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By L. Sun

In this work, strontium doped lanthanum ferrite (LSF) and their composite cathodes were fabricated by screen printing on yttria-stabilized zirconia (YSZ) electrolytes. Their electrochemical properties were evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods. All the cathodes were screened by comparing their total polarization resistances before and after activation processes at different temperatures. The improved LSF composite cathodes were also screen-printed on YSZ/NiO half cells to fabricate solid oxide fuel cells (SOFCs), which have reached the output power densities of 170 mW/cm2 at 650 °C, 230 mW/cm2 at 700 °C, 304 mW/cm2 at 750 °C and 388 mW/cm2 at 800 °C.

Jan 1, 2005

By X. Cao, M. Xiao, M. Jahazi

Magnesium alloys have low hardness, wear, erosion and corrosion resistance. The repair of service-damaged aerospace components made of magnesium alloys is an attractive solution in terms of time and cost saving. The feasibility of applying laser beam technology to repair ZE41A-T5 magnesium alloy sand castings in the machined surface conditions was studied using a continuous wave 4 kW Nd:YAG laser system. The influence of process parameters such as laser power, cladding speed, wire feed rate and defocusing distance on the shape, size and area of single cladding beads is discussed using a process optimization software. Sound single clad beads with good geometric characteristics were obtained using strictly controlled laser process parameters. The overall results indicate that laser surface cladding using filler wire has the potential for repairing aerospace components made of cast magnesium alloys.

Jan 1, 2006

By L Mariani, G. Mendoza-Suarez

In this investigation, TiH2 powders were coated with copper and nickel by electroless plating to delay hydrogen evolution. Copper-coated samples were found to have a mixed acicular (2D growth) and cauliflower (3D growth) morphology whereas the nickel-coated samples had a cauliflower morphology. Examinations of the coated powder cross-sections revealed that the coating thickness ranges from 0.2 µm to 4 µm. Uncoated areas on the powder surface and coating flakes unattached to TiH2 particles suggest poor adhesion between the coating and the substrate. The phase transformation undergone by the TiH2 during dehydrogenation was studied in samples taken at intermediary points in the heating cycles and examined by XRD. The findings reveal that as the powder is heated from room temperature to 800°C, it changes from TiH1.971 to Tiu and to aTi. Differential Thermal Analysis (DTA) was performed to study the effects of the coatings on the temperature of hydrogen release. It was found that increasing the number of plating iterations, and therefore the thickness of the coating, creates a significant shift in the temperature of gas release.

Jan 1, 2006

By David L. Sprott

This paper presents an evaluation of underground-to-surface haulage options for a relatively large deposit. Specifically, it presents a recommended haulage option to provide the greatest value to the Project. Options considered included conventional truck, trolley-truck, conveying and shaft hoisting. The work was done at the level of a preliminary assessment as input to an internal pre-feasibility study. The Base Case for the analysis in this study was a Long Hole Open Stoping option (LHOS) using conventional truck haulage. Two scenarios were considered for the evaluation and included: 1. The current resource to ~700 m depth. 2. An expanded resource to ~825 m depth. The haulage options evaluated included three trucking options, three conveyor options and two shaft options. The paper presents the results from evaluating these options within the two mining scenarios using a Discounted Project Cost (DPC) comparison. Recommendations are made for the options that will provide the greatest overall value to the project.

