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By M. I. Abbas, M. A. Shahin, M. S. Ahmed

"The influence of annealing of galvanized steel (galvannealing) on its corrosion kinetics in a saturated solution of Ca (OH)2 has been studied by means of the polarization resistance method.Galvannealing heat treatment was carried out at 450°C and 550°C for varying times. Annealing at 450°C for 24 hr or at 550°C for 5 hr showed the highest corrosion potential (Ecorr) ~= - 400 m V/ SCE as well as, the lowest corrosion current density (icorr ~= 3 mA.cm-2, while Ecorr and icorr of the unheated specimens were ~= - 1400m V/SCE and == 20 mA.cm-2, respectively.Polarization curves were also obtained for the as-received galvanized specimens together with the galvannealed ones.INTRODUCTIONHeat treatment of galvanized steel (i.e . galvannealing) is carried out at a temperature range of 450°C to 550°C for a time sufficient to convert the free zinc coating to an alloyed one consisting of layers of iron-zinc intermetallic compounds. Table I is a review of the properties of the Fe-Zn intermetallicphases while Figure I is a reproduction - of the Fe-Zn equilibrium phase diagram taken from Hansen.Several authors have studied the formation of intermetallic phases through the interdiffusion of Zn/Fe couples. Their results confirmed the stability of intermetallic phases that could be shown up on the outer surface as a result of galvannealing of galvanized steel.Bernick and Sievertv"" investigated the processing of galvan nealed steel. They found that the galvannealed coating with the best forming qualities consisted of a mixture of Zeta phase and Eta phase."

Jan 1, 1989

By J. Keough

During industrial electrowinning of copper, uneven growth can impact current efficiency, cause short-circuits in the cell and negatively impact the final quality of the metal product. Copper electrodeposits can be made smoother by incorporating a host of additives in the electrolyte but uneven copper growth may still occur due to variations in electrolyte composition throughout the cell-house. To quantify roughness, 3D images of the surface may be combined with scaling analysis to gain further insight into the deposit structure. Moreover, scaling analysis may offer a method to predict long-term deposit structure using short-term copper deposits. In this paper, the application of Atomic Force Microscopy (AFM) and scaling analysis are used to monitor copper growth and extract surface roughness characteristics. The cathode was a 304 stainless steel disc that was polished to a mirror finish. Copper was deposited onto this surface over a range of 10, 20 and 30 minutes from an acidic sulfate solution (40 g/L Cu) at 40oC from an electrolyte that contained or was free of guar. AFM images were acquired to obtain 3D topographical information on the samples and scaling analysis was performed to extract the root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. INTRODUCTION During the process of copper electrowinning, the dissolved metal ions are reduced and thereby deposited onto a cathode substrate which is later recovered by stripping the metal from the cathode surface. Although this process is widely used in the industry, the conditions of the deposition procedure may cause the growth of the metal product to be uneven which can not only impact the current efficiency and final copper product quality but may also lead to plant interruptions through short-circuits if the anode and cathode make contact. To create more uniform copper deposits, a host of additives may be included in the electrolyte which may act as brighteners, leveling agents and inhibitors which may include guar gum, glue, thiourea or polysaccharides or polyacrylamides and their industrial use has changed over time (Moats, Luyima, & Cui, 2015). As such, the electrolyte composition is often complex and subtle variations in the solution matrix throughout the cell-house may impact the surface morphology of the final copper product. In an effort to quantify the roughness of copper samples, image analysis is often applied and may include Scanning Electron Microscopy (SEM) or Atomic Force Microscopy characterization. While both are appropriate, AFM offers 3-dimensional information which may be used to both qualitatively and quantitatively characterize the surface characteristics.

Jan 1, 2019

By Keith Donovan

Why are we here? Improve equipment performance & health ? Eliminate undesirable downtime and expensive secondary damage ? Maximize equipment life, optimize running costs (reduce costs) ? Improve safety and environmental performance ? Capture and consistently apply equipment knowledge ? Improve Proactive Maintenance processes & practices

May 1, 2009

By David McMullen

Radiation plays a critical role in the thermal behaviour of hydrometallurgical process equipment. This effect is particularly important when designing refractory lined equipment used in pressure leach/oxidation processes. In order to simplify this non-linear mode of heat transfer, the effects of radiation had previously been incorporated in an equivalent convective film coefficient in finite element methods (FEM). This prior method omits the effects of radiosity, a critical aspect of radiation heat transfer, which affects the design of refractory lining systems in autoclave vessels. Given that 60% of the heat loss in actual plant practice of an autoclave is due to radiation, reliability in the FEM is therefore impacted. This study validates the use of radiosity in FEM through thermal loading using a combination of simple geometries to be applied to complex environments such as vessel nozzle clusters. The added benefits of using a radiosity load includes an increase in confidence in thermal distribution results, greater accuracy in determining appropriate refractory lining systems, weld overlay sizing, and increased accuracy in structural analysis.

