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Despite the research interest on non-cyanide gold lixiviants over the past three decades all the non-cyanide gold processes are still at the developmental stages with limited understanding on solution and pulp chemistry in some cases. This is partly associated with:the difficulties in measuring reliable equilibrium data for various gold(I/III) complexes with non-cyanide ligands; the lack of knowledge on mixed-ligand complexes; and different kinetic stabilities of gold(I) complexes with respect to disproportionation. This paper presents reliable equilibrium data for complex formation, dissolution, precipitation, hydrolysis and disproportionation reactions of gold(I/III) compounds with a range of non-cyanide ligands: S2-, HS-, S2O32-, SO32-, SCN-, SC(NH2)2, OH-, NH3, Cl-. Solubility of gold(III) compounds with non-cyanide ligands follows the order: Cl- > NH3 > OH-. In the case of gold metal the solubility order at a given temperature is MgS > Fe(III) or Cu(II) / Cl- > Cu(II)/NH3 > NaOH, but the solubility increases with increasing temperature. Rate of gold oxidation with different non-cyanide lixiviants depends on the oxidant, ligand and temperature and follows the general order of oxidants: Fe(III) or Cu(II) > X2 or OX- > O2 (X = halogen). In the case of metal ion oxidants oxygen is required to reoxidise Cu(I) or Fe(II). Some of the reported data on chloride and thiosulfate leaching of gold are presented to highlight the effect of additives and the copper, silver and sulfur contents of the starting material on the success of non-cyanide leaching processes.

Jan 1, 2004

In June 1992, the High Court of Australia recognised native title of the Meriam people over parts of the Mer Island in the Torres Strait as a form of common law. The Court also indicated that native title may have survived European settlement of the mainland Australia where it had not been extinguished by Governments and Aboriginal people have maintained their traditional connection with the land. The decision meant that two systems of land law were seen as existing side by side in Australia: ò one which derived from grants from the Crown under laws passed by Parliament; ò another which derived from the diverse laws and customs of the many Aboriginal groups in Australia.

Jan 1, 1996

By Blair J. R, Barrett J. R

In many underground mining applications where-dry fill is used, only a token acknowl- edgement of the fill properties is given. It is the aim of this paper to induce mining engineers to consider dry fill as an engineer- ing material rather than a mass to place in unwanted voids. Dry fill is generally cheap, inert and readily available, but it can still contribute to mining performance. In particular, the choice of the dry fill becomes more critical as stope sizes increase, controlled choked draws are used or pillar recovery introduced. Selection must be initiated from an evaluation of the role of the fill in the mining operation. In most cases the fill must be chosen before quarrying begins and an investigation must be made of available sources and appropriate quarrying methods. Some of the properties of fill are described together with evaluation techniques. A com- parison of placement conditions is limited by the complexities of material flow and degrada- tion: However, field and model tests can aid interpretation in these cases. Examples are given of aspects of dry fill selection and their incorporation in mining design.

Jan 1, 1973

By Johns A. L

The concept of the Melbourne Underground Rail Loop and the organ- isation to achieve its construction are covered in the companion papers (Reference 1, 2) and will not be repeated here. The Victorian Railways, as well as being the eventual operator of the Loop when it is completed by MURLA, have also been responsible as "Contractors" to MURLA for the construction of the "cut and cover" or "box" tunnels and related approach works located on existing Railway property. These tunnel connections link the existing suburban system to the new underground works. The following tabulation indicates the significant work volume involved in this cut and cover tunnelling exercise and which is covered in some detail by this paper.

