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By J. C. White

A research study was conducted to devise a method for producing phosphoric acid directly from unbeneficiated Florida phosphate matrix. This research was performed as part of the Bureau of Mines, U.S. Department of the Interior, goals of improving minerals and metals recovery from domestic resources and of minimizing the environmental impact associated with mineral recovery operations. This report describes research in which unbeneficiated, dry, south-central Florida phosphate matrix was digested with sulfuric acid in a continuous-circuit, five-tank reactor to yield phosphoric acid and gypsum residue. Feed capacity of the reactor was 100 pounds (45 kg) of dry matrix per 24-hour day. When digestion was carried out at 185° F (85° C), acid filtration rates of up to 420 pounds of P20S per square foot per day were attained. Combined iron and aluminum impurities in the product filter acid were about 60 percent greater than values reported in commercially produced acid derived from concentrate. phosphate recovery was 87 to 90 percent of the phosphate contained in the as-mined matrix.

Jan 1, 1978

By R. K. Koch

In seeking substitutes for such critical metals as chromium, cobalt, and nickel, the Bureau of Mines investigated techniques for shape-casting titanium in rammed sand molds. Castings were made in olivine, garnet, chromite, and, for comparison, zircon. It was found that commercial-grade castings up to 31 lb (maximum capacity of furnace) could be made in zircon or olivine molds if a zirconia mold wash was used. Castings up to 4 lb could be made in chromite molds, but heavier castings suffered from some mold-metal reaction. Garnet molds were found to be unsatisfactory for castings of all sizes because of gas blows and rough surfaces. In other tests shell castings of acceptable quality were produced in water-glass-bonded zircon and olivine molds up to weights of 8 lb, but chromite molds were unsatisfactory because rough casting surfaces were caused by mold-metal reaction. Unlike the currently used commercial processes, neither the rammed-sand nor the shell-molding processes developed by the Bureau of Mines generate noxious fumes at any step.

Jan 1, 1980

By H. B. Cooke

In connection with its researches on the crude petroleums of the United States, the Bureau of Mines has made a particular study of apparatus for the distillation of hydrocarbon mixtures. While this study is still incomplete it has already resulted in the development of considerable laboratory and semi-plant equipment, motet of which has been described in various publications of the Bureau. The laboratory apparatus (Hempel distillation) and method gives satisfactory comparative results in the laboratory examination of crudes and have been found applicable to crudes of all types, but the agreement of laboratory and plant distillations is not as close as might be desired. This is due, in part, to limitations in size and construction of the laboratory apparatus. Some refiners claim that the Bureau of Mines' laboratory method (Hempel distillation3) for distilling crude petroleum, does not show the full gasoline content of the oil, while others have stated that it indicates more gasoline than can be obtained from the crude commercially. This difference of opinion among refiners results largely from the great variation in stills used and methods of operating them. The Bureau's experience has shown that crude oils from different fields vary widely in character; in fact, that it is not yet possible to classify crude's adequately on the basis of their Down chemical and physical characteristics. As a result of the differences that exist among crudes, and of the difficulty of designing refinery equipment, no standard practice has yet been adopted for the commercial distillation of petroleum, and ma" types of stills are used in the refineries of this country. Although many factors enter into the design of equipment and the development of commercial practice in refining of crude oil, there

Jan 1, 1924

By Spencer P. Hwell, Charles E. Munroe

"Among the surplus explosives left on band with the War Department was a quantity of that styled Trojan Grenade Powder, which was especially designed during the war for use as a bursting charge in grenades and for which naturally there would be very little military use in time of peace. With a view to its disposal through use in civil projects a quantity was sent to the Bureau of Minas explosives experiment station, where analysis showed that its characteristic explosive ingredient was nitrostarcn and that the powder bad the following composition:Trojan Grenade Powder appears as a dark gray granular substance, part of which is slightly pulverulent. The granules fairly hard. The explosive is not at all dusty, and has the consistency of granulated sugar.Nitrostarch is a substance produced by treating starch with nitric and sulphuric acids and in appearance it looks very little different from powdered starch. It resembles nitrocellulose and nitroglycerin in its constitution and explosive properties and has been longer known than either, it having been prepared by Braconnet in 1833. Nitrostarch explosives have in recent years been developed for industrial use in this country, they having been used to an extent in blasting in the Canal Zone, yet as this grenade powder was a special composition it seemed desirable that a complete series of tests should be run upon it. This was done, and the results are reported in the following table in comparison with those previously obtained in testing ammonia dynamite."

