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By C. P. Browning

Copper, as far as we know, was the first metal used by man, and due to the fact that it occurs in many places in the 'native' state, and also to the ease with which it may be shaped, it has played an important part in the evolution of civilization. Copper tools with inscriptions dating back to 6,000 B.C. are known in Egypt, where the metal probably got its start as a useful material in human hands. Just how far back the use of copper in Canada dates is difficult to say, but it was in use by the Indians in the Lake Superior country long before the arrival of the first white man. For many generations the Eskimos also have used copper derived fr0m deposits of the native metal found in the Coronation Gulf district. Due to the metal's many unique qualities, imperishable with age, ancient implements and utensils are apparently as good today as when they were made, having withstood the onslaught of time probably better than objects of any of the other base metals. Copper alloys so well with other metals that today it is second only to iron in its industrial value. Even at the beginning of the eighteenth century the world's production of copper was probably not more than seven thousand tons a year, with Great Britain producing three-fourths of this. One hundred years ago the mines of the United States, Chili, Mexico, Canada, South Africa, Australia, and Tasmania, which now produce about nine-tenths of the copper of the world, were totally undeveloped. Ln 1926 the world production of copper was approximately 1,658,000 tons, which was seventy thousand tons greater than in the preceding year; but growing demand absorbed the increased production, so that the stock of rough copper throughout the world is comparatively small. Of this huge tonnage of the metal, Canada produced four percent, two-thirds of it emanating from British Columbia, nearly one-third from the Province of Ontario, and the balance from Quebec.

Jan 1, 1927

By Sazol Das, Hany Ahmed, Ganesh Bhaskaran, Zhuoru Wu

"Friction stir welding (FSW) process in lap configuration for dissimilar materials has been developed and tested for steel to aluminum joining. A novel cylindrical tool was designed for improved material flow. The joining of steel to high strength 5xxx and 6xxx aluminum was carried out by FSW technique using optimized process parameters. The microstructure, micro-hardness, joint strength and corrosion properties at the weld interface have been investigated. Optical and scanning electron microscopy reveled a well layered structure at the interface and lap shear tests of the welds showed excellent fracture resistance. Neutral salt spray tests for up to 500 hours (ASTM B117) were carried out on the bare steel to aluminum FSW joints, which did not show neither evidence of corrosion at the weld interface, nor any degradation of the weld strength. The FSW lap configuration was applied to prototype commercial vehicle structural component whereby a steel stiffener insert was friction stir welded to high strength 6xxx aluminum alloy. The interface microstructure showed layered root without any steel shattering in aluminum side. A finite element study was carried out to quantify the benefits where it was found that the stiffness increases by 76% under bending loads and 36% in torsion loads.INTRODUCTION Energy preservation and environmental issues, namely carbon footprint and legislation around emission in transportation industries has led to a growing need to use of lightweight materials such as aluminum and magnesium alloys along with various grades of steel in structural application, while still maintaining their strength and crashworthiness. Assembling dissimilar materials within integrated structure is thus a stringent requirement related to optimum performance. In order to achieve an efficient technology of joining dissimilar materials such as aluminum to steel, it remains difficult to select an effective welding process for a given joint configuration. The use of aluminum in transportation industries for structural component is not exclusive in a design and is almost always used along with various steel grades for a mixed materials solution, thus dissimilar aluminum/steel lap joining is of great interest since this is widely used in the assembly of parts (e.g. pillar, frame rails, chassis, body in white (BIW), CAB, etc.)."

