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By Ted C. Briggs

Equations for the elastic pressure distortion of the volumes of a Burnett compressibility apparatus are developed and presented in this report for volumes under internal and external applied pressures. An experimental method for the determination of the external pressure distortion coefficients is presented. Young?s modulus and the internal-pressure distortion coefficients are computed from the experimentally determined external-pressure distortion coefficients. The temperature dependence of the pressure distortion coefficients and of Young's modulus is evaluated for the temperature range 0° to 80° C.

Jan 1, 1968

By M. M. Jones

A procedure for the spectrophotometric determination of uranium has been developed in support of minerals research being conducted by the Bureau of Mines. Uranium is separated from the sample by tributylphosphate extraction from acid solution containing added aluminum nitrate and (ethylene dinitrilo)-tetraacetic acid solutions. The colored uranium-dibenzoy1methane complex is developed in the organic phase by adding an ethanol solution of dibenzoylmethane buffered with triethanolamine. Absorbance is measured at 410 nanometers, and the response is linear up to at least 100 micrograms U30S in the aqueous aliquot taken for analysis. Aliquots containing as little as 8 micrograms U30S may be analyzed with relative errors no greater than ±5 percent. For aliquots containing at least 35 micrograms U308, relative standard deviation at the 95-percent confidence level is about ±2.2 percent. Appropriate procedures are given for analyzing a wide variety of samples.

Jan 1, 1980

By Daniel Edelstein

Demand for arsenic trioxide increased markedly during 1984 as a result of increased use of arsenical wood preservatives and increased use of arsenicals in agriculture. The increase in agricultural demand was due to a return to production of land with-held from cotton planting under an agriculture program for acreage diversion for some 1983 crops. Supplies of arsenic trioxide were more than adequate to meet increased demand, and prices either declined from, or remained at, the low 1983 levels. In June, ASARCO Incorporated announced plans to close its Tacoma, WA, smelter by mid-1985. Domestic Data Coverage.-Refined arsenic trioxide was produced by two U.S. companies. The major producer voluntarily reported its production to the Bureau of Mines, but to prevent disclosure of proprietary data, the production data have been withheld.

Jan 1, 1985

By A. Visnapuu

High-grade synthetic rutile has been produced in the laboratory from domestic ilmenite concentrates by a new carbonyl process. The ilmenite was first reduced to convert the iron oxides to metal and then treated at temper-atures over 1000 C in high-pressure carbon monoxide (CO) to convert the iron to the pentacarbonyl. Rapid carbonylation was achieved in the presence of small quantities of selected promoters. Maximum iron removal occurred at temperatures between 110° and 130° C at CO pressures from 1,000 to 1,400 psig. Iron pentacarbonyl appeared as liquid and vapor in the reactor and could be removed by gravity flow and vapor transport. More than 90 pct of the iron was extracted in 2-hr experiments at pressures of 1,000 psig and above. The Ti02 product is porous owing to the removal of the iron, has the rutile crystal structure, and is suitable for chlorination. Waste disposal problems associated with the process would be minimal because the iron pentacarbonyl can be decomposed to produce iron powder or pellets for sale and CO for recycling.

Jan 1, 1973

By E. J. White

Data from oil well logs and core analyses were used to quantitatively evaluate formation porosity and water saturation of heterogeneous carbonates and to study the pore geometry and performance characteristics of cores from these formations. Logs and cores from the Madison limestone from 233 wells in three fields in the Williston basin were used in the investigation. A comparison of log and core analyses shows that log porosities are consistently larger than core porosities, and the differences are correlatable with core porosity ranges. Water saturations from logs are usually smaller than the corresponding core saturations by summation of fluids, but the difference is attributable to mud filtrate invasion into the cores during drilling. Petrophysical studies show that the low permeabilities and high residual water saturations in these reservoir rocks are due to their fine crystalline texture and complex pore geometry (heterogeneity). It is concluded that both log and core analyses must be used for reliable evaluation of these carbonate formations.

Jan 1, 1971

By Stephen C. Tadolini, Thomas M. Barczak

Western mines have had limited choices for standing support. Wood cribs were often too soft and unstable. The introduction of the Can support in the early 1990’s provided a very effective alternative and remains the dominant form of tailgate support. Water-filled prestressing cells are now used to cap the Can and preload it to provide an active roof load. The Cluster Prop, consisting of three timber wedge props bundled together, provides more capacity than an equivalent sized Can support and improves transport efficiency. However, the Cluster Prop is less stable and does not maintain a consistent load throughout its loading profile. Pumpable roof supports are another alternative support, but they have not been proven in high deformation environments. Alternative supports are also being used in longwall recovery operations. These include the Rocprop and Omni Prop, which are extendable support systems. They also provide active roof loading which can be beneficial in these applications. Specialty supports, such as the Sand Prop and Spider Prop, have also been introduced into western longwall operations. This paper compares the performance characteristics of these various support systems.

