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By Linge HG, Klauber C

The key element in the carbon-in-pulp process for gold processing is the loading of dissolved Au(CN)2 from solution onto activated carbon. The mechanism and kinetics of this step have been examined by solution adsorption-desorption and X-ray photoelectron spectroscopy for both coconut derived activated carbon and peat-based activated carbon. The results show that these carbon types have the same mechanism and kinetics of adsorption. There is no contribution to the bonding from carbon-oxygen functionalities on the carbon surface, as has been invariably supposed in all previous theories for the mechanism of the reaction. It is shown that Au(CN)Z is reversibly adsorbed intact on and parallel to the graphitic planes of the carbon with the formation of a weak carbon-gold n-donor bond. The kinetic measurement of carbon gold loading reactivity is discussed and use of the Murdoch equation for this test is critically assessed.

Jan 1, 1989

By Pollard D. M

In the batch phase disengagement test, an organic and an aqueous phase are mixed together for a known period to produce a dispersion which may be either organic continuous (aqueous phase droplets) or aqueous continuous (organic phase droplets). The continuity of the dis- persion will depend upon the method of init- iating the dispersion, the conditions under which the system is operating, such as temper- ature and impeller speed, and the properties of the liquids, such as viscosity, inter- facial tension and solute content. Once the dispersion has been agitated for the required period, the agitator is turned off and the position of the coalescence interface and the sedimentation interface recorded as a function of time. This will produce a plot similar to Figure 1, where the overall dir- ection of travel of the droplets of dispersed phase is away from the sedimentation inter- face and towards the coalescence interface where the droplets coalesce with the homophase.

Jan 1, 1987

By Hashimoto H, Arai Y, Sikong L

For utilization of solid carbonaceous materials produced in processes of cracking heavy oil, such as petroleum pitch, as powder fuel, it is necessary to develop a process for fine grinding of these materials. It is known that grinding' additives are effective for fine grinding of cohesive and heat-sensitive materials such as petroleum pitch, therefore in this study, effective methods for fine grinding of petroleum pitch with some grinding additives were investigated. Experiments were carried out by using comminution kinetics based on mass balance. From the results of the investigation by using a batch ball mill, it was found that sodium stearate, calcium stearate and carbon black were effective additives for the improvement of grinding efficiency. Optimum concentration of the grinding additives was also found to give a required particle size of products. Concerning to the action mechanism of these additives, it is considered that the additives which adhired to, or were absorbed on the surface of petroleum pitch particles not only prevented cohesion of the particles but improved dispersion of the particles as well. From the results of the investigation by using a laboratory screen mill which is a representative built-in classifiered impact crusher, carbon black was found to be an effective additive for the improvement of grinding efficiency and mill performance. It is also considered that the improvement of classification efficiency by carbon black affected the mill performance.

Jan 1, 1987

Better quality at lower cost is today's formula for remaining competitive in a world market. For an integrated steel company, high quality low cost steel production must originate before the blast furnace. In 1979, when U.S. Steel initiated a Quality Management Program throughout its steelmaking operations, efforts began at the coal, ore and flux mines. The objective was to improve the quality and reduce the variability of the critical parameters for steelmaking raw materials, to get the blast furnaces, and subsequently the melt shops, under optimum control. The general details of U.S. Steel's Quality Management Program are discussed and how it was used to promote the desired improvements in steelmaking raw materials. Some of the outstanding results obtained by the cooperative efforts between the mines and the steel plants are reported. The lessons learned by U.S. Steel were through upgrading existing operations and facilities. These principles should now be applied to new projects and the benefits of good quality management should commence from the time new projects are Commissioned.

Jan 1, 1986

By R Lau

In recently completed road tunnel projects in Queensland, such as the Airport Link and the Clem7 tunnels, there is a smoke duct running along the roof of the carriageways to extract smoke in case of fire. In New South Wales, no road tunnels have a smoke duct. In the Melbourne City Link tunnels, there is a small smoke duct running along the roof. All of the tunnels are safe as claimed by the designers and authorities. However, there is significant cost associated with providing a full size smoke duct compared with no smoke duct. This paper is going to present a comparison of the road tunnel safety with a smoke duct and those without one from a risk perspective. It further discusses the cost-effectiveness of such provisions and whether similar levels of safety could be achieved without a smoke duct.CITATION:Lau, R, 2014. Smoke duct or no smoke duct for road tunnels, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 83–86 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By Cutler JL

At the present stage of the Rundle oil shale project planning, with depressed world oil prices, early development of the resource is unlikely. However, this postponement is being used to carry out technical studies required to evaluate alternative rehabilitation strategies and establish a sound environmental planning basis. Major technical data from the following studies are reviewed: Resource: - mine planning; material characterisation; retorting; geology; Environmental: - meteorology; surface water management; laboratory and field leachates; revegetation; waste characterisation; hydraulic and chemical modelling; dust suppression; plant/water interactions; and impact evaluation. These studies have shown that topsoil replacement, seeding mixtures, fertilizer application rates, subsoil quality and handling, waste pile slope and most importantly soil water storage are key factors in successful rehabilitation.

