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By W. Holding

Since the 1975 International Mine Ventilation Congress in Johannesburg there has been a trend in South Africa towards making the mine ventilation departments responsible for monitoring the total environment. This includes the taking of noise and illumination measurements and there is in fact a debate taking place as to whether the departmental title should be changed to 'Environmental Control Department'. The organisers of the 2nd international Mine Ventilation Congress have decided that noise and illumination will not be included as Congress subjects and 'Total Environment' includes only those facets which are open to debate at the Congress. The choice of mine is significant in that while most Congress papers from South Africa will be devoted either to coal mining or to the somewhat unique deep level gold mines, Prieska Copper Mine is a mine which can easily be identified with similar mines in many other parts of the world. The mine is situated some 750 km south west of Johannesburg and about 600 km north east of Cape Town. Current production (ore and waste) is about 340 000 tons per month and the total underground labour force is just over 2 000. The ore body is a massive sulphide, the main minerals being copper and zinc and the method of mining is sub-level open stoping. Daily average surface temperature conditions range from 85°F (29.5°C) dry bulb and 69.8°F (21°C) wet bulb in mid-summer to 42°F (5.5°C) dry bulb and 36.5°F (2.5°C) wet bulb in mid winter. The information presented in-this paper is limited to what can be gathered by mine ventilation staff as part of an on-going exercise and is obviously not as comprehensive as would be the case if a fully equipped research establishment were to become involved. The paper will be divided into three sections 1) Gases 2) Dust 3) Heat In each section statutory and/or other standards will be set down followed by a discussion of assessment and in some cases control methods.

Jan 1, 1980

By Frank E. Dalton, Forrest C. Neil

INTRODUCTION The Tunnel and Reservoir Plan (TARP) (Figure 1) was adopted in 1972 as the most cost-effective way to bring Chicago area waterways up to Federal and State water quality standards. TARP will significantly reduce pollution of these waterways and provide flood relief for Chicago and 53 adjacent suburban communities. These communities, covering an area of 971 sq km (375 sq miles), are at present served by combined sewers, which carry both raw sewage and stormwater. Because porous ground surfaces have been covered over in recent years by buildings, streets, and parking lots, stormwater runoff into sewers frequently exceeds the capacity of the sewers. When this happens, sewers back-up into hundreds of thousands of basements, and the overflows on the combined sewers discharge rainwater mixed with raw sewage directly into the area's waterways at 645 overflow points. The result is severe pollution of the waterways and flooding in 53 communities. During particularly heavy rains, overloaded rivers have to be relieved by opening the locks and allowing the polluted waterways to flow into Lake Michigan, the region's water source. Goals of TARP 1. PREVENT BACKFLOWS INTO LAKE MICHIGAN. 2. ELIMINATE WATERWAY POLLUTION CAUSED BY COMBINED SEWER OVERFLOWS. 3. PROVIDE AN OUTLET FOR FLOOD WATERS.

Jan 1, 1981

By M. J. Shulman

The exploration geologist is frequently confronted with the problem of allocating his resources, i.e., exploration effort, among various areas. Although geologic, financial and logistic considerations influence the allocations, no objective criterion is usually given which determines the optimal allocation. Maximizing the gain in information, subject to the constraint of a limited exploration budget, is used as the objective criterion to allocate reconnaissance effort. The information function, I(x), quantifies the expected gain in information, where x is the scale of exploration. To calculate the information function the following data are necessary: 1. The probability that an area contains a target must be estimated. 2. For each scale of exploration, four probabilities must be estimated: the probability that an anomaly is produced by the target; the probability that an anomaly is not produced by the target; the probability that an anomaly is produced by a barren area (false signal); and the probability that an anomaly is not produced by a barren area. Alternatively, the barren area can be replaced by other targets. To illustrate the allocation model, the optimal number of line kilometers/line spacing per area is determined for an aeromagnetic survey for iron in Egypt.

