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By T. van Heerden

A range of supported gold catalysts was prepared by ion exchange, varying many of the preparation variables, including concentration in the precursor solution, washing procedure, as well as drying and calcination procedures. These catalysts have been characterized extensively. TEM images show essentially the same crystallite size distributions, between 2?5 nm, for almost all catalysts, the only exception being catalysts not washed in ammonia, which did not show any small crystallites. Additional characterization with SEM yielded an interesting discovery. Catalysts that appear identical on the TEM also contain some large crystallites in the range of 50?500 nm. Differences in dispersion due to the drying procedure not seen on the TEM can now be observed. Oxygen chemisorption is being investigated as an additional method to characterize gold based catalysts to complement the typically used electron microscope techniques.

Jan 1, 2012

By A. B. Pederson, G. E. Bartlett

As a part of our study of how coal mine dusts injure the lung we have studied the effects of dusts and dust-exposed pulmonary alveolar macrophages (PAMs) on the growth of lung fibroblasts (LF). Fibroblasts were cultured near confluence in low-serum medium, either alone or in the presence of dusts, dusts plus PAMs, dust leachates or superriatants of dust-exposed PAM cultures. We report here provisional conclusions, based on initial observations. Rat LF were relatively unresponsive to direct effects of dusts, showing weak stimulation in only a few cultures, and there was no evidence that dust-exposed rat PAMs had released any growth-regulatory products. In contrast, guinea pig cells were more responsive to the dusts. The pattern of responses was quite complex. Three of the dusts stimulated LF directly (with no mediation by PAMs). Two dusts were essentially inert when added directly to fibroblast cultures, either with or without PAMs, but their leachates were active: 867 leachate was inhibitory and RF leachate was stimulatory. Dust 1361, either directly in the cultures or as an aqueous leachate, was stimulatory, and it activated cocultured PAMs to stimulate LF growth; however, supernatant products of 1361-stimulated PAMs were inhibitory. Direct exposure to 1192 stimulated LF, but its leachate was inert; cocultured PAMs exposed to 1192 had weak stimulatory effects, but supernatants of 1192-exposed PAMs were mildly inhibitory. MP3-3 had effects similar to 1192, except that the cocultured, dust-exposed PAMs had no effect on growth. We conclude 1) that guinea pig lung cells are more responsive to dusts than are rat lung cells, 2) that dusts can influence growth of LF by four kinds of interaction (by direct dust-cell interaction, by release of soluble dust components into the culture medium, by activating P AMs to exert direct cell-cell interactions, and by activating P AMs to release growth regulatory products into the culture medium), 3) that each kind of interaction may be neutral, inhibitory or stimulatory, depending on the dust tested, 4) that four of the dusts tested were neutral, inhibitory or stimulatory, depending on the assay (the fifth <lust was either neutral or stimulatory), and 5) that the effects of soluble mediators (leachates or products of activated PAMs) frequently did not correspond with the direct dust-cell or PAM-fibroblast effects. These results suggest that the nature of the dust-lung interaction at the level of cells and molecules is exceedingly complex. These observations need to be confirmed and extended to determine what characteristics of the dusts determine the nature of the cellular responses, and to determine which patterns of responses are detrimental and which are beneficial in the overall health of the dust-exposed lung.

Mar 1, 1989

Several economic factors have caused the surface mining industry to require large-capacity shovels and trucks for efficient, high-production, low-cost operations. Some of those factors include technological advancements in equipment, commodity market depressions, increased labor and maintenance costs, contractural obligations and harsh operating conditions. The difficult operating conditions in surface mines, however, pose challenges to the use of high-capacity equipment. They include space limitations, weak over-burden, and weathered soils and rocks. So mining companies face major challenges in selecting appropriate shovels to meet the technical, operating, safety, environmental and economic requirements of their mines.