May 1, 2008

By M. F. Gallerneault, V. Fallah, A. Howells, W. M. T. Gallerneault

"The occurrence of recrystallization in cold-worked aluminum sheet during the brazing process leads to loss of strength, an inhomogeneous grain structure and reduced corrosion resistance. AlMgScZr alloys are known for their extraordinary recrystallization resistance due to the influence of Sc and Zr addition on their microstructure. Here, we investigate the effect of alloy composition (i.e. Mn, Mg, Sc, Zr content), cold-roll reduction and pre-aging treatment on the recrystallization behavior of cold-rolled sheets at brazing temperatures typically used during the manufacture of heat exchanger units. The analysis of recrystallization behavior is carried out through microstructural characterization and the results are compared with the behavior of a commercial, AA3xxx-based heat exchanger alloy.INTRODUCTION Control of recrystallization is of critical importance during brazing, which is a widely-used joining technique for aluminum alloys in aircraft structures (Heinz, 2000) and automotive heat exchangers (Miller, 2000; Marshall, 1993). Due to excessive local heat at brazing temperatures, the cold work texture of aluminum alloys in the cold-rolled sheets may undergo a local recrystallization process (Marshall, 1993). This leads to the formation of an inhomogeneous microstructure and thus anisotropic mechanical properties (Miller, 2000) and low corrosion resistance (Marshall, 1993) across the sheet. X800, a commonly-used Al-Mn alloy series for automotive heat exchangers applications, has been developed specifically for a higher strength as well as an enhanced corrosion resistance as opposed to the traditionally-used AA3003 alloy (Marshall, 1993). X800 alloys, however, exhibit a low recrystallization resistance at normal brazing temperatures, i.e. 590°C. In contrast, Al-Sc-Zr alloys have been shown to exhibit an extraordinary recrystallization resistance at such temperatures (Riddle, 2004) while also being corrosion resistant and possessing a high room-temperature strength (Fuller, 2002). This has been shown to be due to the formation of coherent, nanoscale Al3(ScZr) precipitates that effectively impede grain boundaries while also exhibiting very slow coarsening kinetics at high temperatures (Riddle, 2004; Jones, 2003; Ocenasek, 2001). In this study, we analyze the recrystallization behavior of X800 alloys under brazing conditions through introducing Sc and Zr into the system as well as varying the Mn and Mg content. The effect of processing route is also studied by introducing a pre-aging stabilization treatment as well as varying the cold-roll reduction prior to the final brazing anneal."

Jan 1, 2018

By Roger Potvin

Abstract The demand for pure zirconium and titanium metals in Germany increased considerably during the war. Pure zirconium was used in flash bulbs, in vacuum tubes, and in time fuses for bombs, where it has a decided advantage because it gives no gas in burning. Under the form of alloy, it was used with other rare elements for making substitutes for platinum; it was also used as a scavenging agent in high-grade steels. Metallic titanium was mainly used in connection with the manufacturing of special alloys. The authors were sent to Germany by the Department of Reconstruction and have investigated the German process developed for producing these rare metals. They describe the procedure and special equipment used for their commercial production in Germany during the war. General Metallic zirconium and titanium were .produced on a commercial scale in Germany by the thermal reduction, with metallic sodium, of potassium fluozirconate and titanium chloride, respectively, using a mixed potassium and sodium chloride flux. According to the information gathered, the sole German producer of these rare metals in pure form was the Deutsche Gold und Silber Scheideanstalt (commonly called Degussa), at their Werk II, 215 Gutleutstrasse, Frankfurt/Main, which was visited by the authors on September 18th, 1945. As far back as 1934, Degussa was carrying on active research on the manufacture of zirconium, and nearly one ton of the pure metal had been produced before September, 1939. Concurrently, a quite similar process was worked out for the recovery of titanium and it was in commercial operation in the year 1938, during which the production totalled about half a ton (metric). The demand, especially for pure zirconium, increased considerably during the war, attaining a total of about 48 tons during the period October, 1939, to the end of 1944, and reaching a peak of more than 15 tons in 1943. In 1944, the plant was slowed down due to the frequent and disastrous bombing by the Allies, especially in March and September.

Jan 1, 1946

By U. Dillon, G. Blackwell

"Geographic information systems (GIS) provide an efficient means for the recording, manipulation, revision, display and analysis of spatially referenced data. GIS are widely used at the exploration stage of mine development, and are increasingly used for reclamation planning. The ability of a GIS to perform spatial searches and query spatially referenced data make it a powerful tool for use at all stages of mine development. As the amount of data available for analysis increases, so does the power and flexibility of GIS as a planning tool.Starting from the exploration database, this paper describes how a GIS can be used for the development of mining plans based on topography, geology and mineralization information stored in a relational database. Planning decisions approaching the optimal can then be made for a wide range of parameters, including stockpile and waste dump locations, the location of potentially acid generating and neutralizing material for dump design, profitable and risk-controlled mine extraction sequencing, and haul road locations. This is made possible by the overlay and buffer analysis capabilities of a GIS which are explored and exploited to produce a continuous mine production planning program, as well as site remediation and reclamation using a successful case study. The Ore and ProductsThe mines in the Saskatoon area — Agrium, PCS-Cory, PCS-Allan, PCS-Patience Lake, PCS-Lanigan and IMC-Colonsay — extract the ore from the Patience Lake member. The mines in the southeast corner of Saskatchewan — IMC-K1 and K2, PCSRocanville — extract from the Esterhazy member, while IMC-Belle Plaine, near Regina, solution mines potassium chloride from both potash-bearing members.Ore from the Patience Lake member is a medium-grained mixture of sylvite and halite, with a KCl content of 36%, insolubles averaging up to 5.5%, and little or no carnallite.The ore from the Esterhazy member is a coarse-grained mixture of sylvite (KCl) and halite (NaCl) with a small amount of water insolubles, and some carnallite (a K-Mg chloride). Average run-of-mine grades are about 30% KCl."