Jan 1, 1985

"History - How did you get into mining and involved with SME?Unlike many past presidents, I do not come from a mining lineage. I liked math in high school and believed I wanted to be an engineer. I told my math teacher that, and he laughed in my face. I believe that humiliation is what carried me through engineering school. At the time my ability to go to college relied on how inexpensive I could make it. My brother told me that there were a lot of scholarships in mining engineering, and I should apply to mining schools. As usual, he was right and I was off to the University of Idaho to study. My first summer break I got a job with Hecla at a mine in Arizona. I was a laborer on a shotcrete crew. I knew after the first summer that I loved underground mining, and I never considered changing disciplines. Looking back, I was working in miserable conditions (hot, humid), on a miserable job (shotcrete), where I got injured, and two summer student roommates died in a car accident on the commute home after work. I had every reason to hate the industry, as I had seen virtually everything bad about what we do. But I didn’t, I loved it. I said I was good at math, I never said I was smart.I joined SME in college because I was told to by the head of the mining school, Dr. Jack Hoskins. You did what Jack told you to do. I got involved because I went to an annual meeting and the papers in the underground sessions were terrible. I refer to bad papers as the “Tensile strength on cable bolts in sub-arctic regions on Tuesday” papers. Real snoring fodder. I don’t remember who I was complaining to, but they told me to quit my grumbling and fix it. So I chaired a session, and tried to get only good quality papers, something that has been my mantra for years with the Mining & Exploration Division. I also volunteered to help the local sections too. Then one day I woke up as president.What is your opinion of the health of the mining industry?The mining industry is in bad shape. Coal is under attack and will likely never recover to its former greatness. Our President has banned new coal leases, and the state of California is forcing people it does business with to divest their interests in coal companies. And that all happened in just in a few short weeks this January. Usually in America you get a trial before you are given a death sentence, but not with coal."

Jan 1, 2015

By Stuart Lister

"When MacLean Engineering chairman and founder Don MacLean got the first question from a minesite about the possibility of addressing ventilation limits through incremental fleet electrification, he was intrigued. It was back in 2015, and the MacLean scissor bolter was already diesel-electric (jumbo trailing cable), so it made sense to him that if they could engineer a battery drive system for the unit’s tramming cycle, they would have the inaugural electric vehicle (EV) MacLean unit.At that time, there were not any entirely diesel-free hard rock mines in existence on the planet, and that remains the case to this day — although the Borden project in northern Ontario is progressing toward that goal (see page 33). This meant there was essentially zero market demand for battery electric vehicles as well as a complete lack of battery technology to address the battery electrification of heavy haulage. Heavy haulage is the part of a typical mine’s mobile fleet with the largest footprint when it comes to diesel particulate emissions, greenhouse gases and wasted energy in the form of heat.Three years later — the wave of battery electrification that is currently picking up speed across the mining industry promises to hit full swing by the early 2020s when a slew of new build, diesel-free mines will start construction. But this movement toward emissions-free mobile fleets is not a completely new phenomenon. Instead, it is an updating of mining technology from a previous generation. What is going on now is the re-electrification of mining. Up until the 1960s, early generations of battery technology (lead acid) and electric locomotive systems were the norm for material and ore haulage in Canada and elsewhere.The thought of a coming paradigm change in mining was particularly pertinent to Don MacLean back in 2015, as he had been part of the era that ushered in the first generation of rubber-tire diesel equipment, when he was a divisional foreman with Inco in Sudbury in the 1970s. He was part of the operating team that was tasked to build a rail loop on one extraction level of the mine. At that time, events on the ground overtook the project, as diesel-powered mobile equipment became a viable option. Once the first diesel scoop was introduced at Creighton #3 shaft, it was clear what the power, haulage capacity and mobility could do for operations and that era of electric rail haulage underground was effectively over."