Jan 1, 2003

By S. M. Javad Koleini

Processing of phosphate ore sample was investigated for increasing phosphate content and reduction of its gangue minerals such as carbonates and silicates. Experimental designs were per-formed using Taguchi method. Different flotation methods were investigated for Moundon phosphate ore sample and three methods were used as follow: direct cellophane flotation, reverse calcite flotation and reverse quartz flotation. Because of the sensitivity of cellophane flotation to slime content, prior desliming was carried out before the experiments. Direct flotation experiments carried out and a concentrate contained 23.80% P2O5, 6.88% SiO2 and 72.33% recovery were produced. The achieved P2O5 content in the produced concentrate from reverse flotation of calcite was 26.44% and the recovery was 82.56%. The concentrate products obtained at optimum conditions by direct flotation of phosphate and indirect flotation of calcite were subjected to indirect flotation of calcite and direct flotation of appetite and final concentrates with P2O5 grade of the order of 24.19% and 26.96% were obtained, respectively. It was concluded that one stage direct flotation is unavoidable to achieve a product with low SiO2 content.

Jan 1, 2014

By Horacio Reeves

Las maquinarias son elementos importantes en el proceso de minería de tajo abierto -en tanto optimizan el rendimiento del trabajo y de los operarios. Sin embargo, su contínuo uso conlleva riesgos ocupacionales en el trabajador como la exposición a vibraciones de cuerpo entero en el caso de equipos pesados. En ese sentido, el presente texto compara los niveles de vibración en los equipos pesados que operan en Antamina con el estándar europeo: Directiva 2002/44/CE, así como los efectos de este en los operarios.

Sep 12, 2005

By Karsten Beckhaus

"Abstract Tremie concrete for special geotechnical works needs special properties, especially during the casting process. Today’s execution standards for bored piles and diaphragm walls, EN 1536 and EN 1538, as well as the draft version of concrete standard EN 206, all comprise regulations for deep foundation concrete which have not been changed for decades. Considering the recent development in concrete technology at the same time and its actual state-of-the-art, it is essential to develop new normative specifications and specification requirements.GeneralTo allow the required integrity and quality after placing and hardening, concrete for structural elements like bored piles or diaphragm walls, used as foundations of high-rise buildings or as retaining structures for large and deep building pits, must have adequate workability and stability.In addition to requirements on mechanical properties and on durability, both of which have increased within the last decades, concrete must be suitable for being cast in deep or extremely deep excavations, see figure 1. Today’s specialist foundation engineering machinery makes it possible to drill or cut down to in excess of100 m depth. Concrete technology has developed and allows the use of high performance concrete for deep foundations. But is this capability represented by actual regulations?It has become very common for the industry to supply or use concrete with low water cement ratios, nevertheless highly flowable and set-retarded for several hours if needed. Very low water cement ratios allow design strength of 60 MPa or higher (Larisch, 2011), and a very low porosity which is required for a long service life in aggressive conditions, e.g. by chlorides.To achieve best performance, it is obvious that the concrete must completely fill the excavation and fully embed the reinforcement. As vibration of deep foundation concrete is (usually) not allowed and was anyway inefficient, deep foundation concrete must be designed to self-compact under hydrostatic pressure. Generally, it must be considered that after placement the concrete’s quality cannot be influenced anymore. Therefore, both the pouring procedure and the concrete quality must be adequate."

Jan 1, 2014

By Dan A. Brown

The following paper was written by Dr. Dan A. Brown, P.E. Brown is an Associate Professor at Auburn University&apos;s Department of Civil Engineering. The paper was originally presented at a FHWA&apos;s Transportation Research Board meeting and is presented here with the author&apos;s consent. Construction and design of drilled shaft foundations in hard pinnacle limestone requires flexibility from all parties involved due to the variability of the subsurface conditions. This article describes some strategies which have been found useful in the Birmingham, Alabama area. The importance of well trained and experienced field personnel in these conditions is noted. It is also vital that engineers understand the construction challenges so as to provide both quality assurance and cost effectiveness in design and in the specifications.