Jan 1, 2018

By Hang Zhao, Xinping Li, Pingan Wu, Yi Luo

"The deep-buried rock surrounding the Jinping II Hydro-power Station was taken as the engineering background. Using model specimens of classified rock materials to simulate fractured rock mass under high in-situ stress conditions, the test about acoustic propagation law on single fracture model of specimen under different pressures and different angles were carried out. The variation of p-wave velocity in fractured rock mass and axial stress-strain relationship in the whole test procedure was also studied. Based on damage mechanics principle and the acoustic wave propagation in cracked rock mass, comparative study on damage constitutive relation of fractured rock mass under high in-situ stress in consideration of equivalent strain and equivalent energy was performed. As the results showed, with the change of axial stress level under constant confining pressure, the change in wave velocity can be divided into three stages: slow increase (small variation in amplitude), rapid reduce (large variation in amplitude ) and accelerate reduction. When the confining pressure is constant, the maximum p-wave velocity and the peak strength of specimens increases with the decrease of the crack angle.When the crack angle is constant, the maximum p-wave velocity and the peak strength of specimens increases with the increase of confining pressure.It is identified that the theoretical calculation results of constitutive relation about elasto-plastic damage model containing variable wave velocity in the fractured rock mass is consistent with the model test results.Therefore,the constitutive relation can provide reasonable suggestions for engineering practice. INTRODUCTIONThere are a lot of joints and fractures in surrounding rock mass of deep-lying in the Jinping-II hydropower station, which has a great influence on the physical and mechanical properties of rocks and effects the acoustic wave propagation and attenuation law in rock. Many previous research and project examples has proved that sound propagation parameters are closely related to crack and stress condition. Thus, it has certain theoretical significance and practical application value to carry out researches on sound propagation characteristics and establish damage constitutive model of fractured rock mass which is related to sound propagation parameters."

Jan 1, 2015

By Roy S. Celland, K. H. Singh

The introduction of 'post' pillar mining at the Strathcona mine represents a new approach to ground support in cut-and-fill applications. The method has also shown significant economic advantages. It is believed that the development of this concept is one of the few examples where rock mechanics principles have successfully been applied in the development of a stoping method. The paper describes the evolution of this method and contains discussions on the theoretical analysis of the technical, operational and economics aspects of the system. Pillar design procedures and field observations on the practical application of theoretical analysis are also outlined.

Jan 1, 1973

By R. H. Beaton

"About 1905, a plant was constructed at C1ayburn, in the Lower Fraser valley, 4'5 miles east of Vancouver, to process shales from Sumas mountain into heavy clay products. In time, mining operations were found to be more favourable on the opposite side of the mountain, and by 1913 a plant, which soon became the centre of activities, was completed at Kilgard. Destroyed by fire in 1949, the plant was rebuilt on modern lines, and a second plant was established at Abbotsford, six miles to the west. The Company, from its beginning, has grown with development of the Province. In recent years, operations have kept abreast of latest developments, particularly in materials handling. Latest innovation has been the complete conversion of fuel from Bunker C oil to natural gas. In 1957 the Company became associated with Harbison Walker Refractories, Limited, a leader in its field in the United States, and its title was changed from Clayburn Company, Limited, to Clayburn-Harbison, Limited. Currently, the Kilgard plant produces sewer pipe, agricultural tile, and flue liner; the Abbotsford plant, refractories and facebrick. Improvement of products and development of new ones are tasks of a recently-completed testing and research laboratory.Almost all ware produced is marketed in Western Canada or Washing-ton State. The Vancouver area absorbs the bulk of structural clay products."

Jan 1, 1959

By J. D. Aitken

"DEFINITION OF THE REGIONTHE REGION considered in this paper is bounded on the south by the 60th parallel, on the north by the Beau-fort Sea and Amundsen Gulf, on the east by Archean rocks or by highly deformed Proterozoic rocks of the Canadian Shield (certain weakly deformed Proterozoic strata being regarded as belonging to the Great Plains), and on the west mainly by the Mackenzie and Richardson Mountains.Only the unmetamorphosed strata of the region are considered; that is, the geology of the crystalline basement is ignored.SIGNIFICANCE OF THE REGIONThe region is significant from three points of view -namely, the economic, the scientific and the social. It constitutes 46 per cent of the area of the Western Canada Sedimentary Basin."

Jan 1, 1970

By P. Bakke

Following extensive R&D efforts, Hydro Magnesium has launched a new alloy series with remarkable combinations of properties. The AE alloy family is based on additions of aluminium and rare earth elements to control mechanical properties, including elevated temperature creep strength. By combining these alloying elements with manganese additions, high purity alloys with outstanding corrosion performance are defined. A basic philosophy behind the developments has been to simultaneously approach all the critical issues related to developing a commercial material. Apart from the obvious requirements for material properties, the critical issues relate to die casting performance, as well as alloy production, recycling and environmental compatibility. Some of the important elements related to alloy production and recycling are addressed in the present paper.