Jun 1, 1920

By E. D. Calvert

As part of its goal to minimize the requirements for critical and strategic minerals, the Bureau of Mines is conducting research to foster the use of domestically abundant materials such as molybdenum. This report describes the development of an investment shell molding technique that can be used to make castings of molybdenum and its alloys. The mold material is cubic Zr02 with a monoclinic Zr02 binder. The shell, formed by standard investment molding techniques described in the text, is prepared for molybdenum casting by firing for 6 hours at 1,550° C (2,822° F) or for 4 hours at 1,650° C (3,002° F). The resulting castings have predictable and reproducible dimensions with good detail. As-cast strength is poorer than the strength of wrought materials below 1,600° F. At and above this temperature, tensile strengths of cast and wrought materials are nearly equal. Aqueous corrosion of the castings in most media is insignificant.

Jan 1, 1982

By C. E. Jordan

Under its program of advancing minerals technology, the Federal Bureau of Mines has invented a laboratory apparatus for continuous separation of minerals based on differences in dielectric properties. The separator consists of a rotating drum electrode and a wire screen electrode positioned 3 mm apart. A high voltage applied across the electrodes that are immersed in a dielectric fluid produces a high-gradient electric field. The high-dielectric-constant (K) minerals are attracted to and conveyed through the separator by the rotating drum electrode, while the low K minerals settle through the screen electrode. Several design and operating parameters, such as electrode configurations, the dielectric liquid and its dielectric constant, electrical voltage and frequencies, feed rates, and particle sizes were studied. In addition, 28 different mineral mixtures were tested with the dielectric separator. In typical tests, a sample of rutile and quartz gangue containing 10-percent rutile was concentrated to 62-percent rutile with 94-percent rutile recovery. A second-stage dielectric separation of the rutile concentrate produced a 92-percent-rutile concentrate. The overall rutile recovery for the two-stage dielectric separation was 86 percent.

Jan 1, 1980

By Carla A. Kertis

Because coalbed discontinuities often pose serious economic and safety problems in underground coal mines, criteria were documented for the recognition and prediction of discontinuities in advance of mining. Pennsylvanian strata in Indiana and Armstrong Counties, PA, were deposited as part of fluvio-deltaic complexes with channel-phase sandstones as the predominant type of coalbed discontinuity. Coalbed isopach maps constructed for this study delineated numerous want areas (areas of no coal) with elongate to linear geometries. A comparison of coalbed isopach and corresponding sandstone isolith maps of the study area revealed many examples of a thick-sandstone, thin-subjacent-coalbed relationship. Nearly 60 pct of the want areas in the study area were found to lie subjacent to thick (> 20 ft [6 m]) sandstone accumulations. In addition to erosion of the coalbed, channels may contribute to coalbed splitting, coalbed thinning over paleotopographic highs, abnormal coalbed thick- nesses, and deterioration of coal quality. If these features are considered, then approximately 80 pct of all interruptions in the economic coalbeds in this area result from channel activity. By using the criteria developed in this study and described in this Bureau of Mines report, the occurrence of coalbed discontinuities may be predicted and anticipated in advance of mining.

Jan 1, 1985

Water pollution has been an integral part of most mining operations in the past. Most mine planners had designed their mining operations with little or no regard for prevention of water pollution. The main planning element was always the economics of mineral recovery. Quite often the cheapest means of mineral recovery resulted in the largest water pollution problems. Recent water pollution laws have introduced a new economic element - water pollution control costs - to be considered in mine planning. Water pollution control costs can be extremely high. Foresighted planning can minimize these costs and provide better water pollution control. Effective pollution control preplanning can eliminate pollution from active mines and minimize pollution that may occur after completion of mining. Presently available technology can practically eliminate water pollution by treatment of the mine water. Use of water treatment during mining has no effect on the levels of water pollution after treatment ceases and the mine is abandoned. Therefore, this section of the report deals with preplanning to reduce water pollution, both present and future, by using at-source control techniques. Proper planning of mining and pollution control techniques should follow the concept of a complete, comprehensive reclamation plan. This plan should have control measures designed for all phases of mining from initiation through completion. Preplanning involves acquiring complete information concerning the future mine site, defining the reasons why mining could cause pollution from the site, and determination of available techniques to prevent or minimize formation or transportation of pollutants. Location of haulage and access roads and other mine related facilities should be included in preplanning for water pollution control. Mine site planning is the primary step in establishing any new mining area and is the key to a successful, non-polluting and economical

Jan 1, 1973

By Peter F. Steidl

As part of the Bureau of Mines methane control program, the Upper Free- port coalbed was studied in Fayette County, Pa., where this coalbed lies about 650 feet below the Pittsburgh coalbed and contains the largest remaining reserves of any coalbed in the county. Coal and overburden isopachs, structure and joint pattern maps, and a fence diagram were prepared using data from gas and oil exploration logs and coal outcrops. These maps will aid in determining the need and/or feasibility of degasifying the Upper Freeport coalbed in the study area. Much of the coalbed in this area is under 600 to 1,400 feet of overburden. By correlation with data from the Pittsburgh coalbed, the gas content at depths of this order is estimated to be between 140 to 300 cf/ton of coal, for a total of 190 to 400 billion cubic feet of methane in this coalbed in Fayette County.