Objective To develop and evaluate the effectiveness of safety training tools specific to underground metal/nonmetal mining. Background In a series of stakeholder meetings held in the western United States beginning in 1998, participants identified a critical lack of appropriate training materials applicable to metal/nonmetal mining. Participants in the meetings provided many insights into what types of training materials are most effective in dealing with both experienced and inexperienced miners. Most important was that the materials should be realistic and interesting and that some way should be found to capture the wisdom and expertise of older miners before they retired. In response, training videos that focus on safe practices during the mining cycle are being produced. Two videos one on handling explosives underground and one on identifying roof hazards and proper scaling techniques were completed during1999, and a third video is now available. This video, entitled “Ground Support...It’s Important, or Miner Mike Saves the Day,” presents information on why ground supports work and how to install them properly. Approach The new video, “Ground Support…It’s Important,” presents a scenario in which two young miners make a bad decision to leave some supports out in order to catch up in their mining cycle. An expert miner, “Miner Mike,” sees this potentially disastrous situation and educates the young miners about what could happen if they continued to leave supports out. He introduces the young miners to several expert miners, who explain how to install different types of supports correctly, as well as share what experience has taught them over the years. How It Works All footage was taken in operating, underground mines, using14 experts to provide the teaching. Because of the wide variety of supports used underground, it was necessary to focus on those types more common to hard-rock mining. While more complex support systems, such as shotcrete and cable bolts, are mentioned, detailed material is not included. In the course of educating young miners Jeff and Jason, Miner Mike provides information on— •Why supports are necessary in underground mines. •The main types of supports commonly used in underground hard-rock mines. •How supports work. •How holes for bolts are drilled correctly using jacklegs, drill jumbos, and bolting jumbos.• How wire mesh, wire panels, metal mats, and different types of bolts, including mechanical bolts, friction bolts, grouted bolts, and cable bolts, are installed properly. •How to recognize that supports have failed and what to do about it.

Jun 1, 2000

By Dennis A. Long

"The size of off-highway trucks has increased substantially over the last decade, bringing about a radical change in truck maintenance practices and procedures. As a result, surface mine maintenance mechanics today are faced with the increased hazards of working with larger and heavier tools and components and doing repairs at greater heights, thereby exposing them to a high potential for serious injury or death. Not surprisingly, the number of accidents involving truck maintenance mechanics is significantly increasing.The Bureau of Mines has assessed the haulage truck maintenance safety problem, analyzing maintenance-accident data over the 7-yr period, 1978- 84, in terms of personnel, job activities, truck components and systems, tools involved, and truck design. This assessment, based on the review and interpretation of 1,225 haulage truck maintenance accident reports, identified major factors contributing to these accidents. Overall, young, inexperienced workers are involved in most accidents. A typical maintenance accident involves a male mechanic under 33 yr old, with less than 5 yr job experience. INTRODUCTIONOver the past decade, surface mine maintenance and repair operations have changed radically. The number of maintenance personnel has grown along with the hazards of working with larger and heavier components at greater heights and with larger and heavier tools. Furthermore, transfer of skills from over-the-road vehicle mechanics is not as feasible as it once was, because of the ever increasing size of mining equipment and the complexity of its design. In short, surf ace mine equipment maintenance and repair has become increasingly sophisticated as well as labor intensive, necessitating further research and evaluation in terms of both safety and efficiency (1, 7-8) 2"

Jan 1, 1986

Maintain good blowing face ventilation while taking deeper cuts with a radio-remote, scrubber-equipped miner. Approach A six week in-mine study of face ventilation effectiveness was made by comparing the existing MSHA-approved blowing curtain setback distance of 25 ft with brattice set back distances of up to 50 ft. Effectiveness was determined by measuring methane levels at the face and in the immediate return. How It Works Blowing ventilation systems are commonly used in mines because the high velocity air stream created by these systems rapidly mixes with and dissipates methane generated during the cutting of coal. A drawback to blowing ventilation is that the work area is placed in return air and this may create dust compliance problems for the shuttle car and mining machine operator. To clean dust from the return a number of mining machine manufacturers supply dust scrubbers built into the machine. Dust-laden air is drawn into ducting at the front of the mining machine's boom and is ducted to a scrubbing unit located on the machine's main frame. The clean air from the scrubber is discharged as a high velocity jet toward the return, generally from the left fender of the mining machine. When taking cuts deeper than 20 to 25 ft with a scrubber-equipped machine, the machine's discharge is in by the mouth of the blowing curtain, creating a concern by mine workers that a loss of air to the face could result. However, Bureau of Mines research found that the push or throw of air toward the return by the scrubber discharge jet allows good face ventilation to be maintained with extended curtain setbacks.