Jan 1, 2006

By Omkar N. S. Beruar

Extraction of sill pillars has always been problematic because of high risk of seismicity and rockburst. Depending on a number of factors, a sill pillar can undergo different failure modes and cause problems in the mine. Of these, sudden and uncontrolled failure of part(s) of the pillar leading to highenergy seismic events and rockbursts is a main concern because it is not possible to predict the location and time of a rockburst apart from its potential to cause extensive damage to the mine structures. To date, a comprehensive technique for sill pillar design and recovery does not exist. Conventional methods of pillar design, such as the pillar stability graph method, are utilized to design stiff sill pillars. In these design approaches, the post-peak response of the pillar-rock system is not considered. This is in part due to a lack of clear and comprehensive understanding of the post-peak behaviour and failure mechanism of sill pillars. In general, the strength of a rockmass is described using a failure criterion. When stresses reach the strength of the rockmass, the rockmass does not necessarily become unstable and knowledge of the loads alone is not enough to assess the instability conditions accurately. In fact, it is not possible to predict instability of rockmass based on the strength/stress ratio alone because instability depends not only on this ratio but also on the loading condition and loading system characteristics. The loading system can dictate whether the sill pillar will go through a stable or unstable failure process. This paper examines the influence of various parameters such as the pillar width to height ratio, the extraction rate, and placement of backfill on the Loading System Stiffness (LSS) and the Pillar Stiffness (PSS). The ultimate goal is to design yielding sill pillars that would yield in a stable manner and will reduce the risk of pillar rockburst. Plane strain finite element analysis is conducted using the generalized Hoek-Brown failure criterion with elastic-brittle-plastic parameters. Examples are given to demonstrate how to calculate these stiffness values and assess the stability condition of sill pillars. It is found that increasing the rate of extraction increases the likelihood of unstable yielding of the pillar as has been found in other studies. Placement of backfill in a timely fashion in the stopes above and below the sill pillars increases the stiffness of the loading system. This indicates that backfilling of stopes while creating the sill pillar increases the likelihood of stable yielding of the sill pillar.

Aug 1, 2013

By Grant Small, Jessica Kinal, Christopher J. Greet

"The conversion from an electrochemically reactive grinding media (forged steel) to a more electrochemically inert alloy (high chrome white iron) not only reduces the wear rate of the grinding media, but also has an impact on the grinding chemistry. Typically the grinding chemistry becomes more oxidising, with less reducing Eh values and more dissolved oxygen in the pulp. There is also a decrease in the EDTA extractable iron, which is an indication of the change in the media corrosion. These changes are indicative of alterations in the surface chemistry of the minerals that the operator is trying to separate. For porphyry copper ores the changes in the pulp and surface chemistry not only affect the copper sulphide minerals, but also impact the iron sulphides (i.e. pyrite and pyrrhotite). Generally, with more oxidising pulp chemical conditions during grinding there is an increase in the oxidation of the iron sulphides which renders their surfaces hydrophilic, thereby depressing flotation. This leads to improved selectivity for copper sulphides against iron sulphides.INTRODUCTIONPorphyry copper deposits are the dominant source of copper that is mined today to satisfy global demand. These style of deposits typically contain one percent copper mostly as chalcopyrite, but may contain other copper bearing minerals (for example, bornite, chalcocite, azurite, malachite), small quantities of pyrite and quartz. Porphyry copper deposits also contain economically significant quantities of gold, silver and molybdenum. Interestingly, the majority of the world’s porphyry copper deposits are concentrated along tectonic plate boundaries (Figure 1)."

Jan 1, 2016

By Nick Vayenas, Ming Cai, Hongbin Zhang Lorrie Fava, Enrique Acuña

"A hybrid methodology is proposed to improve the accuracy of Diesel Particulate Matter (DPM) concentrations simulated in a ventilation network model by using Computational Fluid Dynamics (CFD). DPM, as a primary concern for underground hard-rock mines, has been studied in two dominant numerical models, ventilation network solvers and computational fluid dynamics. Ventilation network solvers are efficient, but they are not able to provide three-dimensional DPM concentration contours and only accept area-average DPM data as input. CFD simulations are time-consuming, but generating DPM concentration results with high accuracy. Besides, both monitoring points and planes can be created in a CFD model, which can take both point data and area-average DPM data as input. The hybrid methodology is intended to combine the advantages of the two by using the CFD results to update the network model results at key locations. A field study was conducted in a dead-end heading in an underground gold mine in the United States. Real-time DPM monitors were used to collect data. A CFD model and a network model were built for the experiment area. The CFD model was calibrated to the experimental data. In the study presented here, results from a calibrated CFD model are converted to equivalent diesel emission rates in the ventilation network model at a shared outlet. The hybrid methodology is used to provide better input for the network model. INTRODUCTION Mine ventilation system is one of the most important parts for an underground mine. It not only provides fresh air to the personnel but also helps clear the contaminants generated from the diesel-powered equipment. For most underground metal and non-metal mines, diesel particulate matter is the main contaminant. It is also the focus of this paper."