Jan 10, 2018

By S. J. Swan

A computerized on-line process control system designed to monitor and control the seven-cone copper precipitation operations at Kennecott Copper Corporation's Chino Mines Division in New Mexico has been continuously operating since April, 1972. The cone monitoring system consists of plant sampling components, process measurement instrumentation, on-stream X-ray spectrometer, control computer, typewriters for programming and for operating reports, foreman's communication console, and cone automation hardware. The system provides the following functions: (1) assays for copper and iron from ten process streams on a continuous rotating basis, (2) directs hardware to automatically flush and start up cone units based on measured performance variables, (3) provides continuous plant operating data and calculates metallurgical averages as well as production figures for shift and daily summaries, and (4) provides data logging capabilities. The system is very reliable and improves plant performance by increasing yields, reducing scrap iron consumption, and reducing operating manpower requirements.

Jan 1, 1975

By Robert E. Ennis

Several important economic variables must be studied when planning a major underground conveyor haulage system if the objective of tow cost haulage is to be met. The purpose of this paper is to call these economic factors to the attention of the mine planner and encourage their serious consideration. To illustrate, the importance that some of these variables hole for the mine operator who wishes to reduce costs and maintain sound belt haulage practice, these areas of discussion will be covered. 1. Selection of economical flite lengths. 2. Economics of wire rope frame vs. rigid frame conveyors. 3. How idler design affects conveyor costs. 4. Economies in drive design. 5. How speed affects conveyor cost. 6. P.V.C. vs. Neoprene belt - what savings? 7. Maintaining, conveyor investment through maintenance. 8. Miscellaneous factors affecting the cost of belt haulage.

Jan 1, 1967

By Mogens Henriksen

In the past decade, numerous urge scale drilling projects have made use of reverse circulation air lift methods. Reverse air lift pumping can be established by injecting gas into a column of liquid; the subsequently decreased density of the gas-liquid mixture allows atmospheric pressure outside the lift conduit to establish flow. The rate of flow can be controlled by varying the gas to liquid ratio. A typical reverse circulation air lift system is depicted in Figure 1. Allen1 has described a number of reverse air lift drilling projects. Although cited examples are generally related to large diameter holes, the method has seen use in other applications such as sand dredging, chemical pumping, water well pumping and continuous coring. One particular benefit obtained with enclosed reverse circulation drilling is elimination of lost circulation. The required air/water ratio for pumping at a given submergence and lift has been established experimentally by Gibbs2. His data, however, do not reflect sensitivity of flowrate to air/water ratio. Further, in Gibbs' work, air apparently is injected continuously along the column of water. This configuration differs from that used in reverse air lift drilling where air is injected at discrete points only. Gas lift theory has received considerable attention over the past decades. Orldszewski3 defined flow regimes in two phase flow. Griffith and Wallis4 determined relative velocities of gas to liquid. Two-phase flow has been studied extensively for oil transport in inclined and vertical pipes by Chierici et a15, Beggs and Brill6, and Gould, Tek and Katz.7

