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By E. Wusaty

"Fording Coal is a wholly owned subsidiary of Canadian Pacific Limited. The company was founded in 1968 to mine metallurgical coalfor export at the Fording River operations in southeast British Columbia.Today, Fording Coal Limited also operates the Whitewood mine under contract to TransAlta Utilities and the Genesee mine under a joint venture arrangement with Edmonton Power. Both these operations are located just west of Edmonton and produce subbituminous low-sulphur coal which is used for power generation. Fording also owns and operates two industrial mineral mines in the United States and is mining overburden under a lo-year contract with Syncrude Canada at Fort McMurray.As of December 1992, Fording Coal Limited owns and operates the Greenhills mine which was closed due to bankruptcy. This papers deals with the innovations and changes which have been made and those which are currently being implemented to make this operation competitive in the world export coal market. IntroductionOn December 4, 1992, following a tendering process, Fording Coal was awarded 80% controlling interest in the Greenhills mine by Trustee Arthur Andersen Inc. Assets acquired included 100010 of the land and coal leases and 80% of the major joint venture assets including all structures. The remaining 20% is owned by Pohang Steel Canada Ltd., a wholly owned subsidiary of Pohang Iron Steel Co. of Korea. The Greenhills mine had been in continuous operation since 1983 and was finally closed due to bankruptcy of its majority owner on October 31, 1992.A permit to operate the Greenhills mine was issued by the British Columbia government on January 29, 1993, and Fording Coal Limited started mining operations in late February 1993.To return the Greenhills mine to profitability significant changes were required in workforce productivity, mining methods and equipment selection. These mine plan changes are designed to make the Greenhills operation competitive in world markets, provide longterm employment for the company's workforce and ensure that a secure supply of coal is available."

Jan 1, 1994

By Robert A. Creaser, Iain Mitchell, Robert L. Linnen

Abstract - The Bermuda Zn-Pb showing is hosted by dolomitized Blue Fiord Formation of Devonian age, located east of the Ensorcellement dome on the Grinnell Peninsula of Devon Island. Fluid inclusions in hydrothermal calcite indicate that the mineralization precipitated from low-temperature, highly saline brines. The ?34S compositions of sphalerite, galena, and marcasite range from 16.1‰ to 35.2‰. Consequently, the Bermuda showing is interpreted to be Mississippi Valley-type (MVT) mineralization. The apparent age of mineralization has been determined by the Rb-Sr method from sphalerite separates, and a Late Devonian age of 357 ± 50 Ma (MSWD=65), with an initial 87Sr/86Sr ratio of 0.7083 ± 0.0020 is indicated. This date, within error, is the same as the Polaris deposit. This suggests that the mineralization formed during the Ellesmerian Orogen, although it is also possible that mineralization is associated with extension, related to the opening of the Sverdrup basin. The strontium and sulfur isotopes and fluid inclusion analyses indicate the involvement of a brine that acquired its salinity from interaction with evaporites, lower in the stratigraphic succession. The Polaris mine is the type deposit in the Cornwallis Zn-Pb district and is hosted by the Thumb Mountain Formation. The results of this study are significant because they demonstrate that regional brine movement is more widespread than previously recognized, and that MVT mineralization in the Cornwallis Zn-Pb district is not restricted to the Thumb Mountain Formation.

Jan 1, 2004

By M. Sider, D. L. Piron

"The cost of energy is a growing factor in the cost of zinc production. Electrowinning from sulphate solutions with periodical reverse current or from acidic chloride or alkaline solutions could be the way to lower costs. A comparison of the energy consumption for electrolysis shows that the alkaline solution may be considered the most promising alternative. IntroductionZinc electrowinning from sulphate solutions is a very energy intensive process (typical specific energy usage : around 3.1 kWh / kg zinc). This energy consumption represents 35% of the total cost of electrolysis and is the most important cost component.In order to lower costs, the energy efficiency of the sulphate process should be improved or alternative processes should be developed. In this laboratory, that objective has resulted in research on electro winning in sulphate solutions with the use of periodical reverse current (PRC) and in acidic chloride and alkaline solutions.Some of the results obtained in this laboratory and already published and new experimental results reported in this paper make it possible to present a more critical comparison of the energy consumption of the three processes mentioned.ExperimentalThe experiments at constant current were carried out as described previously. Specific conditions are indicated in Table I. Current efficiencies were obtained by weighing deposits.ResultsThe best energy consumptions for electrolysis obtained in this laboratory for the three media are presented in Table I. More detailed results can be found in the papers already mentioned."