Jan 1, 1984

By M. D. Schlesinger

As part of the development of processes for producing synthetic fuels from coal, the Bureau of Mines prepared a special jet fuel in a pilot plant for evaluation by the Air Force. This jet fuel had all the required physical properties, including the important specifications of high heating value and high density. However, the finished fuel did not pass the stability test specified by the Air Force and conducted by the Southwest Research Institute in a high-temperature research coker. The cause for this instability is being investigated because pure compounds of the type identified in this fuel are known to be stable. The tar acid oil used was a 230° to 300° C. fraction of low-temperature tar obtained by carbonization of a West Virginia bituminous coal in the pilot plant of the Consolidation Coal Co. Both the desulfurization at 400° C. and saturation at 300" C. were done in the vapor phase at 2,500 p.s.i.g. After catalytic treatment and distillation the final jet fuel had a boiling range of 194° to 247° C., a net heating value of 18,420 B.t.u./lb. and a specific gravity of 0.8463 60° F./60° F. It also had u pour point below -62° C., and at 0° C. its viscosity was 4.5 cs. The oil was virtually all bicyclic, 41 pct. noncondensed and 56 pct. condensed.

Jan 1, 1961

By J. J. Cummins

The Bureau of Mines heated at 150° to 350° C for 0.5 to 360. days Green River oil shale that had been previously extracted by benzene to provide information on in situ processing conditions, to determine the effect of low-temperature heating on the unconverted kerogen, and to determine the composition of benzene-soluble thermal products. The methods used in determining the composition of the soluble thermal products consisted of fractionation of the soluble material, elemental analysis of the soluble products, fractionation of the polar resins by ion-exchange chromatography, gas chromatographic analysis of [n]-alkanes3 and mass spectral analysis of the branched plus cyclic alkanes and aromatic oils. The methods used to determine the effect of low-temperature heating on the unconverted kerogen remaining in the oil shale heated residues consisted of carbon-hydrogen analysis, volatile material determination, carbon residue determination, and oxidation rate determination. In general, it was concluded that significant increases in the degradation of kerogen to oil occurred between the temperature range of 250° to 350° C; that the composition of the soluble products depends upon the temperature at which they are formed; and that the [n]-alkanes are pyrolytically degraded from the kerogen structure. In particular, the 250° C heating temperature is beneficial to the formation of branched plus cyclic alkanes. Also, the heated and unconverted oil shale kerogen and the soluble thermal products become more aromatic as the temperature increases from 150° to 350° C.

Jan 1, 1974

This section contains a summary of our investigation of the soil conditions (type, porosity, moisture content, etc.) at the two sites (Lanse and Kato, Pennsylvania) selected for field testing of latex as a soil sealant. Other natural conditions such as rainfall, frostline, depth of the water table, etc., were also measured and recorded for possible later use in assessing the effect of the latex seal on the total environment. The numbered sites referred to throughout this report are shown on the maps of the Lanse and Kato sites (Figures 1 and 2). KA, RB and KC are positions at the Kato site - all other numbered positions refer to the Lanse site. Two other terms used throughout the report which should be explained are “horizon” and "profile". These are synonymous terms for soil layer, A horizon (or A profile) referring to topsoil and B horizon (or B profile) referring to subsoil. The properties that control the flow of water through the soil are of special interest because these will also govern the passage of a sealant into and through the soil. Normally the particle size distribution is a good measure of soil permeability, which is directly proportional to sand content and inversely proportional to silt and/or clay content. Tables I1 and I11 show the percentages of gravel or stones, sand, silt and clay of Lanse and Kato soil samples. According to the United States Department of Agriculture classification, the gravel is ,ignored and the residue separated into sand, silt, and clay fractions. Figures 4 and 5 indicate by means of the USDk soil texture triangle that the variability of composition of Lanse soil ranges from sandy loam in the creekbed to clay loam. The variation is even greater among soil samples from Kato. Porosity of soil, also known as percent voids, is another indication of how readily water will travel through soils. Soil density usually increases and porosity decreases with depth, and as expected, the porosity of the top soil at Kato, a forest, is exceptionally porous and open (see Table IV) The pore diameter and length of soil capillaries is extremely variable, and its distribution in the field is impossible to determine. In addition to the capillaries, soil also contains many macro cracks, crevices, and passages around stones and roots. All these affect the flow rate of water through soil. Poiseuille's law states that the rate of flow of a liquid through a narrow tube is proportional to the 4th power of the radius of the tube. Pore size normally decreases with depth and in soil containing appreciable amounts of silt and clay this is especially true. Thus, deeper soils should be less permeable and such was the case at Lanse and Kato.