Jan 1, 1991

By José Calderón

Poderosa tiene sus concesiones en las provincias de Pataz y Bolívar en la región La Libertad y son parte de la zona de amortiguamiento (ZA) del parque nacional Río Abiseo (PNRA) y de la zona de transición (ZT) de la reserva de biosfera Gran Pajatén (RBGP). Esta área natural protegida (ANP) es uno de los dos únicos sitios en el Perú que tienen carácter de patrimonio cultural y natural de la humanidad (doble caracterización dada por Unesco). Poderosa ha firmado un convenio de cooperación interinstitucional con el Servicio Nacional de Áreas Naturales Protegidas por el Estado (Sernanp) del PNRA, el mismo que le ha permitido contar con su asesoría, mejorar los instrumentos ambientales y cumplir a cabalidad los compromisos socioambientales.

May 22, 2019

By J. C. W. M. de Wit

An excavation, within which a tunnel is sunk as a part of the Centraal Station underground station (platform section) of the Noord/Zuidlijn (&apos;North/South Line&apos;), is to be created beneath the Amsterdam Centraal (&apos;Amsterdam Central&apos;) station. The section beneath Amsterdam Centraal Station is characterised by the application of a particular technology in the form of, inter alia, the so-called &apos;sandwich wall&apos;. This is a composite wall consisting of two rows of Tubex piles with a body of jetgrout columns in-between. This wall acts both as an excavation support wall and also provides vertical bearing. The installation of the wall, including both Tubex piles and jetgrout columns, within these specific conditions (limited height, sensitive historical building), within the design requirements set in terms of construction tolerance and water and soil retention, may be regarded as being a pioneering achievement. The environmental constraints are that the trains should continue to run, the inconvenience to passengers should be kept to a minimum and the historic station should not suffer any damage. Because of the complexity of the working conditions, the project is being overseen by a steering group of experts in the specified construction processes. In order to manage the project risks, jet grouting trials were initially carried out, in order to highlight and control execution problems; the practicability of the design is then tested. Work commenced on the sandwich wall in 2003, when the wooden piles were extracted at the locations where the sandwich wall was to be constructed; in 2004, the steel Tubex piles for the southern wall sections were installed. From May 2005, the construction of the sandwich wall got under way; in addition to the described process supervision, an extensive measuring programme was established, so that the process could be adjusted as necessary and the quality of the finished product determined. This applied to both individual columns and for the end product, the sandwich wall. The measurement results were processed for each column, interpreted and the effect on the work still to be conducted was assessed for each future column. Preventative and corrective measures were, if necessary, taken in order to control or counteract the measured defect. In addition to the process-oriented and qualitative measurements, various independent measurement systems at the station building served as a further control in order to prevent damage to the building.

Jan 1, 2006

Previous methods for measuring the flow of solids in Jnrdraulic conveying have not considered the important effects of slip velocity and particle concentration. In this paper an extension of the method proposed byShirato et al. (J. Chem. Engng. &apos;Japan, 1: 164-167) for determining mass flow in a vertical conduit is outlined.The present method consists of measuring&apos; the volumetric flow of the slurry (by a magnetic flow meter for instance) and the density of the slurry in two pipe sections of different diameters. Effects of variation of slip withparticle concentration, not previously considered, are allowed.Problems involved in estimating the density of a slurry from differential pressure measurement are discussed.The major problem is the uncertainties in estimating frictional losses due to the wall in two-phase flows. The greater reliability of a more &quot;direct&quot; technique, such as by &apos;Y-ray absorption, for measuring solid concentration is emphasized.

Jan 1, 1971

By Khamis Y. Haramy

Quality assurance and quality control of drilled shafts has become a concern due to difficulties in accurately locating construction anomalies and determining load bearing capacity of defected drilled shafts. Various non-destructive evaluation techniques have been developed to estimate the integrity of the concrete in drilled shafts. While these techniques have been widely accepted, variables and unknowns can affect the measurement results. Results are typically difficult to interpret, leading to unnecessary construction delays and possible litigation over shaft integrity. In addition, influences of surrounding ground materials, stress states under different load conditions, and crack and residual stress development during concrete curing further complicate determination of shaft performance. This paper focuses on the evaluation of load bearing capacity of defected drilled shafts under various conditions by numerical analysis and modeling.

