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By Bryan C. Smith, Duane R. Skidmore

Volumetric mass transfer coefficients and gas holdups were measured in a concentric tube airlift reactor designed for the microbial desulfurization of coal. The slurries were comprised of an acidified basal salts solution containing thirteen different weight percents of coal (74 µm Ohio #1) at three temperatures. An enhancement in the mass transfer coefficient, KLa, with respect to that measured in pure solution was found at weight percents of 5 (volume fraction solids, ES = 0.035) or less, the greatest enhancement being as great as 37% at approximately 2 weight percent (ES = J 0.014). At higher solids fractions, the mass transfer coefficient decreased with further solids additions, decreasing by as much as 91% at 40 weight percent coal (ES = 0.315). KLa increased with temperature at all solids concentrations, the greatest increase being 392% at 72°C vs that measured at 30°C. Gas holdup, EG decreased with all increases in solids loading by as much as 65% and increased by as much as 67% with temperature. KLa and EG were correlated with operating conditions separately, and the separate correlations combined to yield overall correlations for the mass transfer coefficient and for the gas holdup. The correlations are suitable for inclusion in system models devised earlier for microbial coal desulfurization processes, and may be used for design, operation and cost estimation for such systems.

Jan 1, 1989

By S. J. Ripke

To pelletize fine moist magnetite concentrate, a 40% water slurry must be dewatered to about 10% by filtration, before it can be agglomerated into pellets. Slurry pH, typically ranging from 8 to 11, gives the magnetite particle surface a strong negative charge and thus causes two adverse effects. First, this negative charge attracts calcium and magnesium cations, which strongly retard the effectiveness of the bentonite clay binder added during agglomeration. Second, a repulsive force created by the negative charge functions as a dispersant that reduces filtering production rates. Tests were conducted to remove these cations during filtration, by rinsing the moisture remaining in the filter cake with a small amount of water adjusted to pH 6 with HCl. Laboratory work was also conducted at Michigan Technological University (MTU) and at Cliff’s Mining Services Company (CMSC) to corroborate the plant tests. In some cases HCl caused filter bag blinding, therefore CO2was investigated to reduce pH. The CMSC lab tests showed that using carbon dioxide to reduce slurry pH from 7.6 to 7.0 improved filtering production rates by 11%. Plant-scale filtering rates were improved by 23.7% when carbon dioxide addition reduced the slurry pH from 8.6 to 6.7.

Jan 1, 2004

By Osvaldo A. Bascur, J. P. Kennedy

Companies have installed powerful desktops for their personnel and instrumentation and control systems in their plants. These desktops are, in many cases, connected to a company intranet. Still, process engineers have to obtain their data manually. Engineers use process calculations from manually calculated averages from the plant; field operators collect equipment data on log sheets; and maintenance engineers collect critical information on log sheets. All of this information resides in individual machines. What are the strategic tools that will enable collaboration between them? How can operators, engineers, and managers access plant information to proactively increase their effectiveness in process troubleshooting, plant debottleneclung, aligning with business strategic and customer demand, satisfying environmental and safety regulations, developing capital projects, and implementing control strategies? A nonintrusive environment at the desktop is required to provide the process information to these workers. How can value be added to MS Windows technologies with the legacy systems at a minimum cost? There is no straight answer; however, there is a proven framework to leverage the large investments in new technologies. Objects and components are changing the way everyone relates to their computer and networks. Three examples will be described to demonstrate paradigm change. Today, process engineers can access data at the required level of detail for analysis of critical process variables at their desk or remotely. 1. Process Troubleshooting and Analysis: The engineer can develop an inferential calculation, trigger a process advisor to deter- mine the behavior of the units for the last day, and get the population of a set of batches (heats, blocks, rolls, sheets, etc). 2. Process Control and Optimization: The engineer can connect to a process simulator at steady state or a dynamic simulator of the process to evaluate new control strategies or process unit line-ups and use the process simulator as a process observer for fault diagnosis. 3. Collaboration with Accounting and Maintenance: The engineer can review reconciled data and the process mass balances, suggest maintenance cleaning or recalibration of flowmeters, and evaluate key control performance of all advanced controls.