Jan 1, 1987

By H P÷llmann

Calcium aluminates, calcium aluminate ferrate and calcium aluminate sulfate were synthesised by solid-state reaction, sol-gel method, a self-combustion method and by a polymeric precursor process. For chemical sintering methods the base chemicals CaO, CaSO4, Al2O3 and Fe2O3 were used. As precursors for sol-gel synthesis metal nitrate hydrates and Al2O3-Sol were used. In order to synthesise pure phases by a self-combustion reaction glycine was used as fuel and nitrates as metal components. In the polymeric precursor process metal nitrates and diluted H2SO4 were used as metal components and the resin was made using citric acid (C6H8O7) and ethylene glycol (C2H6O2). Precursor phases synthesised by these different methods were sintered step-by-step in order to investigate the crystallisation. Further on single phases were hydrated and their hydration behaviour was studied by heat flow calorimetry, X-ray diffraction and cryo-transfer scanning electron microscopy. Due to the different synthesis procedures different hydration reactions and microstructures of the phases will be shown.

Jan 1, 2008

By Kim YC

An alternative development drilling strategy to the one currently in use at an open pit mine was investigated using geostatistics for a portion of the pit. The massive orebody, the 3-D nature of the problem, and the location of ultimate pit limit in the study area all created some unique problems in devising the development drilling strategy. Rather than using confidence interval of the global reserve estimate as the main criterion for development drilling, the confidence interval of short and medium range mine planning blocks was used as the objective. Based on somewhat arbitrarily selected level of confidence, the results from the study showed that a total of 50 diamond drillholes (DDHs) rather than the planned 62 DDHs is sufficient in the study area, if the selected confidence levels are acceptable to the management. The paper also emphasizes the importance of particular objectives being used in development drilling and how they influence the "optimal" placement of the development drillholes.

Jan 1, 1986

By C V. Putnis, T Geisler, A Putnis

In nature, ilmenite (FeTiO3) undergoes weathering through oxidation and removal of Fe to form an apparently continuous series of compositions from ilmenite to pseudorutile (ideally Fe2Ti3O9), and with further weathering, to leucoxene. To determine the mechanism of acid-leaching of ilmenite to ultimately form rutile, we have carried out an experimental study of ilmenite alteration in autoclaves at 150¦C in HCl solutions. Resulting products were studied by X-ray diffraction, scanning electron microscopy, electron microprobe and Raman spectroscopy. In some experiments the solution was initially enriched in 18O and the distribution of the isotope in the alteration products mapped from the peak shift in the Raman spectra. The results indicate that the alteration may proceed in two stages, each with a sharp interface between the parent phase and the product. The alteration begins at the original ilmenite crystal surface and along cracks through which the fluid can migrate. The first alteration product is pseudorutile û no phases intermediate between ilmenite and pseudorutile were detected. The textural relationship between ilmenite and pseudorutile suggests a coupled dissolution-reprecipitation mechanism rather than a solid state continuous oxidation and Fe diffusion mechanism. The second stage involves a further dissolution-reprecipitation step to form rutile. Raman spectroscopy shows that the 18O is incorporated in the rutile during the recrystallisation. Throughout the alteration process the original morphology of the ilmenite is preserved although the product is highly porous. The rutile inherits crystallographic information from the parent ilmenite, resulting in a triply-twinned rutile microstructure.

Jan 1, 2008

By Mauk JL, McOnie A, Simmons SF

Three cross sections, 200 m apart, display the distribution of indicator hydrothermal minerals across the Empire zone of the Golden Cross epithermal Au-Ag deposit, Waihi, New Zealand. These minerals are used to interpret the temperature and composition of hydrothermal fluids. The distribution of interstratified illite-montmorillonite and illite indicate that temperatures ranged from 140 to >220¦C, with temperatures above 220¦C predominating. The mineral assemblage of quartz-adularia-chlorite-illite-calcite-pyrite envelops the Empire vein system and stockwork, and reflects formation from an alkali chloride water, whereas the mineral assemblage of replacement calcite-interstratified illite - montmorillonite- kaolinite forms a carapace and reflects formation from a C02-rich steam-heated water. Alkali chloride waters appear responsible for the epithermal Au-Ag mineralisation.