Jan 1, 1981

By D Craw

Middle and Late Cenozoic fluvial conglomerates and gravel in northeastern Southland record the transport of alluvial gold from Central Otago into Southland, and subsequent reworking and concentration of this gold into economic placer deposits. A corridor of geochemically distinctive, Hg-free gold derived ultimately from veins in Torlesse Terrane schist in Otago extends through the Caples Terrane and into Southland. The initial repository in Southland was fluvial sediment of the East Southland Group, specifically weakly auriferous, quartzose delta plain strata of the Gore Lignite Measures (GLM), a downstream equivalent of Dunstan Formation in Central Otago. Miocene uplift along the northwest trending Old Man Range beheaded the parent river system, isolating GLM from its Central Otago source area and establishing the proto-Waikaia River system. Rising topography between Otago and Southland increased fluvial gradients, and initiated erosion of cover strata and a sequence of tectonically induced gold recycling events. Auriferous GLM were recycled from the hinterland into broad braided fluvial channel and floodplain deposits of the Waikaia Group (new), specifically the highly auriferous Waikaka Quartz Gravels and equivalent Waimumu Quartz Gravels downstream (WQG), superimposing more proximal depositional environments over parts of the former GLM delta plain. WQG were deformed, and locally cannibalised during the later stages of their deposition by reverse movement on north-northeast trending faults of the Dunsdale System (NW side up). Increased tempo of uplift in the hinterland (Old Man, Garvie, Umbrella, and Blue Mountain Ranges) in the Pliocene and early Quaternary resulted in further reworking of GLM and WkQG from the hinterland as well as basement erosion. Progressively more basement-rich detritus was deposited as a locally auriferous piedmont (Gore Piedmont Gravels - GPG) over earlier channel and delta plain (GLM, WQG) strata, extending from the Blue Mountains to Waikaia, and southward through the Gore Gap to beyond Mataura. Southward propagation of the north-northeast trending ranges, local warping, and uplift of the Murihiku Terrane in Pliocene and Quaternary progressively deflected GPG fluvial systems and ultimately constrained them to the present valleys. Pre-existing auriferous strata (GLM, WQG, GPG) were reworked and deposited with or without basement detritus as these fluvial systems migrated toward their present positions. Auriferous remnants of these transitional deposits are preserved in local structural depressions on the uplifted blocks that deflected the systems (eg King Solomon Mine), and on locally abandoned floodplain segments on the lowlands (Pebbly Hills-Gore Gap). The present drainage has continued to incise and cannibalise its own and earlier deposits during late Pleistocene-Recent uplift to form confined channel placers within the present valleys.

Jan 1, 2002

By Coppock BW

Sintering of lead and zinc concentrates is practised by Sulphide Corporation Pty. Limited to provide both desuiphurised lump sinter feed, for simultaneous reduction to zinc and lead in the Imperial Smelting Process blast furnace, and sulphur dioxide gas for sulphuric acid manufacture. From November, 1969 a 20 percent increase in production rate has been obtained through improvements in operating technique. A gradual increase in bed permeability was achieved by modifications to the feed mix conditioning equipment and by improving moisture control. However advantage could not be taken of the higher permeability to increase sulphur elimination because the hardness of the lump sinter decreased. Higher throughput, better quality sinter and more stable sintering conditions were however made possible by simultaneously: 1. reducing segregation and compaction in the sinter bed, by narrowing the discharge opening of the main layer feed hopper, 2. reducing the sizing of sinter returns to give a closer size spectrum of particles in the feed mix, and 3. increasing the sulphide sulphur content of the feed mix to give higher bed Temperatures.

Jan 1, 1972

By Propster M, Choudhry M

THIS note gives comments on the paper by Kitaev et al on p. 68 of this book and compares results with those obtained by ourselves. We wish to say that the authors are to be congratulated on their sophisticated approach to an important problem and that it complements our efforts on flow maldistribution.1-5 It is our view that Eqs. (1)-(5) on p. 69 are impressive, but unfortunately with present day computers and computational facilities, it would be quite impractical to contemplate the numerical solution of these. Eq. (8) in the authors' paper, on p. 70, does provide the logical starting point for tackling flow maldistribution problems and strictly speaking this equation is more accurate than Eq. (1) in our paper in this book. We note in passing that there is direct experimental evidence to support the contention that our Eq. (1) is at least a reasonable approximation and one may question in a practical sense whether the refinement afforded by Eq. (8) in the paper by Kitaev et a/ is justified. While one must readily accept the appropriateness of Eq. (8) of Kitaev et al as a starting point, the subsequent mathematical manipulation by the authors is open to serious criticism. In order to solve this complex, non-linear equation Kitaev et al postulated irrotational flow, which afforded considerable simplification. One can argue simply on physical grounds that the assumption of irrotational flow is inappropriate, a fact which should be readily apparent on inspection of the flow fields shown in Figs. 2 and 3 of Kitaev's paper. It follows that while the starting point through the use of Eq. (8) is correct the results derived from this starting point may be suspect because of the erroneous nature of the irrotational flow assumption.