Jan 1, 1972

By C. H. Elder, Fred N. Kissell, S. D. Maksimovic

The Bureau of Mines evaluated the hydraulic stimulation of a gob-degasification borehole to determine if this procedure would aid in degasifying a longwall panel. The stimulated borehole did not degasify the longwall panel as expected either before or after mining of the panel started. It reduced the underground methane emission only 11 pct, considerably less than the reductions effected by two unstimulated boreholes in the same panel. Some probable reasons for the reduced methane flow from the hydraulically stimulated borehole are very low reservoir gas pressure, location of hydraulically stimulated zones within the grouted casing, a casing break caused by lateral shifting, possible vertical movement of rock strata during caving, grouting of a 4-inch pipe blocking three stimulated zones, plasticity of shales, and possible hole damage by swelling of water-sensitive minerals. The borehole was also located between two second-mined areas, which may have allowed partial degasification of the overburden and the coalbed in advance of mining. Finally, a period of 3 months is probably not long enough for the borehole to degasify the overburden before mining.

Jan 1, 1977

Reduce or prevent acid mine drainage from coal refuse piles and surface mines by inhibiting the growth of acid-causing bacteria. Approach A dilute surfactant or deter? gent solution is applied directly to coal refuse piles or overburden using a hydro-seeder or road watering truck. The surfactant treatment can be used either as a preventive measure to avoid a potential acid drainage problem or to reduce water treatment costs by controlling acid drainage at its source. How It Works Acid drainage is prevented or reduced by inhibiting the growth of Thiobacillus ferrooxidans, a type of bacteria which obtains most of the energy it needs to survive by oxidizing ferrous iron in water. The oxidized iron in turn attacks pyrite, which forms an acid and additional ferrous iron for the bacteria to oxidize. T. ferrooxidans is protected by an outer membrane which enables it to survive in its acid environment. Anionic surfactants, or surfactants containing negatively charged ions, can be used to destroy this membrane, thus killing the bacteria and slowing down the oxidation of acid-forming pyrite. Of the anionic surfactants tested to date, sodium lauryl sulfate (SLS) appears to be the most effective as a bactericide. Alpha olefin sulfonate and alkyl benzene sulfonate are acceptable alternatives. These surfactants are major components of common household products, such as laundry detergent, shampoo and toothpaste. They are, therefore, readily available, inexpensive, biodegradable and present no environmental problems at low concentrations.

Jan 1, 1983

By R. B. Schluter

The Bureau of Mines investigated the flotation responses of two copper-nickel ore samples from the Duluth Complex with the objective of recovering bulk sulfide concentrates. One of the ores studied was taken from a test pit; the other was taken from a test shaft. The samples were quite similar except that the pit sample analyzed 0.35 pct Cu and 0.11 pct Ni and the shaft sample analyzed 0.69 pct Cu and 0.14 pct Ni. Flotation responses were studied in both laboratory and pilot plant tests. Pilot plant flotation responses were similar for both samples resulting in grades of 12.2 pct Cu and 2.5 pct Ni for the pit sample and 12.2 pct Cu and 2.1 pct Ni for the shaft sample. Weight recoveries were 2.5 pct for the pit sample and 5.2 pct for the shaft sample. Copper and nickel recoveries for the pit sample were 87 and 62 pct, respectively, and 92 and 73 pct for the shaft sample. Both concentrates contained small but significant values of cobalt and precious metals. Cobalt recoveries were low--less than 40 pct for both concentrates. Precious metals contents of the concentrates were 1.59 oz/ton for the pit sample and 0.99 oz/ton for the shaft sample. Silver was the predominant precious metal by weight, but platinum and palladium represented the highest values.