Jan 1, 1988

By I. Osvath, I. Gombköto, G. Mucsi, Z. Molnár

"In the present research, a deposited brown coal fly ash was used as raw material for geopolymer. The reactivity of the fly ash was altered using mechanical activation, which is one of the promising methods to improve bulk and surface reactivity. The mechanical activation experiments were carried out in a high energy density mill using 5 m/s circumferential speed, and various residence times (1, 3, 5, 10, 15 and 60 min). The effect of mechanical activation on particle size distribution was measured by a laser particle size analyzer and structural changes using FT-IR. Geopolymer samples were prepared from mechanically activated fly ash with an alkali solution. The progress of geopolymerisation was monitored using an Isothermal Conduction Calorimeter. The heat flow curve obtained indicated that reactions were more prominent and started much earlier in the mechanically activated samples. This observation is further supported by the compressive strength results which also improved in geopolymers using mechanically activated fly ash. Based on the obtained results, it can be inferred that mechanical activation is a possible way to enhance the reactivity of fly ash and consequently properties of resulting geopolymers.INTRODUCTIONCoal fired power plants generate fly ash and slag in huge amount worldwide, about 780 million tons/year (Heidrich et al. 2013). Due to the relatively low utilization rate, enormous quantities of these wastes are landfilled in ponds. The fly ash is the finest grained particle fraction of the solid ash, which is transported with flue gas, and removed by electrostatic or bag filters. The fly ash has pozzolanic activity, it does not react with water, but in the presence of calcium hydroxide solution hardens and solidifies, producing a reaction product practically insoluble in water (Opoczky, 2001). The most important property of the fly ash regarding geopolymerization is its reactivity, which depends on the chemical and phase composition, the dispersity (specific surface area, particle size distribution), and the morphology of the fly ash particles, and determined by the physical properties and chemical composition of the fly ash. Geopolymers concerning their chemical structure are polysialates, where the sialate (silicon-oxoaluminate) network is built up from the bonds of Si-oxide and Al-oxide by sharing oxygen atoms (Davidovits, 1988)."

Jan 1, 2016

By S. Eckert, M. Reuter, O. Keplinger, D. Obiso, N. Shevchenko, M. Akashi

We report on laboratory experiments focusing on bubbling phenomena arising from gas injection through a top submerged lance (TSL) in a liquid metal layer. The objective of this study is to reveal the characteristics of the formation and behaviour of the particular bubbles at different gas flow rates and submergence depths of lance. Visualization was performed in the eutectic alloy GaInSn using X-ray radiography. Argon bubbles were injected through the injection positions at three different submergence depths. Essential parameters such as the bubble size, bubble shape, detachment frequency and the two- dimensional gas distribution in the flat vessel were obtained by image processing. The results show that the deep position of the submerged lance causes an asymmetric large-scale circulation inside the fluid vessel. Bubble detachment frequencies were calculated by Fast Fourier Transformation from fluctuations of the image intensity in the vicinity of the nozzle injection point. This frequency does not show strong variations with respect to changes of the gas flow rate and the submergence depth of the nozzle. An increasing gas flow rate results in an increasing two-dimensional projected bubble area and the occurrence of a significant number of small bubbles being trapped by the strong fluid flow in the liquid metal layer. INTRODUCTION The Top Submerged Lance (TSL) process has been an essential component of the metallurgical industry since the emergence of first concepts about 50 years ago (Floyd, 2005). The process, which is characterized by blowing reactive gas through the submerged lance into a liquid bath, was developed mainly for improving the tin smelting process and has been applied for waste treatment or the production of several metals such as copper, lead, nickel and zinc. The productivity of the reactor is determined mainly by the efficiency of the chemical reaction between the gas or solid particles and the liquid. To achieve a high efficiency requires good exchange between the gas-liquid phase and therefore a large interface area. The efficiency changes greatly with the number and size of bubbles injected from the nozzle and the extent of splashing on the free surface. The degree of turbulence in the bath plays a decisive role here. For the reason, the design of an efficient TSL process requires a profound knowledge of the fluid dynamics especially for complex multiphase flows.