Jan 1, 1977

By S. Horton, F. L. Stanley, P. J. Bethell

Introduction The McClure River Processing Plant is located at McClure in Dickenson County, VA. The plant was originally constructed in 1979 as a 600 st per hour facility. The plant is fed by coals from numerous mines in the area as well as a major longwall mine onsite. Coal is processed predominantly for the metallurgical coal market. The original plant was comprised of three separate processing circuits incorporating a heavy medium vessel for the coarse material (+10 mm). Intermediate sized material (10 x 0.6 mm) was beneficiated in heavy medium cyclones, with the remaining fines (0.6 mm x 0) passing to froth flotation for upgrading. The products from all three circuits were combined prior to thermal drying and then stored in silos or ground storage prior to shipment to the metallurgical coal markets. A middlings heavy medium cyclone circuit was also present to rewash the vessel and primary heavy medium cyclone rejects. The original circuit is as shown as Fig. 1 (Editor's note: All figures are reproduced at the end of this paper.) In reasonably close proximity to the McClure Plant is the much older, less efficient Moss 1 Plant, (Chance cone, table, water only cyclone, froth flotation, Fig. 2), which prior to the McClure Plant expansion was processing considerable tonnages of coal. At that time, the McClure River Plant was processing coal at the maximum possible feed rate, and the Moss 1 Plant was finding increasing difficulty in maintaining the stringent quality specifications on its major metallurgical coal accounts. Given the fact that many of the feeder coals to Moss 1 could be moved with minimal difficulty and cost to McClure, an exercise was conducted to evaluate the potential of expanding the McClure Plant. This would result in transferring coals from Moss 1, thereby increasing yield, reducing operating costs, and enabling customer specifications to be met more easily. After evaluating many possible ways of expanding the McClure Plant, we eventually settled on an approach based on the idea of Gallagher at German Creek in Australia (Gallagher, 1986). Our objective was to increase plant capacity by removing the coarser size fractions (0.60 x 0.15 mm) from froth flotation and at the same time eliminating the finer fractions (1.25 x 0.6 mm) from the heavy medium cyclone circuit, thereby allowing these circuits and therefore the plant as a whole to increase its capacity. These size fractions (0.60 x 0.15 mm from froth flotation and 1.25 x 0.6 mm from the heavy medium cyclone circuit) would be treated in a new spiral circuit. After desired evaluation of the various circuit capacities, including desliming screen, clean coal filter and thermal dryer capacities, etc., it was concluded that we should be able to maintain high levels of processing efficiency in the existing circuitry while at the same time expanding plant feed rate from a nominal 600 st per hour to 1000 st per hour, thereby achieving the objectives The circuit that was finally settled on is shown in Fig. 2. Several unique features were incorporated in this circuit in an attempt to maximize processing efficiency and reduce maintenance costs. First, the idea of a single-stage spiral circuit was abandoned in favor of a two-stage circuit incorporating rewashing the primary spiral middlings in a secondary spiral (Bethell, 88). The spirals selected were Mineral Deposits Model LD4 units. It was felt, after much previous testing, that spiral middlings rather than being a true middling gravity fraction were in fact a combination of true middlings with a preponderance of misplaced light coal and high-density rock. Consequently the insertion of this material directly into either clean coal or refuse streams (per normal practice) would only lead to loss of efficiency. The operating philosophy behind the design of the circuit was to produce the purest coal and rejects possible by adjusting the spiral splitters. Misplacement of refuse into the clean coal and vice versa would be minimized by taking a fairly large middlings cut. By reprocessing this material (10%-15% of primary spiral feed) in a secondary bank of spirals the misplaced material in the primary middlings would be reprocessed and its probability of reporting to the correct stream greatly enhanced. To minimize fines loading on the spirals, fine aperture sieve bends were to be included. A further novel feature of the circuitry is the desliming/ dewatering system. A philosophy of accepting inefficiency but forcing it to work in our favor was developed. The dewatering screens (Linatex Combis) were chosen not for their ultimate screening efficiency but for their ability to remove slimes (tolerating a fair quantity of oversize in the effluent) and their enhanced maintenance characteristics. Any oversize passing into the effluent, together with the fine coal centrifuge effluent, would pass to classifying cyclones, the objective of which was to reject to overflow (and hence froth flotation) as many fines as possible (-150 µm) without running the risk of losing coarse (1.25 x 0.15 mm) material to oversize. Hence, by a process of producing a "slime free" screen product coupled with a "coarse free" cyclone overflow, sizing efficiency could be maximized. Obviously, recirculating load had to be factored into the Combi Screen design capacity. The spiral circuit as shown in Fig. 2 was installed at McClure River in January 1988. The spiral circuit efficiency was very high immediately, and, after the normal debugging, plant capacity has been increased to the point at which we are currently processing of the order of 1100 st per hour. Test program The performance of the spiral circuit has been evaluated by two major samplings of the entire new circuit, coupled with routine bi-monthly tests on all other major components of the plant circuitry.

Jan 1, 1992

By S. Behl

In the selective flocculation process, polymers with specific functional groups can yield highly selective adsorption and, therefore, high separation efficiency. Selectivity in polymer adsorption may also be attained by specific additives that inhibit the adsorption of the flocculant on some solid surfaces but not on others. Generally, these additives have a different chemical nature than the flocculant. In this study, the lower molecular weight fraction of the flocculant was successfully evaluated as a site blocking agent, leading to higher separation efficiency than obtained otherwise.