Jan 1, 1980

By F. N. Kissell

The Bureau of Mines used sulfur hexafluoride (SF6) tracer gas to evaluate the effectiveness of gob ventilation and/or sealing practices at three coal mines, each having different problems associated with their mined-out areas. The purpose of these ventilation studies was to better understand whether current techniques employed for ventilation or sealing are successful at minimizing the potential for gob fires and explosions. The work performed at each mine is discussed: One is a long-wall operation that uses ventilation to carry off hazardous gases, and two are room-and-pillar operations, each with far different concerns, that seal off the gobs to isolate them from the main mine ventilation. In all cases employment of the Bureau's SF6 tracer gas technique resulted in answers to questions raised by the mine operators concerning the effectiveness of their gob ventilation or sealing practices in preventing mine fires.

Jan 1, 1986

By Alan R. Buehler

The Bureau of Mines conducted a mineral investigation of the 32,270-hectare Cache Peak study area in 1992; the area had been proposed as wilderness. Bureau personnel examined and sampled prospect workings; 50 rock and placer samples were taken during the investigation. The study area is centered about 25 km southeast of Challis, Idaho, in the Challis National Forest. According to May, 1993, Bureau of Land Management mining claim records there were no current mining claims located inside the study area. Up to 100 claims may have been located in the study area in the past. Gold, silver, copper, lead, zinc: Significant analyses, poor exposure precludes resource estimate. Limestone: More than I billion tonnes may be chemically suitable for a variety of uses, markets too distant to favor mining. Dolomite: More than 1 billion tonnes may be chemically suitable for producing magnesium metal, markets too distant to favor mining. Sand and Gravel: Several million m3, but markets and transportation costs do not favor mining. Chalcedonic nodules: Two localities in the study area may be of interest to hobbyists who cut and polish stone. There is no reported past production from the study area.

Jan 1, 1993

Design, fabricate, and test a machine capable of operating in coal seams 48-inches and thicker that can reduce the time, expense, and injury potential inherent in extending and retracting mine-wide section belt conveyors, while eliminating the need to use additional machinery or equipment in accomplishing such moves. The Problem Many underground coal mines use a belt haulage system to move cut coal from the face to the loading area. This system usually consists of a main line belt conveyor fed by section belt conveyors. A shuttle car at the face carries the coal cut by a continuous mining machine to a feeder breaker that breaks the large lumps of coal into smaller, transport-able pieces and unloads them onto the tail piece of the section conveyor. This tail piece is skid-mounted so it can be readily moved as needed. The conveyor is kept close to the face during mining in order to shorten the haul distance of the shuttle cars. Section belts can be lengthened by adding belting, wire rope, and support hard-ware. During pillar retreat mining, these section belts are shortened to keep pace with pillar extraction operations. However, these belt moves, either the extensions or retractions, usually require six to eight workers and three to eight hours to complete. In addition, a 100-foot belt move requires workers to handle up to 4,000 lbs. of material, not including the tail section. Strain and sprain injuries can be incurred during this heavily labor-intensive task. The time required to move the section belt can also create losses in the mine's production. To help solve this problem, the Bureau of Mines

Jan 1, 1984

By D. L. Paulson

The Bureau of Mines is investigating pyrometallurgica1 and" chemical methods to recover valuable constituents from metallurgical dusts and slags. Under this program a technique was developed to recover iron from molten copper smelting furnace slags by carbon injection. Slags from gas-fired reverberatory and electric copper smelting furnaces were treated in an 800-kva electric-arc furnace by injecting coke breeze into the bottom of the molten bath. Over 95 pct of the iron and over 90 pct of the copper contained in the smelting furnace slags were recovered, while up to 85 pct of the carbon injected into the system was utilized. It is anticipated that the metal product containing approximately 95 wt-pct iron and 2 wt-pct copper will be a satisfactory medium for recovering copper by cementation.

Jan 1, 1977

By J. W. Paul

This paper deals with the third phase of on extensive research on coal-mine ventilation factors. A comprehensive report of the entire work is in course of preparation, but abstracts of the various chapters are being prepared in order to make the results public as rapidly as possible. Parts I and II of this paper were issued Serial 2621 and Serial 2647 of the Bureau of Mines in July and October, 1924. They dealt with the resistance of unobstructed entry and the resistance caused by mine cars in untimbered entry. Description of the Tests After the resistance of unobstructed entry and of mine cars in untimbered entry had been determined by tests in the Experimental Mine, three different types of timbering were installed in the test section and the increased resistance caused by the timbering was determined.

Jan 1, 1925