Jan 1, 1977

By J. E. Hamak

This publication contains analyses and related source data for 165 natural gas samples from 21 States and 1 foreign country. Of the total samples, 155 were collected during calendar year 1988. The remainder were collected earlier, but releases granting permission to publish were not received until 1988. All samples were obtained and analyzed as part of U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1989

By Edward J. Kansa

In a Bureau of Mines study, unsteady, spherically symmetric, one-dimensional, compressible-flow (finite sound speed) equations were solved numerically for a spherical deflagration propagating concentrically in a spherical vessel with Mach numbers ranging from 0.2 to 0.7; trajectory histories agree with the infinite-sound-speed theory developed by Perlee, Fuller, and Saul (PFS). A preliminary result of this study shows that flames propagating with speeds greater than 20 pct the speed of sound in the unburned gas mixture generate a complex history of aerodynamic waves distributed throughout the spherical vessel. Although the average pressure and flame radius agree with those predicted by the PFS models, the aerodynamic waves have a pronounced effect on the flame velocity, differing appreciably from that predicted by the PFS model.

Jan 1, 1976

By Arnulf P. Hagen

This project was designed to explore the suitability of using fluorinated inorganic materials as solvents for the in situ mining of thin seamed, heavily overburdened coal; to build a data base for the selection of an inorganic solvent for use for coal cleaning; to determine if fluorinated solvents will reduce the organic and inorganic sulfur contents of the coal, as well as to lower the ash content. The coal samples have been combined with pure solvent, as well as with aqueous solutions at atmospheric pressure and at increased pressure. The increased pressure experiments are important since they duplicate the conditions anticipated for an in situ cleaning and mining operation. Trifluoroacetic, difluorphosphoric (phosphorodifluoroidic), and trifluoromethanesulfonic acids have been found to be effective for the cleaning of high sulfur, high ash coal at 300°C and at atmospheric pressure. At pressures up to 20,000 psi the effectiveness of these reagents is not decreased.

Jan 1, 1983

By C. H. Herty

[Ferromanganese continues to be in indispensable requirement in steel manufacture. Approximately 470,000 tons of the 80 per cent ferro-alloy was consumed in 1929 and increasing amounts will be required annually by the steel industry unless some satisfactory substitute is found. An average of 14 pounds of metallic manganese is for each ton or steel produced, The principal use of manganese is for deoxidation of the metal in the steel refining processes, although a considerable amount r s also used for the production of special manganese steels. Unfortunately, domestic production of manganese ore is inadequate to meet normal peace-time requirements, not to mention increased abnormal war-time demands.]

Jan 1, 1930

By Eric E. Cather

In 1981 the U.S. Bureau of Mines and U.S. Geological Survey conducted a mineral survey of the 5,100 acre (2,065 ha) Rubicon RARE II area (No. 5026) in the El Dorado National Forest (fig. 1). Work by the Bureau of Mines indicates that potential for mineral resources in the area is low. Samples from small gravel deposits along the Rubicon River and from favorable structures in the area contained smart amounts of economic minerals. A Tertiary river channel near the north area boundary contains gold values as much as $137.60 per cu yd ($180 per cu m) [(gold at $400 per troy oz ($12.86 per g)]. The channel does not cross the study area. Energy resource potential, including oil, gas, or geothermal, does not exist in this geologic environment.

Jan 1, 1982

By Frank D. Lamb

Pyrophyllite, a hydrous aluminum silicate (Al2 Si4O10 (OH)2 ) has been mined in North Carolina and marketed without beneficiation for the past 100 years, but recent demands for higher-grade material indicate that an economical concentration method is needed for at least a part of the pyrophyllite production. Past production has depended upon selective mining and hand sorting, which is often unsatisfactory because of the finely disseminated character of the ores. The major impurity in North Carolina pyrophyllite ores is quartz, which accounts for the abrasiveness of the commercial product. Since pyrophyllite is only slightly heavier than quartz, those ores cannot be beneficiated by simple gravity-concentration methods. Some separation can be attained by differential grinding and air classification because of the difference in hardness of the two minerals) but the separation is not sharp. Froth flotation of pyrophyllite from Quartz has never been attempted commercially, but if the demand for high-grade material is sufficient, it would seem that this process offers the most premise of being economically feasible.

