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By Simon P. Fricker

Gold drugs have been used for the treatment of rheumatoid arthritis since the mid 20th century as disease-modifying antirheumatic drugs (DMARD) class. Methotrexate is often the preferred DMARD, and with the advent of new therapies gold drugs are now used infrequently. Since the introduction of auranofin in 1985 there has been no new clinically approved gold drug. In spite of this apparent lack of progress there has been a great deal of interest in the use of gold compounds for cancer therapy and early promising indications were achieved with a gold phosphine complex [Au(dppe)2]Cl. This compound was not entered for clinical trials, however, due to problems with cardiotoxicity highlighted during pre-clinical toxicology studies. Gold(III) is isoelectronic (d8) with platinum(II) and likewise forms square planar complexes. It is therefore tempting to speculate that such complexes would have similar antitumor activity to cisplatin. In order to stabilise the gold(III) oxidation cycloaurated complexes were synthesised with a single mononegative bidentate ligand, damp, (2-[(dimethylamino)methyl]phenyl), and two monodentate anionic ligands e.g. Cl or acetate. The damp ligand forms part of a five-membered chelate ring. The monodentate ligands are readily hydrolysed and are available for substitution. These compounds had limited anti-tumor activity in in vivo against human tumor xenografts. Mechanistic studies indicated that these compounds had a different mechanism of action to cisplatin. An alternative molecular target for these compounds is biologically important thiol-containing molecules such as the cysteine protease cathepsin B. Modifications were made to the Au(III) damp structure to give compounds with a six-membered chelate ring. These compounds were shown to be inhibitors of cathepsin B. Compounds were also tested for cytotoxicity against a panel of human tumor cell lines. Three compounds were selected for further evaluation against a human colon tumor xenograft. The compounds showed modest anti-tumor activity but with no marked improvement over the parent Au(III)damp complexes. Initial indications are that Au(III) compounds targeted against disease-specific thiol-containing biological molecules have potential as drugs, particularly for cancer. However, further work is required to produce a target-specific drug with a suitable pharmacological activity and toxicity profile.

Oct 1, 2003

By J. Gillies

"Extraction of Gold in Ketone from a suitably prepared sample of sulphide or siliceous ore or concentrate permits a rapid and accurate determination by Atomic Absorption. Mill test products and exploration development samples are acid-treated to effect complete dissolution of silver, copper, zinc, lead, molybdenum and iron present. Interferences in the determination of molybdenum are described. Results by Atomic Absorption are comparable to those afforded by other acceptable methods.INTRODUCTIONDuring recent years much has been written and discussed concerning Atomic Absorption Spectrometry as a technique for determining the concentration of metallic elements. We would, however, recommend a perusal of the paper presented by J. C. Ingles at the annual meeting of Canadian Gold Metallurgists held in Ottawa, January, 1966. The paper was published in the August, 1966, issue of the Canadian Mining Journal, and contains general information on Atomic Absorption.The purpose of our paper is to present certain specific method procedures for the determination of several precious and base metals normally present in Mine, Mill and Smelter products. Of necessity, analytical results should be as accurate as the most suitable available method permits, whether for metallurgical balance, settlement purpose, ore beneficiation programs, or exploration property development. The success of such programs is relative to the accuracy, speed and economics of the analysis. It is obvious, therefore, that in presenting our paper we consider the technique has achieved the desired evaluation."

Jan 1, 1968

By Bing Li, Kai Liu, Yongcheng. Zhao

With the ongoing development of copper smelting technology, the improvement of environmental emission control and achieving an automated continuous copper pyrometallurgical process have become the key development goals for copper smelting. The double bottom blowing continuous copper smelting process combine bottom blowing smelting (SKS) and bottom blowing converting (BCC) process and fire refining as “three-connected furnaces” arrangement is a pyrometallurgical process independently developed by China’s ENFI which can continuously produce copper from raw material through to anodes. This technology can improve energy efficiency and reduce environmental emissions for the overall copper smelting and converting process. This paper discusses the engineering characteristics and production practice of the SDIC Jincheng Metallurgical Project, which operates SKS smelting and BCC converting process with “three-connected furnace” arrangement for the first time in the world. Advanced engineering concepts and tools were used to optimize the configuration during the project engineering stage. The operation shows that the process has good environmental performance, reduced energy consumption and high level of automation, which is a new choice for copper continuous smelting process. INTRODUCTION One of the most important developing trends for the overall copper smelting process is to develop a continuous operation. Continuous copper smelting can maximise energy efficiency in copper concentrate and make full use of the rich heat treatment system. Cold charge and a part of low-heat-generating materials, which are processing with additional equipment in traditional copper smelting process, can be processed with rich reaction heat in continuous copper smelting and converting process to achieve good economic benefits. Yuan and Wang (2017) noted that SKS+BCC copper smelting process can reduce the secondary SO2 emissions compared with discontinuous copper smelting process, which required transportation of melted matte by matte ladle and may cause secondary pollution. The continuous copper smelting process can also reduce the generation of intermediate cold materials.

