the removal of an other actinoid element, thorium ion, which may be present with uranium in refining effluents.In this paper, the removal of cobalt, strontium, or cesium from the solution containing each metal ion using A. nicotianae cells is discussed."

Jan 1, 2012

By R. F. Sharpe

THE Bullion mine, in the famous Cariboo district of British Columbia, is situated on the left bank of the South fork of the Quesnel river, approximately three miles below the outlet of Quesnel lake. A good road leads 63 miles northeast to the property from Williams lake, the railhead on the Pacific Great Eastern railway. The mine may also be reached over good roads from Vancouver via the Fraser canyon, Ashcroft, Clinton, and the 150-mile house, a total distance of 407 miles. In the early days of placer mining on the South fork of the Quesnel, several rich bars were found. The 'pay' on one of these at the mouth of Dancing Bill gulch was followed up the gulch by a Chinese company, who proved to be the discoverers of the present Bullion mine. This Chinese company commenced working in 1884, in what was then referred to as the China pit. Although working under very primitive conditions, it is reported that, during the ten years they operated the property, they recovered in excess of $900,000 in gold. This somewhat large recovery was due to a local concentration, the result of Dancing Bill creek having meandered down that portion of the channel and washed off the overburden. In 1894, a syndicate composed largely of the Canadian Pacific Railway directorate of that time, with J. B. Hobson as their field manager, acquired the property, as the apparent magnitude of the operation was too great for the resources of the Chinese company. Mr. Hobson, during the first ten years of his regime, developed the mine into a large-scale hydraulic operation, and during that period, from 1894 to 1905, recovered approximately $1,234,000 in gold. In 1906, the property was sold to the Guggenheim Exploration Company, who retained Mr. Hobson as Manager and embarked on an extensive programme to bring in additional water. This project was never completed, however, work being suddenly abandoned in 1907 and the mine closed down. Shortly afterwards, the property was purchased by a small operator on what is believed to have been largely borrowed capital. This venture resulted in no production, but in much litigation, which eventually reached the Privy Council in 1920.

Jan 1, 1939

By K. Prajapati, P. Hes

Transmission of vibration to the operator from percussive vibrating tools is increasingly of concern in industrial and mining applications. Prolonged exposure to high levels of vibration transmitted via the hand causes disorders known as hand-arm vibration syndrome (HAVS). The vascular component of HAVS is called vibration white finger (VWF) and has a debilitating effect on the hand. Vibration at frequencies below 1250 Hz, a tight hand-grip force and cold environments are reported to increase the likelihood of developing VWF. A vibration damping handle design with patents pending that addresses some of the causes of VWF has been developed and retrofits onto jackleg pneumatic rock drills. The handle is decoupled from the drill while maintaining jackleg twist-grip controls on the hand-grip using a combination of sealed self adjusting hydraulic pistons and compliant materials in series, and a new air control valve. The ergonomics of the hand-grip was also modified by the addition of a polyurethane sleeve with a diameter of 50 mm. The new hand-grip reduces direct cold metal contact and minimizes grip force. Measurement of vibration as the quantity acceleration was made in accordance with international standard ISO 5349. Overall vibration damping in all axes of 50% to 63% was attained at frequencies below 1250 Hz. The dimensions of the damping handle are comparable and its weight is only 100 g heavier than a standard handle.

Jan 1, 2001

By C. W. Eggert

This paper gives an account of the E.V.O.P. tests made at the Copper Rand mill of the Patino Mining Corporation in Chibougamau, Quebec. The runs were made to acquire an understanding of the method. A description of events, along with conclusions, observations and opinions, is out-lined.

Jan 1, 1967

By C. Allen

In 2004, Boliden Odda underwent an extensive modernisation project targeting mainly the leaching section of the plant. Direct leach technology was introduced as part of this project. The Direct Leach process, developed by Outokumpu, is an atmospheric oxidative leach of zinc sulphide concentrate. The effects of this new processing operation on behaviour of iron in the plant are discussed. As well, the filterability of the new residue on belt filters prior to its deposition in mountain caverns is also discussed. The solids from the direct leach process have been analysed by scanning electron microscopy, and the results of these analyses are presented.

