Search Documents

By Jae-Chun Lee, Sadia Ilyas

We investigate the technical feasibility of bioleaching of metals from low grade sulphidic ore. Experiments were conducted with an adapted consortium of Sulfobacillus thermosulfidooxidans and Thermoplasm acidophilum in batch bioreactors (1.5 L), small columns (10 kg ore load, 8 % S0 sludge) and large columns (80 kg ore load, 12 % S0 sludge). Approximately 83 % Ni, 85 % Cu, 55 % Fe and 81 % Zn was leached out in batch mode while 93 % Ni, 89 % Zn, 81 % Cu and 65 % Fe was leached out in column reactors. Bioleaching potential improved by acid pre-leaching, adaptation of microbial consortium and periodic bleeding of effluents.

Jan 1, 2014

By J. C. Li, Y. Zou, L. He

"The effect of rock joints is significant in characterizing dynamic behaviors of discontinuous rock masses. To reveal the relation between the transmission coefficient and the contact situation of the joint surface, an experimental study on stress wave propagation across an artificial rock joint was carried out using a modified Split Hopkinson Pressure Bar (SHPB) apparatus. All the bars and specimens were norite cored from the same site, and one surface of the specimen which contacted to the transmitted bar was sawn with a number of notches to simulate the artificial rough joint. According to a wave separation method, two strain gauges were mounted on each pressure bar at a specific spacing, then the incident, reflected and transmitted waves across the joints were obtained from the test data. It was found that the contact situation of the rock joint surface makes a different on the wave propagation. Finally comparisons of the transmission coefficients with different contact area ratios and different joint thicknesses were made respectively. The results show the effects of contact area ratio and thickness of joints on wave transmission.INTRODUCTIONJoints affect the dynamic mechanical behaviors of the rock masses significantly. When propagates across the rock masses, wave usually attenuates in amplitude and frequency due to the presence of the joint as a discontinuous interface in the rock masses. Rock joints are the main factor that affects the behaviors and properties of rock masses. Many researchers have focused on the mechanical properties of rock joints under quasi-static conditions. Nowadays, the effect of joint dynamic properties on wave propagation across rock masses is gradually taken into account in theoretical and numerical studies.The effective contact area, joint roughness, and properties of the asperities and filling materials have been found to influence the normal stiffness of joints (Bandis et al. 1983). As suggested by the International Society for Rock Mechanics (ISRM), the roughness of the discontinuities can be generally characterized by large-scale “waviness” and small-scale “unevenness” (Brown 1981). Many researchers focused on the roughness of rock joints that affects the mechanical properties of rock masses and wave propagation. For example, Brown and Scholz (1985, 1986) presented theoretically and verified experimentally a closure model of contact between two random nominally flat elastic surfaces, which showed that the joint closure property depended both on the surface topography and material properties. Pyrak-Nolte et al. (1997) presented the quantitative aperture data for three-dimensional interconnected fracture networks, which were imbedded in intact opaque rock samples several centimeters in length, using x-ray computerized tomographic (CT) imaging. Fardin et al. (2001) systematically investigated the effect of scale on the surface roughness of rock joints and concluded that samples should be equal to or larger than the stationary limit for surface roughness to be accurately characterized on a laboratory scale or in the field. Zhao et al. (2006) conducted excellent ultrasonic tests across intact cement mortar specimens, singlefracture specimens, and two-fracture specimens."

Jan 1, 2015

By D. Bouchard, J. Langlais, A. Lemieux, N. Andrade

A concerted effort between Akan International Limited and the National Research Council of Canada (NRC) has been initiated to develop a liquid-based slurrymaking process, dubbed SEED (Swirled Enthalpy Equilibration Device) for semi-solid forming. The technology is presently entering the industrial and commercial stages, and will be used by the first customers at the end of 2006. Semi-solid processing of aluminium alloys offers many advantages in fabricating economically near-net-shape parts of superior quality. The SEED process helps to overcome problems experienced with thixocasting and especially the high cost of feedstock. The SEED process involves two main steps: 1) heat extraction to achieve a desired liquid/solid mixture, and 2) drainage of an excess liquid to produce a self-supporting semi-solid slug that is formed under pressure. The heat transfer plays an important role (enthalpy equilibrium) during the manufacture of the semi-solid slurry and its analysis is briefly described. The semisolid material is obtained using different processing times and initial conditions. The impact on the solid fraction distribution and the morphological evolution of the microstructure is presented. The influence of the SEED processing parameters (slurry preparation) and the resulting mechanical properties for the alloy A356 are also reported.