Jan 1, 1999

By Takeshi Tanaka, Yasuhiro Komamura, Yuusaku Tominaga, Takayoshi Iwamoto

In order to assist better countermeasures for ventilation control in normal/abnormal condition of mine ventilation network in real time, branch relation table derived from a macroscopic characteristic of ventilation network is introduced in this study. The main results in this study are as follows; 1) One of macro characteristics of a ventilation network, as a relation between airflow rates in two branches chosen arbitrarily, is specified under the change of aerodynamic resistances in a branch. Airflow rate in a branch can be estimated by airflow rate in other branch changing aerodynamic resistance by using empirical formula. The empirical formula by computer simulation of the Horonai coal mine, Japan is considered to be a one-valued function with monotone or extremums. 2) A branch relation table shows the macro characteristics, mentioned above, of all the set of two-branch combinations in a network. Elements in the table give both information of control possibility range of airflow rate and total number of extremums in an empirical formula. 3) It is important that when aerodynamic resistance change in a branch is estimated by measuring airflow rates in two typical branches, the two branches should be chosen from branch combinations with monotonous relation in the branch relation table. 4) A flexible expert system to assist ventilation control in the specified branch in real time has been developed by using a branch relation table for a ventilation transfer diagram of the specified branch, such a coal face and an advancing face. A fuzzy reasoning is utilized in the recognition of the safety factor, methane concentration, in the system. And when conviction degree in recognition for methane concentration at the specified branch is too low, the system searches for other branch combinations in the branch relation table stored in the system, to use other ventilation transfer diagram of the specified branch. When a needed ventilation transfer diagram is not stored in the system, the expert system asks automatically the ventilation simulation from other computers linked to the main computer automatically. The system repeats consultation until conviction value of safety in the specified branch approached

Jan 1, 1993

By J. C. Willett, J. R. Sanfilipo, S. M. Podwysocki, P. D. Warwick

The U.S. Geological Survey is concluding an assessment of the major coal regions of the country. In this program, the quantity and quality of coals that are expected to be mined during the next 30 years are characterized. For the Gulf Coast region, the evaluation includes reviews of the stratigraphic setting, coal resources, and the quality of the Cretaceous to Eocene coals in four coal-producing areas. The coal-bed methane potential for these areas will also be evaluated. The results of these efforts will be a series of digital maps, text, and tables that will be published in a CD-ROM format.

Jan 1, 2000

By John H. Archibald, Arthur L. Miller, George A. Savanick

As part of its continuing research on selective mining, the Bureau of Mines has made progress toward developing a tool capable of remotely extracting hard minerals through a borehole. As the successor to the successful borehole miner, which extracted soft materials through a straight borehole, this new device has several innovative features: 1) it can propel itself in and out of an 8-inch borehole; 2) it can cut hard rock with an abrasive jet and transport the cuttings to the surface; and 3) it can negotiate deviated boreholes--the feature that enables it to follow a vein and extract only the values. This paper describes the development and feature testing of the reamer/miner.