Jan 1, 2007

By L. Forsbacka, M. Nakamoto, L. Holappa

Viscosity of the slag is one of the central parameters when producing FeCr in submerged arc furnaces. It contributes to smelting behaviour and reduction kinetics of chromite ore as well as to the Cr recovery by influencing the separation of dispersed metal droplets from the slag. A typical FeCr process slag contains 5-10pct chromium oxides, CrO and CrO1.5. The neural network computation was applied to the evaluation of viscosity for slags containing chromium oxides, and the prediction of viscosity in FeCr process slag was conducted. The main results in this estimation were that the chromium oxides in FeCr process slag lower its viscosity, and that the effect of CrO on the viscosity decrease is greater than that of CrO1.5.

Jan 1, 2007

By Jim Rozek, Robert A. Gee

The Epping to Chatswood Rail Line project is the largest publicly funded infrastructure project in New South Wales. Construction commenced in November2002 with opening scheduled for 2008. The work includes 13 route km of twin TBM driven 7.2 m diameter lined running tunnel, three cross-overs and three new underground stations. The new stations have platform caverns of 20m span with similarly proportioned concourse caverns alongside. The ground is bedded sand stone and shale with high horizontal stresses. Predicted stress-relief induced ground movements during staged excavation led to innovative use of rock anchors for permanent support.

Jan 1, 2005

By R. D. Lindsay

Pamour Porcupine Mines, Limited has been actively engaged in the ''Custom Tolling'' of Gold-Bearing materials throughout the past decade. Experience acquired in this area was utilized to design and commission a custom gold milling facility at its operations in Timmins, capable of:(a) Accepting a bulk ore test sample at the rate of 150 t/d for crushing, sampling, and metals analysis;(b) Processing gold-bearing ores at a rated capacity of 150 t/d, to produce a goldbearing sulphide concentrate;(c) Processing free milling gold ores at a rated capacity of 80 t/d for total cyanidation;(d) Cyaniding custom gold flotation concentrates at a rated capacity of 80 t/d; and(e) Processing of complex gold/copper or carbonaceous ores, requiring an impurity flotation concentrate separation stage prior to cyanidation, at a rated capacity of 100 t/d.Items considered in the process design and development included:- various gold ore types available for processing;- flowsheet flexibility required;- sampling strategy as related to head grade determination and metals accounting; and- contract considerations.This paper highlights how these various considerations were used to design Pamour's ''Custom Gold Milling Facility''.

Jan 1, 1987

By E. T. Boshoff

Paper written on project work carried out in partial fulfilment of B. Eng. (Metallurgical Engineering) The weathering of kimberlite can be accelerated with cations in solution if swelling of the kimberlite occurs in contact with the weathering medium. The type and amount of swelling clays present, along with the surface charge and cation valence, determine the degree of swelling that can occur. Crystalline swelling occurs by the incorporation of cations in the interlayer spacing of the silica sheets. Kimberlite exposed to cupric cations showed very strong weathering, indicating that this type of weathering may be considered a viable process option. Kimberlite fines generated after weathering with monovalent cations showed poor settling behaviour compared to kimberlite weathered with di-, and trivalent cations.

Jan 1, 2005

By Fisher N. I

Disequilibrium ratios (U3O8/eU3O8), which assess the degree to which gamma activity represents the uranium content of a sample, have been measured on a representative set of samples from the ore zone of a carnotite ranium deposit located at Yeelirrie, Western Australia. A statistical analysis has been performed to investigate the dependence of the ratios on lithology and on the location of the sample in the orebody. The analysis indicates that dependence on lithology and on position across the orebody is negligible. Samples from the western end of the orebody and those from below the water table level tend to have slightly lower ratios than samples from other positions, although these trends are small compared with a large random variation in the data. The large random variation could result from some redistribution of the daughter isotopes of uranium within the orebody. On the basis of the results from all the samples, the estimated deficiency of uranium relative to radium in the ore zone of the deposit is 11 per cent.

