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By M. Tanaka, Y. Sato, H. Narita, S. Alam, T. Ogata

To ensure a stable supply of rare earth elements (REEs), it is highly necessary to establish the corresponding recycling technologies for RE magnets and phosphors in inplant wastes and endoflife products. Solvent extraction using 2ethylhexylphosphonic acid mono2ethylhexyl ester (EHPNA) is often applied in the separation and purification of REEs. In this study, the equilibrium distribution ratios of neodymium and dysprosium between 1 mol/L nitrate solution and the EHPNA in an alkane diluent were measured at 298K. The experimental data were analyzed by correcting the nonideal behavior of the organic phase using the Alstad empirical equation under the assumption that a complex with a molar ratio of 1:6 (REE:extractant monomer) was formed. The model correlated well with the experimental data and the extraction equilibrium constants were obtained. The extractant equilibrium constants obtained by this methodology would be useful in the design of REE recycling processes using solvent extraction.

Jan 1, 2014

By E. V. Manlapig, U. Erol, V. Ross, K. Tshimanga

Lonmin RoM ball mills are treating two types of feed ore produced by conventional mining and mechanised mining methods. It was reported that reduction in mill throughput was observed when treating the mechanised mining ore. Detailed grinding surveys were conducted for troubleshooting. Ore samples were collected for breakage characterisation using a JKRBT based on different particle density components. XRD analysis was conducted to investigate the association of minerals with density components. The plant surveys and the breakage characterisation tests all suggested that the two mining methods did not significantly affect either the ore breakage properties or the RoM mill performance. Instead, the mill discharge open area exerted a remarkable influence on mill throughput. The RoM ball mill operated at Lonmin K4 Concentrator has been proven to be a versatile mill that performed stably with variations in feed size distribution and feed ore changes by different mining techniques. The reasons are elucidated by the multi-component breakage characterisation and the plant surveys data.

Jan 1, 2012

By J. Shahabpour

"Breccias with angular and rounded clasts of a late-mineralization, ""barren"" hornblende porphyry dike set within a comminuted matrix consisting of rock fragments and quartz, cemented by quartz and K-feldspar of hydrothermal origin is observed in diamond drill cores from the Sar Cheshmeh porphyry copper deposit. Studies of age relationship between vein types, phyllic-altered clasts and the breccia groundmass suggest that the brecciation is a late event. The breccia clasts record evidence of hydrothermal reaction between the clasts and fluids responsible for the brecciation.Formation of bornite, in the breccia clasts of the originally barren hornblende porphyry dike, and in the breccia matrix, along with the scarcity of bornite in the Sar Cheshmeh deposit itself suggest involvement of fluids which are later and of different composition from the fluids responsible for the known mineralization at Sar Cheshmeh. These later fluids may be related to a later plutonic event and suggest the possibility of a later, and concealed deposit."

Jan 1, 1994

By P. Woo, N. Brodusch, R. Gauvin, H. Demers

For developing new technologies, it is important to characterize the microstructure of materials with high spatial resolution at the nanoscale. To achieve high resolution, field emission scanning electron microscopes (FE-SEM) were developed. These microscopes allow working at low accelerating voltage, below 5 kV, to take advantage of the reduction of the interaction volume with accelerating voltage. Furthermore, their higher gun brightness compared to conventional thermo-electronic emitters, allow a probe size at the nanoscale. At low accelerating voltage, the emission volume of backscatter and secondary electron (SE) of the type II signals approach that of SEI signals. However, it is not enough to reach the highest resolution. A magnetic field above the sample improves the spatial resolution by collecting mostly high-resolution signals. In addition, the energy-filtration of the electron signals allows selecting the type of contrast detected: topographic, compositional, or crystallographic. The development of these new technologies permits to extend the imaging capabilities of the SEM towards new nanoscale applications.

Jan 1, 2014

By T. Watanabe, M. Nakagawa, K. Kimapong

Ultrasonic wave was irradiated on metal surface in water to introduce compressive residual stress. The ultrasonic wave that was oscillated with 19.5 kHz ultrasonic transducer and amplified with a step type horn was irradiated. Slight plastic deformation occurred at the surface region of pure metal such as Cu and compressive residual stress was introduced. It seemed that the plastically deformed depth from the metal surface corresponded approximately to the depth of introduced residual stress. The higher compressive residual stress could be introduced into the surface of Cu-Zn brass and SUS304 stainless steel because work-hardening was simultaneously induced to those alloys. Furthermore, since martensitic transformation was induced by the plastic deformation in the case of SUS304, the compressive residual stress could be introduced more deeply into the surface region. The residual stress of SUS304 reached to the maximum value of 574 MPa by irradiating for 5min.