Jan 1, 1995

By Stein A

The general mechanism of recrystallisation for cold worked metal is well established, and need be only briefly summarised with a few references to recent articles which clarify minor points. The types of extension, whether by stretching, drawing, hammering, rolling, etc., do not alter the general principles (1), although quantitative results may differ somewhat, particularly with regard to differences between the surface and interior of samples.These principles can be summarised as follows: The first stage in annealing is a recovery (sometimes known as relaxation) of physical properties such as hardness, elongation, etc., without any appearance of recrystallisation; the second stage involves a further alteration in physical properties, accompanying the formation of new recrystallised grains which replace the original structure; a possible third stage involves an increase in the grain size of the completely recrystallised structure by absorption of smaller grains by larger ones. These three stages will be referred to as recovery, recrystallisation, and grain growth. Depending on conditions, the three stages may be clearly marked or may occur more or less simultaneously.For a given annealing temperature, cold deformations below a certain amount fail to give recrystallisation, and the final structure consists of the original grains which have recovered and possibly become more equiaxed. When a certain deformation, critical for that annealing temperature, is given, recrystallisation can occur, and will give the maximum recrystallised grain size.Increasing deformations beyond this give progressively smaller grain sizes.For each material there is a minimum recrystallisation temperature, below which recrystallisation will not occur whatever the deformation or time of annealing. For a given deformation there is a temperature, critical for that deformation, below which recrystallisation will not occur, and above which it will take place with increasing rapidity.

Jan 1, 1947

By Shonhardt JA, Bagster DF

This paper firstly examines the pollu- tion potential of burning colliery wastes. A comparison of two means of estimating the pro- pensity for coal to combust spontaneously is next presented. The use of microwaves, as a new procedure, is discussed in detail, while a comparison of the results is made with a modi- fied adiabatic technique. A number of coals that are known to combust spontaneously was tested, as were some coals that are not consi- dered to have self heating potential.

Jan 1, 1987

By Heyes GW, Orrock GI

The fine grained complex orebody at Elura contains galena, silver and sphalerite in a matrix which is mostly pyrite; sulphides account for about 90% of the orebody. A differential flotation circuit is operated to con- centrate lead and silver in the first section and zinc in the second. The metallurgical performance to date indicates the need for improvement. The lead section has been sampled in detail to comprehensively assess its overall performance and to define problems associated with lead and silver flotation. The substantial amount of pyrite in the feed dominated the perfor- mance of each stage of the separation. It was responsible for extensive dilution of all concentrates and, as a consequence, for very large circulating loads. The rougher concentrate contained 68% pyrite some of which was rejected through the three stages of cleaning to 39% in the final concen- trate. However, this was still sufficient to hold the assay of this product below 45% Pb. Size by size behaviour shows that flotation rates of the valuable minerals, as characterised by their rate coefficients, were low through- out the circuit. There was a significant deterioration in these rates between rougher and cleaner I stages which resulted in large circulating loads between these stages. There was practically no recovery of coarse valu- able minerals to the final concentrate. The dilution of the final concen- trate by non-sulphide gangue was not a major problem. If the recovery of the galena and silver in the +38¦m size range could be raised to that of the - 381Lm size range, galena recovery would rise from 78% to 86% and silver recovery would improve from 46% to 59%. The Pb grade of the final concentrate would remain the same.

Jan 1, 1988

By Tsuchiya N, Takada Y, Okabe K

Alkalis in the blast furnace are removed mainly by the slag, Alkali removal by the slag was studied as a rate process of alkali vapor- ization from the slag flowing through the dropping zone in the blast furnace. The vapor-, ization rate of I:20 from CaO-Si02-A1203 IZ20 slag was- measured under various experimental conditions. An empirical formula for the vaporization rate was obtained as a function of slag basicity, temperature and surface area per unit mass of slag. A simulation model of IC20 vaporization in the dropping zone was evaluated using the rate equation when the true velocity and surface area of the slag was de- termined from a flow dynamic model of counter- current gas-liquid flow through packed beds. The influence of the dynamic conditions of flow, as well as the slag basicity and temperature, on alkali removal by the slag was estimated.

Jan 1, 1980

By Sergeant G. D, Norman J. R

The importance of reducing the moisture content of fine coal, the nature of the retained water and the means of its removal are discussed. A statistical technique, using a balanced block design, was used to isolate the significant factors determining water content of a coal filter cake, The most significant factor was particle size distribution. A simplex evolutionary operation (evop) was used to determine the optimal quantities of additives required to produce the lowest moisture content for a selected coal size. For this optimum condition (18.6 lb xÇ20 per 100 lb dry coal), additions of 0.045 lb magnesium ion, 0.0026 lb separan A.P. 30, and 0.098 lb aerosol O.T., per 100 lb dry coal were required. The work illustrated the uses of statistical evop technique for the determination of optimal conditions in industrial research projects.