Jan 1, 2019

By Ayako Iwakoshi

Highly concentrated pastes of gold nanoparticles were successfully produced by use of a special kind of protective polymer and a mild reductant. Solid part of the pastes consists of up to 85wt% of gold nanoparticles, 10~30 nm in diameter, and residual protective polymer. This component can be diluted by any kinds of solvent at arbitrary rates. Electronics, optics, catalysts, colorants and surface metal coatings are possible application fields. 1. Introduction Noble metal nanoparticles are of interest in a variety of fields ? such as colorants, metal coatings, electronics(1), optics(2), and chemical catalysis(3). Especially, in the color field, the gold nanoparticle has been known as an aesthetic red colorant for stained glass and fine glassware, such as Venetian glass. The mechanism of coloring is attributed to surface plasmon absorption of gold nanoparticles(4,5). The gold nanoparticle in stained glass shows very clear red color, which is very durable for hundreds years. On the other hand, the red color of organic pigment in paint films often fades away within several years. We intended to reproduce the elegant and stable coloring of stained glass in paint films. In order to color a very thin, 20~50?m, paint film like stained glass, production of highly concentrated dispersion of gold nanoparticle is necessary. To achieve this, there were two issues to be overcome. One is how to prevent the coagulation of gold nanoparticles in highly concentrated solution. So far, several methods to prepare gold nanoparticles(6,7) were reported. But only a few methods succeeded to stabilize the gold nanoparticle dispersion at higher concentration than ppm order. The other is controlling of the particle size, this is because the color of gold nanoparticles is very sensitive to the particle size. Only when the particle size lies around 10 nm, the suspension exhibits red color like stained glass.

Oct 1, 2003

By Ron Hatch, M. K. Witte

"INTRODUCTIONThe proper selection of carbon for a gold carbon in pulp (CIP) circuit involves careful evaluation of several physical, chemical and economic factors. A series of evaluations are required to maximize gold recovery at the lowest capital and operating costs, whether the carbon is selected for an existing gold mill circuit or a new mill under design.Although evaluation may proceed through various stages, it is the intent of this paper to outline some of the preliminary testwork that should be carried out to screen potential carbons for a particular application.An examination of the specification sheets supplied by the various carbon manufacturers may indicate some desirable properties on which to make cursory selection. This exercise by itself will not provide the basic data needed for selecting the best carbon for a particular ore pulp and metallurgical circuit. The necessity of further metallurgical evaluation is indicated by the fact that different carbons perform differently depending on the physical and chemical nature of the leach pulp. In the case of an existing mill, actual leach slurries using mill water are available and should be used for testwork. In the case of new mills, leach pulps must be prepared to simulate the proposed circuit.Five coconut shell activated carbons were obtained from various suppliers, all reported to be 6 x 16 mesh carbons recommended for CIP circuits. A metallurgical evaluation was made utilizing two leach pulps with significantly different characteristics. This paper describes the test procedures utilized and the results obtained from the testwork."