Jan 1, 2019

By Esa Peuraniemi, Hanna-Leena Heikkilä

Boliden Harjavalta has been operating a copper flash smelter since 1949. Thus, in 2019, the smelter is celebrating its 70th anniversary of flash smelting. Slag formation is an integral part of the smelting process; currently the processing of slag is based on froth flotation at the slag concentrator. It provides high recovery of copper but restricts slag utilization; the final copper slag is deposited in a landfill. The Harjavalta smelter commissioned a new landfill area for final slag in May 2018. This paper describes the full project from permitting to commissioning of a new landfill area. The permitting process is described comprehensively, including environmental impact assessment together with the environmental and dam safety monitoring. During the environmental impact assessment, observations on rare animals protected on European level were made as well as archaeological findings. Successful completion of the permitting allowed the construction phase to start on time. After six years of intensive work, the new landfill was commissioned in May 2018. The new landfill area provides a sustainable way to store the smelter’s slag for decades to come. INTRODUCTION Slag processing Sulphide based concentrates have always formed the main raw material stream at Harjavalta’s copper smelter. During the smelting and converting steps, the iron included in the concentrate is oxidized and fluxed using a silica-based sand. Originally, the slag was processed by using an electric slag cleaning furnace after which the final slag was water granulated. Froth flotation has been utilized for slag treatment since 1966. In the beginning, the slag was cooled in open ditches. In 1984, controlled slow cooling of slag was licenced to enhance copper recovery at the flotation plant. Today, the slag from both the smelting and converting is tapped/skimmed to slag ladles and treated in the following steps: Slag ladle transportation from the smelter to the cooling area by slag hauler Slow cooling of slag in the ladle to allow mineral precipitation Unloading the slag by tilting the ladle; causing the slag to crush as it drops from the ladle Feeding the crushed slag (-500 mm) by wheel loader to a slag concentrator’s feed funnel followed by a conveyor belt transporting the slag to the concentrator plant Crushing and grinding using lump and pebble mills Froth flotation of the valuables Recycling the slag concentrate back to the smelter feed after dewatering Pumping the final copper slag to the landfill area.

Jan 1, 2019

By Song (Bruce) Li

This paper presents a three-tier web-based GIS application that uses Java Server Page (JSP), Java Servlet and relational database to manage performance monitoring and reporting in the oil sands mining industry. It is a real-time Earth Structure Performance Monitoring System (ESPMS), which allows the user to record and store instrumentation monitoring readings as well as technical observations and instrumentation installation documentations into a complete relational database. The ESPMS introduces the advantages of precise field record keeping, due diligence, security, consistency and completeness while at the same time simplifying the task of reporting. ESPMS combines web-based Geographic Information System (GIS) mapping and data management to facilitate the collection, organization, retrieval, reporting and communication of the vast amounts of monitoring data related to mining and tailings engineering associated with site investigation and construction information. ESPMS utilizes web-based GIS technology to incorporate referenced aerial photographs, Energy, Mines and Resources (EMR) maps or AutoCAD drawings as a base map for the monitoring site. It dynamically creates and administers all instrumentation monitoring locations and reading frequencies. It enables the user to collect and manage the data associated with an unlimited number of reading events. It provides the designer with real-time monitoring data (what, why, when, how), thereby allowing them to make early adjustments to design protocols or procedures, or to take remedial action(s) regarding the subject earth structure under construction or after completion. It provides more cost-effective reporting and data sharing through the Internet. It improves security on data entry and eliminates unauthorized data changes. It allows better integration of graphics and illustrations with numerical data files. It is capable of managing the continually expanding workload resulting from new and larger structures in the oil sands or other mineral mining industries. The ESPMS facilitates easier data gathering for preparation of as-built and after-built or regulatory reports, etc. It enables quick location of the interested instruments and summarization of the performance of the instruments. It enables one to visualize performance data and QA/QC construction test results spatially on any given cross-section. Data can be exported to MS Excel for detailed analysis and to evaluate the stability of the earth structures.