Jan 1, 2006

By L. Yuan, J. H. Rowland, R. A. Thomas, D. Bahrami, G. P. Cole

"The past several decades have seen a steady increase in the use of atmospheric monitoring systems (AMS) in underground mines as sensor technology has advanced and costs for this technology have decreased. The AMS is a reliable tool for early mine fire warning by detecting gaseous products of combustion in underground mines. During a mine fire emergency, mine decision makers rely heavily on the prompt and accurate knowledge of the ventilation and fire situation in the mine, such as fire location, fire size, and the spread of smoke to make effective and efficient decisions on firefighting strategies and miner evacuation. Meanwhile, a prediction of the potential for fire development at a later time, such as whether the currently designated mine escapeways will be contaminated by smoke and toxic gases with the progress of the fire, is critical for effective decision-making to save lives that are in danger. The AMS monitoring data, including carbon monoxide (CO) concentration, airflow rate, smoke, etc., can provide information as to whether the smoke has reached the locations where AMS sensors are installed and if a mine-wide smoke spread has occurred. The National Institute for Occupational Safety and Health (NIOSH) has undertaken a task to integrate real-time AMS monitoring data with the mine fire simulation program, MFIRE, to simulate and predict the spread of smoke and toxic gas in a ventilation network based on the real-time AMS data. This paper reports the developed real-time method for characterizing the size and location of an underground mine fire and for predicting the spread of contaminants throughout the mine ventilation network using sensor data from the AMS.INTRODUCTIONNIOSH conducts research to develop workplace solutions to improve detection of and reduce the risk of hazardous conditions in underground mines. The advancement of senor technology and the increasing demand for real-time mine parameters monitoring have led to extended applications of atmospheric monitoring systems (AMS) in underground mines worldwide. In the United States, AMS is primarily used for early mine fire warning by detecting carbon monoxide (CO) in fire hazard areas, such as belt entries. Mine fires can grow rapidly, and time is the critical element. Prompt detection, timely and accurate warnings to those miners potentially affected, and a proficient response by underground miners can have a tremendous impact on the social and economic consequence of a small underground mine fire (Conti et al., 2005). The early detection of a mine fire could gain time for the first responders to put out the fire before it develops into a disaster. An AMS system with CO sensors has especially played an important role in the early detection of mine fires. The continuous monitoring of an underground mine atmosphere with an AMS could generate a large amount of data in a mine fire event. However, the current application of AMS is mainly limited to sending out an alarm when monitored CO concentration exceeds a certain level. An opportunity arises as to whether these data can be further used in fire emergency response. In order to make effective decisions on firefighting strategies, mine workers’ seeking refuges, evacuation and escape, and the timing on when to send rescuers, decision makers need accurate and timely knowledge of the ventilation and fire situation in the mine. Information about the fire intensity, where in the mine the smoke and toxic gases have spread, and whether designated mine escapeways have been compromised by smoke and toxic gases from the fire would greatly increase the effectiveness of these decisions. However, the monitored AMS data only provides atmospheric conditions in the vicinity of sensor locations. What is concluded from the monitored AMS data highly depends on the decision makers’ capability and experience. Predictive insight into fire growth and smoke transport would greatly help decision makers during a fire emergency."