Jan 1, 2014

By A. Ghahremaninezhad, E. Jorjani, A. Riahi, Islamic Azad University, B. Nazari, H. Hani, Z. Manafi

The presence of a high iron concentration, 9.1 g/L, in the raffinate of the Sarcheshmeh copper heap bioleach process led to the formation of various types of jarosite, (K,Na,NH4,H3O)Fe3(SO4)2(OH)6, on the heap mineral surfaces. This study probes iron removal from the raffinate using a bio-oxidation process based on A. ferrooxidans bacteria in the presence and absence of jarosite seed. The jarosite seed was biologically synthesized using A. ferrooxidans bacteria. The effect of solution pH (1.5 to 2.5) and jarosite seed dosage (0 to 15 wt.%) on iron removal was examined. It was demonstrated that the concentration of iron ions present in the raffinate decreased from 9.1 g/L to 2.5 g/L with the addition of 10 wt.% jarosite seed at pH 2 and 130 rpm mixing rate at 32°C. Three different types of raffinate including (1) native raffinate containing 9.1, 3.4, 5.7 g/L of total, ferric and ferrous iron, respectively, (2) bio-oxidized raffinate in the absence of the jarosite seed containing 8.5 g/L total iron (mainly ferric with negligible ferrous), (3) bio-oxidized raffinate in the presence of jarosite seed containing 2.55 g/L total iron (mainly ferric with negligible ferrous) were used in mesophilic, moderate thermophilic and thermophilic bioleaching processes. The results of the flask tests showed that the highest copper bioleaching recoveries of 9.4, 49.4 and 90.8 % were achieved using raffinate (3) with mesophilic, moderate thermophilic and thermophilic bioleaching processes, respectively.

Jan 1, 2016

By V. G. Papangelakis, G. A. Moldoveanu

"One of the major commercially viable secondary sources of rare earths elements (REE) are the ion-adsorption ores, containing 0.05-0.3 wt% rare earth oxides physically adsorbed on the surface of clay minerals formed during weathering of lanthanide-rich rocks. Although ion-adsorption deposits are substantially lower grade than other types of rare earth sources, this is offset by the easier mining and processing costs and the low content of radioactive elements. The conventional extraction route involves ion exchange leaching with monovalent cation solutions (usually ammonium sulphate) under ambient conditions; during the process, the lanthanides are desorbed and transferred into solution, being replaced by the exchange cation. While ammonium ions are known to perform best, there is increased environmental motivation to investigate alternative lixiviants in order to minimize ammonium sulphate impact via reducing its use without considerable loss in rare earth recovery.The objective of the present research was to screen various cations salts (alkaline and alkalineearth metals present as sulphates, chlorides and acetates, respectively) in order to comparatively evaluate lanthanide desorption levels and provide a theoretical base of the observed behaviour. The overall aim is to gain a better understanding of how both cation and anion may affect the overall REE recovery from ores in order to provide alternative processing routes. The distinct exchange capabilities of cations were explained in terms of differences in cation hydration enthalpy within the same group, i.e. Cs+ > NH4 + > K+ > Na+ > Li+ and Ba2+ > Ca2+ > Mg2+. For the same cation, it was determined that REE extraction efficiency follows the order sulphate > acetate > chloride, based on dissimilarities in constants of formation values. Various process implications scenarios will be described based on using mixed cations and anion matrices."