Jan 1, 1993

By Hasan Sevim

This paper summarizes recent developments in modeling of underground coal slurry haulage networks for determination of optimum design and operating parameters. The model presented here is based on a stochastic dynamic programming formulation, applicable in any typical room-and-pillar and/or longwall mining configuration commonly practiced in the United States. The formulation and the structure of the model is general enough to handle design problems involving more than one face and mining method. Given the stochastic operating characteristics and a system layout, the model can be used to determine the equipment configuration and operating regimes that minimize the overall unit cost of coal haulage.

Jan 1, 1983

By S. E. Phifer

The Haile gold mine was the largest gold producer east of the Mississippi River before 1942. It was the first gold mine in the Southeast to reopen following deregulation of the gold price by the United States Government. The Haile mine was also the first gold mine in the Southeast to use heap leaching and carbon recovery for gold production. Current production involves mining and heap leaching about 1.8 kt/d (1600 stpd). Carbon is used as a recovery medium. Due to the clay and excessive fines in the oxidized ore, agglomeration using portland cement is required before leaching. Agglomerated ore ranges in screen size from 50 mm (2 in.) to less than 75 µm (200 mesh). The agglomerating step combined with certain other conditions has enabled Piedmont Mining Co. to achieve recoveries of about 90% or better.

Jan 1, 1987

By Peter Krag, Rob Henson

It is well known that titanium and zirconium alloys offer superior corrosion resistance in the oxidizing sulfuric acid environments present in sulfide pressure leaching operations. The use of these materials is limited, however, due to their pyrophoricity; several accidents attributed to titanium equipment have been described in technical literature, and other, minor incidents·occur regularly1 • We describe an application of a commercial titanium alloy, Nb-55 Ti, with suitable mechanical properties, corrosion resistance similar to Grade 2 Ti, and featuring a significantly reduced field of ignition conditions