Jan 1, 1975

Extensive reserves of kaolin of the type suitable for use as a high quality paper coating exist on the Weipa Peninsula. In 1986 a commercial processing plant was constructed to produce 100 000 tonnes per annum of coating quality kaolin targetted principally for export. A number of processing difficulties have limited the production capability of the plant. The prime area being the pressure filtration operation with achieved cycle times being around 50-60% of design. The rate determining steps being press filling, press unloading and filter cloth washing. This paper details and summarises testwork and results from our attempts at decreasing the filtration cycle time.

Jan 1, 1989

By Reichardt Y

Fine feed fractions in the size range from 1 to 40 ¦m of materials with different hardness as limestone and silicon carbide have been stressed in two different devices. A tungsten-carbide-blodc allows a single stressing with a pressure up to 2000 MPa and a 4-piston-block enables a multiple stressing procedure in which the material bed is stressed in alternating directions with a pressure up to 700 MPa. The experiments show energy absorption as the major factor for the interparticle breakage of hard material, like quartz, zircon silicate, silicon carbide and smelted oonindum, pressure, however, does not influence the results within the investigated range from 100 to 700 MPa and even up to 2000 MPa for corundum. But the breakage of the middle-hard limestone depends on the pressure so far as more fineness can be produced if the same energy is introduced at a lower pressure level. The creation of very fine and microfine fragments decreases strongly with increasing hardness of the feed materiaL The energy consumption for producing microfine material with a multiple stressing procedure on a particle bed is much lower than that one of a usual milling process. But this procedure needs a classification with a seperation cut at a couple of microns, which is not easy to accomplish.

Jan 1, 1993

Lightweight polymer grids have recently been introduced to the mining industry. They are currently being used for roof and rib control, longwall shield recovery, safety guarding or barricade, highwall screening, internal reinforcement of gunnite/shotcrete applications, sub-base reinforcement, construction of steepened slopes, retaining walls, mine reclamation (i.e. erosion control, turf reinforcement), and in numerous mining waste related projects. These polymer mining grids utilize a strong, lightweight polymer, usually special grades of polypropylene or polyethylene. High tensile strengths are achieved by molecular orientation of these polymers in the manufacturing process. The first step in the manufacturing process is to extrude the polymers into thick continuous sheets. These sheets are then punched, and drawn into open grid structures. Aperture size and configuration are controlled by the geometry of the punched hole and the degree to which the grids are stretched. The drawing process is the key to the molecular orientation required for the tensile strengths. These long chain polymer molecules in their natural state have a random orientation. When stretched, the molecules are pulled into a parallel alignment, thus creating a lightweight product with tensile strength comparable to Steel.

Jan 1, 1992

By Smith R. N

The Olympic Dam copper-uranium-gold-silver deposit is located approximately 520km north-northwest of Adelaide, South Australia. The deposit was discovered in 1975 by the Exploration Division of Western Mining Corporation (WMC). A joint venture, to facilitate development of the deposit was formed in mid 1979 between WMC (51%) and the British Petroleum Group (BP) (49%).

Jan 1, 1990

With increasing depth of mining, geotech nical factors assume increasing importance in the design and operation of open pit coal mines. Dragline strip mines are particularly sensitive to stability conditions since the draoline is a relatively inflexible machine, particularly in relation to its limited dump- ing radius for overburden disposal. Geotechnical factors relevant to strip mine design include: 1. spoil pile stability 2. wall stability 3. floor stability 4. excavation characteristics 5. groundwater conditions A basic geotechnical investigation pro- gram for new mine feasibility studies is described. This includes: 1. terrain evaluation 2. geotechnical drilling and logging 3. geophysical logging 4. materials testing 5. seismic refraction traversing 6. groundwater studies Such a program will give an overall geotech- nical assessment of the site and highlight any areas which may require further, more detailed Investigations