Jan 1, 1991

By Erhard M. Winkler

The rapid decay and disfiguring of stone monuments in urban and desert rural areas has challenged conservators to protect stone surfaces from premature decay. They attempt to halt the natural process of stone decay and possibly to restore the original strength lost mostly by chemical weathering and the loss of binding cement. Ageneral solution is not possible because the physical and chemical characteristics must be considered for different stone types. The failures of stone preservation and restoration are greater in number than the cures. The need for repair of stone decay goes back to evidence of Roman replacement of decaying stone. The presence of excess water in buildings has long been recognized. Moisture tends to enter masonry from air in humid climates, a most important but often underrated factor (Fig. 1) suggesting that sealing should be the answer. Undesirable staining and efflorescence result in accelerated scaling. Today, the great variety of chemicals available to the modem conservator for sealing. consolidating, or hardening stone fall into two very different categories: surface sealers and penetrating stone consolidants, or a combination of both. SEALERS Sealers develop a tight, impervious skin which prevents access of moisture. Surface sealing has saved monuments from decay by eliminating the access of atmospheric humidity. Pressure tends to develop behind the stone surface by moisture escape. Efflorescence, crystal growth action, and freezing can cause considerable spalling (Anderegg, 1949). Flaking results when moisture is trapped behind the sealed surface. Yellowing and blotchiness are also frequently observed. The following sealants are in common use today: linseed oil, paraffin, silicone, urethane, acrylate, and animal blood on stone and adobe. Extensive cracking and yellowing has resulted soon after application. In the past many such treatments have created more problems than cures: 1. Linseed oil and paraffin have been in use for centuries. Embrittlement and yellowing occur rapidly because these are readily attacked by solar ultraviolet radiation. 2. Animal blood as paint has temporarily waterproofed adobe mud and stone masonry. The origin of blood paint has a religious background rooted in the Phoenician and Hebrew cultures. Instant water soluble dried blood can substitute for fresh blood. Winkler (1956) described the history and technique of the use of blood. 3. Silicones have proven very effective and are long lasting. In contrast, acrylates, urethane, and styrene are generally rapidly attacked by UV radiation (Clark et al., 1975). Sealing of Different Rock Types Granitic rocks have a natural porosity traced to 4.5% contraction of quartz, during cooling of the parent magma, compared with only 2% contraction of all other minerals; protection against the hygric forces may require waterproofing of granite in some in- stances. The Egyptian granite obelisk in London is an example. Soon after its relocation from Egypt to London, Cleopatra's Needle was treated, in 1879, with a mixture of Damar resin and wax dissolved in clear petroleum spirit; surface scaling became evident after half a year of exposure to the humid London atmosphere. The treatment of the ancient granite monument from Egypt has denied access of high relative humidity (RH) in London to the trapped salts inherited from the Egyptian desert and has protected the monument from decay (Burgess and Schaffer, 1952). The sister obelisk set up in Central Park, New York City, has fared less favorably because similar treatment was done too late, only after the salts hydrated and hundreds of kilograms of scalings disfigured the obelisk surface (Winkler, 1980). Surface coating of other common stones may be needed. Crystalline marble absorbs moisture from high RH atmospheres: dilation may ensue when curtain panels bow as the moisture starts to expand during daily heating-cooling cycles. A good sealer may prevent the moisture influx provided that no moisture can enter from the inside of the building. Limestones, dolomites and all carbonate rocks are subject to dissolution attack by rainwater, especially in areas where acid rain prevails (Fig. 2). The interaction of sulfates in the atmosphere with the stone can be halted by waterproofing to avoid the formation of soft and more soluble gypsum. The stone surface attack can be diminished if nearly insoluble Ca-sulfite crusts can form, instead of Ca-sulfate. Replacement of fluorite or barium compounds at the stone surface acts as a hardener, rather than a sealant. Sandstones have generally high porosity and rapid water travel can occur along unexpected routes and from any direction. Any surface sealing may do more damage by scaling and bursting than if the stone is left without treatment. Sealing of sandstones is therefore not advised at any time. Testing the efficiency of sealants: Several authors discuss waterproofing materials, silicones, urethanes, acrylates and stearates, as to their water absorption, spreading rates of water on the treated surface, water vapor transmission, resistance to efflorescence, and general appearance (Clark et al., 1975). De Castro (1983) measured the angle of contact of a microdrop (0.004 cm3) on a stone surface as characteristic of the wettability. Laboratory tests and limited field performance are described by Heiman (1981). The crest of a Gothic sandstone arch, which was sealed with silicone,

Jan 1, 1994

By M. C. Mound

A recent development using XRD techniques, a unique fixed detector, specifically permitting full mineralogical information simultaneously for the first time, specially designed sample preparation and presentation system and Rietveld codes provide a continuous real- time analysis on the true contained mineral polymorphic composition of powder streams such as ore materials, cement, ground clinker or any other mineral stream conducive to XRD analysis. There are several COSMA systems currently operating in the US, Canada, Italy and Australia, proving service and reliability of this concept. The mineralogical information generated continuously in real time is used for automated efficiency, product quality and reduces costs. Quantitative Phase Analysis information is transmitted to the plant DCS via Modbus over RS422 or ethernet. Some limited information is stored in the on-board computers for optional future use at the operator?s option.