Jan 1, 2019

By L. I. Kiss, S. Perron, D. Toulouse, S. Poncsák, A. Perron

Bubbles play an important role in many industrial processes. In a Hall-Heroult cell, used for aluminum production, bubbles contribute to induce flow in the cell. The induced flow is important for the thermal balance of the cell as well as for the distribution and dissolution of the alumina. The existence of the bubble layer does not have advantages only. It increases the voltage of the cell and causes deformation along the cryolite-molten aluminum interface. The role of the anode inclination in the behaviour of the bubble layer as well as in the hydrodynamics of the bath is not clearly understood. In this work, the effect of the anode inclination angle on the bubble driven flow is studied in an industrial scale air-water model. The inclination angle is varied up to 5° from the horizontal. The instantaneous flow field is captured by Particle Image Velocimetry (PIV) system. The mean velocity fields were calculated by ensembleaveraging the instantaneous velocity fields measured at different time. The existence of the counter-flow in the interpolar space and the vortex in the side channel has been confirmed. Furthermore it has been observed that the effect of anode slope on the velocity field is weak.

Jan 1, 2006

By N. Hwang

There has been increasing interest in the use of robotic machines, and several prototype robotic machines have been developed to automate the grit-blasting process for the purpose of steel bridge maintenance. To utilize such a robotic grit-blast machine effectively, the first consideration is automating the determination of the rust surface area to blast, on the basis of standards of practice, in a rapid manner. This study aims to propose a method to rapidly and accurately determine the rust surface area on steel bridges to blast, with consideration for the standards of practice, from images acquired via a blasting machine. The first step is to perform a color space conversion to transform the input image from a red/green/blue (RGB) color space to a hue/saturation/intensity (HSI) color space. The next step is to detect the presence of rust, using pixel-level classification via the C4.5 decision tree algorithm. Then it is necessary to confirm the blasting area by verifying whether the rust detection result satisfies the specified criteria on the basis of standards of practice. The proposed method was validated on 39 test images with various characteristics with respect to the degree of rusting and rust distribution type. The experimental results showed that the average accuracy rate of rust area classification was about 97.63%, and the success rate of the final decision of blasting area determination was 100.00% for 39 test examples. The whole processing time took an average of only 0.86 seconds per image. The preliminary results demonstrated that the proposed method not only determined whether rust was present in an image and the amount of rust but also indicated whether blasting was necessary, and, if necessary, it rapidly specified the rust surface area that should be blasted on the basis of standards of practice. The proposed method could be successfully incorporated into a robotic grit-blast machine.

Aug 1, 2013

By E. F. Evoy

"The Gunnar uranium deposit was within metasedimentary rocks of the late Archaen Tazin Group. These rocks were intensely altered by albitization so that the immediate host to the ore consisted dominantly of albite, and by the subsequent introduction of calcite. The ore consisted of disseminated pitchblende and uranophane in a pipe-shaped breccia zone. Oxidation of the ore was more intense near surface than at depth, but there was no near-surface enrichment.IntroductionThe Gunnar Mine site is on the tip of Crackingstone Peninsula, on the north shore of Lake Athabasca, Province of Saskatchewan, Canada. The peninsula forms the southern part of the Beaverlodge mining area. The ore consisted of disseminated pitchblende and uranophane in brecciated metasedimentary rocks of the Tazin Group, and the deposit was characterized by extreme albitization and subsequent carbonatization of the host environment.Production from the mine began in 1954 and the ore was depleted by 1963. In that interval the deposit yielded about 5 million tonnes of ore containing about I. 75 kg/tonne U3O8. It was mined initially from an open-pit and subsequently from underground; the open-pit contributed about 55% of total tonnage. Uranium was recovered by atmospheric leaching in sulphuric acid, ion exchange concentration, and precipitation with magnesia.This paper is based on studies made during the productive life of the mine and is concerned primarily with pre-ore alteration of the rocks containing the deposit, and with the ore mineralogy."

Jan 1, 1986

By D. L. Cramp

The Direct-Connected Electric Hoist In the latter part of 1931 a new electric hoist was installed at the Lake Shore mine. A number of interesting features were incorporated in this machine, which is the first direct-connected, direct-current-operated hoist to be placed in service in the Kirkland Lake district. Many factors requiring care and study enter into the selection of hoisting-engine drive. In this instance, conditions warranted the selection of the generator voltage control system (Ward-Leonard), utilizing a direct-current driving motor and a separate motor generator unit. It was further deter-mined that additional economies could be secured by the selection of a motor generator unit with a flywheel, and consequently the Ilgner-Ward Leonard flywheel set was adopted. Some of the advantages of this system are: 1) Greater accuracy of control, resulting in increased flexibility in hand-ling with increased precision and safety; especially desirable in large, important installations where the rope-speed is high or where frequent shifting is necessary. (2) Reduced energy consumption. (3) Feasibility of load equalization, without which, in some cases, the power system would be unable to carry the fluctuating load imposed on it by the operation of the hoist. ( 4) Elimination of reduction gearing in the construction of the hoist. The hoist is located on the surface and is used for skip operation at the main shaft, hoisting ore from a present maximum depth of 4,200 feet.