Jan 1, 1980

Mining steeply dipping coal seams is a difficult task in the mining industry. Prior to 1996, fully mechanized longwall mining methods along the seam strike direction were tried in China and other countries. Due to its larger coal reserve in steep seams, China made more but still limited progresses on mining in such seams than the other major coal-mining countries. In the last two decades, accelerated research efforts have been made to improve the mining technology in steeply dipping coal seams. Based on these works, a dynamic model of ?R-S-F? system under asymmetrical constrains in mining steep seam is established and the theory of strata control and hazard prevention begin to be formed. The key technologies for mining steep coal seams include: global and regional strata control methods in longwall face, methods for the longwall face machines to sustain static and dynamic loads, and flexible protection technology. These theory and technologies have been successfully applied to mining of steep coal seams of varying thickness and hardness, with hard and soft roof and floor, and with high potential of spontaneous combustion in China. In the recent years, the technology has been introduced to Russia, India, Uzbekistan and other countries where steep coal seams are mined.

Jan 1, 2012

By Choon Sunwoo, Chang-Ha Ryu

There are various methods available for the recovery of dimensional stone in open pit quarries. Explosive blasting has more advantages in the economic point of view over the other methods but was not widely used in Korea because owner was concerned about much economic loss when it failed. Several years of efforts have been made in order to develop more effective cutting methods and to spread to the quarries for strengthening the competitiveness in the market. Rock cutting by jet flame and black powder was generally used in the early stage. Black powder was applied to cut the last horizontal plane after forming other vertical planes using the jet flame. Jet flame operation, however, is time consuming and produces excessive noise, and as the result, brings adverse effects on the operator as well as the complaints from the residence adjacent to the quarry. Some mechanical methods such as the slot drill, diamond wire saw or in-situ scale of diamond saw cutting were introduced. Most effective cutting methods using the explosive blasting were developed and applied successfully. Black powder was replaced with the detonating cord. A new air decking technique where plug was not used was developed. This paper reviews the technology for dimensional stone cutting and case study in Korea.

Jan 1, 2003

By M. S. Fleming

The objective was to evaluate central lubrication systems for potential use on underground mining equipment. Previous use on continuous mining equipment resulted in poor system performance because of improper selection of lubricants, component failures, and an inconsistent delivery of lubricant to the bearings. The principles and operational characteristics of systems are reviewed and evaluated, and it was concluded that systems are available which can provide reliable central lubrication if properly applied, installed, and maintained. The procedures for applying a system to a continuous miner are discussed. Investigation revealed the lack of significant information on lubrication-related equipment failures and injuries related to maintenance and repair operations, the lack of significant failure rate data for central lubrication system components, and the lack of performance standards for central lubrication systems and components. To continue the development of systems for underground mining equipment it is recommended that a data bank on failures and reliability for equipment with and without central lubrication systems be created, and standardized specifications and performance criteria be developed for central lubrication systems and components which will be used on underground mining equipment.

Jan 1, 1979

By M. Ksiazek

Keywords: Thermal conductivity, thermal diffusivity, flash method, specific heat capacity, manganese ore Manganese ferro-alloys manufacturing involves a combination of quality raw materials and an energy source to produce high-quality products with low energy consumption. The thermal properties of manganese raw materials such as ores, sinters, and briquettes, are among the many factors that determine the amount of energy needed for processing. Thermal expansion, thermal diffusivity, conductivity, and apparent specific heat capacity of solid samples and compacted powder samples of manganese ores were examined from room temperature to 1000 °C. The effect of porosity (of the materials used) on the thermal properties was also investigated. The laser flash method and a pushrod dilatometer were used.

Jan 1, 2011