Jan 1, 2010

By Jr. Smith

Industrial minerals are just other rocks, except for the unique characteristics that make them useful in an industrial process. There is not a ready market for this type mineral and one or more uses must be developed to sustain production. The name "olivine" is a generic term used to indicate a group of orthosilicate minerals in a solid solution series, with forsterite (Mg2SiO4) and fayalite (Fe2SiO4) as endpoints. Since neither is found alone in nature, the mineral is always a combination of the two. The commercial deposits are high in magnesium and on the high end of the melting scale in the series. The name comes from the olive-green color.

Jan 1, 1992

By Y. Gonzalez

The reaction kinetics of sulfuric acid leaching of brass foundry flue dusts were studied. As received flue dusts were separated into two size fractions, a coarse fraction (median size 103.5 microns) and a fine fraction (median size 3.4 microns). Experiments were performed on both fractions al-though most results are reported for the coarse fraction. Leaching experiments were conducted in a stirred reactor to determine those factors which govern the kinetic response of the sys-tem. The kinetics were followed by determining the increase in the concentration of dissolved copper with time. The effects of temperature, concentration and oxygen partial pressure on the rate of copper dissolution were examined. In addition, reaction residues were examined by SEM, EDAX and X-ray analysis. An activation energy of 4.8 kcal/mole (20.08 kJ/mole) was calculated. The rate was found to be significantly dependent on oxygen partial pressure and acid concentration. The order of the reaction with respect to oxygen partial pressure and hydrogen ion concentration was approximately 1.50 and 0.37, respectively. Results indicate that the dissolution reaction is limited by diffusion and can be described by the following mathematical expression where ~ is fraction of copper extracted in time t

Jan 1, 1988

By George A. Lawrence

A new super-large 100 m3 (3500 ft3) pneumatic mechanical flotation cell is now available to meet today's mineral processing challenges. Several innovative design concepts represent a marked departure from conventional flotation cell designs. The radial discharge from the pump action rotor and the overhung vane type stator is contained in a conical bottom round tank with no dead comers. Peripheral launders collect froth overflowing the entire circumference of the tank and these launders are of a hexagonal design permitting cells to be nested together in a honeycomb fashion. The mechanism drive is either a customized right angle gear reducer or a conventional Vee belt drive. Both drive systems are available with an optional variable frequency control system that permits infinite speed adjustment of the rotor in each flotation cell or group of cells. Results of side-by-side comparative testing between three major manufacturers of super-large pneumatic mechanical flotation cells are discussed. These results were obtained at a large copper concentrator in Chile during several weeks of commercial scale testing.

Jan 1, 1995

By D. W. Dew, D. M. Miller, P. C. van Aswegen

The bacterial oxidation (BIOX®) process for pre-treatment of refractory ores for gold recovery is marketed by BIOMIN Technologies S.A. The process was originally developed by GENMIN who are still providing testwork, design and commissioning assistance to BIOMIN. This process offers an alternative to the more conventional roasting or pressure oxidation techniques with the following advantages: • Greatly reduced capital costs for small to medium size plants. • A relatively flexible and easily controllable process requiring relatively unskilled labour for operation. • Improved gold recovery. • A process that is environmentally friendly. The principal disadvantage of bacterial oxidation is the relatively slow kinetics compared to pressure oxidation and roasting, a plant residence time of 4 to 5 days typically being required to obtain complete liberation of gold from refractory sulphide minerals. Bacterial activity is also slow to recover from disruptions such as air supply failure or contamination by toxic species such as cyanide. Optimum plant performance depends on judicious management and sound training of operators.

Jan 1, 1993

By Y. J. Wang

The use of controlled recirculation began in the early 1930s. Although this method has been applied in many mines since then, a generalized comprehensive network analysis is still lacking. This paper presents a unique approach in which the ventilation network with a controlled district recirculation is divided into two subsystems: a main subsystem and a recirculation subsystem. The subsystems are analyzed individually, and the results and their relationships are then integrated into discussions of the total ventilation system. The analysis of the recirculation subsystem is facilitated by introducing a nondimensional parameter (A), which represents the ratio of the air quantity for the working face to that for the subsystem. As a result, far and regulator pressures and air power for various recirculation arrangements can be effectively expressed as a function of and the subsystem air quantity. Numerical examples are included.