Jan 1, 1985

By J. W. Jefferies

"Plant availability up 13%, production output up 40%, tons per employee up 15% and labor turnover down 52%. One mine manager states these were direct spin offs from the work being done to qualify for a safety award in the program known as the ""IMSRS 11 over a three-year period of time. ""Of Course"", stated this manager, ""these were in addition to an 87% reduction in our disabling injusry frequency rate.”Officially known as the International Mine Safety Rating System or the Five Star Mine Safety Rating, a new approach to mine safety is being used with enthusiasm by a significant number of mines in Canada, the U.S., Australia, Chile, Indonesia, the Philippines and South Africa. Significant results are coming into the International Loos Control Institute from over 125 mines from these countries.The program is built around a mine safety audit system that gives positive recognition to a mine at 5-step intervals along the way, (a star with each step attained). The Institute has licensed auditors in locations in Canada and the U.S. available to audit.It is believed the success of this program is the result of the premise upon which the program is based. The results being achieved are due to the concept that a modern, well-managed mine safety program maintains the basic foundation of a complete management system. When properly implemented, it reinforces those factors common to production, quality and safety. (Attitude - skill - knowledge - fitness - structure - machine - equipment - materials and processes). The IMSRS contains elements that reinforce all these factors. It uniquely treats safety as part of the ""right way"" to do the job and not just the ""safe way"" as a distinctly separate entity. Mines using this program now recognize that many of the older safety techniques were not necessarily the right way or the most efficient way to do things. It appears that this new approach to mine safety is a new avenue for the attainment of management's real goals for being in business, and at the same time achieves optimum support for the important target of safety and health for the mine worker."

Jan 1, 1983

By Magdy Ibrahim

Detailed as-built project schedules are necessary to close out construction projects, benchmarking, forecasting, dispute resolution, and improving cost estimates of future projects. Manual procedures for developments of as-built documentation is time consuming, involves numerous interfaces and human interventions. This paper presents computational framework that encompasses automated site data acquisition and generates schedule updates utilizing commercially available project scheduling software. The work is carried out collaboratively with a Hydro Quebec team. The site data is captured employing mobile computing using iPad® type computers and Wi-Fi. The information is directly compiled in a centralized database server. The synchronization tool is a bi-directional application and is used on servers to communicate with iPad® computers deployed onsite. The captured data is stored in Microsoft SQL® relation database that consists of 63 entities. Computer software application has been developed in Microsoft Visual Basic® (vb.net) environment for extracting the collected site data, linking the database to the as planned schedule, and generating the actual, also known as as-built schedule. The development can be utilized in automated progress reporting, evaluating future bids, generating master schedules and a wide range of efficient EVM applications.

Aug 1, 2013

By H. J. Chalmers

"Since the advent of large volume flotation machines, Cominco Ltd. has actively studied possible application of such machines to their various milling operations. A number of installations have been made and more are on the drawing board. This paper gives a description of these units, information as to choice of equipment, and information as to operating experience. Mechanical and operating details of six installations are summarized. Three different types of machines are discussed.Pine PointThe original Pine Point zinc flotation circuit comprised conventional roughing with two stages of cleaning. Over the years with increase in feed tonnage there have developed two adverse conditions; namely, a reduction in zinc concentrate grade coupled with an increase in MgO in the concentrate. This resulted in higher freight payments along with more severe smelter penalties. An intensive test program, in 1971, showed that the concentrate grade could be raised by 1.5 units of zinc along with a reduction in MgO from 0.8% to 0.47.. Subsequently this was done by adding two additional stages of cleaning using 16 cells of Denver 200-V's. The project was completed in January 1973 at a cost of $510,000 to give an estimated annual savings of about $390,000.Selection of the Denver Model 200-V was based on minimum floor space requirement, availability, and favourable operational and maintenance experience with Denver 100’s. As it happens it was possible to ""shoe-horn"" the 16 cells into place with a minimum of plant alteration. Some problems have been encountered with a tendency to ""sand up"" at high pH, particularly at the corners. Otherwise operational service has been very good."

Jan 1, 1974

By Juan C. Sotomayor Álvarez

The Huantajalla mine is seated on Uchucchacua 's Mixing District that is the fourth producer of Silver in the world. Huantajalla Mine is a new mine that nowadays is being explored and recently it has began to operate. The project for 4-A vein exploitation in Huantajalla Mine using Longhole drillings as a new method of mixing is developed by Planning Department of Uchucchacua Mine in coordination with Geology Department of this mine, started in June 2004. This project is funded by Company of Mines Buenaventura S.A.A In July 2002, Geology Department started the exploration on the area of Huantajalla Mine, discovering the 4-A vein. The reconnaissance and definition of the vein finished June 2003, finding 79,080 Ton of mineral of Silver with a grade of 40.0 Oz Ag/ton and a thickness of 1.85 meters (6 feet ). Using the longhole method on the vein exploitation will replace the cut and fill and shrinkage methods, and it will keep a dilution of 15%.