Jan 1, 2003

By Jinsuo Zhang

Investment in coal resource development is affected by a variety of uncertain factors. Investors can make a flexible, strategic decision to achieve the value of risk implicated in those uncertain factors. Therefore, based on real-option theory, we identified key uncertain factors that affect a coal resource investment project, and revealed the formation mechanism of option value in coal resource developing investment project. Then, a multi-factor decision making model was established for a coal resource development investment project with random changes of coal price, interest rate, convenience yield and production cost. Finally, we tested the model and analyzed relevant parameters by applying living data. Our results indicate this model reflects the value of risk implicated in uncertain factors for coal resource development investment, and is able to determine a critical point of decision making change when coal price and production cost varym respectively. By means of parameters analysis, the convenience yield has a positive effect on the project value. The interest rate has a negative effect.

Aug 1, 2013

By Bryon Bisiaux, Walter Valery, Sonny Mwansa, George Amonoo, Adrian Dance

"Newmont Ghana Gold Limited’s Ahafo operation have been working with Metso Process Technology & Innovation (PTI) since early 2009 to increase mill throughput from a combination of controlled blasting practices and optimised primary crusher and grinding circuit conditions. For such Mineto-Mill projects, PTI’s methodology is termed Process Integration & Optimisation (PIO).Ahafo operate a SAG mill, ball mill and pebble crusher (SABC) circuit that processes a range of primary ore of varying hardness from different pits which is blended with soft oxide material. The PTI study focussed on ball mill limited material from the Apensu open pit.Following a benchmarking study of all blasting, crushing and grinding practices in January 2009, PTI recommended changes in both blasting and crushing conditions in order to generate a finer feed size to the SAG mill. Additional operating changes in the grinding circuit were recommended.A series of trials were conducted in November 2009 where three blasts were fired using a different blast design (hole diameter and explosive type) in the same area of the Apensu pit as the benchmarked material in January 2009. Top and bottom benches (or flitches) from each blast were sent exclusively to the grinding circuit and the material was tracked using PTI’s SmartTag™ system.The results from the six trials showed a significant increase in primary ore throughput at a reduced blend of oxide material. Ahafo have since standardised on these modified blasting conditions for all Apensu ore zones and have been able to sustain higher throughput compared to historical performance on similar material.This paper summarises the phases of the PIO project, the changes made in operating practices and the outcomes of the blasting trials that validated the predicted increase in mill throughput."

Jan 1, 2012

By Evans B. Mayo

ABSTRACT Orange Footwall 'sill' is locally concordant locally discordant, with the structure of its sedimentary walls. The sediments were folded in two directions. Folds, following both these directions, are preserved in the concordant portion of the 'sill'. It seems, therefore, that the porphyry has replaced the sediments, thus preserving within itself their structure. During replacement, the nascent porphyry may have been much weaker than its walls. Accordingly, under directed pressure, the porphyry could have flowed locally, disarranging the replaced structures within it and developing a flow structure discordant with the folds in the sediments. Some such action may account for the discordant parts of the 'sill'. INTRODUCTION The senior author has seen certain granitoid massifs that have an internal structure vastly different from, and discordant with, the structures in their wall rocks. It seems that? such massifs have moved independently of their surroundings. Yet, a structure section elsewhere in the same mountain range may reveal granitic rocks with internal structures that appear to continue the structure of the invaded rocks. In such a case, it is at least thinkable that the granite has replaced the older sediments or volcanic rocks. In February, 1950, the writers mapped, on 15 level of the Nickel Plate mine, near Hedley, B.C., a diorite or gabbro porphyry 'sill' that, in one cross-cut (1503), appeared to be quite concordant with the wall-rock structures, whereas in another cross-cut ( 1500) about 100 feet to the south, the same porphyry was discordant (see Figure 1).