Jan 1, 2019

By M. E. Bilir

In this paper, we review cases in which dramatic and visual swelling problems are experienced in underground structures. Swelling rocks have caused many problems in underground engineering projects. They pose severe problems to the design, construction and maintenance of underground openings. If an appropriate integrated design procedure, which proceeds from exploration, tests, analyses and realistic assumptions of swelling behavior, is used during the design stage, the execution of the project can be completed without any serious delays or dramatic design changes. The case histories were subdivided into three classes that include tunnels, underground coal mines and others. For the evaluation of cases, the surrounding rocks, swelling minerals, water inflow, swelling test results and swelling problems were considered. The main purpose of this review is to inform the reader about potential problems with swelling phenomenon and to emphasize the rehabilitation and extensive cost which are encountered due to the lack of necessary integrated design approaches.

Aug 1, 2013

By H. R. Butler, R. N. Browne

"The International Nickel Company of Canada Limited consumes some 33 ½ millions of gallons of fresh water and reuses more than 100 millions of gallons of water daily. The continuing search for suitable recycle methodology has enabled the Company to put one 25,000 TPD mill on line utilizing recycled water entirely and a second 35,000 TPD mill is under construction which will likewise employ the concept of recycled water. Future milling plans are aimed at the replacement of all fresh water with recycled water, including sewage effluent and mine waste water.WATER REUSE AT INCO’s SUDBURY MILLSAs man searches unexplored horizons for new and economic industry, he must be constantly and acutely aware of the presence or absence of that precious commodity without which Industry, indeed Man himself, could not survive -- W A T E R. The water requirements of the world today are magnanimous, considering that in 1960 the estimated consumption in the United States was over 300 billion GPD (l) or more than 1,700 GPD per person(5) The magnitude of the problem can be visualized as one considers that three times this quantity of water will be required in the United States by the year 2000, when the dependable supplies of water are estimated to be only two-thirds of that required(2). How, then can we continue to wreak such havoc on that life-sustaining substance - WATER?"

Jan 1, 1970

By M. L. F. Paullo, S. Cristian Mejia, D. Roehl

"Rock fracture simulation most often presents non-linear behaviour due to loss of material integrity and strain concentration in the fracture zone. These strains generate local instabilities that propagate to the global system of equilibrium equations, generating convergence problems of the numerical solution. Often, in such cases, analyses in the post-critical regime are unfeasible. To overcome the numerical difficulties associated with problems of stiffness loss in the post-critical regime control methods, also called continuation methods, are employed. Among them are the arc-length method, the energy control method and the indirect displacement control method. These methods are employed in conjunction with a Newton- Raphson scheme for the solution of non-linear systems of equations. However, depending on the system instability, convergence in not guaranteed even with very small increments. In the present work these control techniques are investigated in combination with cohesive elements to simulate rock fracture. The constitutive model employed with the cohesive elements represents stiffness degradation through a damage law, which leads to serious convergence difficulties as reported in the literature. Here the continuation methods mentioned are applied to a Mode I rock fracture problem and to hydraulic fracture simulations. The effectiveness of the different continuation methods is compared.INTRODUCTIONThe process of rock fracture induced by the fluid pressure is called hydraulic fracturing. The propagation of a hydraulic fracture is a complex process, which is basically defined by the mechanical deformation of the rock, the fluid flow within the fracture and the fracture propagation itself (Mokryakov, 2011). In the works of Bendezu et al. (2013), Chen (2012) and Carrier et al. (2012), vertical hydraulic fracture propagation is modeled by cohesive elements with traction-separation law. The softening behavior of rock in post-critical regime is demonstrated by experimental testing and is characterized mainly by high strains and low stresses (Crowder and Bawden, 2004). This nonlinear behaviour can arise due to material nonlinearity, such as micro-cracking and damage, leading to softening behaviour (Chandrakant, S.D., 2012). The cohesive fracture model considers in its formulation the softening behaviour that most rocks present in post-critical regime with propagation criteria."