Jan 1, 2006

By J. R. Giegerich

"IntroductionMINING operators in common with other operators are confronted today with two serious problems, shortage of experienced workmen and rising costs. The following review of practices at the Sullivan mine of The Consolidated Mining and Smelting Company of Canada, Limited, outlines certain measures that have been responsible, during recent years, for minimizing the effect of these two problems. The paper is divided into three main sections:( 1) Training programmes and job studies( 2) Improved mechanization and equipment( 3) Large-scale methods of operationTraining Programmes and Job StudiesJob TrainingJob training courses were introduced at Cominco immediately after the last war and proved to be a great benefit to the operations. There were three courses given, Job Instruction Training, Job Safety Training, and .Job Relations Training. These were spread over a period of two years and were taken by all operating supervisors and some key operators.The courses were introduced by a trained instructor from the British Columbia Department of Labour. This man trained twelve of our employees as instructors by giving them an intensive one-week course. Similarity between the three courses was such that the instructors trained in the first one were very readily trained for instruction in the two succeeding courses."

Jan 1, 1952

By Narasimha Mangadoddy, Teja Reddy Vakamalla

"Vertical hydrocyclones are very common in most of the comminution circuits. Inclined cyclones are also found for specific mineral processing applications. In this work, Computational Fluid Dynamics (CFD) technique and experiments are used to find the reasons behind the inclinations effect on hydrocyclone performance characteristics. The water and silica slurry experiments are conducted with 75 mm hydrocyclone at different inclined positions (0-600) to the vertical plane. Corresponding two-phase numerical simulations are performed with Volume of Fluid (VOF) model coupled with Large Eddy Simulation (LES) turbulence model. Multiphase simulations are carried out with Algebraic Slip Mixture model modified with lift, drag forces and Newtonian rheology model corrected with fines for various feed solids concentration. A raise in the under flow solids percentage, cut diameter and a reduction in the water split is observed with the inclination. Electrical Resistance Tomography (ERT) and High Speed Video (HSV) data is used to cross validate the inclined cyclone’s CFD air-core and solids concentration data. Predicted efficiency curves are found in a close agreement with experiments for all the inclinations. Comparison of experimental and predicted flow data clearly follows trend with the literature. Key words: Hydrocyclone, CFD, ERT, inclination, water splitINTRODUCTIONHydrocyclones are devices used to separate or classify particles based on particle size difference in the water medium. Their usage is very wide in chemical, petroleum, mineral and bio industries due to its structural simplicity, high throughput, small volume, low cost and maintenance. Cyclone mainly consists of a cylindrical section followed by a conical section attached to a single feed inlet and two product outlets named vortex finder and spigot. It works on the principle of centrifugal sedimentation. The slurry is fed tangentially to the hydrocyclone, in which larger particles are moved towards the wall and separated by centrifugal forces to the underflow. Smaller size particles follow liquid due to drag forces to the overflow. With its simple structure, the flow behavior inside the hydrocyclone is quite complex. Vertical cyclones are common in practice in most of the comminution circuits. Horizontal cyclones can be found in extreme cases which are for installation convenience rather than for process reasons. Inclined cyclones are also present for specific mineral processing applications. In coal preparation plants, dense medium cyclones are operated near to horizontal inclination of 20 degrees to allow large spigot sizes for sinks removal, self-drain of contents during shutdown. In the phosphate removal, dense medium cyclones are inclined with an angle between 0-90 degrees for better separation of ore and tailings (Liu Feng et al., 2006). Even in the clusters, hydrocyclones are mounted with an inclination around the feed distributor for uniform distribution of slurry and under flow collection. It is believed in mineral processing industry that inclined cyclones would fetch the benefit in number of ways while classifying the material by size. Gravity influences the cyclone performance through the air core size and position variations in large cyclones. It also favours the cyclone operation at coarser cut points without varying any other design and operating parameters. Minimizing fines misplacement to underflow can be achieved with inclination."