Jan 1, 1997

By J. C. Rhodes

The demand for good white minerals for many industries including paint and plastics have made it necessary to import high grade industrial minerals from various parts of the world. Some of the calcium carbonate, barite and talc minerals are from China, Mexico, Jamaica and Haiti. These materials can be processed by custom processors. The custom processor can provide a service to the Industrial Mineral owner. The imported materials can arrive in various feed sizes from lumps (3"-6") down to 325 mesh. The materials can also be in various size shipments or container loads. The economics for importing should be investigated thoroughly. The two factors just mentioned can influence the quantity of material to be processed. These two factors can also influence the total cost for each end product.

Jan 1, 1989

By R. V. Ramani, R. Bhaskar

The results of an experimental and theoretical research study into the spatial and temporal behavior of dust in mine airways is summarized. Experiments were performed in mine airways under both controlled and normal operating conditions. The controlled experiments included the documentation of the concentration and deposition patterns for two types of dust under three different velocities. Real-time dust concentration data were obtained using real-time aero- sol monitors (RAM-I) to determine the dispersion coefficient in a mine airway. On the theoretical font, a convection diffusion model of the dust flow phenomenon in mine airways was developed considering dominant mechanisms affecting dust transport and deposition in mine airways. Mechanisms modeled include turbulent and gravitational deposition, coagulation, and dispersion. In this paper, comparative analyses of results (8 the controlled experiments with the predictions of the mathematical model are presented. In addition to the overall validity, the adequacy of the individual components of the model, such as deposition in the total and respirable range, and dispersion are examined in light of the experimental observations. The experimental data from controlled experiments compared more favorably with model predicted results for similar conditions as opposed to the comparative analysis results for in-mine experiments. Specifically, the model predictions for an 800-m stretch of a mine airway reveal some significant differences from the behavior noticed in the mine. The deposition was lower than that predicted by the model. Consequently, concentrations were higher than those predicted by the model. The implications of these and other findings for further investigations are discussed in the paper.

Jan 1, 1987

By M. S. Kabibwa, E. K. C. Chanda

In planning for the future, Nkana Division deepened the Mindola sub-vertical shaft which was commissioned in 1994 in order to access the 30 Mt of ore between 1274 and 1570 m levels. The Nkana Synclinorium which is estimated to contain 250 Mt of ore is being accessed from the vicinity of Central Shaft. These areas are being planned with the intention of maximizing the use of computers in geological modelling and mine design so as to overcome the inadequacies of manual planning techniques. As a result, there is an increased demand for quality output from the computerized mine planning system the division has been developing over the last few years. A new workstation comprising the Hewlett Packard HP 71 51100 MHz and a CRX graphics monitor was acquired in 1995 together with the LYNX (version 3.09 and version 4.0) Mine Modelling System. Currently the workstation is being used for geological modelling and mine design for the Zerofold at Central Shaft and the Mindola mining at depth project. AutoCAD and Mine Works Planner have been added to the sys- tem configuration. Mine Works Planner is likely to replace Lo- tus123 for mine scheduling tasks. Computer applications in the area of mine planning at Nkana has led to considerable time savings and improved efficiency in areas formerly performed manually and has allowed speedy processing of data that would otherwise have proved too time consuming. Nevertheless, a lot of work still needs to be done in the areas of geostatistics, stope design and financial modelling of mining options. For the foreseeable future computer based planning will operate parallel to manual methods until such a time as sufficient personnel are proficient in the use of computer systems. This paper describes the program of computerization at Nkana Division, reviews current applications and the benefits and experience gained and discusses the promise of current and future developments.