Jan 1, 2004

By M. Kawahara, H. Sunayama

Oxidation rates of the cubic specimens, which were prepared by cutting the shaped magnesia-carbon bricks, were measured continuously with a thermo balance in the temperature range from 1273 to 1 823 K in N2-02 and Ar-02 mixed gas with 2.1 x 104 and 3.7x 102 Pa of oxygen partial pressure respectively. The effect of the graphite content, the maximum grain size of magnesia clinker and the oxygen concentration in the atmospheric gas on the oxidation rate for the MgO-C refractory has been investigated. The value of effective diffusion coefficient of O2, which diffuses through the porous decarburized layer, decreased with the decreasing of the porosity and the oxygen concentration in the external gas phase. It was speculated that the dense layer formed easily due to the high tortuosity of pores and the low recession speed of the carbon interface in the MgO-C bricks.

Jan 1, 2004

By Masatake Haruta

Gold can be deposited as nanoparticles on a variety of support materials by coprecipitation or deposition-precipitation of Au(OH)3, grafting of organo-gold complexes such as dimethyl-Au(III)-acetylacetonate, mixing of colloidal Au particles, and vacuum deposition. Owing to the moderate adsorption of at least one of reactants (for example, CO) on the edges and corners of Au nanoparticles and to the activation of the counter reactant (for example, O2) at the perimeter interface with the supports, supported Au nanoparticle catalysts exhibit unique and practically useful catalytic properties at relatively low temperature below 473K. They have already been commercially used for deodorizers in rest rooms in Japan and will find growing applications in indoor air quality control, pollutant emission control, production of hydrogen energy carrier, and innovations in chemical processes. Cluster science of Au may also open an exciting area of research showing some magic numbers for dramatic changes in reactivity.

Oct 1, 2003

By S. Xu, A. Ramesh, F El-dabbagh, Z. Fang, A. Sobhy, J. A. Kozinski

Waste remediation is a goal that will be driven forward by economic conditions. As the cost of waste disposal increases, new methods of waste reduction will become economically attractive, and will be implemented. It is difficult to imagine, however, a time when there will be no waste generation. For the foreseeable future, despite effective reduction practices, there will still be hundreds of millions of tons of waste that must be destroyed or controlled to protect the public health and the sanctity of the environment. To remain faithful to environmental covenants, the mineral and metallurgical industries will face these new challenges. This paper discusses novel waste remediation approaches and techniques focusing on hazardous wastes and thermal remediation. Aspects concerning technological and environmental importance are examined. Solutions for neutralization of environmentally hazardous compounds are proposed.

Jan 1, 2004

By I. Thobadi, C. Pawlik, K. Bisaka, S. Mokoena, M. Erwee

The PyEarth™ process developed at Mintek has been demonstrated successfully at pilot scale. Nine tons of ore containing 2.3 mass % of total rare earth oxides (TREO) from a dormant mineralogically complex iron-rich ore deposit, was subjected to a concentrating smelting step in a 200 kW DC open-arc pilot furnace and the rare earths from the resulting slag were extracted via a hydrometallurgical route. This ore deposit is practically not amenable to extraction by conventional methods. The testwork results proved that the PyEarth™ process was able to optimize the extraction of rare earths while minimizing waste through the removal of iron as a saleable iron alloy. Reduction of iron to the alloy in the smelting step was found flexible, efficient, and controllable, while rare earths were left virtually unreduced in the slag phase. The slag chemistry is selected to optimize both the smelting and leaching performances as well as the alloy composition. Leaching of the resulting slag was found possible and most efficient in hydrochloric acid amongst other lixiviants tested.

