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Provide an accurate, reliable means for determining when a sealed mine or mine section can be safely reopened after a fire. Approach The Bureau of Mines performed a research investigation that resulted in the development of a mathematical formula for deriving a quantity, called RATIO, which can be used to define when a sealed mine or mine section has returned to safe recovery conditions after a fire. Research Results There were two major results from this Bureau research. Over a period of several years, the Bureau of Mines conducted six experiments at its Bruceton Experimental Mine in Pennsylvania. The experiments involved sealing the mine after several tons of piled coal had been allowed to burn continuously for 2 to 3 days. Although gas data obtained during the experiments revealed nothing significant, measured smoke particle levels were found to correlate with the stages of combustion and temperatures of the smoldering coal pile. Moreover, it was found that no smoke particles are produced when high-temperature smoldering exists deep within the mass of the coal pile since the smoke particles are filtered by the coal surrounding the hot region. Smoke is emitted into the mine atmosphere only if combustion is occurring near exposed surfaces. As suggested by these findings, any decision to recover a sealed mine area based primarily upon the absence of smoke particles is not a wise derision.

Jan 1, 1988

To provide a means for mechanically separating and recovering nonferrous metals continuously from non-magnetic reject material produced at scrap automobile shredding facilities. Approach The Bureau of Mines developed a water elutriator system that separates metals from shredded scrap auto-mobiles based on differences in specific gravities. A premium-quality product, containing aluminum, magnesium, lead, zinc die cast, copper, copper alloys, and stainless steels, is obtained. How It Works Mixed nonmagnetic reject material currently being separated at automobile shred-ding facilities is introduced onto the top of an upwardly flowing vertical column of water. The water, overflowing a weir in the top of the vertical column, carries with it the floating, lightweight waste materials, mostly combustibles, while the heavier pieces sink through the rising water. Medium-density substances such as glass, rubber, and heavy plastics are carried off through a side port, located in the upper third of the column. The cleaned, mixed metal product sinks to the bottom and is continuously removed from the base of the column with a bucket elevator having perforated buckets. All three categories of material are removed from the system on separate wire mesh belt conveyors. Most of the water drains through the belts into a holding tank and, after settling, is recirculated back through the elutriator column. The purity and recovery of the metal product are influenced by two elutriator operating variables: the flow rate of water through the vertical column, and the height of the overflow weir at the top of the column.

Jan 1, 1983

By R. C. Ellman

Significant effects of in-the-mill drying on the pulverization of lignite have been demonstrated in an experimental impact-type pulverizer by tests in which the primary variable was temperature of the sweeping gas. Reduced power requirements and increased product fineness were observed as the extent of drying was increased. Pulverization with in-the-mill drying was studied in comparative tests made on lignites from five mine sources. All of the lignites responded in a similar manner; however, differences in the pulverizing characteristics of the individual lignites were significant. For one lignite, the electrical input to the pulverizer driving motor with minimum sweeping-gas temperature was 33.9 kw.-hr. per ton, decreasing to 14.0 kw.-hr. per ton with a sweeping-gas temperature of 658° F.; for another lignite, at comparable operating conditions, the electrical input decreased from 59.1 to 19.0 kw.-hr. per ton. In the first case, the product fineness increased with increasing temperature of sweeping gas from 65.2 to 79.2 percent through a 200-mesh sieve, and in the second case, from b2.7 to 86.9 percent through a 200-mesh sieve.