Jan 1, 2016

By M. S. Diederichs, J. Oke

Surface limitations and a need for more direct transportation routes require serious consideration be given to the development of underground construction works in geotechnically unfavourable conditions. Due to geographical and logistical limitations, the construction of these underground works is restricted to difficult ground conditions that require temporary pre-support before excavation in order to avoid tunnel collapse or severe surface settlement. One type of pre-support is the umbrella arch system, which has been gaining popularity due to cost and time commitment in comparison with other pre-support systems (e.g., ground freezing). The umbrella arch system has been employed with significant frequency around the world, yet without a complete understanding about the mechanical response of the system. As such, literature has found the temporary support system to be both under and over designed with regard to safety and/or economical impact. The authors of this paper have made three major contributions to increase understanding of the umbrella arch system and to help optimize the design process. Firstly, the authors have developed nomenclature in order to categorize and define umbrella arch elements and systems, which also stimulated the creation of the empirically driven Umbrella Arch Selection Chart. Secondly, the authors have established a design methodology that is primarily based on advanced numerical modelling techniques to aid in the optimized design of the umbrella arch arrangement for site specific conditions. Thirdly, the authors have developed a semi-analytical model for umbrella arch systems employed in squeezing ground conditions by incorporating elastic foundation theory as well as convergence confinement theory. These three major contributions to such a widely employed tunnelling pre-support system will be introduced and explained in detail, and will include discussion of how each is incorporated in the complete tunnel support design process and throughout the construction and monitoring phase of a project.

Jan 1, 2015

The Millennium deposit, located in northern Saskatchewan between the McArthur River mine and the Key Lake mill, has considerable potential for becoming an operating mine. Located in the Athabasca Basin, Millennium is blessed with both the riches and the challenges that this basin offers. The potential for ground water inflows during shaft sinking, and the unconventional challenges associated with underground uranium mining, render the successful development of a new mine in this area especially rewarding. The preliminary design and engineering of the Millennium Project has tapped into the experience of other operations in the area, and has utilized new applications of geophysics technology to enhance the understanding of the local geological structure. This discussion will focus on the innovations, and the challenges specific to uranium mining, for a deposit that is poised to be one of the next mines to supplement Saskatchewan's uranium resources.

May 1, 2008

By A. Darragh

"Past Growth The Canadian coal industry has grown rapidly during the past two decades. Coal production increased over four-fold between 1965 and 1982; consumption almost doubled, imports remained relatively flat, exports soared and total demand increased nearly two and a half times. Coal production grew during this period at an average rate of 8.60/o, compounded annually; this remarkable performance is shown in Table 1 and Figure 1. The relationship between production and consumption is shown in Figure 1, where in 1981 the total Canadian production of coal for the first time exceeded total Canadian consumption. ln Figure 2, the relationship between imports from the United States and Canadian coal exports is shown; in_ 1981 again for the first time, exports offshore exceeded imports into Canada. The rapid growth in Canadian coal use between 1965 and 1982 followed a major decline after World War II, as the country moved rapidly to an oil based economy. Changes in consumption patterns between 1945 and 1982 are shown ~n Table 2. Railway consumption of coal was reduced to zero m the early 1960s. The industrial and domestic consumers market share fell from about 660/o in 1960 to 6.70/o in 1975; this share, however, appears to have stabilized in recent years and actual volumes can be expected to increase in the future. The steel industry's share of the coal market fell over the same period, but the volume in recent years has remained fairly constant at about seven megatonnes per year.Perhaps the most significant change in consumption is in the share of coal consumed in the generation of electricity; this has increased from 80/o in 1960 to over three quarters of the total Canadian coal consumed in 1982. This increase in thermal coal consumption has been supplied by indigenous coal, and was accompanied by a decreasing share for coal imported from the U.S.A. into central Canada. It is expected, because of the nuclear power commitment in Ontario, that this share will continue to decrease, although the total volume of coal imported may increase slowly over time. This will likely also have a dampening effect on future coal sales to Ontario from western Canada."

Jan 1, 1985

By Ferri Hassani

Some future challenges ? People ? Shortages of HQP (e.g. engineers, scientists, geologists) ? Environment ? Regulatory standards - GHGs and air pollutants ? Mine waste management and rehabilitation ? Downstream processing (e.g., alternatives to cyanide) ? Climate change adaptation ? Lowering costs and improving productivity ? Energy efficiency ? Mine automation ? Health and safety ? Deep mining

May 1, 2008

By W. A. Gow, V. F. Harrison, H. H. Mccreedy

A semi-continuous bench-scale, countercurrent-decantation system, in which the ore was moved countercurrently to the flow of leaching solution, was used to conduct acid-leaching tests on uranium ore with the aid of bacteria. This method, which involved a low degree of agitation, was successfully applied to extract uranium in practical amounts and at practical rates. The acidity of the leaching solution was the main variable investigated in the bench-scale tests done at the Mines Branch, Ottawa. Over 90 11er cent of the uranium was extracted in a six-stage system. The results suggest that this technique could be ap-plied in the utilization of bacterial oxidation and leaching as a method for treating Elliot Lake uranium ore.