Jan 1, 1933

By E. Larsen

Marine tailings disposal may in some cases be the best solution to one of mining’s major environmental problems. The public standing of this solution is poor, partly because of past bad practices. Among the tailings problems spreading of super-fines and toxic substances stand out. The two are often interrelated as heavy metals, insoluble to sea water, tend to adsorb on fines and spread piggyback on them. Only one paper seen, has addressed the mineralogy of fine particles in suspension. The topic was a secondary tailings deposit. Studies on the sedimentation of fines in large river estuaries show that different minerals sediment sequentially as the salinity of the river increase. Mineralogy in the particle size range where particle separation takes place, has so far, naturally been in focus for the mineral processors. Next to nothing is known about the fines which may cause environmental problems. Tailings disposal has, due to its complexity, to a large extent been taken over by specialists in other fields, biologists, engineering geologists, chemists. The basics of the subject ought also to be given more input by the mineral processing community. A drawn out battle about tailings discharge into some fjords has taken place in Norway. The detractors focus at fine particles (could be dangerous nanoparticles) spreading and emphasize the effects. Calculation is simple: 5 million tonnes tailings annually discharged, containing 1 wt. % < 1µm determined by laser diffraction, results in 50 000 tonnes of nanoparticles let loose in the environment. The industry`s difficulty to answer, is lack of basic research on this topic. Test work to develop a methodology to address the problem is described. One thing the mineral processors know is that final tailings may be comprised of tailings from separate separation processes, with different properties, some of which may require special treatment. One tailings stream from a Norwegian mine is investigated in such a context.

Jan 1, 2016

By T. G. Sitharam, Resmi Sebastian

"Wave propagation studies across jointed rocks have significance in the fields of rock mechanics and geophysics. The passage of a seismic wave induces strains in rocks and often, these strains are of low magnitudes except at the vicinity of source. These low magnitude strains are generally in the elastic range and hence elastic constants necessary for the design and analysis of strength of rock mass, can be derived from wave velocities. Measurement of travel time velocities and measurement of resonance frequencies are the two methods usually adopted for obtaining wave propagation velocities.Resonant column apparatus measures wave velocities from the resonant frequencies obtained during testing. Depending on the type vibration applied, torsional or flexural, shear and compression wave velocities are secured. By varying the amplitude of vibrations applied, various strain levels can be introduced and corresponding resonant frequencies and wave velocities can be calculated. The resonant column experiments were performed on a model material, hardened Plaster of Paris (POP) samples, in laboratory. The paper explains the preparation of samples and the working mechanism of resonant column apparatus along with the estimation of wave velocity from resonant frequency. The numerical simulation of resonant column apparatus using distinct element method and its validation with the experimental results are presented in the paper.A distinct element code is usually used to simulate the movement of materials with intersecting discontinuities. Finite rotations and displacements of individual blocks representing the material are permitted and new contacts between the blocks are identified as the calculation progresses. Three dimensional Distinct Element Code (3DEC), the software intended for the numerical simulation of rock engineering projects, can well simulate the behavior of jointed rocks under static and dynamic loading conditions. The numerical simulation of resonant column apparatus has been performed with 3DEC considering its efficiency in modeling jointed rocks.The numerical modeling of the resonant column apparatus with application of torsional and flexural vibrations to the sample is elaborated in the paper. The response of samples to a range of frequencies is obtained and the frequency that induces maximum displacement in the sample is measured as the resonant frequency, for any particular strain level. The displacements measured at various points of the sample during application of vibrations are compared and presented. The numerical modeling of resonant column apparatus with an intact sample (without joint) and a sample with a joint incorporated are explained at a particular strain level. The resonant frequencies obtained from laboratory experiments and numerical simulations are compared and illustrated. It has been found that resonant frequencies obtained using numerical and laboratory experiments are in good comparison and can be extended for various strain levels and sample conditions."