May 1, 2004

By Jun Shan

The preparation of poly(N-isopropylacrylamide)-monolayer-protected clusters (PNIPAM-MPC) of gold nanoparticles was carried out in a homogeneous phase using three ways, in which three types of PNIPAM ligands were employed. The first type comprised of PNIPAMs with narrow molar mass distributions, synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and thus, bearing a dithiobenzoate at the chain end. These polymers were used directly to passivate the gold nanoparticles upon the Schiffrin reaction in a one-pot synthesis. The second type of ligands was derived from the first one through hydrazinolysis, and they therefore contained a thiol end group. The third type of ligands was PNIPAMs obtained through conventional radical polymerization, post-modified to contain thiol end groups. The PNIPAM-MPCs were characterized by high-resolution transmission electron microscopy, and by dynamic light scattering. The one-pot synthesis utilizing the ligands of the first type turned out to be a simple and facile method, compared with the other two ways, with which the size of the gold nanoparticles can be easily manipulated mainly by adjusting the molar ratios of PNIPAM / HAuCl4. PNIPAM is a more efficient ligand to stabilize the gold nanoparticles in water and in organic solvents than alkanethiols. The surface density of PNIPAM chains ranged from 1.8 to 3.6 chain/nm2, which is much lower than that typical for alkanethiols. The thickness of a PNIPAM monolayer bound to the gold core is somewhat larger than the size of the random coil of corresponding free PNIPAM in aqueous solution, which suggests that the conformation of a PNIPAM chain bound to the gold core is to extended.

Oct 1, 2003

By J. L. Chakravarty, S. K. Dutta, S. Banerjee, D. Putatunda

"General purpose uniprocessor systems used in control applications, however fast they may be, at a certain stage attain saturation, forcing the user or designer to consider other avenues for solving the problem. This paper gives a broad overview of multiprocessing with special reference to transputers. Virtually all aspects, from parallel systems real-time control to artificial intelligence (AI) and expert systems, have been highlighted. The application of transpurters in unilayer and multilayer control are discussed in detail, with specific attention to sensor integration. Two case studies describe at length the utilization of transputers. IntroductionIn conformance with the high level taxonomy of parallel computer architectures as given by Ralph Duncan(l) (an improvement to Flynn's classification, which maintains the essential elements of useful taxonomy based on instructions and data streams), the MlMD architectures are categorized into two groups: (I) shared memory, and (2) distributed memory type. While the shared memory multiprocessors are more popular than the message-passing multiprocessors because they can be programmed in a conventional sequential fashion, their aspect of the architecture creates a perfonnance bottleneck. In contrast, message-passing multiprocessors (MPM) suffer from no such limitation and can attain linear speed increases that are directly proportional to the number of processors put into use. The MPM implementation also has its own advantages and disadvantages. Because the performance of the system is heavily dependent on it, the interconnection strategy in a distributed memory MIMD machine is of paramount importance. The transputer(2.J), a multiprocessor node of the distributed memory type, is becoming very popular. The advantages offered by the transputer make its application in the mining and processing industries very promising."