Jan 1, 1951

By R. W. Pugh, S. L. Ma

"High carbon rods are typically used as the grinding media in rod mills. Usually an AISI I 090 grade of steel is used which provides the high hardness needed for abrasion resistance and sufficient toughness to prevent rod breakage.Work to improve performance in the past has mainly concentrated on increasing the hardness for improved abrasion resistance. This has been accomplished by adding alloys to the steel which uniformly increase the hardness across the rod section.However uniformly increasing the hardness of the rod produces a more brittle product and at high hardness l1evels can lead to rod breakage problems. Heat treatment processes can be used to selectively increase the surface hardness to high levels while maintaining the core at lower hardness levels to give a product that wears slower without breakage. AltaSteel has developed and mill tested a higher hardness heat treated grinding rodThis paper describes the development of a simple model to predict performance improvement with different hardness profiles and the AltaSteel heat-treated grinding rod process. Mill characteristics of the Endako operation are summarized and predicted performance improvements based on hardmess are compared to the approximate 25% achieved in trials running since July, 1991 at this mill. Early results of other mill trials are also presented.INTRODUCTIONAltaSteel, in Edmonton is a major supplier of grinding media. We have a strong desire to continually increase the quality and performance of our products and thereby improve the efficiency of our customers' processes. In the area of grinding rods, we wanted to produce a product with a significant improvement in wear rate. Second to energy, rod consumption usually represents the next highest cost in processing. This paper presents our development of a heattreated grinding rod that has reduced consumption by about 25% in trials to date."

Jan 1, 1993

By K. P. Plucknett, Z. Memarrashidi

WC-Co ‘hard metals’ are widely used in a variety of industrial applications due to their resistance to abrasive wear, in addition to their high hardness and toughness. However, in contrast to their mechanical properties, the corrosion response of these materials is relatively poor. In the current work the corrosion mechanisms of two WC-Co cermets are analysed, with 10 and 30 vol. % of the Co metal binder, in a 3.5 wt.% NaCl aqueous solution. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential, potentiodynamic polarisation and cyclic polarisation, together with systematic analysis of the post-corrosion solution chemistries using inductively coupled plasma optical emission spectroscopy. The corrosion potential and current density were determined, following Tafel extrapolation, allowing the calculation of the corrosion rates. It is demonstrated that continuous dissolution of the cobalt phase occurs during corrosion, which is a result of poor cermet passivation behaviour, and this response increases with the amount of binder in the cermet.

Jan 1, 2015

By Benoît Valley

Optimization of the mining sequence in terms of economics (maximizing net present value) often leads to multi-front mining methods generating pillars. Significant resources are tied up in these pillars, but mining them is often challenging. In order to improve our understanding of rock mass behaviour while extracting these pillars, an extensive monitoring program has been designed and implemented at Vale?s Coleman mine (Sudbury, Canada). The program focuses on existing and new technologies that have potential for monitoring deformation and rock mass property changes. It includes both active and passive methods: gravimeters, multi-point borehole extensometers, fiber optic strain meters, fixed and portable three-component seismic arrays, borehole imaging and sonic logging, and, repeated LiDAR surveys. This paper reports results from an initial project phase, when only a small amount of mining has taken place. The goal was to test and compare technologies in order to assess their sensitivity, accuracy, repeatability and suitability for underground mining conditions. Value is gained by having a broad range of monitoring devices running side by side, enabling comparisons and benchmarking.