Jan 1, 2015

By K. Thuro, H. Käsling, C. Wieser, G. Nuijten

"The time-dependent behavior of brittle rocks during stress relaxation is of great interest for mining industry, nuclear waste disposal as well as tunneling and underground construction. Several studies have shown that both elastic as well as inelastic deformation occur during stress relaxation (Emery, 1964; Zang & Berckhemer, 1989). While elastic strain occurs already during the drilling process, inelastic deformation is time-dependent and can endure for hours, days or weeks. To investigate the evolution of microcracks during core relaxation, two crystalline core samples were recovered from high in situ stress conditions in Europe’s deepest mine in Pyhäsalmi (Finland). Samples were prepared for testing within one hour after coring such that a large portion of the time-dependent component of relaxation could be recorded over several days using ultrasonic velocity as well as acoustic emission (AE) measurements.Results from AE analysis show an exponential decrease in the number of events over a period of several hours. Repeated sudden increases of acoustic events can be related to the propagation or the interaction of cracks. In the first hours of recording also the signal energies reached the highest values and the increases in signal energy correlate well with increased event rates. On additional drill cores, P-wave velocities were measured parallel and in 45° distances perpendicular to the core axis. After core recovery, stress-induced microcracking caused an exponential decrease in wave velocities similar to AE rates. Lowest compressional wave velocities were measured parallel to the core axis and thus normal to the foliation and in the direction of the maximum in situ stress component. The highest measured velocities occurred parallel to the foliation plane. Within the samples, the anisotropy ratios were up to 1.37 at the beginning of the measurements and increased to values of up to 1.8 after 45 days. The wave velocity anisotropy is in agreement with the in situ stress orientations."

Jan 1, 2015

By D. K. Sarkar, Jiawei Xiong

"Self-assembled monolayers (SAM) on the aluminum substrates are used as the adhesion promoter between two aluminum substrates when bonded with the adhesive in adhesive bonding technology. Traditional surface analysis tools are not capable of identifying the presence of SAM on a surface; therefore, EIS has been used to determine their presence on the aluminum substrates. In this study SAMs have been deposited on aluminum using the monomer of (3-Glycidyloxypropyl)trimethoxysilane (GPTS) organosilane. AA6061 aluminum alloys substrates were chemically cleaned with NaOH and HNO3 to remove the native oxides, followed by immersion in silane solutions. In a second method, SAMs were prepared by applying a spin coating of silane solution to the samples. The prepared SAM coated aluminum samples were analysed by EIS in the three electrode corrosion cell using a diluted alkaline solution. The impedance of the SAM coated aluminum is found be higher than the as-received aluminum. It has been also observed that the open circuit potential (OCP) of the SAM coated aluminum is higher than the as-received aluminum. Both elevated values of the impedance and OCP confirm the presence of SAM on aluminum.INTRODUCTIONSelf-assembly (Schreiber, 2000) is defined as the spontaneous formation of complex hierarchical structures from pre-designed building blocks, typically involving multiple energy scales and multiple degrees of freedom. Generally speaking, SAMs are created by the chemisorption of ""head groups"" onto a substrate from either the vapor or liquid phase followed by a slow organization of ""tail groups"" of a molecule. Typically, head groups are connected to a molecular chain in which the terminal end can be functionalized with groups such as –OH, –NH2, –COOH, or –SH to vary the wetting and interfacial properties (Chauhan et al., 2007; Ulman, 1996; Vashist, Lam, Hrapovic, Male, & Luong, 2014). Though there exist several methods to prepare SAM (Chauhan et al., 2007; Chen, Yang, & Zhang, 2014; Cho, Park, Jon, & Choi, 2007; Igor Luzinov, 2000; Reis, de Melo, & Costa, 2006; Song, Zhai, Wang, & Jiang, 2006; Sugimura, Hozumi, Kameyama, & Takai, 2002; Vashist et al., 2014), the two methods vapor phase (Song et al., 2006; Sugimura et al., 2002) and solution(Chen et al., 2014; Igor Luzinov, 2000) are commonly used. Recently, many articles have been published on the fabrication of superhydrophobic surfaces with SAM technology (Cho et al., 2007; Pan, Shen, Shang, & Xing, 2012; Siddaramanna, Saleema, & Sarkar, 2014; Song et al., 2006). Brassard, Sarkar, and Perron (2011) successfully obtained a superhydrophobic film by applying fluoroalkylsilane via self-assembly on monodispersive silica. SAMs are also reported as good candidates for anti-corrosion and adhesion promotion (Chen et al., 2014; Saleema, Sarkar, Paynter, Gallant, & Eskandarian, 2012). However, papers on the characterization of SAM properties are rarely seen. The most commonly used substrate for SAM is silicon and the method implemented is scanning probe microscopy (SPM) such as atomic force microscope (AFM) (Igor Luzinov, 2000; Moores, 2011; Zhang, 2003, 2005). Igor Luzinov (2000) analyzed the epoxysilane SAMs’ surface morphology and microstructure properties using scanning probe microscopy (SPM) and ellipsometry on single-crystal silicon wafers. SAMs have been used to improve the adhesion bonding of aluminum or plastics but no characteristic data have been presented yet (Saleema et al., 2012; Telegdi, 2007; Wang, Xu, Luo, Wang, & Wang, 2009). Recently, Reis et al.(Reis et al., 2006) have studied SAM of alkane diphosphonate (Gardobond X4661) on Al 5052 alloy samples by EIS in a naturally aerated sodium sulfate solution."