Jan 1, 1994

By Chen Bang, Xia Xiao’ou, Zhang Feng

"Ores with compressive strength lower than 150 MPa are usually easy to be crushed by conventional jaw crushers and cone crushers. However, for hard ores with compressive strength exceeding 150 MPa and 200 MPa and even up to 250 MPa, such as andesite, hard basalt and olivine, it is difficult to reach satisfactory crushing size and yield or difficult to meet service life and stability use requirements of quick-wear parts by using conventional crushers. As continued increase in ore mining depth and constant generation of new type materials, equipment demand for crushing hard ores becomes increasing high. A new type inertia vibrating crusher is designed. It is powered by a high-speed rotating vibration exciter and can obtain required crushing force by adjusting eccentric mass, eccentricity and rotating speed so as to crush various ores with high hardness. This paper introduces the design process of its structure and working principle, discusses the design calculation methods of vibration excitation system, vibration damping and energy storage system and other key mechanism and provides technical references for this type of vibrating crusher.DESIGN PHILOSOPHYThe conventional jaw crusher mainly acquires extrusion force from crank motion to realize crushing. The motor drives the eccentric shaft via the transmission device to bring the moving jaw to swing relative to the stationary jaw. When the moving jaw moves close to the stationary jaw, ores between them are crushed by extrusion; when the moving jaw moves away from the stationary jaw, crushed ores are discharged from the discharge gate at the lower end between the moving jaw and the stationary jaw.The conventional spring cone crusher and the hydraulic cone crusher mainly acquire extrusion force from cranking motion to realize crushing. The motor drives the eccentric sleeve via the transmission device, the moving cone shaft generates an eccentric distance to make cranking motion under the action of the eccentric sleeve. When the moving cone moves close to the stationary cone, ores between them are crushed by extrusion. When the moving cone moves away from the stationary jaw, crushed ores are discharged from the discharge gate at the lower end between the moving cone and the stationary cone under the action of dead weight."

Jan 1, 2016

By Alex Luyima, Michael Moats

"In the present work, the oxidation of manganous and chloride ions on a mixed metal oxide (MMO) anode from a 40 ºC electrolyte containing 160 g/L sulfuric acid (H2SO4) with various concentrations of Mn2+ and Cl- was studied using cyclic voltammetry. These results indicated that Mn2+ concentration does not affect Cl2 evolution on a non-MnO2 coated MMO anode. However once MnO2 deposits on the MMO anode, Cl2 evolution is inhibited. The effects of manganous concentration and chloride concentration on the amount of MnO2 deposited in one hour were also evaluated. Cl- concentration did not affect the amount of MnO2 generated. Increasing Mn2+ concentration resulted in an increase in the amount of MnO2 deposited.INTRODUCTIONThe electrolytic recovery of zinc (Zn) is a well-known process and is estimated to produce approximately nine million tons of Zn per year worldwide (Recendiz, Nava, Lartundo-Rojas, Almaguer, & Gonzaleza, 2009). The Zn produced by this process is of high purity and has a wide range of applications, such as galvanizing (car body parts, pipes, metal wires, etc.), sacrificial anodes in offshore industries, casting alloys, alloying of brass, primary and secondary battery industries, etc.The electrochemical production of Zn employs aluminum cathodes and lead-silver anodes (Pb- Ag) (Recendiz et al., 2009). The Zn containing mineral (ZnS) is usually associated with other elements such as Mn, Mg, Ca, Cd, Cu, Cl, Fe, F, Co, Ni, Al, As, Sb, Si, Sn, Ge, Hg etc. (Nijjer, 2000). After processing of ZnS concentrates, the electrolyte obtained still contains residual metallic and non-metal impurities. Some of these impurities can impact the corrosion rate of Pb-Ag anodes."

Jan 1, 2016

By Rodrigo A. Marinho

Erratic high grade values are as common in Nature as they are a source of problems for resource estimators. In some highly erratic metal deposits, less than 2% of the drilling samples can represent more than 10% of the total metal in the blocks and they are associated with a high risk level. There is a risk of local overestimation but also of global overestimation, with the high grades being projected over too large a volume. Capping or restriction of these outliers control is being widely used in the industry and commonly applied in resource estimation for the last three decades. The primary purpose of this paper is to present and describe the most applied methodologies for restricting the extrapolation of high grade samples and discuss the results based on a theoretical simulated model. Additionally, this paper demonstrates the economical impact associated with the high-grade and the project risk profile associated with each method.

