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By Manuel Gomez

Primary, low-temperature tars are generally known to alter with time. The effect is believed to occur, in some instances, without the external influence of air, light, or heat. Since one of the processes occurring during extended storage is oxidation, the action of mild oxidation induced by air and heat, in addition to the effect of storage, was studied. The principal effect in aging and oxidation is formation of pitch at the expense of the distillate fraction. The fraction boiling above 270° C. is mainly involved in pitch formation due to storage, whereas all fractions are affected to some degree when tar is heated at 125° C. in the presence of air. If the effects of air are considered, the aromatic and tar-acid fractions seem to be important in pitch formation.

Jan 1, 1956

By Irving Hartmann

In recent years various modifications in the methods of blasting have been tried as a means of increasing the production of cod and of reducing mining costs. Following an investigation by the Bureau or Mines, authorization was granted to increase the charger limit for permissible explosives par shot hole from 1.5 to 3 pounds under contain conditions; this greatly facilitates the blasting of coal in some cool fields the practice has gradually evolved of simultaneously charging several shot holes in a face and then firing the charges singly without inspecting for gas after each blast. This practice is disapproved by the Bureau of Mines. In other coal mines the explosive chews in several adjacent shot holes are fired simultaneously. This form of shooting is claimed to increase the rate of production, generate smaller volumes of noxious gases, promote the health and safety of workers by eliminating the need of inspection of the face after each charge is fired, produce less float dust, and require less explosive than single shooting. However, simultaneous blasting may have a more harmful effect on the immediate roof strata; in some instances it leads to wedging of the broken coal, thereby making the coal more difficult to load out; it makes misfired shots more difficult to detect and possibly increases the chances of misfires. This lacy be duo to variations in the characteristics of detonators, because of more stringent requirements for adequate firing current, to the need for better electrical connections in the shot-firing circuit, and partly to the inadequacy of present permissible multiple blasting devices.

Jan 1, 1952

By J. Koster

During the past several years, alunite from the Marysvale (Utah) region has been the subject of investigation by the Electrometallurgical Section of the Bureau of Mines. The nature and occurrence of this mineral, with considerable data on the Utah deposits, together with a number of results of preliminary experiments, have been given in a previous report.6/ The geology of the Marysvale region has been reviewed recently.7/ The present paper reports the results obtained by a method involving the sintering of alunite with boric acid and subsequent treatment of the sinter to produce alumina and potassium sulphate.

Jan 1, 1939

By A. G. Galaitsis

The two volumes of this report summarize the noise control work performed by BBN on a rail personnel carrier operated in coal mines. Volume I of the report - submitted November 1977 - describes the aboveground work performed to identify the noise sources, design, fabricate, and install the treatments, and evaluate the treatments through noise and vibration tests. The current volume (II)-describes the underground work conducted by BBN to determine the deterioration, if any, of the treatments when the vehicle is operated normally in a mine. There were no significant changes in the acoustical performance or mechanical integrity of the treatments at the end of a three-month period.

Jan 1, 1980

By K. J. Liles

The U.S. Bureau of Mines evaluated the physical properties of ceramic particulate composites made from titanium nitride (TiN), alumina (AI203), and aluminum nitride (AlN) as part of a program to meet the high-performance demands on structural materials for new and emerging technologies. Samples containing from 20 to 80 wt pct TiN were pressed and fired, and their composition, Vickers hardness, modulus of rupture (MOR), and fracture toughness were determined. X-ray diffraction and scanning electron microscope (SEM) analyses showed that, depending on the amount of TiN added, the microstructure of the samples consisted of either a titanium-aluminum-oxynitride (TiAlON) particulate in a spinel matrix or a spinel particulate in a TiAlON matrix. The best results of the physical tests were achieved on a mixture of 40 wt pct TiN, 30 wt pct A1203, and 30 wt pct AIN. Sintering aids were added in 1-and 3-mol-pct increments to the 40-30-30 mixture to determine their effect on microstructure and physical properties. Results of an analysis of variancf' on a 4 by 4 factorial analysis showed significant effects on density, MOR, and Vickers hardness.

Jan 1, 1989

By Fred D. DeVaney

The Mesabi iron district of Minnesota has a potential production of over 50 million tons of iron ore annually. The large shipments of ore each year are gradually depleting the reserves, and if the present rate of production is to be maintained there must be a growth in the present available ore supply. Growth is a natural course. The growth of a city may be affected by the addition of city blocks or by the improvement of utilities necessary for its betterment. These may go on in the order named or concurrently. The city-block type of growth of the Mesabi has been tremendous, and the "betterment" type has followed in due course. Probably the former has reached its limit, and if so, more time will be allotted to the latter. It is not the intent of this paper to present either a eulogy of the wonderful mining methods or a history of the milling, but it is pertinent to say that if the lean-ore area continues to produce, the continuance will be more the result of further improvement of milling methods now well under way than of extension, of boundaries by the city block plan of growth. In an examination of the western end of the Mesabi district one finds sludge basins containing millions of tens of millable ore rejected by washing plants which were built for economy in operating cost and with little thought of conservation, and rich tailings piles of jigging plant rejects. In addition, there is an appreciable tonnage of bowl rake products so low-grade that it requires mixing with the best ore of the district to make it merchantable.