Jun 1, 2012

By J. Duriez, L. Scholtès, F. V. Donzé

"Fracture propagation process in brittle rock is investigated by means of numerical simulations performed with an adapted formulation of the discrete element method. The progressive failure mechanism is simulated through the breaking of the bonds making up the cohesion between the elements constituting the simulated medium. The use of appropriate contact laws associated to a near neighbor interaction feature provide the model the ability to reproduce fundamental characteristics of brittle rock behavior such as, for example, high values of the tensile to compressive strength ratio. Great attention is given to accurately describe the properties of the pre-existing joints or faults in the model. A specific joint model gives the possibility to define a tailor-made behavior of the discontinuity surfaces without suffering from discretization bias.Compression test simulations are performed on pre-flawed samples and compared to experimental results in order to validate the numerical approach for describing the initiation and propagation of fractures in brittle rock under mode I+II loading. It is shown that the crack mechanical parameters can greatly influence the fracturing pattern, in particular its frictional properties. Overall, the numerical simulations reproduce fairly well the failure patterns that are obtained experimentally.The discrete model is then used to study mode I+III loading to give an insight into fracturing problems occurring at the scale of the continental crust. The ability of the model to support mechanically the physical modelings performed with wet clay or sandbox is shown. As an example, the model is used to track the development of a twist crack system (wrench fault) through the nucleation and coalescence of microcracks."

Jan 1, 2015

By Siavash Zamiran, Abdolreza Osouli

"One of the most concerns of room and pillar mining system is subsidence of the ground surface due to coal mining particularly in room and pillar mines. Subsidence of ground surface is a result of floor, pillar, or roof failure of the mine. At the same, due to many difficulties associated with surface disposal facilities of coal refuse, some mining companies are trying to use underground space as a disposal storage place. In this study, stability and subsidence analyses of an underground coal mine located in the Illinois Basin are conducted. This room and pillar mine was abandoned and later on was used as a storage place to accommodate the coal fine refuse with slurry backfilling method. The geological stratigrophy and geomechanical properties of the mine floor and roof were collected. Floor and pillar stability analyses were conducted for areas with various extraction ratios. The stability of the mine was evaluated both prior and after slurry backfilling. The floor and pillar stability analyses results of the mine due to moisture exposure after slurry backfilling are discussed. The subsidence potential due to mine failure is also evaluated.INTRODUCTIONA typical lithology of coal seams in the Illinois Basin consists of weak underclay stratum. The immediate weak underclay causes frequent floor instability problems in Illinois underground coal mines. There are two different stages in assessing floor stability of the mines where slurry backfilling is planned. The first stage is during the mining operation when weak underclay layer squeezes under pillar stress and results in punching or bearing capacity failure. The second stage is after slurry backfilling. During this stage, the slurry material soaks non-durable floor layers and causes strength reduction in floor material. Pillar stability conditions should also be taken into account during both the operational period and after the slurry backfilling."

Jan 1, 2015

By A. R. Laplante

"In this paper, the performance of the Knelson Concentrator and of the batch and continuous Falcon Concentrators are compared. The units are based on different operating principles, and as such they perform quite differently. The Knelson yields very high free gold recoveries over a wide size range of both the recovered and rejected species. It is ineffective in recovering very fine ( <15 µm) or flaky gold, as encountered in flotation feeds, concentrates or tails. It is the: preferred unit for gold recovery from grinding circuits. The batch Falcon is effective in the fine range, typically less than 37 µm for gold. Its recovery zone is quickly saturated when there is significant heavies in the feed. It works best as a pre-concentration unit. The continuous Falcon is a versatile unit which is capable of recovering fine heavies (density down to 5 g/cm3 ), especially from coarser gangue. INTRODUCTIONThe purpose of this presentation is to describe the mode of operation of two Canadian centrifugal concentrators, the Knelson and Falcon. It is hoped that it will prove informative to prospective users in the selection, testing and optimization for applications of either machine. The work is based on testwork both in Canadian mills and at McGill. I am indebted to many colleagues at these locations. Appropriate references will be made to articles further describing the work, either already in the open literature or in preparation.Although this work is meant to be more practical than scholarly, it is appropriate to begin by considering how the two units achieve selective recovery. This will become useful in establishing a suitable testing methodology, which will then be described, and interpreting typical results. In the last section I will attempt to define appropriate applications for the two units. This is a thankless task, as I am likely to miss some applications or to make projections based on partial results, as much of the work is still in progress. In deference to the reader and both manufacturers, areas where reasonable doubt still remains will be identified."