Jan 1, 1992

By Lewis L. Oriard

INTRODUCTION In recent years, there has been a trend in the direction of larger drilling equipment and larger diameter blastholes. Although this change has improved the efficiencies and reduced the costs in many operations, it has increased the potential for damage to underground openings. In addition, in many instances one now finds more sophisticated delicate instruments, automated control facilities, and a large variety of structures in proximity to blasting activity. The combined effect of larger-scale blasting activity and its proximity to various features of interest is such that there is an increased need for a more refined analysis of blasting effects and their control. BLASTING EFFECTS ON ROCK SURFACES The Breakage Mechanism In order to develop techniques for controlled blasting, one must first understand the features of the mechanisms by which blasting causes rock breakage to occur. These features have not been easy to demonstrate, mostly due to the difficulty in making tests and observations at the high stress levels and short time durations involved. When an explosive charge is detonated, the material surrounding the charge is subjected to a nearly instantaneous, very high pressure [on the order of 1.4 to 13.8 GPa (0.2 to 2.0 X 106 psi), depending on the explosive]. If the charge is coupled to "average" rock, this pressure will pulverize the surrounding rock for a distance on the order of 1 to 3 charge radii in hard rock, and to a greater distance in softer rock (this is also dependent on the type of explosive). As the pressure wave passes into the rock, high tangential stresses cause radial cracks to appear, and the nearly discontinuous radial stress zones gen¬erated by the shock front may cause tangential cracks to appear. The extent of these cracks depends on the energy available in the explosive, how quickly the energy is transmitted to the rock, and the strength properties of the rock. The discontinuous shock front is quickly dis¬sipated, but the expanding gases generate a longer-acting pressure. A compressive pulse travels to the nearest face or internal rock boundary where it is reflected in tension. The tensile strengths of most rocks are roughly 40 to %o of their compressive strengths, so the rock may now fail in tension whereas it may have been able to support the diminished compressive phase without failure. The ten¬sile deflection typically produces a failure described as tensile slabbing or scabbing. Laboratory experiments and field experience have pretty well established that several mechanisms are involved. These include (1) the classical case of tensile parallel slabbing when the pressure pulse is reflected at a free surface; (2) failure under quasi-static compressive loading (the shape is normally irregular due to discontinuities in the rock); (3) radial cracking under the action of tangential stresses at the periphery of the expanding pressure pulse; (4) peripheral cracking at the discontinuous shock front which is quickly dissipated; and (5) additional mass shifting due to the venting of the explosive gases. The first three items have received much attention in the laboratory and the literature. The complex effects of gas venting are difficult to test in the laboratory because of the difficulty in reproducing the many weak planes and discontinuities typical of most field conditions, which play such a prominent role in determining the behavior of the rock mass subjected to blasting. Unfortunately, gas venting effects can be pro¬jected to significant distances under certain field conditions, and are sometimes difficult to control. It is not unusual for gas venting to be the overriding factor in determining the final geometric shape and physical condition of the finished excavation. Sources of Damage For the purposes of this discussion, damage includes not only the breaking and rupturing of rock beyond the desired limits of excavation but also an unwanted loosening, dislocation, and disturbance of the rock mass the integrity of which one wishes to preserve (such as mine pillars, underground openings, etc.). The sources of damage include, of course, all those physical features of the rock breakage mechanism. Each of these effects must be limited to the desired zone of breakage and excavation if the integrity of the remaining rock mass is to remain undiminished. The primary zone of rock breakage usually can be controlled in the normal process of field experimentation to determine proper charge sizes and location for primary excavation. However, it frequently happens that there is damage from sources which are more difficult to account for in the design process, which are often overlooked. These are (1) the overbreak due to poor drilling control, (2) dislocation of rock (mass shifting) due to venting of explosive gases, and (3) loosening or dislocation due to the influence of seismic waves (ground vibrations). CONTROL OF ROCK BREAKAGE Importance of Geometry In studying the rock mass and blasting design con¬siderations, it is important to keep in mind the geometric relationships among charge size, shape, and position, and the physical features of the rock mass to be preserved. The features of principal interest are the external shape and position of the rock mass relative to blasting, and the position and attitude of any weak planes in the rock mass. The Sequence of Blasting and Excavation Events Unfortunately, there are too many times when the task of preserving delicate rock is considered hopeless, and because of this attitude, no further effort is ex¬pended towards caution or control. In such cases there is often a failure to recognize the importance of the se¬quence of the procedures. Attention to this can greatly reduce unwanted effects at minimum cost. Perimeter Control The requirements for perimeter control are highly dependent on the special needs of each particular proj¬ect. The desirable degree of control is a highly variable

Jan 1, 1982

By N. Parra, M. N. Herrera, T. Vargas, B. Escobar, C. Gonzalez

originally published May 1998, Vol. 15, No. 2, pp. 15-1 9 Discussion by G. Rossi, University of Cagliari Reply by T. Vargas, University of Chili

Jan 1, 2000

By H. L. Ford

Flocculant testing should be initiated for economic or performance reasons. When the decision has been made to test, the laboratory can provide valuable information concerning the various products under consideration. Properly conducted laboratory tests can determine: 1. If two flocculants are needed to achieve clarity or density. 2. Ease of mixing. 3. How quickly the material goes into solution. 4. Stability of prepared f locculant solution. 5. Stability of the floc formed. 6. Amount of mixing required for proper floe formation. 7. Optimum flocculant concentration. 8. Optimum pulp density. 9. Approximate location of the point of addition. 10. Single or multiple addition points. When a flocculant shows promise in the laboratory, a plant test should be scheduled. During the plant trial, arrange for normal conditions and start testing with a crew that is most familiar with the unit operation where the flocculant will be applied.