Jan 1, 2016

By J. P. Norrie

The presence of copper-bearing rocks in the Coppermine River area of Arctic Canada has long been known. Word of this was probably circulated along the Arctic and Hudson Bay coasts by the Eskimo, who no doubt traded articles made from native copper among themselves. It is not known whether any of these ever reached the southern shores of Hudson bay. The Indians, also, knew of the occurrence of copper here, as they served as guides to Hearne when he made a successful trip over land from Hudson bay to the Coppermine river. The possible commercial importance of these copper deposits was early appreciated by the Hudson&apos;s Bay Company, who on December 7th, 1770, despatched Samuel Hearne from Fort Prince of Wales, now Fort Churchill, to investigate them. He reached the then unnamed river at a point forty miles from its mouth on July 14th, 1771, and after surveying the river to its mouth and naming it the Coppermine, he retraced his steps to Fort Churchill by an overland route. Hearne&apos;s expedition was probably the most remarkable and arduous ever attempted in Arctic exploration, but the actual value derived from the trip was entirely out of proportion with the hardships he must have suffered. He verified the occurrence of native copper, but his astronomical and other observations were of little value. Until 1912 no concerted effort was made to obtain any definite information as to the geology and economic value of the Copper-mine deposits.

Jan 1, 1931

By Q. B. Li, B. Gonçalves da Silva, J. T. Germaine, H. H. Einstein, Z. Moradian

"Shale gas and oil production has grown rapidly in recent years, and consequently there are increasing demands to understand the mechanical and microseismic properties of shale. Acoustic emission (AE) monitoring provides useful information on the fracture mechanisms of shale rocks, and provides a basis for interpreting field seismic observations. While there have been attempts for microseismic monitoring of conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted to understand the characteristics of the AE waveforms propagated through Opalinus shale rock in the time and frequency domains. Frequency range, arrival time, first arrival amplitude and other parameters such as counts, duration and energy of the waves generated from artificial and natural sources in the shale specimens were detected and compared with AE characteristics of granite, a brittle rock that has been extensively investigated. The experimental tests showed that there are some important factors that influence the analyses and interpretations of seismic surveys and microseismic monitoring of shale compared to granite. One of these factors is the anisotropic behavior of shale that causes the wave to propagate with different velocities in different directions. Also bedding planes and micro-discontinuities in the shale cause attenuation of the waves. Thus the AE waveforms that arrive at the sensor are a distorted and attenuated versions of the source waveform.INTRODUCTIONMonitoring microseismic activity from hydraulic fracturing of shale provides vital information for mapping injection paths and fluid migration in order to check the effectiveness of the hydraulic fracture stimulation. Analysis of microseismic source locations can be used to identify fracture networks induced or mobilized during the hydraulic fracturing operation (Rotherd and Shapiro, 2003). On the other hand, by monitoring and assessing detected signals from hydraulic fracturing one can evaluate the induced seismic impact of the stimulation operation.While there have been attempts to monitor microseismic events in conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted on Opalinus shale to understand its acoustic emission (AE) characteristics in the time and frequency domains."