Oct 1, 2009

By S. Pinard, A. Desbiens, R. del Villar, D. Jakelski

"During the fall of 1993, a new Pill-based control strategy was installed in the B grinding circuit at the Kidd Creek Division of Falconbridge Ltd. The control strategy was first evaluated on a grinding circuit dynamic simulator (DYNAFRAG), which permitted the discrimination between more than a dozen possible control alternatives. Once the final choice was made the necessary instruments were purchased and installed. The control strategy was configured on the plant computer and is planned to be commissioned shortly.This paper summarizes the control strategy, the design procedure, the installation and the controller tuning. Some preliminary problems posed by the process prior to implementation are also presented.IntroductionIn 1990 the GRAIIM (french acronym for Research Group on Computer Applications to the Mineral Industry) of Laval University started a research project on Knowledge Based Automatic Control (KBAC). This project is sponsored by a consortium of eight mining companies under the umbrella ofMI1EC (Mining Technology Council of Canada), the Quebec Mining Association (AMQ), CANMET and the Centre de Recherches minerales (CRM). The project also benefits from important grants from the Ministere de l'Education Superieure et de la Science and the NSREC-CRD program.The main objective of this project is the screening of advanced (knowledge-based) methods for data processing (filtering, mass balancing, etc.) and automatic control (model-based control) for their use in the mineral processing operations. The project also aims at transferring these tools to the industrial partners through annual workshops for plant engineers, annual symposia, and through specific in-plant projects where the participation of plant engineers is strongly encouraged.The main objective of this project is the screening of advanced (knowledge-based) methods for data processing (filtering, mass balancing, etc.) and automatic control (model-based control) for their use in the mineral processing operations. The project also aims at transferring these tools to the industrial partners through annual workshops for plant engineers, annual symposia, and through specific in-plant projects where the participation of plant engineers is strongly encouraged."

Jan 1, 1994

By F. Rosenblum, P. Spira

"A correlation has been established between the oxygen demand of Brunswick Mining and Smelting ore and flotation results at the bench, pilot plant and operating plant scale. A method of dete""1llining the aeration requirement of sulphide ores on the basis of this correlation is presented. It is shown that abraded iron from grinding media plays an important role in aeration and flotation. Laboratory grinding must therefore be conducted under controlled conditions with suitable grinding media in order to obtain the true aeration requirement of the ore.A method of evaluating aerator efficiency, also based on oxygen demand measurements, has been used successfully at Brunswick Mining to design pilot plant and full-scale aeration systems.1. IntroductionPre-flotation aeration of sulphide pulps has been practiced in the Noranda Group for many years to help in the depression of pyrite and pyrrhotite and to promote chalcopyrite and/or galena. Recently, two out of three parallel circuits at the Brunswick Mining and Smelting Corp. Ltd. concentrator have been converted on a test basis to a new flowsheet incorporating aeration as a basic step. Among other benefits, a substantial decrease in the middlings load has been achieved as a result of improved pyrite rejection. There has been increasing interest in other organizations in the potential advantages to be derived from' aeration in terms of improved metallurgy and/or decreased reagent consumption."

Jan 1, 1978

By A. Miura, R. Winarko, D. B. Dreisinger

Chalcopyrite leaching in acidic ferric sulfate media at ambient temperature exhibits slow kinetics and poor leaching efficiency, which is typically attributed to surface passivation. Recently, the presence of small amounts of iodide in the leaching media has been reported to significantly accelerate chalcopyrite dissolution. To further explore the behavior of chalcopyrite leaching in the presence of iodide, it is essential to determine the factors that control the leaching kinetics. In this study, we investigated the effect of initial solution potential, iodide concentration, particle size, and temperature on the kinetics of copper extraction from chalcopyrite. The key in the experimental setup was to minimize iodide loss by iodine evaporation and precipitation as cuprous iodide. The former was achieved by performing the leaching tests in fully sealed leaching systems. The latter was achieved by maintaining the solution potential higher than 420 mV (versus Ag/AgCl electrode), where formation of CuI precipitate is possible. The experimental results show that higher solution potential and higher iodide concentration had a pronounced positive effect on the rate of chalcopyrite dissolution. There was no effect associated with particle size, which might be due to the narrow size range tested. The positive effect of increasing temperature only manifested itself when the solution potential was sufficiently high. INTRODUCTION The main challenge of chalcopyrite leaching using ferric ions as the oxidant at ambient temperature is the slow kinetics and poor extraction. The reason for this leaching behavior has been attributed to passivation resulting from formation of insoluble passivating layers on chalcopyrite surfaces, which could be metal-deficient sulfides, elemental sulfur, polysulfides, and iron precipitates (Klauber, 2008). To overcome passivation, technologies using higher temperature and pressure have been developed to leach chalcopyrite concentrates, such as the CESL process (Mayhew, McCoy, Mean, & Woeller, 2013), FLSmidth Rapid Oxidative Leach (ROL) process (Mulligan et al., 2017), Galvanox (Dixon, Mayne, & Baxter, 2008), Albion process (Hourn, Turner, & Hourn, 2012), HydroCopper (Hyvärinen & Hämäläinen, 2005), TPOX (Dreisinger, 2006), and AAC/UBC process (Dreisinger, Dempsey, Steyl, Sole, & Gnoinski, 2003). Even though they are effective in accelerating copper leaching kinetics, those technologies typically have higher capital and operating costs associated with production of concentrates and application of autoclaves. This makes them unsuitable for treating low grade primary copper sulfide ores.