Jan 1, 2017

By A. J. Russell

"This paper investigates why it is critical for a mine to accurately determine thermal rock properties and virgin rock temperatures. Theoretical simulations of deep mining production zones have demonstrated that thermal conductivity (k), virgin rock temperatures and specific heat (cp) significantly impact rock heat predictions which can be the dominant component of a mine’s heat load. Natural variability in these factors showed that realistic errors can have a significant effect on mine heat loads. This can ultimately affect miner safety and introduces risk to the viability and sustainability of a project. INTRODUCTION Accurate heat load determinations are critical to ensure that underground working conditions are maintained within legislated and mine specific parameters to safeguard the safety and productivity of employees. Underpredicting mine heat loads will result in hot underground conditions, which risk the health and safety of employees, reduce the productivity of employees or stop production if legislated temperatures in working areas are exceeded. Overestimating mine heat loads will result in increased capital and operating costs reducing the viability of the project. Over- or under- predicting the heat load for a project will increase the project risk. Heat sources in a mine can broadly be broken into two categories. These two categories are defined by Hemp and Rawlins (2014) as natural and artificial heat sources. Those sources which depend on the size, location and depth of the mining areas are defined as natural heat sources, whereas those heat sources which are a result of the actual mining activities are defined as artificial heat sources. Autocompression, or the conversion of potential energy, to enthalpy is an important consideration when determining the air temperature in the mine and its interaction with natural and artificial heat sources. It is documented by Jones (1985) and Hemp and Rawlins (2014), that the heat flow from rock in deep mines can dominate other heat sources; information from BBE’s archives show that this is between 40% and 60% of the total heat load. They also point out the importance of accurately measuring both the thermal rock properties and virgin rock temperatures (VRTs) for determining and planning the ventilation and refrigeration requirements for a mine. Both of these texts cite multiple methods for calculating the heat-flux and ultimately the heat load for the different working areas in a mine. All of these methods demonstrate that the heat flux and heat load will increase proportionally with increased thermal conductivity (k), specific heat (cp) of the rock or mineral, and VRT depending the area of the mine or mining method."

Jan 1, 2019

By Richard Samson

"RésuméComme l'exploitation d'un gisement à grande profondeur représente un défi de taille et que la profondeur à laquelle se situe celui d'Ansil varie de 1200 m à 1460 m, nous avons dû mettre en place une infrastructure de surface d'envergure incluant un treuil de production et un chevalement d'une très grande capacité. De même, l'infrastructure sous terre a été proposée en tenant compte de ce fait important; d'ailleurs, l'excavation de deux puits circulaires dont l'un est en beton et acier et l'autre exclusivement en béton en témoigne. De plus, la plupart des cheminées principales qui furent excavées sous terre sont de forme circulaire.L 'exploitation du gisement s'effectue par une méthode chantier ouvert (abattage par longs trous), remblaye immédiatement âpres avec un mélange de roche stérile et ciment. Un taux de minage de 1750 tonnes par jour est requis pour assurer la production.L 'utilisation d'une technologie de pointe tels: les ventilateurs et les portes de ventilation sous terre contrôlées de la surface, un système de relèves macroséismiques, de chargeuses-navettes contrôles à distance, en passant par le dessin et la planification assistes par ordinateur nous permet d'optimiser l'exploitation du gisement Ansil.IntroductionEtant donne la grande profondeur a laquelle le gisement Ansil se situe, no us avons à mettre en place une infrastructure souterraine et de surface d'envergure pour nous permettre d'atteindre nos objectifs d'exploitation.Infrastructure de surfaceLa mine Ansil dispose d'une infrastructure de surface d'importance possédant une grande capacité (Fig. I). Les deux facteurs qui furent déterminant pour le dimensionnement des infrastructures furent le taux d'extraction de 1990 t/jour et la profondeur a laquelle I 'exploitation s'effectue, puis que cette dernière affecte le temps de cycle et la capacité de hissage.La première composante principale de I 'infrastructure de surface est un treuil de production a 2 tambours de 3.65 m de diamètre et de 2.0 m de largeur chacun. Ce treuil de marque Fullerton, Hodgart & Barclay construit en 1970, opère avec 2 moteurs de 930 kW a une vitesse de 700 m/min. et il a une capacité maximale de 32000 kg. Deux câbles d'acier de 45 mm de diarnètre et de 160 000 kg de résistance a la rupture servant au hissage des bennes d'une capacité de 12 tonnes. De plus, un moteur/générateur de 3000 kW (M.G. Set) raccorde au treuil de production sert a stabliser son alimentation électrique."