Oct 1, 2004

By Peter Heine

Diavik Diamond Mines Inc. (DDMI) has treated systems development as an integral part of the construction project when it built Canada?s second diamond mine. Fully aware that the proper collection and processing of operational data is needed to drive business decisions during production and planning, key Performance Indicators (KPIs) were defined to effectively manage operations when the mine went into production. The Production Information Management System (PIMS) allows KPIs to be measured, reported, and transferred to other systems in a reliable and convenient manner. PIMS provides a mechanism to collect real time production data from the various control systems around the site and acts as a tool to ?drill-down? and establish the important cause-effect relationships that impact the value of a KPI. Thus PIMS provides a data collection, storage, management, and an environment in which cause-effect relationships can be analysed and statistically verified. This understanding of the real cause-effect relationships, close to the source of the data and in the context of the operation, can be used to improve both operations and maintenance performance. The PIMS includes the PI Database implementation, its associated external interfaces with the various Control Systems, Cleaning Packaging Weighing System, Environmental System, Enterprise Asset Management (EAM) System, and Diamond Tracking System (DTS), as well as laboratory data collection, custom applications (downtime tracking, data reconciliation) and user clients. The interface with the EAM system provides material flow quantities and equipment availability on which the plant performance reports are based. The transfer of equipment usage to the EAM system is fed into the maintenance notifications and work orders functionality in the EAM. The environmental system interface provides the mechanism for capturing water consumption data required to generate the various regulatory reports. The interface to the cleaning-packaging-weighing system provides the mechanism for capturing batch data for transfer to the DTS for diamond product tracking at the production splitting facility in Yellowknife. The PIMS lab application provides a means of getting sample data into the system for critical metallurgical metrics, and the data reconciliation application provides a means of manually verifying the data before it is published or passed onto other systems.

May 1, 2003

By W. M. Lupton

"Internal grinding mill entries are routinely done by mill personnel during scheduled maintenance periods. Reasons for entry include mill liner life profiles, liner inspcections and replacement and grinding media investigations. These entries require employees to adhere to safety regulations and policies including special permitting, testing, procedure-following practices and the wearing of proper personal protective equipment.A realized semi-autogenous mill entry safety hazard is the unpredicted breakage and occasional shattering of large diameter grinding media while personnel are inside. This was a concern to both media user and supflier. American Barrick's Holt McDermott Mine has improved mi l operational procedures and the media manufacturer has assisted by their developments to essentially eliminate this problem.This paper presents the improvements instituted; and the author's wish to communicate this potential hazard to other large diameter SAG ball users or potential users.INTRODUCTIONAmerican Barrick' s Holt McDermott mine is situated on Highway 101, some 70 kilometers northeast of Kirkland Lake, Ontario, 120 km east of Timmins and 90 km northwest of Rouyn Noranda, Quebec. The mine draws 160 employees from these surrounding areas to extract and process the underground ore, and recover near 60,000 ounces of gold per year. The mill department is completing it's fifth year of operation this spring.The company and the employees are proud of the safety improvements realized over the short history of the mine. Post accident/incident reviews and pro-active safety awareness programs have substantially reduced the mine's accident frequency and severity to date.One of the mill department's objectives is to provide a safe working environment for mill personnel, which includes the interior of the grinding mills."

Jan 1, 1993

By Chris M. Healey

"Perhaps the single most significant variable in the evaluation of a mining project is the reserve estimate. Many parameters are considered when estimating reserves, among them geology. This paper examines the link between the quality of a reserve estimate and a good understanding of the geological controls for the deposit. A clear understanding of the geometry is essential to the accurate definition of the shape and size of the deposit. This includes the definition of any structural controls as well as the proper interpretation of the stratigraphy. Further when the distribution of grades is erratic and there is consequently a high nugget effect, there are significant problems in estimating the true grade of the deposit.Two Saskatchewan examples are presented, one with good knowledge of the controls and therefore good estimates of reserves, and the other with a poor understanding of the geology and resultant problems in deriving good estimates. In both cases the reserve estimates at various stages in the project development are compared to actual results from underground work. The first example is the Star Lake Mine where just about all the estimates were within 10070 of the actual on both tonnage and grade. The Laurel Lake deposit is discussed to show how problems in interpreting the geological data make reserve estimation very difficult. Laurel Lake has the additional problem of erratic grade distribution."