Jan 1, 1962

By Forrest T. Moyer

Injury experience in the mineral mining and processing industries during 1968 was slightly improved in the nonfatal-injury record but worse in the fatality record. The resulting frequency rate of all injuries was slightly better, whereas the injury-severity rate retrogressed appreciably from the figure for 1967. Overall operating activity, as measured by man-hours of worktime, was slightly higher in 1968. However, there were several major segments of the mineral industries in which activity was lower owing to reduced demand for mineral products and to several major work stoppages. These statistics comprise the injury and work experience of all personnel engaged in production, exploration, development, maintenance, repair, and force-account construction work, including supervisory and technical personnel, and working partners and owners at mineral-producing and mineral-processing establishments in the United States. Data concerning officeworkers are excluded except for the oil and gas industry for which such information is not separable. All injury rates and totals are calculated from data before rounding. The data for 1968 are preliminary except for the anthracite, coke, petroleum and natural gas, native asphalt, peat, and slag industries, which are final. The figures represent full coverage for all industries except oil and gas for which coverage is not complete, particularly with respect to small companies.

Jan 1, 1970

By W. E. Robinson

Oil-shale samples selected from a core of the Green River Basin (Wyoming) were studied to ascertain differences in the composition and/or chemical structure of the organic material in the samples relative to stratigraphic position within the Green River Formation. This involved a systematic study of the soluble organic material and the insoluble kerogen present in the samples. Emphasis was placed upon the distribution of the alkanes (normal and isoprenoid compounds) in the soluble extract and upon the aromaticity of the kerogen. In general, it was concluded that significant differences exist in the chemical structure of the oil-shale organic material from various strata within the Green River Formation of Wyoming. Most of the compositional and structural changes were not related to burial depth but were related to source material variations, environmental differences, or other factors.

By John J. Sammarco

As part of a project to automate coal extraction, computer control of a continuous mining machine test bed has been developed and tested by the Bureau of Mines. A computer system and control software were developed for accurate positioning of the conveyor elevation and swing, stabilizer jack, gathering head, and shear elevation. Tramming actions are also controlled by the computer. The computer system was designed to access data from sensors installed on a continuous miner and to interface with the existing control circuits of the miner. Testing in free space was used to characterize the operation of the machine. From this information, control algorithms were written and stored in the computer. The ability to control each function of the continuous miner with a high degree of accuracy and stability was successfully demonstrated in a series of tests in free space and in mining a block of simulated coal. In the mining of simulated coal, the cutting drum was instructed to position the shearer at the top of the block and shear down to the bottom under closed loop control. The cutting drum came within 0.27 in of the top and within 0.49 in of the bottom of the block for this shearing test.

Jan 1, 1988

By John C. Holtz

The Bureau of Mines studied air contamination caused by diesel exhaust in a 10,000-ft ventilated tunnel. Sequential air samples were taken at the ends and middle of the tunnel during an operating cycle. Observed and calculated results for carbon dioxide, carbon monoxide, and nitrogen oxides were essentially in agreement. Nitrogen dioxide was present only in trace amounts. It was found that contamination was related to the volume of ventilating air, the number of haulage trips, train speed, and engine load.

Jan 1, 1968

Improve face ventilation in mines with large cross-sectional entries. Approach Oil shale, salt, and limestone mines typically have large entries. Providing adequate airflow to the working faces of such mines for worker comfort, health, and safety is a substantial ventilation problem. If diesel equipment is used at the face or if a methane hazard exists in the mine, the problem becomes even more complex. To address this problem, a study was conducted under a joint contract between the Oil Shale Committee of the Colorado Mining Association and the Bureau of Mines. The study evaluated two face-ventilation concepts for large-entry mines. Improving Ventilation Two face-ventilation systems were selected for testing of an oil-shale mine, based on results of a cost/benefit analysis. The systems were a free-standing jet fan and a ducted fan operating in the blowing mode. The jet fan was spotted on the intake side in the mouth of the entry being advanced with final positioning, in or out, deter-mined by minimum recirculation. The ducted fan was also positioned in the mouth of the entry being advanced, with its tubing terminating 75 feet from the working face. The mine face entry was a dead heading 55 feet wide, 30 feet high, and 320 feet long. Sulfur hexafluoride (SF.) tracer gas was used to measure the performance of the two systems in diluting mine face pollutants including after-gases from blasting, hot diesel emissions, methane roof layers, and methane emitted from muckpiles.