Jan 1, 1991

By James J. Roettger, Robert J. Mitchell

"The results of a series of model stope pours designed to investigate working pressures on bulkheads during hydraulic pouring of classified tailings backfill are reported. Total bulkhead pressures and fill water pressures were monitored under the condition of a fully saturated backfill. Similitude of the model testing is discussed and equations are developed to estimate bulkhead pressures under prototype conditions. The model results show that good base drainage, combined with a bulkhead setback, can reduce the expected bulkhead pressures to values such that timber or concrete block structures should be capable of supporting a saturated backfill. Introduction Bulkheads are used in underground running operations to block drift openings in order that hydraulically placed sand backfill can be contained in stope pours. Whenever possible, the sand fill is designed to have sufficient percolation rate so that excess hydraulic transport water will gravity drain out through the bulk headed drifts. This avoids costly decanting systems. Early bulkhead design assumed that the bulkhead pressure could be as high as 0h = Hy where H is the fill height and ""y is the saturated unit weight of the fill (Thomas et al., 1979)(1). A typical design pressure for a 50 m fill height would be 1250 kPa giving a design force of 12,500 kN on a bulkhead located in a drift of 10m2 in area . Typical bulkheads were 1 m thick heavily reinforced concrete structures formed and poured into a notched drift. Not only were these expensive structures but the associated problems of inside drainage systems and curing time delays increased production costs. As experience with bulkheads for large bulk pours increased and fill pressure measurements became available [see, for examples, Libby et al., 1975(2), Askey et al., 1978(3)] , 'free drainage' timber and concrete block bulkheads were designed. Substantial savings have been realized using these types of bulkheads but greater engineering design and monitoring of backfill pours is necessary to ensure that backfill pressures do not exceed the bulkhead design pressures.The effective and total stress components of fill pressure, the engineering concepts associated with the 'free drainage' design and some detailed design considerations have been discussed by Smith and Mitchell (1982)(4) . It is important to the safe use of these designs, however, that the basic engineering concepts be demonstrated and communicated to those responsible for the day-to-day backfill operations. This paper describes and explains observations from a series of model studies designed to measure bulkhead pressures in a saturated fill."

Jan 1, 1984

By Jayesh B. Patel, Zhongyun Fan, Hu-Tian Li

"Melt conditioned direct-chill (MC-DC) casting is a novel technology which combines vertical direct-chill (DC) casting with a high shear device directly immersed in the sump for in situ microstructural control. In this paper, the solidification mechanism of DC casting under varying conditions is discussed. The temperature profiles in the sump were measured under the steady state casting conditions by using sacrificing thermocouples. Detailed comparisons of the derived thermal condition are made. The individual role of grain refiner additions, natural thermosolutal convection and forced convection in the sump and the interplay of these factors in determining the solidification structures of DC cast billets are discussed. The MC-DC casting technology can be used to control microstructural constituents and casting defects in DC cast billets/ingots by in situ manipulating of the thermal and fluid flow conditions.INTRODUCTION Direct-chill (DC) casting of aluminium, has been the essential commercial process for producing feedstock suitable for subsequent processing, such as extrusion, rolling or forging. Fine and equiaxed grain structures in the as-cast billets/ingots are required to enable a fine and uniform distribution of second phase particles and microporosity. This leads to higher productivity, more cost-effective homogenisation and more efficient downstream thermomechanical processing. The addition of chemical inoculants has been the standard industrial operation prior to casting for grain refinement of Al alloys. However, it has been established that less than 1% of the grain refiner particles added actually act as heterogeneous nuclei to refine the grain structures, showing a very low grain refining efficiency (Greer, Bunn, Tronche, Evans, & Bristow, 2000). Moreover, the remaining particles from the grain refiner addition in the final casting may cause surface defects during downstream processing. A major issue of the metallurgical quality of large sized ingots/billets is the non-uniformity of microstructures even with chemical grain refiner additions. This is due to the fact that the grain structure formed in the different zones of the billet depends on the local chemical composition and local cooling rate. The local cooling rate can vary from 0.4~1 K/s at the centre of the billet to around 10–20 K/s at its surface zone (Nadella, Eskin, Du, & Katgerman, 2008). The large thermal gradient along radial direction between billet surface and interior of the melt during conventional DC casting induces thermal stress and cold cracking even with grain refiner addition. Therefore the control of casting defects, such as macrosegregation, porosity, cold/hot cracking and distortion of the billets/slabs, etc., is still challenging in industry, causing high scrap rate of DC cast ingots/billets even with grain refiner addition."