Jan 1, 1992

By M. Timberlake, A. J. Jonaitis

"The DENVER Tube Press is a simple, high pressure (1500 PSI (100 bar)) filtration unit, developed for processing difficult-to-dewater materials and to produce a handleable filter cake and clear filtrate product.Lab and Pilot testwork conducted in Australia on coal fines (55-70% -35 micron (400 mesh)) have shown that total moisture contents of less than 20% are consistently achieved in the final cake products from the Tube Press.currently, these coal super fines are sent to waste due to uneconomical mechanical dewatering methods, which were only able to reduce total moisture levels in excess of 30%. Calculated, throughput rates for the 500 series Tube Press exceeded 1700 kg/hr (3750 lbs/hr). Feed solids concentration requirements are between 45 and 50% to achieve these results.INTRODUCTIONThe DENVER Tube Press is an automatic membrane high pressure filter press, which operates at hydraulic water pressures up to 1500 PSI (100 bar). The Tube Press was developed in the late 1960's by Charlestown Engineering, st. Austell, Cornwall, England, formerly a division of English China Clays, Ltd., to address more effective methods of moisture reduction of micron-size china clays. The Tube Press reduced moisture sufficiently to produce a hard surface-dry, handleable cake and clear filtrate discharge, which was recycled into the process. This development work was conducted using a 200 Series Tube Press (200 mm diameter x 2500 mm long filter surface)."

Jan 1, 1993

By D. J. Bowen

"The Great Dyke extends for 540 krn along strike, to unknown depth, and varies in width from 3 krn to 11 krn. Rb/Sr age determinations gives values of approximately 2470 Ma.The Dyke consists of a variety of mafic and ultramafic rocks, many altered to serpentinites. These include, from top to bottom, successions of gabbro/norites, pyroxenites, peridotiteslharzburgites, and dunites/picrites.The layers dip in from either margin, steepest at the edges (20°) and flattening toward the central sections. Four separate complexes are present. From north to south these are termed the Musengezi, Hartley, Selukwe and Wedza Complexes, and are described as 'boat-shaped' or 'pig-troughed'. All are similar in petrological sequences. Physiographically, the Dyke is spectacular in the north, where as a mountain range it meets the Zarnbezi Escarpment. Elsewhere in the central parts there is little surface expression and wide open treeless vleis. Dyke rocks cut through granite and schist belt terrain and are termed 'The Magnesia Belt'.Vast mineral resources exist. These include chrome, asbestos, platinoids, nickel, copper and gold. Up to eleven chrome seams numbered from top to bottom occur in the lower ultramafic sequences. Seams are narrow at 10 em to 30 em but of high grade. The platinum occurs 10 m to 40 m below the norite/pyroxenite contact.A 60 m wide zone of Light Sulfide Mineralization (LSM) of less than 1070 sulfides extends from the lower gabbronorites into the upper pyroxenites. In this LSM, four enriched zones carry up to 5% sulfides. The most widespread is termed the Main Sulfide Zone (MSZ), below which is No. 2, No.3 and No.4 Sulfide Zones. The MSZ carrying pyrite, pyrrhotite and chalcopyrite is a multielement ore with components of PGE (pt-Pd-Rh), nickel, copper and cobalt, and gold and silver.Extensive exploration programs have been carried out and the intention is to begin large-scale mining. However, with Russia supplying metals to the western markets, South Africa's cutback on production, and an end to the Cold War, delays have arisen."