Jan 1, 2015

By A. A. Holland

Introduction The world's largest known deposits of natural sodium sulphate (Glauber salt), generally termed 'alkali ' throughout western Canada, are located in the Province of Saskatchewan: reserves are estimated to exceed 200,000,000 tons. These are surface deposits resulting from the recent or present-day natural evaporation of brines, in which respect they are similar to those occurring in certain other parts of the world, as in semi-arid sections of the United States, Russia, Germany and Austria. In some areas, underground deposits formed hundreds of thousands of years ago have been _encountered in drilling, and indications are that they also were formed under arid or semi-arid conditions. The master key to the formation of deposits of natural sodium sulphate, wherever they occur, is a climate, either past or present, under which evaporation exceeds precipitation over a considerable period of time. Commercial development of the Saskatchewan deposits began about thirty years ago. Previously, the demand for sodium sulphate had largely been met by salt cake produced as a by-product in the manufacture of hydrochloric acid from common salt. The rapid increase in the production of Kraft paper and, more recently, the development of synthetic detergent materials, have caused a marked increase in the market for sodium sulphate. This chemical gives the extra toughness to Kraft paper and is used in detergent compositions in proportions as high as 75 per cent. Saskatchewan now has six commercial plants producing natural sodium sulphate. Production from each in the fiscal years 1947 and 1948 is shown in Table I. The newest and latest plant is that of Saskatchewan Minerals, at Chaplin, which 1s designed to produce up to 150,000 tons of salt cake, 98.5 to 99.5 per cent pure, yearly. This is equivalent to about 24 percent of the total United States production of crude commercial salt cake for 1947.

Jan 1, 1949

By G. Hamel

The LCL&L process (Low Caustic Leaching & Liming) is a patented hydrometallurgical route developed by Rio Tinto Alcan (RTA) to economically process spent pot lining (SPL) generated by aluminum cells. The three resulting end-products (carbonaceous, fluorinated and caustic liquor) are inert and have valorization possibilities. An industrial size pilot plant located in Saguenay (Quebec) was inaugurated in mid-2008 to demonstrate and optimize the technology. This paper describes characteristics of the LCL&L process and the experience acquired by RTA since the plant's start-up, including ramp-up capacity and technology challenges that were overcome. Possible end-products valorization methods are also presented. The carbonaceous end-product can be separated into carbon and brick rich fractions and used as either alternative fuel, reducing agents, or as raw material for third party processes. The development of a conversion process for the fluorinated end-product would allow its reuse as a substitute to fluorspar mineral for aluminum fluoride production. Finally concentrated caustic liquor is already valorized at the nearby RTA Vaudreuil alumina refinery.

Jan 1, 2011

By L. Haavanlammi

Iron is a significant component of all copper concentrates leached in the HydroCopperTM process. The metals in the concentrate are leached in a chloride solution by oxidation with cupric ions. Copper enters into the solution as a cuprous chloro¬complex. Iron dissolves at the same time in the ferrous form, but it is immediately oxidized to the ferric state. Oxidation is effected by sparging air or oxygen into the leaching reactors. Because the pH is 1 - 2.5, ferric ion precipitates as akaganeite (T<90°C) or hematite (T> 90°C). Arsenic, antimony and the main part of the bismuth co-precipitate with iron and report to the leach residue. Cupric leaching is faster than iron oxidation; thus, leaching of low-iron concentrates (secondary copper minerals) is quicker than leaching high iron concentrates (chalcopyrite). Pyrite does not dissolve during copper leaching, but is oxidized slowly at higher redox-potentials after the copper has been leached.

Jan 1, 2006

By J. F. Liu, L. Chen, C. P. Wang

"Calcite-cemented joints abound in the rock masses of Beishan area, which is the most potential area for the high-level radioactive waste (HLW) disposal of China. The mechanical properties of Beishan granite containing a calcite-cemented joint with a dip angle of 82° was investigated under uniaxial compression and the acoustic emission (AE) characteristics were also studied in this paper. Compared to intact granite, the calcite-cemented joint caused a decrease more than 50% in uniaxial compressive strength and a decrease more than 90% in shear strength. The Young’s modulus was also decreased, while the circumferential deformation of jointed granite was sharply increased. The AE monitoring system successfully recorded the process of micro-crack development and the results indicated that the risk of rock-burst could be reduced due to the appearance of calcite-cemented joint.INTRODUCTIONThe properties of jointed rocks differ considerably from that of intact rock. Due to the difficulties in specimen preparation, analogue experiments with artificially prefabricated fractures are often used to study the mechanical behavior of jointed rock (Chen et al. 2012; Kulatilake et al. 2001; Singh et al. 2001). However, natural joints are not quite similar to the artificial fractures and it is necessary to investigate the mechanical behavior of jointed rocks. Xie et al. 2011 studied the mechanical properties of marbles with natural joints by uniaxial compression tests and found that the uniaxial compressive strength of jointed rock is greatly decreased. With the unaxial compression tests, Jacobsson 2005, 2007 tested the intact and jointed granites, which were taken from the potential site for high-level radioactive waste (HLW) disposal of Sweden. However, no significant difference in strength or modulus was found. The above research results are inconsistent and it indicates the complexity of the mechanical properties of natural joints."