Jan 1, 2019

By Liguang Wang

The froth phase in flotation has received much less attention than the pulp phase despite the fact that froth stability plays an important role in determining flotation performance. Froth stability is largely determined by the stability of thin foam films, which in turn has a strong correlation with the critical rupture thickness (Hcr) of the films. In the present work, a new approach to predicting the Hcr values of thin foam films in flotation froth phase was proposed and examined. The Hcr values were calculated using an advanced capillary wave model with input parameters being surface tension, film radius, capillary suction pressure, and intersurface force. The intersurface force was estimated by using the Stefan-Reynolds lubrication approximation to fit the measured thinning rates of single foam films formed in a Scheludko ring cell, where the film radii were less than 50 microns and were kept constant during the film-thinning process. A comparison between the predicted and experimental Hcr values was made for the films with the use of sodium chloride as background electrolyte and in the presence of various frothing reagents such as methyl isobutyl carbinol (MIBC), polypropylene glycol with an average molecular weight of 400 (PPG400), and sodium dodecyl sulphate (SDS), at different concentrations and film radii. It was found that the model correctly predicted the trends of Hcr-versus-concentration and Hcr-versus-film radius curves. Moreover, the predicted Hcr values matched well with the experimental ones of the foam films containing either SDS or PPG400. For the foam films containing MIBC, however, the model overpredicted the Hcr values. The reason for this discrepancy was discussed.

Jan 1, 2016

By Xuanxue Mo, Kaihui Yang

"The Laochang mine, located in the Sanjiang area of southwestern Yunnan Province of China, is a volcanogenic massive Pb-Zn-Cu sulfide deposit. It is hosted by a pyroclastic sequence of Early Carboniferous age, namely the lower member of the Yiliu Group, which was intruded by syenite and rhyolite porphyry. The volcanic suite is basaltic or basaltic-andesitic in composition, has alkaline affInities, and is associated with the initial rifting along the margin of the Baoshan-Shanstate continental microplate (Yang, 1989). The ores are typically Pb>Zn>Cu in composition, averaging 3.820/0 Pb, 3.51% Zn, from 0.01% to 1.85% Cu (0.107% av.), a high average content of Ag (113 glt) and recoverable amounts of Au, n, Gd, Ga, Ge, In. A massive sulfide zone, in which lenticular and stratiform orebodies are localized in a sulfide-<:arbonate-silica shale unit or sulfidic tuffIte horizon that usually overlies coarse-grained pyroclastic rocks, is underlain by a stringer sulfide zone developed in a subvolcanic intrusion or volcanic sequence. The sulfIde mineral assemblages, from the top to the bottom of the deposit, are: realgar + orpiment - galena + sphalerite + pyrite - chalcopyrite + pyrite + pyrrhotite + arsenopyrite. Oxide and sulfate minerals occur rarely in the massive ores. The massive ores are generally fme-grained and banded, but coarse-grained ore, colloform and framboidal texture, and growth-zoned pyrite and sphalerite are common. Sedimentary features such as graded bedding, brecciated and deformed ore clasts, and chaotically emplaced blocks, are well preserved, indicating that the massive orebodies have undergone slumping and displacement. Alteration is weak in the hanging-wall rocks, but strong in the stringer zone. Two distinctive alteration zones have been identifIed: the upper zone, characterized by an assemblage of quartz, carbonates, chlorite, albite, zeolite and sericite, and the lower zone containing diopside, tremolite, actinolite, gamet, clinozoisite, and epidote.The general features of the Laochang deposit are in accord with the descriptive model of VMS deposits (Lydon, 1984). However, it falls into neither the Zn-Cu group nor the Zn-Pb-Cu group chemically (Franklin et al., 1981). The depositional setting of the Laochang deposit is quite different from Cyprus or Besshi-type massive sulfide deposits. Laochang is hosted by alkaline lavas that were erupted in a submarine continental rift. Although some features of the Laochang deposit are similar to those of Kuroko-type deposits, there are remarkable differences in the alteration mineral assemblage, the proportion of ore-forming elements (lead enriched) and the amounts of oxides and sulfates. These suggest corresponding differences in ore fluid composition and the associated ore-forming environment. Thus, the authors suggest that the Laochang deposit may be a distinct type of VMS deposit."