Jan 1, 1987

By Basil Dimitriades

Five recently developed methods for determining nitrogen oxides in automotive exhausts have been evaluated from the standpoint of accuracy and applicability in current exhaust studies. Results showed that methods requiring conversion of nitric oxide to nitrogen dioxide as a part of the analytical procedure are subject to errors introduced by the instability of NO2. The extent of some of these errors has been determined and procedures have been developed to minimize undesirable influences. On the basis of the results obtained from this study, recommendations are made regarding procedures for batch type or continuous measurement of nitrogen oxides in exhaust streams.

Jan 1, 1968

By B. G. White

NIOSH researchers have identified a pattern of fracture zone development that suggests an explanation for fracture formation around rectangular openings in underground mines. This pattern is characterized by shearing and dilation that result in either faults or in the repeated formation and propagation of en echelon fractures from sites of tension. Two computer modeling codes, Fast Lagrangian Analysis of Continua (FLAC) and Particle Flow Code (PFC), were used to model different aspects of this pattern. Use of very small elements with FLAC enabled the identification of sites of initial tension near the skin of square-cornered rectangular openings, while PFC allowed the initiation and progressive development of fractures from these sites to be followed as the fractures evolved. Such studies can lead to a greater understanding of how roof support can be better selected and installed for specific conditions in underground mines prone to roof falls and rock bursts. These studies may also lead to modifications of corner and opening shapes that could be incorporated into mine designs to produce more stable mine openings and reduce the risks of rock falls and rock bursts.

To develop a system which will effectively detect and extinguish fires in underground fueling areas while also providing a warning for nearby miners. Approach A system involving optical fire sensors. automatically-released dry chemical and aqueous film-forming fluid (AFFF) fire suppressants, and automatic alarms was designed from off-the-shelf, state-of-the-art components, and was in-mine tested at two mines in the two typical underground fueling area situations: fuel transfer areas and fuel storage areas. How It Works As mines become more mechanized, the number of fire hazards increases since fueling areas are more abundant. Fire hazards are especially serious in deep mines, since escape time is longer. To help solve this growing problem, the Bureau of Mines, in cooperation with the Mine Safety and Health Administration (MSHA) and the National Fire Protection Association (NFPA), has developed and in-mine tested a cost-effective fueling area fire protection system. The system was designed to be rugged enough for reliable, long-term use, yet to utilize state-of-the-art, off-the-shelf components to maintain cost-effectiveness. The system consists of cross-zoned, ultraviolet flame sensors used for quick response to fire, and a dual-agent fire suppression subsystem. A dry chemical is used for fast fire -knockdown," and AFFF (or "light water") is used for long-term, fire-securing capability. The basic components of the system are shown in the schematic illustration.

Jan 1, 1982

By Gerrit V. R. Goodman, Charles D. Taylor, Edward D. Thimons

Future coal mining systems will be able to cut from crosscut to crosscut where advances could exceed 100 ft. However, limitations arise when ventilating such mining systems. In deep advance mining, there would be no workers at the face to advance ventilation tubing or curtain manually. Traditional methods also provide no means for maintaining face ventilation after the miner backs away from the face. U.S. Bureau of Mines research is studying means to provide effective ventilation at cut depths beyond the current limit of 40 ft. Several innovative ventilation schemes are currently being considered. One such method is the use of a jet fan to ventilate a deep cut. A jet fan is simply a freestanding fan using little or no ducting to direct the ventilation flow. Jet fan testing in a 90-ft entry revealed that higher exit velocities and greater penetration depth occurred when various configurations were used to confine and direct the air flow. Additional testing also indicated that 2,200 cfm of fresh air was delivered to the face 90 ft distant when a check curtain was used to limit entrainment around the fan. Without this curtain, this quantity dropped to only 1,000 cfm This testing indicated that a jet fan was capable of providing ventilation to a distant face area. It also highlighted potential problems, such as recirculation at the fan and reentrainment in the jet flow. Despite these potential problems, jet fans may be adequate for ventilating cuts exceeding 40 ft.