Jan 1, 2018

By R. Bruce Ferguson

"The Kettle River Operation of Echo Bay Minerals Company is located about thirty kilometers north of the town of Republic in northeastern Washington State. In tum, Republic is about a hundred and seventy kilometers north and a little west of the city of Spokane, Washington. It is also about fifty kilometers south of the town of Grand Forks, BC, Canada. At this time it is the only gold mining and milling operation in the State.Tailings are stored in a double lined, zero discharge facility. It became evident in mid 1996 that the rate of free water accumulation in the tailings pond was going to result in the level in the pond reaching its permitted freeboard elevation long before the solids plus pore water capacity was reached.We then embarked on a mission to manage tailings pond water on several fronts: reduce fresh water usage in the process, divert spring seeps and surface runoff and install a system to enhance evaporation.IntroductionThe Republic area is an historic gold mining district. Hecla operated its Republic unit from 1892 until closure in 1994. The Kettle River Operation processing plant is located in the San Poi! river valley at an elevation of just under a thousand meters. The facility consists of a ninety thousand ton ore storage pad as the mines are remote and truck haulage is subject to interruption due to weather and road restrictions, jaw and cone crushing with screening, rod and ball milling to an eighty percent passing size of seventy five microns. This is followed by preaeration with high purity oxygen supplied by a vacuum pressure swing adsorption plant plus lead nitrate addition to achieve passivation of the sulfide mineralization such as chalcopyrite, pyrite and pyrrhotite. Conventional cyanide leaching and carbon in pulp adsorption completes the loop. Tailings are treated with air/S02 to achieve cyanide destruction. Plant capacity is 1,815 tons per day. Our license requires that there be no detectable free cyanide in the tailings pond water and a maximum of forty parts per million weak acid dissociable cyanide. The operation started in 1989 with production from the Overlook Mine located about five kilometers further up the same valley at an elevation of twelve hundred meters, hence the location of the mill. Current mine production comes from Lamefoot in the Curlew Lake valley, about ten kilometers distant, and K2 in the Kettle River valley about fifty kilometers away. Both are at an elevation of about 800 meters. Lamefoot produces 1,360 tons per day and K2, 455. Both are underground operations."

Jan 1, 1998

By Unknown

With the present-day trend of rising labour costs and a lowering of production efficiency of workmen, it has become imperative that every effort be made to use manpower to the greatest advantage and to mechanize mining as much as possible. During the past few years this trend has gained much prominence in the Porcupine camp. In view of this, the executive of the Porcupine Branch considered that the Mechanical Movement of Muck would be a very timely subject for a Symposium. Accordingly a Committee was formed, with A. K. Douglass, Mine Superintendent for Delnite Mines, Ltd., as Chairman, and the Symposium was held in the Auditorium of the McIntyre Community Building, Schumacher, on March 25th last. Papers dealing with shovel loader and mechanical scraper operation at six of the larger mines of the camp were presented and discussed, and a tabulation was prepared giving data on the machines in operation at a total of eleven mines. The papers and tabulation, reproduced below, will doubtless be of considerable interest to operators of mines in all parts of Canada.

Jan 1, 1948

By T. D. Chatwin

Acid rock drainage (ARD) is one of the most serious and potentially enduring environmental problems of the mining industry. High liability costs carried by many mining companies to cover potential obligations of ARD are a clear indication of the gravity of the problem. Unchecked, ARD can result in water quality impacts that could well be the industry's most significant financial and credibility risk. Effectively preventing acid drainage is a formidable challenge that requires the total commitment of the mining industry throughout the entire life-cycle of a mine. To achieve this commitment a strong business case for ARD prevention must be developed. This paper will address the elements of acid prevention and discuss their importance not only to the company but the entire industry as well. The International Network for Acid Prevention (INAP) is an industry-led group created to help meet this challenge. In 2009, INAP published the GARD Guide (www.gardguide.com), a web-base best practices guide for the prevention of ARD [1]. In this paper, the GARD Guide will be used to identify preventative actions for all mining industry stakeholders. It will, in turn, be used to estimate ARD management and mitigation value accrued to the company from ARD prevention, which will be used in developing a business case for acid prevention.