Jan 1, 1969

By M. Leroux, J. A. Finch

"Sizing below 38 µm (400 mesh) is an increasing requirement in mill testing laboratories. The Cyclosizer is gaining wide acceptance in this role. A recent alternative is to use electro-formed sieves (micro-sieves), which are available with openings down to 5 µm. The advantage of micro-sieving is a cut size which is independent of mineral density, easier retention of the fi nest fraction and reduced purchase cost. A simple method of microsieving using an ultrasonic bath, which performs readily to 10 µm, is described.A systematic study of Cyclosizing and micro-sieving is reported for three samples; silica, copper oxide and a lead concentrate. Micro-sieving gave comparable results. Comparison with a standard sizing method, the Sedigraph 5000D, revealed misplaced material in each fraction by both methods. The range for micro-sieving was from 20% to 60% depending on the sieve and material; for the Cyclosizer it was a consistent 40-50% for all cones and all materials. The Cyclosizer can be sensitive to feed mass and particle size for dense materials. It is recommended that for minerals of specific gravity greater than 5, no more than 35 g of -38 µm be used.The disadvantage of micro-sieving is that it requires continuous operator attention and sieving time depends on sample mass. To fractionate 35 g-as used on the Cyclosizer and considered at reasonable mass for mill testing purposes-through 25-, 15- and 10-µm sieves requires about 80 minutes.IntroductionParticle size has a pronounced influence on mineral separation processes. Consequently, the measurement of particle size plays an important part in mill testing. By far the most common method is by screening. This, however, is usually limited to 38 µm (400 mesh) or occasionally 25 µm (500 mesh). Increasingly, mineral products are becoming finer than this limit and consequently finer sizing methods are required."

Jan 1, 1982

By K. Becerra, D. G. Almond, T. D. Maru

"Nkomati Nickel Mine in South Africa processes one of the world’s hardest ores in a 375k TPM autogenous grinding circuit. The plant employs an unconventional processing circuit, comprising a primary autogenous mill (AG or FAG) and pebble crushing circuit followed by a secondary hybrid pebble/ball mill and classification cyclone cluster.Advanced Process Control (APC) or Expert Control is now generally accepted as an advantage in most modern high capacity concentrator grinding circuits. This paper reviews the installation of model predictive control at Nkomati and examines the results and benefits of installation in an autogenous mill during plant ramp-up. The paper also demonstrates how predefining process control objectives together with good plant and supplier cooperation can achieve a robust and reliable APC implementation on a very short site program.The results conclusively demonstrate operational and economic benefits during circuit operation with the advanced process control system ON. Production performance and circuit stability were significantly better than during manual control."

Jan 1, 2012

By D. J. Charlton

"IntroductionMaintenance is a business, which to be successful, requires good management, systems and reporting. The prime objective of the maintenance management group, be they large or small, must be to anticipate and prevent interruptions in operations by keeping equipment in good mechanical condition. This objective should be carried out at minimum cost consistent with maximum productiveness.The objective of this chapter is to give an insight into the various aspects of maintenance management that must be considered to effectively and efficiently operate a mill complex. The degree to which the maintenance sub-systems are developed in an operating mill will be determined by the size of the mill and the needs of the operation.The criterion of the management system used is that the system serve the operation and not vice versa. The systems presented should be considered as tools and, as with all tools, they must be sharpened and replaced as the need arises or as more effective tools become available.To understand what is involved in maintenance management, it is worthwhile to consider a systems approach to analyzing management problems. This approach was developed by J.A.B. Rae while reviewing maintenance management systems for Cominco Ltd.A very simple system involving managing results and objectives is shown diagrammatically in Figure 1.The systems approach to organizational development involves four basic elements: an objective, a result, an activity and feedback. In the analysis, the activity element is broken down into individual actions that people could be held responsible for. If we introduce the action of operating into the diagram of Figure l, we arrive diagrammatically in Figure 2."

Jan 1, 1989

By M. Sahoo, P. Burke, Y. Fasoyinu, J. P. Thomson

The effects of grain refinement, mold temperature and chemical composition on the hot tearing resistance of aluminum alloys 535.0 and 206.0 has been studied by pouring constrained rod castings in metal molds. In addition, two prototype components that could be used in automotive applications were also poured from both alloys by gravity tilt-pour and low pressure permanent mold casting processes. This paper summarizes the results and issues encountered during the casting trials. It was shown that grain refinement and mold temperature ::::: 400°C reduced, and sometimes eliminated hot tear cracks in both alloys. The two prototype engineering components could be cast successfully from both alloys in metal molds. The metallurgical issues related to molten metal treatment and processing temperatures were well controlled. However, issues related to the control of hot tearing, casting and mold design must be addressed in future studies to guarantee the production of defect free castings.