Jan 1, 1992

By Charles L. Kimbell

For 1991, the aggregate value of world international export trade in mineral commodities was roughly estimated at $685 billion in current 1991 dollars. The estimated level was about 6 % higher than that for 1990, but still more than 3 % below the record high set in 1980, and the year was the fifth in a row in which the value of exported minerals advanced. Table 8 provides a data series for the estimated value of world export trade in all mineral commodities from 1979 through 1991, as well as a breakdown of this total into fuel and non fuel commodities. The data shown are based on the historically more traditional and realistic (from the viewpoint of data availability) practice of reporting trade values for the year before the year of review. Despite the considerable increase in the dollar value of mineral commodity exports, their share of total export merchandise trade declined to 19.1 % in 1990 from 19.7% in 1989. At 19.1 %, this share was very near the recent year record low of 19.0% reached in 1988. Comparable 1991 figures were not available in time for inclusion here, but it is expected that the mineral commodity share of the total will be little altered from that of 1990.

Jan 1, 1993

By Launa Mallett, Charles Vaught, Michael J. Bmick

Since 1991 the Pittsburgh Research Center (PRC formerly part of the U. S. Bureau of Mines) has been tapping u valuable resource-researchers have recorded extensive interviews will, 30 individuals who are recognized as experts in the area of mine emergency response. These veterans related stories and observations from events experienced during as many as 47 years of response activities. Overall, the response veterans averaged 29 years of mine emergency response experience and 35 years mining experience. Individuals [ ] interviewed included representatives from mining companies, the UMWA and state and federal government agencies. This information was gathered so dial it could he provided to today's miners and to tomorrow's emergency response personnel. It is hoped the collective wisdom that has been obtained can be used to help train new responders and guide those decisions which mill have to be made on the scenes of future events. During interviews file emergency response experts were asked to discuss lessons they had learned through experience. The interviewers asked them to tell what they had learned that would cause them to handle similar situations differently and to tell about things they saw at past events shat the would warn others not to do in the future. In response the experts discussed a variety of things. Most of their responses, however, touched on some of the same topics including: preparedness, experience people on-site mine rescue teams, and decision making. A summary of their responses provides alt overview of [lie lessons learned on-site at tile largest mine disasters in the country.

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

8. Refuge Chambers 8.1 Refuge Chambers - Technical Discussion 8.1.1 Introduction As a part of the overall escape system, refuge chambers can provide a last resort when existing escapeways are blocked. These chambers are intended to provide both protection from toxic gases and a life supporting environment for a period of time before external rescue or further escape efforts can be carried out Escapeways may be blocked physically (due to cave-ins, etc), by fire, or by the presence of a toxic or oxygen deficient atmosphere. In the first two cases, the trapped miners would most likely await external rescue efforts, and hence the design of the chamber will have to consider the time durations that such efforts may take, It is also possible, in the second case, for fire fighting and fire protective equipment to be stored in the chamber so that miners may attempt their own escape. In the third case, it should be recognized that a compact, beltmounted 1-hour self-contained breathing apparatus has been developed(9), and that other, less compact equipment is available for up to 4 hours of self-contained breathing supply. If such equipment were stored in the chambers, then miners could escape by travelling from chamber to chamber, taking temporary refuge in each before proceeding to the next. 8.1.2 Background The concept of "barricading" has long been recommended for those emergencies where miners are trapped inby a fire. Barricading, which is the construction of a makeshift shelter in a crosscut or deadend, protects the entrapped miners from toxic gases and enables them to conserve a supply of air. In this manner, they can survive two or three days--hopefully enough time for them to be reached by rescue teams. In the past, many lives have been saved with this technique.