Jan 1, 2016

By Maciej Wrobel, Joerg Hammerschmidt, Dana Nurgaliyeva, Alexandros Charitos, Jochen Guentner

"Smelting of copper concentrates in the flash smelter generates a flue dust stream that contains a substantial amount of copper and accumulates more than half of the arsenic input to the smelter. In view of its high copper content flue dust recirculation to the flash smelter is common practice. Globally traded copper concentrates are affected by ever increasing arsenic contents and cause an increasing circulating arsenic load in flash smelter operation. Control of the arsenic level in the smelter slag becomes a challenge. This interaction of arsenic loaded copper feedstock, need for flue dust recirculation and slag quality control call for possibilities to reduce the arsenic load of the recirculated flue dust stream.The technology of partial roasting is known from pre-treatment of copper concentrates before smelting, and gold concentrates before cyanide leaching, to remove the harmful element arsenic. The partial roasting technology can be adapted for use in the purification of the flue dust. A major challenge for flue dust treatment is its extremely fine particle size compared to usual concentrates. For this reason Outotec developed a new process, which allows handling of such fine flue dust. This process solution provides an efficient possibility to reduce the arsenic burden in copper smelter operations.The suggested process aims at reducing the arsenic load to the smelter by treating the flue dust prior to recirculation to the smelter. The presented results are based on test work in the Outotec R&D-centre in Frankfurt. It is possible to remove 80-85% of the contained arsenic and to collect it in an arsenic trioxide residue with a concentration above 90%. The final off gas contains SO2 from decomposition of sulphates that are contained in the flue dust. The off gas stream is relatively small. We assume that it is possible to combine the off gas stream with other smelter process gas streams and to treat it in an existing sulphuric acid plant. Coal is used as fuel and as reductant to reduce pentavalent arsenate to trivalent arsenite. Arsenite can be kept in gas form at temperatures above 450°C. This permits separation of a calcine stream with arsenic levels of 0.2 – 0.3%, which is recirculated to the furnace.Outotec has a wide range of roasting testing facilities from lab-scale to pilot-scale. Outotec has both capability to modify and adapt technology to specific ore or concentrate requirements, but also the necessary infrastructure in its research centers in Frankfurt and Pori to do appropriate validation tests in lab and pilot scale size plants."

Jan 1, 2016

By W. F. MacIsaac

"The large low-grade Copper Mountain deposit is located in the northern portion of the Gaspé Cooper Mines property. It is approximately 1 mile north of the Needle Mountain deposit. The orebody outlined to date lies in the top 1,000 feet of the Grande Greve formation. Chalcopyrite occurs in association with pyrite and quartz in small veinlets and numerous fractures. The deposit is immediately adjacent and parallel to a quartz-feldspar dyke and may be associated with a nearby porphyry stock. Stratigraphy, alteration and structure appear to have played an important role in ore deposition."

Jan 1, 1969

By Douglas Brand

"The data that many mineral processing plants make use of, is provided by samples taken from sampling systems which are inadequately designed or improperly maintained, and therefore cause detrimental effects to plant operations, production planning and metallurgical accounting! Poorly designed or maintained sampling systems will likely produce low probability samples which give the operator a false sense of security of the product and the process. If data is the basis for action (Flintoff, 1992, p.2), then using the resulting suspect or bad assays by operators, control systems, or metallurgist and administration personnel will act and make decisions which may adversely affect the profitability of a processing plant. Here we will discuss some of the fundamental sampling problems, propagation of errors and a method to estimate what impact this has on an operations Net Smelter Return.INTRODUCTIONIn order to control a mineral processing plant at its best potential, it is necessary to obtain the best possible measurement results of the metal or mineral in question. The sample which is delivered to a measuring instrument, or lab, needs to be of the highest probability to be able to achieve this. This paper will discuss the effects of sampling errors on grade / recovery and grade / Net Smelter Return (NSR) and provide a method to estimate the monetary advantages of using probabilistic sampling in a processing plant.REVIEW OF SAMPLINGSampling, by definition, is the removal of a small representative portion from a total consignment, or flow, for the purpose of accounting or process control.• A sample can only be considered representative, if each and every increment collected, in each of the sampling stages, is representative.• Each particle of the sampling lot must have the same probability of being included in the final sample.• If both of the above conditions are met, then the final sample will be representative of the complete sampling lot.It is commonly known that in order to take truly representative and probabilistic sample, best practices indicate that:• The total stream should be sampled.• The sample cutter should intersect the sample at right angles to the flow.• The sample cutter should travel through the stream at a linear and constant speed and the speed deviations should be less than 5%."

Jan 1, 2016