Jan 1, 2006

By Matt Manson

Renard?1-10 kimberlite pipes and ?Lynx-Hibou?kimberlite dyke system within ?Foxtrot?property 50/50 JV with SOQUEM, Stornoway operator 2001: Discovery of the Renard kimberlite pipes 2003: Discovery of the Lynx-Hibou kimberlite dykes 2006-2007: Bulk sample program 2008: First 43-101 Resource and Preliminary Assessment 2009/2010: Updated 43-101 Resource

May 1, 2010

By William H. McCracken, William G. Holroyd

"The People's Republic of China could very well be considered the largest untapped mineral and metal resource in the world. The proven reserves of antimony, barite, bauxite, fluorspar, graphite, lithium, magnesite, mercury, molybdenum, phosphate, pyrite, rare earths, talc, tin, titanium, tungsten, vanadium and zinc are among the largest in the world.Any company involved in the purchase or supply of industrial raw materials has undoubtedly followed the phenomenal growth of some of the Chinese mineral commodities, where growths in production of more than 200010 have occurred during the past ten years, for commodities like barite, cement, gold, gympsum silver and talc. Others, like bauxite and phosphate, experienced production increases in one year alone of over 45%, from 1986 through 1987!A popular rationale in the United States during the past two years has been the acknowledgment by Professor David Calleo, of Johns Hopkins School of Advanced Studies, that ""America is not sinking-the rest of the world is rising"". While we recognized this rise to be that of economic power for Japan, Korea, Brazil, Taiwan and, more recently, the newly-combined Germanies, China has also successfully completed her own modern five year development binge. But with each boom there is also a bust, and the start of the 1990sfor China shows signs of economic distress. China posted a budget deficit equivalent of US$1.9 billion in 1989 coupled with official inflation at 18010. Projections for 1990 are for US$1.8 billion deficit and inflation as high as 24%. However, government spending in the first seven months of the year climbed 16.4%, outpacing an 11.6% rise in revenue. Spending increases have been related to the government policy to keep prices on domestic goods artificially low, through subsidies, and to bailout inefficient state companies."

Jan 1, 1991

By Doris Stüben, Geoffrey P. Glasby, Akira Usui, Jörg-Detlef Eckhardt, Bruce W. Mountain, Zsolt Berner

"Abstract - Twenty-seven marine Mn and Fe deposits chosen for their diverse origins have been analyzed for five platinum-group elements (PGE). The PGE display their highest concentrations in hydrogenous Mn crusts and nodules, lesser concentrations in diagenetic nodules and two to three orders of magnitude lower concentrations in hydrothermal Mn and Fe crusts. This difference of behavior reflects the well-known fractionation of Mn and Fe from the other transition elements, rare earth elements (REE) and PGE in hydrothermal Mn and Fe crusts. Pt, Ru, Rh, and Ir show a close geochemical coherence in these deposits and are differentiated from Pd which shows a negative anomaly with respect to the other PGE in hydrogenous and diagenetic Mn deposits. Pd is less depleted than the other PGE and the Pd anomaly much less pronounced in the hydrothermal Mn and Fe crusts relative to the hydrogenous and diagenetic Mn deposits.Stability field diagrams show no evidence for the oxidation of Pt to the tetravalent state in seawater as suggested by some authors. Rather, Pt appears to be present in seawater as Pt(OH)2 0. Adsorption of Pt(OH)2 0 onto the surface of Mn and Fe oxyhydroxide minerals may explain the enrichment of Pt in marine Mn deposits. However, Pt metal is the thermodynamically stable solid phase of Pt under seawater conditions and reduction of Pt(OH)2 0 to Pt metal, particularly in the vicinity of the oxygen minimum zone, is possible, although the high Ce/La ratios of the Co-rich Mn crusts do not support this hypothesis. Pt, Ru, Rh, and Ir display their maximum concentrations in the Corich Mn crusts. This may reflect, among other things, the low growth rates of these deposits. The stability field diagram of Pd shows that Pd is undersaturated in seawater and occurs in seawater dominantly as PdCl4 2- and anionic mixed-hydroxide-chloride complexes. This would explain the anomalous position of Pd among the PGE with respect to its uptake into marine Mn deposits. A study of inter-element associations indicates that the incorporation of the PGE from meteoritic dust plays only a minor role in the uptake of these elements into marine Mn deposits. The PGE remain the most poorly studied group of elements in marine Mn deposits. The data presented here emphasize the need for the establishment of a more comprehensive database of the PGE in marine Mn deposits in order to understand more fully their uptake into marine Mn deposits and their pathways through the oceans."