Jan 1, 1976

By D. Z. Hobbs

Because an economic method for preparing pure boron has not been developed, a program was started by the Bureau of Mines to evaluate existing techniques or to develop new methods for preparing the pure element. This report describes investigations directed toward the development of techniques for the preparation of pure boron by fused-salt electrolysis. Only two of the several fused-salt baths tested were satisfactory for the preparation of boron. These baths contained (1) potassium fluoride, lithium fluoride, potassium fluoborate and boron trioxide; and (2) potassium fluoride, potassium chloride, and boron trioxide. Of these two mixtures, the latter was more satisfactory. Elemental boron of from 90- to 95-percent purity and, in isolated cases, as high as 98-percent purity, was prepared from these two types of fused-salt baths. There appeared to be no distinct differences either in the yields or the purity of boron prepared at current densities ranging from 795 to 1,000 amperes per square foot. Current efficiencies were as high as 85 percent.

Jan 1, 1961

By Edmund S. Leaver

This information circular is written is response to the marry requests for information on the recovery, or reason for poor recovery, of fine gold by the amalgamation process. Checking Gold Content Experience has shown that in many cases error has been made because the true told content of a particular sample or deposit was not known. Fire assays of representative samples give accurate results and should be considered final in determining the gold content.

Jan 1, 1928

By R. A. Guidotti

The Federal Bureau of Mines has studied the reaction of oxides of columbium, vanadium, and tantalum with ammonia in vertical, gas-solids reactors at temperatures ranging from 300° to 1,300° C with the goal of preparing nitride intermediates for subsequent preparation of the metals by a thermal-decomposition step. The best nitride conversions were obtained in nonmetal reactors. With Cb205, V2O3, and V205 , low-temperature maxima in reaction rates occurred at 800°,800°, and 450° C, respectively, during oxynitride formation (in A1203) at 1 atm of pure ammonia. Conversion of the oxynitride, in a second step, to the mononitride was optimum at 1,200° C for columbium and 1,050° C for vanadium. In the case of Ta205, the rate of reaction to form Ta3N5 (in a single step) was highest at 900° C, where the presence of up to 5 percent methane was found to be beneficial; improved results were obtained by conducting the nitriding in a rotary kiln. Optimum space velocities (in the vertical Al203 reactor) ranged from 5,280 hr-1 for Cba205 to 7,950 hr-1 for V203. Oxide particle size had little effect upon reaction rates. Under fully optimized conditions, products containing less than 1 percent oxygen were readily obtained in under 6 hours.

Jan 1, 1975

By Walter W. Fisher

A kinetic investigation of copper cementation in a revolving drum was undertaken by the Bureau of Mines to explore the effects of a porous copper deposit attached to the iron surface and a fluidized slurry of copper particles surrounding the iron precipitant. The rate of cementation was found to be significantly enhanced by the increased cathodic areas provided by a porous copper deposit or the presence of a fluidized bed of copper particles contacting the iron precipitant. The cementation rate was found to be retarded by increased ionic strength, low pH, and the presence of oxygen. The cementation reaction was first order with respect to precipitant surface area. Copper cementation on iron is visualized to occur by two basic mechanisms. Precipitation may occur through a series of shorted electrochemical cells, whereby cupric ion precipitates on a growing cathodic copper deposit, or, deposition may occur via a fluidized cathode of copper particles contacting the ion precipitant.

Jan 1, 1976

By Anthony T. Lannacchione, Donald G. Puglio

The Bureau of Mines developed data on the methane content of the Hartshorne coalbed, Haskell and Le Flore Counties, Okla. The methane content is calculated to be between 1.1 and 1.5 trillion cubic feet, based on an estimate of total coal in place of 2.4 to 3.2 billion short tons. Methane increases with depth, but the rate of increase decreases with greater depths. Degasification in advance of mining is recommended for all mines operating at depths greater than 500 feet to reduce hazards and methane explosions, decrease mine ventilation costs, and conserve the natural gas that would be otherwise wasted.

Jan 1, 1979