Jan 1, 1986

By Y. Ye

Induction times for a variety of minerals have been measured at a particle bed. Electrostatic repulsive forces between bubble and particle generally are of secondary importance in determining the hydrophobic state; nevertheless, the shortest induction times are measured at the isoelectric point of the solid. More importantly, the study shows that the film-rupture mechanism at a polished surface might be different from that at a particle bed. The induction time measured at a particle bed, besides being dependent on the surface chemistry of the system, shows a definite relationship to particle size and density. Theoretical analysis suggests that such a measured induction time at a particle bed should properly be defined as an attachment time which consists of the induction time and the film-displacement time. Thus one portion of the measured attachment time is the induction time, the time required to thin the water film between the particle surface and the gas bubble to a critical thickness so that rupture of the film takes place ('1)' The other portion of the measured attachment time is the time required for the film to be displaced to such an extent that the attachment is stabilized with respect to the upward motion of the bubble and the downward gravitational force acting on the particle ('2)' Further, the present study illustrates that '2 is related to the hydrophobic character of the surface, the rate of film displacement after rupture, the upward velocity of the captive bubble, and, most importantly, the particle size and density.

Jan 1, 1988

By Ewan Wingate, Ranjit Prasad, Yanjun Liu

The phosphorus journey begins with the extraction of primary phosphorus in the form of phosphate in apatite through openpit mining and, in some rare cases, underground mining methods. The ores are processed in beneficiation plants to remove impurities before the phosphate rock concentrate is either sold on the open market or converted into phosphoric acid in downstream chemical production facilities by the wet acid process or thermal phosphorus routes. These can in turn be converted into fertilizers, as well as used in the food and electronic industries. The advent of the EV battery has given rise to a new use for purified phosphoric acid in the production of lithium ferro phosphorus (LFP) cathode material for EV battery cathode assemblies. The production of LFP relies on raw materials such as lithium carbonate, lithium hydroxides, iron salts and purified phosphoric acid.

Feb 1, 2024

By E. Valdiviezo, J. F. Oliveira

Adsorption of residual flotation reagents onto equilibrium fluid cracking catalysts is a promising method of purification of flotation process water. In the present paper, adsorption of sodium dodecyl sulphate (SDS), dodecyl ammonium chloride (DAC) and sodium oleate onto a spent catalyst from petroleum industry was studied by analysing the residual concentration of the surfactant after contact with the zeolite catalyst. The adsorption of the DAC was rather low but SDS and sodium oleate presented a high affinity for the catalyst surface. The loading capacity was 4.2 kg/ton for SDS and 5.5 kg/ton for oleic acid. After the treatment of the loaded catalyst with a HCI 1 N solution these surfactants are desorbed and the catalyst may thus be regenerated. This would be an additional advantage to its low cost, not to mention its condition as a discarded product and its availability in large tonnages.

Jan 1, 1995

By Ian P. G. Hutchison

12.1 INTRODUCTION This chapter deals with the tools required to design leach operations to minimize spillage from leach pads and ponds and erosion damage during flood events or prolonged wet periods. It outlines methods used to design for prolonged dry periods when water shortage can be a problem. Seasonal operational aspects such as winter shutdown and coping with spring snowmelt periods are also discussed. General criteria useful when designing pregnant and barren solution ponds are also outlined. The aim of these notes is to provide designers and operators with a simp1ified approach to developing design parameters which make effective surface water management easy to achieve without resorting to extensive or elaborate analyses. Section 12.2 briefly outlines the types of problems associated with wet climates and floods, as well as dry periods. Determination of flood design parameters is discussed in Section 12.3. Circuit water balance and pond sizing are outlined in Section 12.4. Pond design considerations are included in Section 12.5. Worked examples are included in Section 12.6. 12.2 RAINFALL/RUNOFF PROCESSES There are two types of rainfall-runoff processes that are important when designing heap leach facilities. The first of- these is the short-term, intense rainfall or snowmelt events that occur over a period of a few minutes or hours, causing flooding that can lead to erosion damage and overtopping of ponds and containment dikes. Specific problems that can manifest themselves during these events include: • Washout of access roads; • Damage to containment dikes; • Flood water contamination of circuit water; • Damage to process water ponds by perimeter erosion or overtopping and erosion; • Loss of process circuit fluid due to breaks in containment dikes or process water ponds; and • Erosion of leach pile and consequent sediment contamination of process fluid. Other types of rainfall -runoff processes that could cause problems are the long-term-(generally months-long) wet or dry periods. Extended wet periods

Jan 1, 1988