Jan 1, 2015

By M. Aljarrah

The phase equilibria in the Mg-Al-Ca system was investigated experimentally by differential scanning calorimetry (DSC) and X-ray diffraction (XRD) techniques similarly the Mg-Al-Sr system has been studied using DSC and XRD as well as scanning electron microscopy/energy dispersive spectrometer (SEM/EDS) and quantitative electron probe micro-analysis (EPMA). A new ternary solid solution MgxAl4,xSr was confirmed in Mg-Al-Sr system, which is a substitutional solid solution of Mg atoms in Al4Sr. Maximum solubilities of 21.3 at.% Al in Mg17Sr2 and 11.4 at.% Al in Mg were observed. It was also noticed that Mg38Sr9 dissolved 12.5 at.% Al. In the Mg-Al-Ca ternary system, one of the invariant transformations predicted by thermodynamic modeling was verified experimentally and found to occur at 512°C with composition close to 10.8 at.% Ca, 79.5 at.% Mg and 9.7 at.% Al. A ternary solid solution (Mg,Al)2Ca was confirmed where large solid solubility of Al in Mg2Ca was observed.

Jan 1, 2006

By C. Caballero, A. Warczok, K. Itagaki, A. Moyano, J. Font

The Codelco Norte Smelter process 2,500 tpd of arsenic-bearing concentrates with an arsenic content of up to 1.5% in one of its two main smelting units, the Teniente Converter. The product, 1,100 tpd high-grade matte or white metal, is traditionally fed to the PS converters, while the 1,700 tpd of slag is fed to the slag cleaning electric furnace for copper recovery. This is achieved in a very reductive environment which reduces the viscosity of the slag and enhances the sedimentation of the high-grade matte droplets. The behavior of arsenic in this non-oxidative environment was studied at lab-scale and fundamental thermodynamic data were obtained. Based on these data a thermodynamicbase model to assess the arsenic behavior in reductive environment was developed. It is based on a mass balance for the reduction and sedimentation stages performed in an electric furnace which allows the recovery of high-grade matte droplets after decreasing the viscosity of the slag. This model can be a very suitable tool for predicting fractional distribution of arsenic in the slag cleaning electric furnace, when the distribution ratio, vapor saturation degree, temperature, y As and pO2 are given.

Jan 1, 2007

By Norma G. González

La littérature et notre expérience en Bolivie dans une communauté minière très divisée comme celle de Huanuni nous montrent le besoin d?envisager des négociations gagnant-gagnant entre communauté et entreprise minière, non pas comme un point de départ, mais comme un résultat à atteindre, qui nécessite la préparation de conditions préalables. Cela implique fondamentalement de mettre l?accent sur le processus qui permettrait par la suite aux parties de mieux traiter les questions de contenu. Suivant cette hypothèse générale, l?initiative conjointe entre le Ministère des ressources naturelles du Québec et le CECI ?Développement des mécanismes de négociation entre communauté et entreprise minière? peut dégager, après un an et demi d?expérience pilote dans le site minier de Huanuni, département d?Oruro, Bolivie, les leçons préliminaires suivantes. Ce processus requiert: ??Agir, en tant qu?organisme consultant tierce partie, selon des principes et une méthodologie qui relèvent de la Communication publique et de la Médiation ; ??Comprendre et agir à partir de la ?réalité sociale? des parties en présence: l?entreprise minière, l?État et les différents groupes de la communauté; ??Intervenir sur les ?réalités sociales? des parties, par des actions d?éducation et de diffusion dans le but de préparer les personnes, les institutions et les organisations de la société civile, à des changements durables du modèle de communications existante; Approfondir la compréhension de la ?réalité sociale? du conflit (la culture du conflit, les méthodes populaires de résolution des problèmes et de gestion des conflits) afin d?offrire aux bénéficiaires les technologies appropriées pour la transformation de cette culture de confrontation violente en gestion constructive des conflits. Par ricochet, nous espérons ainsi faciliter l?attraction des investissements dans le secteur minier.