Jan 1, 1981

By A Black, J H. Youngson

At least 85 000 tonnes of mine tailings were discharged into Deepdell Creek, east Otago between 1890s and 1940s. The tailings contained about 1 wt % arsenic, so about 850 tonnes of arsenic in the form of arsenopyrite was discharged. Annual floods have removed nearly all tailings within c. 60 years. Small amounts of arsenic-bearing sediments (<250 ppm) remain in Deepdell Creek. About 7 kg/year dissolved arsenic was discharged in groundwater from mineralised Hyde-Macraes Shear Zone rocks in the vicinity of the historic mine sites. Adsorption of this arsenic on to iron oxyhydroxides in the stream sediments may have contributed to the elevated As content of those sediments. Even less arsenic remains in the main Shag valley below the Deepdell Creek confluence (15 - 25 ppm As). Rare relict arsenopyrite grains are trapped in bedrock crevices 25 km from source. No tailings deposition is detectable in theShag River estuary, and the tailings have presumably been discharged into the sea. Natural rehabilitation of the Shag catchment has been rapid and effective.

Jan 1, 2004

This paper concerns a pragmatic approach to a problem that is common to many operations in the mining industry: how, over the short-term, to grasp the extent and distribution of long-term financial risk from environmental causes and reduce these risks strategically, in order to maintain stability and flexibility in the operations. Surprisingly, many companies operate without an environmental master plan or tools that can help managers measure and reduce financial risks. Such companies may be subject to unknown unacceptable financial risks from environmental causes. While many companies have some kind of internal system of environmental standards, it is often the case that such systems have uneven or limited effect, and offer no opportunities for visualising, measuring or managing aggregate financial risks from environmental causes. `Aggregate risks' are defined here as the calculated total expected financial costs to a company, or a subdivision of a company, from environmental causes at nominated operations over a defined time period. Aggregate risks take into account the type and magnitude of an environmental problem set, the likelihood of occurrence, and the time frame during which the problems will develop or solutions are required. For the large corporation, the 'amount of' aggregate environmental risk is a statistic that can be managed, along with other financial parameters, at the corporate level to improve the stability and predictability of operations, and protect the interests of shareholders. This paper concerns development of a management framework and a tool for the large corporation that responds to the need for managing aggregate environmental financial risks. The logical framework proposed to overcome the need for strategic vision is the Environmental Master Plan, and this is described in the next section. The analytical tool proposed to measure aggregate risks and provide relevant data and insights to managers, is called an Environmental Risk Management Information System, and its mechanics are described in a subsequent section.

Jan 1, 1994

By DAVID C LAURENCE

The richer, shallower sapphire deposits of the New England region of New South Wales which have been traditionally mined by the small miner are almost worked out. Larger mining and exploration companies are replacing the small miner and exploring for the primary source of sapphire or lower grade alluvial deposits.Although in recent years considerable exploration effort has been directed at locating the primary source, commercial exploitation of sapphire is still restricted to the working of alluvial deposits.If the Australian industry is to compete against Asian and African producers it must use cost effective exploration, mining, processing and marketing methods.

Jan 1, 1990

By Greg Brown

The underwriting of professional negligence has proved to be an evolving science. As with most insurance products coverage offered in the past was very broad but as legal precedent demonstrated to Insurers areas of unforeseen exposure policy documents per se have become more restrictive until today the insurance market through attrition have produced a basic policy structure with various purchasable extensions which together provide insuring professionals with coverage that has proved to be adequate for their needs. The basic policy provides indemnity and protection for fortuitous negligence. In a practical sense, however, professional indemnity policies are really a defence document in so far as policy holders are relying upon the expertise of Insurers to protect them in the event that a claim is made upon them. Whether damages are awarded is in many respects a secondary consideration, the most important factor is to ensure that policy holders are protected in terms of the legal defence mechanism. By way of illustration we are currently in the process of defending a large professional firm which purchased from us a policy with a limit of indemnity of $10M. The case has been running in a Supreme Court now for 14 months and the defence costs which we have incurred on their behalf are rising close to $8M as I put pen to paper. Defence costs of that magnitude would in effect terminally cripple all but the very largest professional operations in Australia. In more recent times coverage has been provided in Australia for breaches of the Trade Practices Act and similar legislation enacted in various States. No-one really appreciated the comprehensive impact which the Trade Practices Act would have on commerce in Australia. Most professionals thought that indeed they would be exempt from prosecution under this Act. The passage of time has clearly indicated that this is not the case and we have found that it is much more difficult to defend a claim involving breaches of the Trade Practices Act than it would be to defend a claim for breach of tortuous liability.