Jan 1, 1950

By Ray J. Holmquist

"INTRODUCTION The Copper King or Red River copper mine was examined on December 13, 1942, by the Bureau of Mines at the request of Richard Kelly of Santa Fe, N. Mex. The examination was made to determine whether the expenditure of funds for rehabilitation work necessary to make the workings accessible for examination would be warranted.As a favorable report was made, the workings of the Copper King mine were opened and sampled under the direction of the author. The portal of the Copper King adit was opened first. Considerable rehabilitation was necessary in the first 50 feet of the workings, but the remainder of the drifts and crosscuts were sufficiently open to permit surveying and sampling.An attempt was made to open the Waterbury atilt, which was reported to be about 30 feet east of the Copper King portal, and to crosscut the ore body nearly to its southern border. However, slide rock and mine dumps had completely obscured the portal of this adit, and no opening into it could be found or made.Work on the project was started on September 27 and vas completed on November 6, 1943."

Apr 1, 1947

By Robert S. Sanford

This paper deals with truck haulage methods and costs at one of the many open-cut mines that are replacing rail haulage with heavy-duty trucks. At this mine, ore is trucked to a crushing plant, centrally located within one of the open-cuts. The requirements for efficient low-cost truck haulage are: Good trucks designed for heavy loads, adequate truck maintenance, smooth roads, and well-trained truck drivers The weighted average cost of hauling a long ton of ore to the crusher and the waste to the dump was reduced from $0.1993 in 1948 to $0.1114 during the last half of 1949, his corresponds to a cost per ton mile of $0.0864.

Jan 1, 1952

By D. S. DeLong, A. Giza, D. G. Fraser, V. A. Robinson, T. B. Whitmoyer, J. E. Sneckenberger

"A cotton dust animal exposure system has been modified to incorporate a microcomputer feedback loop to monitor particle concentrations. The loop's major components are a minature real-time aerosol monitor (miniram) to estimate concentrations and a microcomputer to read the miniram's data and to control a stepper motor that adjusts the amount of dilutant air mixing with respirable cotton dust. Ninety minute trials of this system indicate that the standard deviation of particle concentrations is within 0.68 Mg/m3 of the average concentration, insuring a near constant concentration of respirable dust throughout the exposure.INTRODUCTION Previous workWeyel et al. (1984) have determined that respirable cotton dust can be shaken from bulk cotton samples using acoustical energy. The particle generator designed to utilize this fact operates like a commercially available sonic sifter, but on a much larger scale.While this generator successfully resuspended trapped respirable cotton dust, the generator output concentration decreased exponentially with time. This disadvantage was solved by Frazer et al. (1986) by operating the generator with a sinusoidal voltage near the minimum resonance frequency of the generator. This adjustment enabled the generator to produce respirable cotton dust for six hours or longer.Frazer et al. (1987) utilized the modified acoustical generator to produce a cotton dust animal exposure system. The cotton dust concentrations were estimated by a miniram, a light scattering aerosol Monitor. The system operator used the miniram values to adjust the system's parameters to maintain the desired concentration level.PurposeThe objective of this study was to introduce a computerized feedback loop to the operator controlled cotton dust animal exposure system. The miniram's estimates were analyzed by a microcomputer to determine what adjustments in the flow of dilutant air were necessary to maintain the desired cotton dust concentration. These modifications were intended to improve system performance and ease the system operator's work burden."

Jan 1, 1988

By Bertrand L. Johnson

Fertilizers are indispensable to national preparedness and defense. Production of adequate supplies of nourishing food for sustaining life in the United States is absolutely dependent in many parts of the country on the use of artificial fertilizers of various types. Only by using fertilizers can we maintain our present volume of production without great additional expense. Otherwise we would have to increase crop areas constantly to compensate for declining yields, we would have to lower the quality of food marketed, and standards of farm living and rural civilization would decline. About 60 million of the 360 million acres of crops grown annually in the United States Vow require fertilizing each year, and between 7 and 9 million tons of commercial fertilizers are consumed annually for this purpose.

Jan 1, 1941

By H. H. Fields, Joseph Cervik, G. N. Aul

Coal is a soft and brittle material. Drilling rates in the Pittsburgh coalbed using a drag bit exceed 3 ft/min at 2,500-pound thrust. However, maintaining the bit on a horizontal trajectory or parallel to bedding planes to attain lengths of 1,000 feet is difficult. This Bureau of Mines report presents a drill string configuration that can be guided through the coalbed. The angle of the borehole is measured periodically and by proper combinations of bit thrust and rotational speed (r/min), bit trajectory can be lifted or dropped to keep the bit in the coalbed. An example of a hole drilled to 2,126 feet is presented to show levels of thrust and rotational speed used to lift or drop the bit, the seemingly unexplainable events that occur, and the strategy used during drilling. Thrust levels during drilling range from 600 to 2,500 pounds. Hydraulic motors powered by a 30-hp, 440-volt motor provide ample power for drilling horizontal holes 2,000 feet long.

Jan 1, 1975