May 1, 2001

By Farnham. G. S.

It is difficult co know how to deal with this subject before a group having such mixed interests. The mining man is not coo concerned with the problems of alloy research. The engineer is more interested in properties of materials than how these properties can be achieved. The business man feels that scientific history and prognostication are not for him, predicting trends or possible developments in the economic field being a more than sufficient occupation. Yet the application of physical metallurgy research to industry is of importance to miner, engineer, and business man, for only through such application can the continuing existence of industries manufacturing or consuming metals be assured. History shows that hard work does not guarantee industrial survival. For instance, the Bessemer method of steel making superseded puddling operations; it, in its turn, has been largely displaced by open-hearth processing; later, steels made in electric-arc furnaces displaced open-hearth products in the quality field; and now, very specialized steels are being made in high-frequency rather than in arc furnaces. It is apparent then, if industry is co remain healthy, complacency must give way co imaginative planning, based on a thorough knowledge of production technique, a knowledge supplied by efficient research.

Jan 1, 1947

By E. C. Keeley

Some Safety Measures at Ontario Mines The following safety precautions have of late been taken by several of the Ontario mines: installation of water crossovers; washing clown of faces to show-up missed holes; insistence on gloves being worn as a protection to men&apos;s hands; wearing of safety boots and hats by underground men; and wearing of goggles by all men using hammers, starting holes, etc. In the summer of 1924 the Mclntyre mine began experimenting with means of removing powder smoke from headings by installing fans and pipe-lines of various designs, also with different means of introducing water into the air-blast when blowing smoke. By October of that year they had devised a scheme of water connection between the water and the air line, at a distance of about one hundred and fifty feet back from the face, using two valves and a short hose. By this means a limited amount of water could be introduced into the air which blew into the face, resulting in a fine spray of air and water combined. This spray not only helped to eliminate fumes but also introduced fine particles of water into the air, raising it above the dew point, with the result that when these fine particles of water settled they had attached to them fine dust particles, thus eliminating, to a great extent, the injurious dust caused by blasting. The combined air and water is turned on immediately after blasting and allowed to blow continuously for from four to five hours, until the muckers come on shift.

Jan 1, 1931

By Georges Houlachi, Akram Alfantazi, Michael Mahon, Maysam Mohammadi

Corrosion resistance of the lead-based anodes directly influences the purity of the final product in the zinc electrowinning process. The anodic MnO2 layer that is electrodeposited on the anodes during this process can protect the anodes against corrosion. Sand-blasted anodes generate a uniform, adherent and shiny MnO2 layer, which gradually blisters and eventually sloughs off after several weeks. In this study, we attempted to develop a new method to stabilize the MnO2 protective layer on the anodes during the electrowinning process by providing suitable nucleation sites for electrodeposition of this layer. MnO2 particles (P80=40µm) were used as seed material for this purpose. Different techniques of galvanostatic and cyclic voltammetry polarizations, scanning electron microscopy (SEM) and atomic absorption spectroscopy (AAS) were employed to investigate the performances of the MnO2-seeded lead anodes. The experimental results showed that growth of the MnO2 layer is influenced by the MnO2 seed particles on the anode surface. The MnO2 layers electrodeposited on the MnO2-seeded lead anodes were uniform and strongly adherent to the substrate. This layer was more stable than those formed on the PbAg anode without MnO2 seeding. This could provide the anode with a higher level of corrosion protection. Moreover, formation of undesirable MnO2 mud in the electrolyte and the rate of manganese consumption were decreased when the MnO2-seeded lead anodes were polarized. These observations could be attributed to the different properties of the electrodeposited MnO2 layer on this anode in comparison with that formed on the PbAg anode.

Jan 1, 2016