Jan 1, 1993

By Xuanxue Mo, Kaihui Yang

"The Laochang mine, located in the Sanjiang area of southwestern Yunnan Province of China, is a volcanogenic massive Pb-Zn-Cu sulfide deposit. It is hosted by a pyroclastic sequence of Early Carboniferous age, namely the lower member of the Yiliu Group, which was intruded by syenite and rhyolite porphyry. The volcanic suite is basaltic or basaltic-andesitic in composition, has alkaline affInities, and is associated with the initial rifting along the margin of the Baoshan-Shanstate continental microplate (Yang, 1989). The ores are typically Pb>Zn>Cu in composition, averaging 3.820/0 Pb, 3.51% Zn, from 0.01% to 1.85% Cu (0.107% av.), a high average content of Ag (113 glt) and recoverable amounts of Au, n, Gd, Ga, Ge, In. A massive sulfide zone, in which lenticular and stratiform orebodies are localized in a sulfide-<:arbonate-silica shale unit or sulfidic tuffIte horizon that usually overlies coarse-grained pyroclastic rocks, is underlain by a stringer sulfide zone developed in a subvolcanic intrusion or volcanic sequence. The sulfIde mineral assemblages, from the top to the bottom of the deposit, are: realgar + orpiment - galena + sphalerite + pyrite - chalcopyrite + pyrite + pyrrhotite + arsenopyrite. Oxide and sulfate minerals occur rarely in the massive ores. The massive ores are generally fme-grained and banded, but coarse-grained ore, colloform and framboidal texture, and growth-zoned pyrite and sphalerite are common. Sedimentary features such as graded bedding, brecciated and deformed ore clasts, and chaotically emplaced blocks, are well preserved, indicating that the massive orebodies have undergone slumping and displacement. Alteration is weak in the hanging-wall rocks, but strong in the stringer zone. Two distinctive alteration zones have been identifIed: the upper zone, characterized by an assemblage of quartz, carbonates, chlorite, albite, zeolite and sericite, and the lower zone containing diopside, tremolite, actinolite, gamet, clinozoisite, and epidote.The general features of the Laochang deposit are in accord with the descriptive model of VMS deposits (Lydon, 1984). However, it falls into neither the Zn-Cu group nor the Zn-Pb-Cu group chemically (Franklin et al., 1981). The depositional setting of the Laochang deposit is quite different from Cyprus or Besshi-type massive sulfide deposits. Laochang is hosted by alkaline lavas that were erupted in a submarine continental rift. Although some features of the Laochang deposit are similar to those of Kuroko-type deposits, there are remarkable differences in the alteration mineral assemblage, the proportion of ore-forming elements (lead enriched) and the amounts of oxides and sulfates. These suggest corresponding differences in ore fluid composition and the associated ore-forming environment. Thus, the authors suggest that the Laochang deposit may be a distinct type of VMS deposit."

Jan 1, 1993

By F. Andrieux

"Extruded aluminum profiles are increasingly used for lightweight vehicle construction. Since fracture strains of aluminum profiles are relatively low, damage modeling is crucial for reliable crash simulation. For aluminum profiles, not only the stress state but also the orientation influenced both the deformation and damage behavior. For the material characterization smooth tensile tests were performed in six orientations, both stress-strain curves and r-values were registered. Moreover notched tensile and shear-tension tests were performed in three directions. Finally punch specimens were tested to investigate biaxial loading. Digital image correlation (DIC) analyses were performed to determine local strain values such as critical values at failure. Numerical investigations were conducted with the strain based damage model GISSMO, which is well suited and widely applied for crash simulation. For a strain based failure model the choice of the deformation model is crucial. Deformation models with increasing complexity were investigated to find the best compromise over all experiments. It was found that there is still a great requirement on development of a material model which describes the orientation dependence of the hardening behavior over all stress states in order to be able to use a strain based failure model reliably.INTRODUCTION Weight reduction is an important step for less energy consumption and as a consequence aluminium is increasingly used in automotive parts. An important field of application is the well-established aluminium extrusion which allows the realisation of quite complex shapes of profiles required for an innovative lightweight design with integrated functions. Typical applications are chassis parts, bumpers, crash elements, air bags, etc. Especially the Al–Mg–Si medium strength alloys of the 6000 series can be easily extruded to form complex profiles and prevail for extrusion. Since fracture strains of aluminum profiles are relatively low, damage modeling is crucial for reliable crash simulation. For aluminum profiles not only the influence of the stress state but also the orientation with respect to the extrusion direction have an influence on both the deformation and damage behavior and need to be characterized. The effect of orientation on deformation behavior has been intensively investigated in the last decades and material models haves been proposed (e.g. Barlat & Lian, 1989; Barlat, Lege, & Brem, 1991; Barlat et al., 2003) to describe accurately anisotropic behavior. However it can be noticed that the parameters of anisotropic material models often rely on the yield stress in different directions, which means that the effect of strain hardening is not automatically accounted for. The accuracy of the models at large deformation is not guaranteed and has to be verified. In contrast to deformation models both the characterisation and the modeling of anisotropic damage behavior are not systematically studied. Isotropic failure models based on a critical strain as function of stress triaxiality (ratio of the hydrostatic stress to von Mises equivalent stress) are widely used for crash application (e.g., Bai & Wierzbicki, 2010; Sun, Andrieux & Feucht, 2009; Sun et al., 2013). The mechanisms of failure are manifold and not fully understood; to develop an anisotropic failure model it is mandatory to also have experimental data in different orientations for loading scenarios other than uniaxial tension, e. g. shear, biaxial tension, which implies an extensive experiment plan. This makes the development of failure models more challenging than deformation models for which it is possible to develop a reasonable anisotropic model using the framework of yield function and calibrate the material parameters based on results of tensile tests in different directions. Moreover the development of deformation and failure models are intricate as the variables governing the damage evolution are predicted by the def"