Jan 1, 1999

By E. Fiset, T. Hennebel, F. Verbruggen, A. Prévoteau, K. Rabaey

Arsenic (As), bismuth (Bi) and antimony (Sb) are known to affect the quality of copper deposits in copper electrowinning operations. The codeposition of As was previously believed to occur only at current densities far exceeding the range of typical current densities for copper electrowinning. In this study, we investigate the copper electrodeposition on different pretreated stainless steel (SS) substrates from bleed electrolyte in galvanostatic mode at –45 mA/cm². Scanning electron microscopy (SEM) micrographs illustrate that during the initial phases of copper nucleation and growth, the current density was locally increased due to the pretreatments. It was reasoned that the codepostion of As could possibly occur in normal electrowinning conditions, but the risk can be substantially reduced by good SS substrate handling and maintenance practices. INTRODUCTION The presence of As, Bi and Sb is known to have a deleterious effect on the copper cathode quality in copper electrowinnings (Hiskey & Maeda, 2003; Hoffmann, 2004; Xiao, Cao, Shen, & Volinsky, 2012; Xiao, Cao, Mao, Shen, & Ren, 2014; Jafari et al., 2017). They are known to influence both the chemical and physical quality of the copper as they can contaminate the copper (Jafari et al., 2017) and affect the copper deposit structure (Hiskey & Maeda, 2003; Kim, Kim, & Chung, 2009), which contributes to a degraded market value of the copper (Tuddenham, 1984). The incorporation mechanisms of these impurities are believed to occur mainly through slime inclusion (F. Xiao et al, 2012) and electrolyte inclusion (Hiskey & Maeda, 2003). Other studies suggested that codeposition of these impurities is possible by their standard reduction potential being close to the one of copper (Xiao et al, 2014). Hiskey and Maeda (2003) investigated the copper electrodeposition on a copper electrode substrate in Cu electrolytes with a Cu, H2SO4, As, Bi, Sb composition representative for commercial copper tankhouses. The combination of voltammographic techniques and Auger electron spectroscopy showed that As was the first impurity to be electrodeposited from this electrolyte, yet at potentials where the limiting current density of the copper electrodeposition reaction is exceeded. The copper tankhouses usually operate at a current density ratio of 0.3 to the limiting current density in order to achieve tolerable copper quality deposits. The codeposition of As could be considered impossible in this current density condition. However, it is known that during the initial phases of electrodeposition on foreign substrates, a substantial part of the reaction proceeds by growth of individual nuclei where the current density is locally high and diffusion limited (Radisic, Ross, & Searson, 2006). Furthermore, it was observed that copper nucleation on TiO substrates occurred preferentially in the scratched oxide free areas which could serve as parts with high localized current densities (Chang, Choe, & Lee, 2005).

Jan 1, 2019

By Derrin A. Auerswald, Jacolien P. Wyethe, Nanne M. \/egter

Base and precious metal refineries often produce effluent solution and slurry streams containing between 50 mg/L and several grams per liter of base metals. Metals have historically been precipitated from these streams with lime to produce effluent streams at pH values between 8 and 9. This effluent treatment process generally does not remove alkali and alkali-earth metals or halides efficiently and with more stringent environmental legislation, more sophisticated effluent treatment plants must be considered which could for example incorporate sulphate removal with ultra-filtration, or the SavminTM process, followed by reverse osmosis for the removal of halides. The flowrates of effluents are often high and if base metals can be recovered before neutralization, the revenue generated from this stream can reduce the cost to produce clean water significantly, and in the case where high concentrations are disposed of, result in a profitable operation. As an add-on to an existing the plant the recovered metal is upgraded and recycled to the plant, but the production of a saleable metal can also be considered. Technology selection for metal recovery depends on the composition and flowrate of the effluent, but could incorporate resin-in¬pulp or other ion-exchange technology; precipitation as sulphides, hydroxides or carbonates; or solvent extraction. This paper describes, as a case study, the technology selection process and uses data from Zincor. Zincor is a division of Exxaro Base Metals (Pty) Limited, a subsidiary of Exxaro Resources Limited.

Jan 1, 2011