Jan 1, 1969

The financing of mineral ventures is usually supported by the valuation of a mineral asset, the physical size and composition of which have been determined within quantified limits of accuracy in order that the lending or investment risk can be assessed. The Resource or Ore Reserve estimation is the measurement of that asset and may be the outcome of complicated processes of interpretation and estimation requiring an extensive knowledge and understanding of the general nature of ore occurrences, and of the particular deposit under review. In arriving at an interpretation of the nature and physical distribution of minerals in a deposit, observations may only be available from widely spaced samples and geological knowledge and principles are of prime importance. Consultants may be asked by the lending or investing body to "provide comfort" on the quality of the Resource or Reserve estimations and providing such comfort casts substantial obligations of diligence on the consultant.

Jan 1, 1990

The comminution process indicates that the most energy-efficient comminution system would be one where the particles leave the breakage field as soon as they reach product size. Contrary to the free falling gravitational (vertical) flow in crushers, the grinding millÆs energy efficiency essentially depends on ore characteristics and the discharge rate of broken particles, which in turn depends on how efficiently the discharge pump (grate and pulp lifters) operates. The essential function of a pulp lifter is to transport the broken material and slurry from the discharge grate out of the mill. Hence, the design optimisation of pulp lifters affects not only the energy efficiency and throughput of autogenous grinding/semi-autogenous (AG/SAG) grinding mills, but also contributes other process benefits such as improved wear life and operator-friendly steady and smooth mill operation. Following its introduction in 2006, OutotecÆs patented Turbo Pulp Lifter (TPLÖ) design has been retrofitted at existing sites and also installed in some new ones around the world. This paper will provide operational experience and data on how the TPLÖ design has allowed AG and SAG mills to operate efficiently.

Jan 1, 2009

In coal room and pillar, and pillar extraction panels, the sidewall conditions were investigated based on underground measurements and numerical simulations. Three-dimensional linear elastic models provided a useful and quick prediction of the amount of sidewall spalling. However, more complex constitutive models were required to simulate more accurately the extent of fracturing and its effect on the stress re-distribution. The input parameters of a Mohr-Coulomb model were determined by back-analysis of underground measurements, and the effect of the depth of the workings and the time dependent occcurrence of coal pillar fracturing were analyzed.

Jan 1, 1992

Comminution of solids is surely one of the oldest technologies which even in this day and age of DNAs, chips and space exploration continues to challenge our scientific acumen and engineering ingenuity. In essence, this challenge is two-fold. One, as much as three to four per cent of all electric power generated world-wide is consumed in crushing and grinding primarily because the utilisation of energy is woefully poor. Studies have shown that the efficiency of mechanical size reduction processes is of the order of 1.5 to 12 per cent only (Schoenert 1986). Two, with the grinding technologies available to us, we have, at best, inadequate and, at worst, almost negligible control over the shape of the comminuted particles, size dispersion of the ground mass, and the sharpness of mineral liberation. Low energy efficiency and lack of control in the sense mentioned above have far-reaching implications for resource conservation, performance of down stream unit operations, and damage to the environment. Our problem is in fact central to the mineral-energy resources triangle shown in Figure 1 which depicts the close interrelationships among mineral resources which are becoming poorer in content and more complex in mineralogy each day, energy resources which are depleting rapidly without any viable alternate on the horizon, and environmental concerns which can no longer be ignored. It is evident that any improvement in the efficiency of the comminution process impacts directly on the control of environmental damage, conservation of energy and the economics of the operation. These concerns have special relevance for the processing of non-ferrous ores.

Jan 1, 1992

By G W. Croft, L E. Krause

The current copper ore handling systems in use at Xstrata CopperÆs Mount Isa Copper Operations are up to 33 years old and have hoisted over 160 Mt at a rate of around 6 Mtpa. The mineÆs production profile is increasing in line with the optimum life of mine plan to over 6.6 Mtpa, which requires a system utilisation and reliability above that previously achieved. Copper ore is hoisted up the U62 shaft, which forms the central part of the U62 ore handling system. In theory this system can cope with the duty planned if the bottleneck is only the U62 winder. To achieve the planned production rate will require increased focus on reliability of each component in the ore handling system so that ore is available at the shaft for hoisting whenever the shaft is available, and the shaft is available for the maximum practical time. Increased availability will be achieved through the outcomes of the study of each component in the U62 system, and the internal ore handling systems that deliver ore from as far as 2 km laterally and 700 m vertically from the U62 shaft. The true capacity of each component is being determined and current performance is being measured with the aim of improving performance through root cause analysis and engineering out the causes of delays. The program began in March 2004 and this paper describes the progress achieved as of April 2005.

Jan 1, 2005