Jan 1, 2018

By R. M. Porter

PILLAR extraction at the Sullivan Mine bas been in progress for over twenty-five years and bas .involved progressively larger pillars. The largest pillar blasted to date exceeds one million tons and is described in this paper. This blast is believed to be one of the largest to take place entirely under-ground. The Sullivan Mine, owned by The Consolidated Mining and Smelting Company of Canada Limited, is located in the southeastern corner of British Columbia on the east flank of the Purcell range overlooking the twenty-mile wide Rocky Mountain Trench (Figure 1). The orebody is a bedded replacement deposit in argillites, varying in thickness up to 300 feet, but averaging about 80 feet. Above the 3900 Level, the dip varies from nearly horizontal to 40 degrees; be-low the 3900 Level it varies from 45 to 20 degrees (Figure 2). Pillar extraction follows a plan of retreating outward from caved areas. The size of each blast is determined by the effect which the removal of support

Jan 1, 1961

By Sina Mostaghel, M. Guo, E. Klaffenbach

The current paper is focused on evaluating the behavior of copper in a copper production slag and the assessment of metal recovery possibilities. For this reason, thermodynamic calculations were carried out to determine the influence of parameters such as slag composition, temperature and oxygen partial pressure on recovery of non-ferrous elements. It was found that the formation of a solid face centered cubic (fcc) phase, mainly consisting of iron, limits the extent of reduction that can be achieved for an industrial process. However, it could be discovered that solubility of iron in the Cu-rich liquid alloy strongly depends on presence of other elements, particularly arsenic. As part of the results of this study, the solubility of Cu in the slag at onset of fcc phase formation is presented as function of temperature, oxygen partial pressure and concentration of MgO and CaO. It was concluded that lower temperature (1200°C) and higher CaO addition (16 mass-% in this study), would result in the highest achievable copper recovery from slag. INTRODUCTION Copper slag is produced as a by-product of the copper production process. The slag is still containing a high amount of copper and other valuable metals. This demands further treatment of the slag as a secondary source of metals. In addition, the physical/mechanical properties of slag allow its use in several applications such as hydraulic engineering, civil engineering, as an abrasive and many more. These applications help reducing the use of natural resources like rock and sand. By decreasing the content of heavy metals such as Cu, Pb, Zn and As in the slag, its application in abovementioned fields becomes more attractive as the probability of releasing these elements to the environment is further reduced. To develop a pyrometallurgical slag reduction process, it is necessary to understand what describes the end point of the reduction. This point is expected at maximum copper recovery without facing operational challenges. Existing literature provide some information on the effect of different parameters such as temperature or concentration of different slag formers, on solubility of copper and heavy metals in different phases. However, due to complexity of industrial slags, equilibrium experiments and accurate thermodynamic modelling are essential to be able to reliably predict the behavior of different elements in the system and determine the end-point of reduction.

Jan 1, 2019