Jan 1, 1995

By Gole MJ

The Goodyear nickel prospect is located 45 km southeast of Kalgoorlie (31.04¦S, 121.80¦E) near the eastern boundary of Hampton Area - East Location 45 (Figure 1). Nickel mineralisation was discovered on the Goodyear prospect in March 1996 when a reverse circulation drillhole (GYC5), initially drilled in December 1995, was deepened to meet a minimum footwall penetration requirement of 20 in that had been set for the drill program. Approximately 3 in of sulphides averaging 4.9 per cent nickel was intersected from 296 metres down-hole, this being within 2 in of the first end-of-hole. Hole GYC5 was part of an eight hole drilling program undertaken by Titan Resources in late-1995. This program was designed to test whether nickel mineralisation in the Dunlop prospect, discovered by the Western Mining Corporation - BHP Camylia Joint Venture immediately east of the East Location 45 boundary, continued across the tenement boundary. The area targeted by the initial drill program had been explored by Western Mining Corporation in the mid-1980s using extensive surface sampling and a drilling program that included 17 RAB and percussion drillholes. None of these holes intersected nickel Mineralisation.\

Jan 1, 1996

By Woodcock J. T, Millett R. N

It was shown that manganese dioxide could be used as an oxidant in acid thiourea leaching of a gold ore. Manganese dioxide could generate high redox potentials and was as effective as hydrogen peroxide in the leaching process. Results obtained under closely controlled leaching conditions confirmed that high redox potentials enabled faster dissolution of gold to be obtained but led to extremely high reagent consumptions (thiourea, acid, and manganese dioxide). Additions of sodium sulphite solution in an attempt to lower thiourea consumption by reducing formamidine disulphide back to thiourea were only marginally successful. Although thio- urea consumption was slightly decreased, the consumption of acid and manganese dioxide was substantially increased and there was no net benefit in using sulphite. Tests in which a single addition of mangan- ese dioxide was made before addition of thiourea minimized overall reagent consumption and gave only a slightly lower dissolution rate of gold. This is a promising technique for further Investigation.

Jan 1, 1987

By Stewart A. M, Price D

This paper presents recent findings concerning longwall caving mechanisms relating to Australian mining conditions and their effect upon longwall support requirements and behaviour. The findings are based on a program of intensive hydraulic support monitoring in a variety of Australian mining conditions coupled with geotechnical observations.

Jan 1, 1992

Computers and other microprocessor technology lead the world of technological change. Nevertheless, the real advances in the world at large are not necessarily in the computer industry, but in the industries whose economics benefit most by the advances that this computer revolution makes possible. The minerals industry has always been in the forefront of this advance. Technological change in the era preceding the industrial revolution, and the mining industry's part in it, provides an instructive lesson for what is happening today. Strong parallels can be drawn for predicting future advances. With each technological advance allowing more efficient production comes a re-alignment of economics - absolute and relative changes to prices, to quantities demanded, and to other market characteristics. This re-alignment applies not only to the mineral industry, but also to the world at large. Adaptability, rather than technical advancement per se is the key to survival and growth in a changing world. 'Adaptability' as a concept is easy to support. As an operational philosophy it is not so easy to implement. As a goal for planning, it is much harder to quantify. A fixed scenario of a future world may provide helpful guidelines, but a scenario that demands adaptability to an uncertain future world is much less definite. Of course, everyone else in the world is also uncertain about the future, and they are making their plans using different assumptions. This virtually guarantees that our future will turn out different to our expectations. This is in part what Hayek (1945) calls the 'knowledge' problem. Until now, most of the planning and technical research undertaken in the world has ignored this problem. This ignorance is a luxury that we can no longer afford. The paper looks at the history of technological change and highlights the characteristics of successful technological revolutions. 'Adaptability' to unforeseen circumstances is the key to success in this environment. The paper examines the knowledge problem from the perspective of the mineral industry, and suggests a number of directions for maximising the returns from application of computer technology in this important area.

Jan 1, 1995