Jan 1, 2011

By Fulchand Shende

Around the world many potash mines experience brine inflow problems. The presence of brine in underground excavations may induce structural and stability problems. A study has been carried out to simulate the effect of brine on the performance of pillar support. The testing program consisted of loading potash specimens in a creep frame, and simulating inflows by continuously pumping brine into an experimental cell. Brine temperatures and load conditions were varied to simulate several mining and inflow conditions. Specimens were fitted with acoustic emission transducers to monitor energy emissions during an eight-hour test duration. Samples of brine were also collected to provide K+ and Na+ concentration data necessary for an accurate assessment of the dissolution process. Test results indicated that dissolution rates are highly dependent on brine temperature and load conditions. Loads approaching 50% UCS tend to generate very high rates of energy emissions, often leading to the failure of the simulated pillars. This study demonstrated that acoustic emission could be effectively used for predicting the performance of pillars when exposed to inflow brine.

May 1, 2001

By Fred A. Webber

STEEL ROPE WIRE is one of the more specialized commodities among the many grades of highcarbon steel wires. In its production there are many metallurgical aspects of interest from the steelmaking on through the final stages of wire drawing. We produce rope wire in an integrated mill com prising all the operations from the blast furnaces to finished wire drawing in the wire mills. Steelmaking is carried out with close control on hot metal, selection of scrap, and fluxing materials. The basic open hearths are of 170 tons capacity. Steel is teemed into 19 1/2 in by 19 1/2 in big-end-down molds and is hot-topped with the use of clay refractory hot-tops. The weight of this ingot is 6,900 pounds. All high -carbon steel ingots are charged hot into the soaking pits and are then rolled through the blooming mill in 16 p asses to a bloom ax~ in. by 41/2 in. and approximately 65 feet long. Necessary bottom and top crops are taken on the bloom as it passes from the blooming? mill to the billet mill. The still hot bloom is continuously rolled through the billet mill in . 5 passes to a 2 3/8 in. square. Billets are cut to 32 feet in length by a flying shear and then allowed to cool on the hot bed.

Jan 1, 1957

By Rodney Trevor Jones, Arthur Robert Barnes

Anglovaal Minerals acquired the Nkana slag dump from Zambia Consolidated Copper mines (ZCCM) in 1998 and embarked on an ambitious project to pioneer the recovery of cobalt from slag using DC smelting technology. Anglovaal Research Laboratories performed initial pioneering smelting tests in a 250 kW DC furnace over a 3-year period before engaging Mintek for three piloting campaigns at the 1.5 MW level. Mintek had previously developed a reductive smelting process, patented in 1995, using a DC arc furnace for the recovery of cobalt from slags. The results of the pilot-plant test campaigns were used as the basis for engineering the commercial 40 MW operation installed at Chambishi Metals plc in Zambia in 2001. This paper traces the development of understanding of the metallurgical fundamentals ultimately used to predict furnace performance, reviews some of the extreme technical challenges faced, how solutions were identified and highlights some of the critical issues identified during piloting and how these impacted both positively and negatively on the final commercial operation.

Jan 1, 2011

By L. Voisin, K. Mühlenbrock

A new pyrometallurgical process is proposed for cleaning complex copper matte and for recovering copper from copper scrap containing lead. In the process, a given amount of pig iron is added to the complex material under a reducing condition to produce two or three liquid phases at the equilibrium, depending on the content of sulfur in system, of copper-rich and iron-rich alloys, and matte, respectively. The novel process is proposed based on the experimental results obtained by performing laboratory scale tests in an electrical furnace at 1473 K followed by a quenching method on the final stage. The samples obtained from the experiments were analyzed by using Atomic Absorption Spectroscopy (AAS), Inductively Couple Plasma (ICP) and Carbon Infrared Spectrometry (CIS) techniques. The results were discussed on the basis of the distribution of lead as impurity in the miscibility gap where equilibrated phases coexist. According to the mass balance calculations, the elimination of lead into the iron-rich alloy phase as a harmless and smaller deposit might be feasible and the process proposed for cleaning the complex matte would be promising.

Jan 1, 2014