Jan 1, 2015

By Donald E. Wakefeld

"The pace at which mining will occur in Northern regions and Arctic lands will depend on the answers to a number of questions. Who are the local aboriginal participants? What land uses are they pursuing? What are their objectives? What is their understanding of the process of mining development? This paper will focus on the last question, communicating the process of mineral development to local aboriginal communities.IntroductionIn the environmental impact hearings for the BHP-DiaMet diamond mine, the smaller Dene Treaty 8 Nation argued for the settlement of its Land Claims as a pre-condition to development. However, the larger Dene Treaty 11 Nation were prepared to permit the mine to proceed on the basis that their people would receive benefits during the construction and operation of the mine.Wherever mining is the significant basis for tax revenues and economic development expectations may be encouraged beyond the realities of the situation. Izok Lake has been known for several decades as a significant mineral deposit but because of its size and the transportation costs involved, it is now a “frozen” ore body. The extent of its mineralization at current metal prices will not support the mining and processing costs without substantial government support for infrastructure and roads. At the opposite side of Canada, Voisey’s Bay clearly satisfies all technical criteria but, nonetheless, two Inuit groups, the Innu, and Métis, have all made LandClaims relating to the mine area.Contrasting the mineral deposits at Voisey’s Bay and Izok Lake emphasizes that the timing of production is dependent on factors such as the grade and amount of reserves, their market price, location and availability of government support. Nonetheless, it is this author’s thesis that given an economic orebody the next most important factor is good communications. It is his view that Arctic mineral development will occur quickly only where good communication has resulted in the trust and mutual respect necessary to implement the mammoth cultural changes required."

Jan 1, 1996

By M. Lindgren, M. Latva-Kokko

Process performance can be significantly influenced by proper design of hydrometallurgical reactors. Optimal reactor configuration is case specific and depends on process requirements such as reaction rate limiting factor and particle size distribution. Choice of materials and manufacturing methods also play important roles in highly corrosive and abrasive environment often involved in hydrometallurgical industry. In this paper performance of different reactor designs has been compared in some typical hydrometallurgical applications. Results show that significant improvement in energy consumption, gas utilization efficiency and equipment lifetime can be achieved with process specific reactor design.

Jan 1, 2014

By A. J. Naldrett

"Sulphurization of peridotite, that is 'to say reaction between sulphur from an external source and iron and nickel in the silicate minerals of the peridotite or in partially consolidated magma, is believed to be the me-chanism by which the small iron-nickel sulphide deposits associated with the ultrabasic rocks of the Porcupine district have formed.The pyrrhotite-pentlandite ore at the Alexo mine, Dundonald township, is localized by a shear that closely follows the lower contact of a peridotite lens. In the past, to account for this orebody, the magmatic segregation hypothesis has been advanced on the basis of textural evidence and the presence of the sulphides at the base of the lens. The nickel sulphide de-posits of the Porcupine, however, are not characteristically found along the basal contacts of bodies of peridotite. Furthermore, this study has shown that textures formerly thought indicative of magmatic segregation have been formed in certain deposits by the selective replacement of silicates by sulphides.At the Alexo mine, very minor amounts of pentlandite and heazle-woodite (Ni3S2) occur in the peridot-ite hanging wall adjacent to the ore. These sulphides are interpreted as having formed by sulphurization, the sulphur involved coming from the pyrrhotite-pentla.ndite ore emplaced along the shear. This reaction aureole raises the question of the role of sulphurization in the formation of the main mass of the sulphide ore. The very localized equilibrium that has been found to exist between sulphides and silicates in deposits throughout the area, the results of nineteen sulphur isotope determinations, and the abundance of pyrite and pyrrhotite in the volcanic country rocks of the Porcupine indicate that these deposits were formed by sulphurization rather than magmatic segregation."

Jan 1, 1966