Jan 1, 1996

By James L. Evers

Introduction There is a continuing search by government and industry for new mining methods that increase production, improve the working environment, reduce labor intensity, enhance recovery effectiveness, improve the reclamation process, streamline the flow of material, and reduce the unit cost. Hydraulic extraction and transport methods have outstanding potential in several of these areas. For example, hydraulic fragmentation produces a significant reduction in respirable dust. The inherent simplicity of hydraulic mining equipment and the resulting high reliability are recognized. Tool wear can be virtually eliminated. There is great flexibility in the size, shape, and orientation of the mineral deposit that can be mined. The cutting, gathering, and transport operation can be controlled remotely, providing more safety for workers. The threat of tool sparking and the resuiting dust or gas ignition are also eliminated. Although hydraulic mining was introduced in the US before the turn of the century, it has not gained the degree of acceptance found in other countries such as the Soviet Union, China, Germany, and Canada. The Hydraulic Mining Research program, initiated by the US Bureau of Mines in 1958, and the subsequent research by others has provided much of the basic technology required to spur the development of these methods into a viable extraction alternative. This article updates the development of hydraulic mining in the US. Particular attention is paid to monitor mining, the long-wall hydrominer, borehole mining, and the semi-autonomous mining system. Whenever the particular mining method is also being developed in other parts of the world, a brief description of the world-wide state of the art is given. Finally, allied studies designed to optimize these mining techniques are described. Hydraulic Monitor Mining Since 1958, the US Bureau of Mines (USBM), the Department of Energy (DOE), and other government agencies have funded more than a dozen programs to investigate the potential of hydraulic monitor mining. For this method, water is directed on the coal face from a monitor nozzle. Sufficient velocity is used to cause local fragmentation (Fig. 1). Coal particles are washed from the face to a trough. They are then flumed to a collection point. Oversized particles are directed through a breaker and then into the troughs. Monitor field tests were conducted in the 1960s in bituminous and anthracite coal at the following locations: • Rosylin No. 9 mine, WA (Nasiatka and Badda, 1963); • Rosylin No. 10 mine, WA (Price and Badda, 1965); • Sugar Notch mine, PA (Buch, 1964); • Thomson Creek mine, CO (Palowitch and Malinka, 1964); and • West Lebanon, PA (Fowkes and Wallace, 1968). In 1975, Ingersoll-Rand Research Inc. was awarded a two-year USBM contract to develop a continuous coal mining system using water jet fragmentation and

Jan 10, 1984

By W. J. Halvorsen

Means for minimizing the disadvantages of thermal drying are suggested. The other ap¬proach of substituting other techniques in place of thermal drying is also discussed. Recent devel¬opments in fine coal screening dry down to 3.2 mm (0.125 in.) and 2.0 mm (10 mesh) offer an econom¬ical means in certain cases.

Jan 1, 1988

By D. V. Professor Keller

The production of premium coal-based fuels (<3% ash) and ultra clean coals (<1% ash) using the process of selective agglomeration requires proper selection of raw coal, rough preparation procedures, milling equipment, product coal size distribution, water purity, agglomerants, agglomeration equipment and operational procedures. Each of the variables can contribute a small fraction to the impurity load in the product coal or limit the ability of the process to separate mineral matter-free coal. Each of the variables and their importance will be examined from data produced at the bench by batch and continuous agglomeratons as well as the results from pilot plant and tonnage production units. The results are discussed which have indicated that some standard commercial coals can be produced with ash contents as low as 0.2 % ash (batch/bench) and several tonnage lots of 0.6% ash in as 200 lb/hr pilot plant. In most cases iron pyrite released from the coal matrix and with proper pH control is rejected from the product coal agglomerates.

Jan 1, 1995

By B. G. McNish

Neutron Activator Laboratory Analyzer used for Rapid Analysis for Ore Blending, Stripping, and Mine Control BAUXITE is a rock and not a mineral. Since it is a rock, its mineral content varies depending upon the parent material, the topographic location of the deposit and the severity of the weathering and oxidation processes which produced it. At Bauxite, Arkansas the major mineralogical constituent of the bauxite is gibbsite with ~IL- purities of silica, iron oxide, and titania minerals. Minor amounts of other minerals are found. Chemical composition varies from 45% to 60% alumina, 5% to 25% silica, 1% to 15% ferric oxide, and 1% to 3% titania. The Arkansas bauxite region is located entirely within the north- central area of the West Gulf Coastal Plain near the northwestern boundary with the Interior Highlands. The region trends northeast-southwest and is about 42 kilometers long. It is divided into two districts; one in Saline County and the other in Pulaski County. The Saline District is the most important since it has produced most of the bauxite. This district is located at Bauxite, Arkansas and the deposits are found around the flanks of the Saline Dome. It is roughly square-shaped and is about 190 square kilometers in area. The source rock for the deposits is a Late Cretaceous, grey, nepheline syenite.

Jan 1, 1979