Jan 1, 1994

By D. G. Cerigo

"INTRODUCTIONAn interim report covering an uncompleted project on revenue mill optimization was presented at the invitation of Mr. C.S. Stevens, the Secretary of the Canadian Gold Metallurgists. The work described summarizes the preliminary work carried out at the Noranda Research Centre on computer mill optimization and is an attempt to arrive at a model of a circuit using the ""black box"" approach and hence by using economic factors related to concentrate dollar value to maximize revenue. The help and cooperation of Mr. J.D. Wild, Mr. M.J.S. Bennett of Noranda and Dr. A. Bobkowicz of McGill University is gratefully acknowledged.DERIVATION OF MODELHistorical data from the Normetal mill were used for the study. Normetal ore contains chalcopyrite, sphalerite, gold, silver, pyrite and pyrrhotite. For simplicity, data were chosen for days when only two concentrates had been derived, a copper concentrate which also contains the gold and silver, and a zinc concentrate. In these periods when pyrite concentrate was not produced, its circuit was used as an extra zinc scavenger unit. Figure I is a schematic drawing of the circuit and Table I explains the nomenclature.The mill had been operated to obtain a fixed grade of copper and zinc in the copper and zinc concentrates respectively, at the same time insuring acceptable recovery levels. The target grade for the copper and zinc concentrates had been derived by manual calculations based on past experience. The data used were 170 sets of daily mill reports, a sample of which is shown in Table II. The data consist of daily tonnages of feed, concentrates and tailings and their average compositions obtained by taking samples every twenty minutes from each stream and analyzing the daily composite samples."

Jan 1, 1967

"The Dome Mine, located in South Porcupine Ont. has been in operation since 1910 and is owned and operated by Placer Dome Inc. The current milling facilities were constructed in two phases with the first being commissioned in 1982. It consists of a grinding, gravity separation, thickening, and leaching circuits. The second phase was commissioned in 1988 with the addition of the CIP, stripping, electrowinning, and carbon regeneration circuits.It is now common practice in the gold processing community to add liquid oxygen to leach circuits to increase both recovery and kinetics. Along with these benefits the metallurgical group at the Dome realized the potential to replace compressed air with liquid oxygen as a source of oxygen for the dissolution of gold. A plant trial of liquid oxygen was undertaken during the fall of 1991. The results of this first test were favourable enough to warrant further investigation, and a second plant trial was conducted in December 1991.The data generated as a result of each trial revealed that oxygen could be economically substituted for compressed air as a source of dissolved 02. The energy savings in required horsepower enabled a rapid payback period. Thus the project was approved in the spring of 1992 and l should be operational during the final quarter of 1992. INTRODUCTIONIn a continuing effort to reduce operating costs and improve recovery at the Dome mill it was decided to investigate the feasibility of adding liquid oxygen (02) to the leach circuit. It is now common practice in the gold processing community to add 02 to the leaching process to increase both kinetics and recovery. It was anticipated that an increase in kinetics would allow us to eliminate one or more leach tanks while maintaining acceptable recoveries. The metallurgical group felt that along with these benefits, the potential was also there to reduce power consumption through the reduction in the processing of compressed air which is quite costly (12 cents/1000 cubic feet per minute in 1991)."

Jan 1, 1993

By Peter Godbehere, Christian Desroches, Viken Baboudjian

"Noranda Copper Smelting and Refining is a unit of Noranda Metallurgy Inc., comprising the Home smelter in Rouyn-Noranda, Quebec and the C.C.R. Refinery in Montreal East. The Home smelter provides custom smelting services for a wide variety of copper and precious metal bearing concentrates and recyclable materials, producing over 200 000 tonnes of anodes and 450 000 tonnes of sulphuric acid annually. The C.C.R. Refinery has an annual production of 360 000 tonnes of copper cathode, and is a major refiner of precious metals.Over the past twenty years, Noranda Copper has developed innovative processes and operating techniques to treat the ever increasing complexity of primary feed materials, while improving the quality of its final products, working conditions and reducing environmental emissions.This paper presents an overview of the operating practices of Noranda Copper with particular emphasis on the impact of impurities in the smelting and refining processes.IntroductionThe treatment of custom materials has been practiced by Noranda Copper since commencement of operations at the Home smelter in 1927 and the CCR refinery in 1931. Copper concentrates from a wide variety of regional, North American and overseas producers account for the bulk of the 800 000 tonnes treated annually, although recyclable and secondaries have increased in importance as feed sources in the past two decades. The geographical disadvantage of the Horne smelter compared with most custom smelters located on tidewater has provided an important incentive for Noranda Copper to develop the necessary technology and operating practices at its smelter and refinery to treat high value complex concentrates and other feeds containing significant concentrations of bismuth, antimony, arsenic, lead, tellurium, mercury, etc."