Jan 1, 1993

By D. T. Aikens, R. Gaudreault

"This paper summarizes structural repairs carried out on a marine wharf consisting of six 13.7 m by 13.7 m reinforced concrete cribs linked together by five 14.6 m long beam spans. As a result of problems during original construction and twenty years exposure to severe weather conditions, the deck support system between the cribs required major restoration work. In particular, some of the beam seats under the crane rail supports had marginal bearing area to support the structural loads. Faced with closure order for the wharf which is required to bring in raw materials to the plant and a long outage to make repairs as stipulated by Ports Canada (owners of the structure) alternate means of making the required repair were examined.The method chosen allowed the work to be done much more quickly, at lower cost, without taking the wharf completely out of service. The badly deteriorated seats were rebuilt using epoxy grout, tapered sole plates and a positioning jig."

Jan 1, 1988

By William DeWit

When rivers are contaminated from industrial operations, as often occurs near repositories of spent mine tailings, decision-support tools can be critically important in evaluating the effectiveness of various engineering impact-management measures. Even where data describing river flows and quality are sparse, simple mixing-zone models can be constructed that can contribute greatly to understanding how impact-management measures can differentially affect existing river-chemistry regimes. There can be circumstances where accumulated surface waters near contaminated land can bear contaminant loadings that could be acceptable to river regimes if there were methods available to evaluate optional discharge rates and to predict post-mixing consequences on river chemistry. Nomographs can be constructed to evaluate discharge regimes that appear capable of releasing contaminated accumulated pond water without compromising water quality in a nearby river. River-mixing zone models also contribute to predicting rates of acceptable discharge and release to the receiving environment.

May 1, 2011

By H. Weissenbaeck, B. Nowak, M. Oesterreicher, R. Stastny

The producers of certain metals like nickel and cobalt increasingly face a shortage of easy-to-mine and easy-to-process ore bodies. Their focus is shifting towards alternative raw materials which in turn demand new, different extraction techniques. One potential route for processing a ferrous ore with a non-ferrous target metal is atmospheric leaching with hydrochloric acid followed by purification of the pregnant leach solution (PLS). For the separation of iron from the PLS, and, in turn, the extraction of the non-ferrous compounds, the following flow sheet is proposed. Pre-concentration of the PLS, oxidation of ferrous (if present) to ferric chloride, hydrolysis of ferric chloride leading to the precipitation of hematite and the evaporation of hydrochloric acid, followed by crystallization of non-hydrolysable metal chlorides by means of sparging hydrogen chloride into the solution. Hydrogen chloride required in the latter step is produced internally by super-azeotropic distillation of regenerated hydrochloric acid. The liquid filtrate from the crystallization step is recycled to hydrolysis. Depending on the specific composition of the PLS, the hematite produced contains only traces of other impurities, whereas the crystallized mix of non-hydrolysable metal chlorides – containing also the target metal in enriched form – contains ferric chloride only in an amount referring to the filter cake moisture. These crystals can then undergo further hydrometallurgical separation and extraction processes. As an example, this flow sheet is proposed for treating nickel laterite ores. Experiments related to the demonstration of crucial assumptions in the flow sheet are presented. Based on those experiments a mass and energy balance of the flow sheet was calculated and is presented here together with a table of the major consumables in order to provide a basis for an operating cost estimate and other process economics.

Jan 1, 2016