Jan 1, 1995

By A. Dunnett, N. J. Turner, J. Koyanagi, M. Ji

The analysis of rare earth element (REE) samples is a necessary part of the metallurgical process for rare-earth bearing ores, providing invaluable information during testing procedures. This requires a fast, multi-element technique, capable of analyzing a variety of matrices for all rare earth elements. X-ray Fluorescence spectrometry and Instrumental Neutron Activation Analysis are typically used for high concentrations of REE, but they have limitations for some process work applications due to an inability to measure all elements, longer analysis times, significant interferences and elevated detection levels. The work reported here uses new approaches with Inductively Coupled Plasma Mass Spectrometry (ICP-MS) in order to achieve high precision and accuracy within acceptable timeframes. A combination of aerosol dilution and Kinetic Energy Discrimination (KED) produce a process solution assay method that is robust enough to deal with changing sample matrices and concentrations, whilst maintaining low reporting limits and precisions of less than 5% Relative Standard Deviation (RSD). For high concentration metallurgical and geological samples, a sodium peroxide fusion digestion procedure was used, followed by ICP-MS analysis using extended dynamic range (EDR) and KED. Using these technologies, it has been demonstrated that the necessary support can be given to metallurgical process work for REE extraction.

Jan 1, 2014

By Paul G. Dunn

Safe rapid drift development results principally in reducing exposure of underground workers to the working face. This reduction in exposure is not achieved until either the rock walls have been suitably scaled or sufficient support has been put in place. Rapid drifting enables quicker access to orebodies (increasing returns), higher production rates and a resultant lower cost of mining. The Mining Innovation, Rehabilitation And Applied Research Corporation (MIRARCO) has been developing technology and a methodology for safe rapid drift development within the underground metalliferous mining industry. In terms of rock scaling for underground metal mines, there is still considerable use of manual and mechanical impact rock scaling techniques. Two main issues result from this approach. The first is that in highly stressed or highly fractured ground, a decision has to be made as to when sufficient scaling has taken place. This is not always easy to do and hence operator judgment is a crucial element in this approach. During a baseline study of current rock scaling practices, a wide range of scaling practices were observed within five different underground mining operations; this demonstrates the difficulty inherent in the rock scaling quality decision making process. The second issue is related to the exposure of workers to freshly created rock surfaces. In manual scaling techniques this is unavoidable and despite the best scaling practices, accidents still occur. In an attempt to provide an alternative scaling technology, MIRARCO has been investigating highpressure water jet scaling for removing loose rock as part of the drift advance process. This technology not only provides a means by which scaling practices can be engineered (remove the loose material you want to in a given rock mass condition), it is also quicker and easily automated. Automating the scaling process removes workers from exposure to freshly created rock surfaces and also enhances the application of spray-on liners through improved adhesion of these support types to the rock surface. This paper describes the water jet scaling technology research and methodology for safe rapid drifting within the underground metaliferous mining industry and highlights the key issues and major drivers behind their continued development at MIRARCO.

May 1, 2004

By K. Sasaki

Ventilation measurements were carried out in a shallow underground-quarry space with relatively large internal volume of 14,600 m3 in order to evaluate its effective ventilation characteristics. Based on air velocity measurements with an ultrasonic anemometer in the exhaust airway connected to the space, it was found that the space was ventilated by natural ventilation airflow with intermittent changes in direction. It was difficult to measure the ventilation flow with typical methods of flow measurement provided from the intake portal and throughout the mine, because the cross-sectional area and volume of the openings were too large and the flow was variable. In the present study, a tracer gas method was applied to evaluate the effective ventilation airflow rate in the space. A photo-acoustic infra-red gas monitor, highly sensitive to SF6 gas used as a tracer gas, was set in the space to determine air exchange rates from gas concentration-time decay curves. The seasonal variations of airflow and thermal environment in the space were investigated through 13 sets of measurements taken over 15 months. Airborne rock dust concentrations were also measured at same time in the opening. The correlations between the effective ventilation airflow rate, thermal environment and dust concentrations in the opening space were analyzed and are discussed based on the presented measurements taken during year. It is concluded that seasonal variations in effective ventilation flow and the dust concentration are mainly due to differences in air temperature in the space, as affected by the rock?s surface temperature and atmospheric temperature. In summertime, the air temperature and associated air density difference generated lower natural ventilation flows resulting in higher dust concentrations.

Aug 1, 2013