Jan 1, 1932

By J. G. Croeni

The high thermal-neutron cross section of gadolinium and the good mechanical and corrosion properties of titanium suggest that alloys of these two metals might be useful as control rod material. To aid in establishing the feasibility of this combination, the Federal Bureau of Mines investigated the titanium-gadolinium system. The results indicate that the system is composed of a single eutectic reaction and a peritectoid reaction involving the alpha-beta transformation of titanium. The eutectic isotherm extends from 1 to 99 pct, gadolinium at 1,240° C. The established eutectic composition is about 95 pct, gadolinium. The peritectoid reaction occurs at 885° C. and extends almost over the entire composition range. Hardness increases slightly with additions of gadolinium, and little change is obtained by heat treatment. Alloys containing less than 10 pct. gadolinium are amenable to extensive cold-working, but alloys having higher percentage of gadolinium content are only moderately cold-workable. All alloys can be hot-worked in iron sheathing at 750° C. Observation indicates that all compositions possess good machinability. Corrosion resistance to water at room temperature is apparently poor, especially in the gadolinium-rich alloys. INTRODUCTION A combination of the good mechanical and corrosion properties of titanium and the variety of thermal-neutron cross sections characteristic of the rare-earth metals suggests that alloys of these metals may be used for control rod materials. For this reason the Bureau of Mines proposed a study of the titanium-gadolinium alloy system, and the Atomic Energy Commission sponsored the investigation.

Jan 1, 1961

By Richard A. Watson, James A. Powell

A seismic system which utilizes in-mine geophones to detect trapped miners has been developed. Tests at the Bureau of Mines Safety Research Mine at Bruceton, Pa., and at two operating mines indicate such a system has a maximum detection range in excess of 1,000 feet. The system is field worthy and portable and requires less than 30 minutes to set up and check. Real-time detection is possible.

Jan 1, 1976

A spectrographic procedure applicable to the semiquantitative determination of 29 elements in tungsten is presented. The method is designed to give estimates of impurity concentrations up to 500 p.p.m. Limits of detectability range from 0.3 p.p.m. for the more sensitive elements to 100 p.p.m. for the less sensitive ones. Tungsten metal samples varying in particle size from minus 300-to 30-mesh are excited in the presence of 5 percent germanium with a direct current arc. Germanium acts to stabilize the arc, minimizes the volatilization of tungsten, and serves as an efficient carrier to sweep impurities from the tungsten into the excitation zone. Curves are presented that show the volatilization behavior of germanium, tungsten, and impurities in tungsten at different concentration levels. Data obtained were used as guides in establishing the method of analysis. In the absence of established reliable analytical procedures for determining many impurities in tungsten in the parts per million concentration range, the spectrographic method described here should prove to be helpful in evaluating high-purity tungsten.

Jan 1, 1961

By Ann G. Kim

Hydrocarbon gases, primarily methane but also the C2 through C5 paraffins, the C2 and C3 olefins and possibly the C4 and C5 olefins, are byproducts of coal formation. Although it is generally believed that coal formation occurred at temperatures below 200° C, most experimental work on gas formation from coal has been performed at temperatures between 200° and 1,000°C. The objective of this Bureau of Mines experiment was to determine if observable changes in the gases from coal could be produced at temperatures below 200° C in relatively short periods of time. The experiment involved heating coal samples from six coalbeds at constant temperatures and analyzing evolved gases. The composition of the gases at three temperatures was compared. At 35° C, over 99 pct of the gas is methane; at 125° and 150°, methane constitutes approximately half of the hydrocarbon gas. Isobutane and pentane are the predominant higher hydrocarbons at temperatures between 100° and 150° C.

Jan 1, 1974

By A. L. Engel

This report is a compilation of results of preliminary concentration tests of nine manganese-ore samples in 1953-1954. Three samples were from Nevada and the other six from California. These samples represent marginal or low-grade ores from deposits that have been mined selectively in the past. The present interest lies chiefly in the possibilities of concentration of the remaining low-grade ores for economical exploitation. The treatment methods included gravity concentration and flotation in most cases. Results were sometimes unsatisfactory, particularly when the ore was too fine grained for liberation of the minerals within economical grinding range. The contaminating gangue minerals, such as quartz and iron oxides, were locked with the manganese to an extent that prevented separation of high-grade concentrates with satisfactory recovery. In cases where fairly good concentrates were made, it was at the expense of recovery, a condition typical of low-grade ores.

Jan 1, 1955

By M. H. Kline

The Scarlet mine, in Randolph County, N. C., was operated on a small scale at intervals from 1899 to 1915, but no records of the quantity of ore produced are available. J. I. Moore unwatered the mine in March 1948, and Bureau of Mines' engineers examined the underground workings. Several assays checked previous sampling of the mine and indicated a small but comparatively high-grade copper-zinc deposit. The high metal content of the veins and the possibility of developing additional reserves prompted the Bureau of-Mines to drill three holes, totaling 530 feet, at the deposit during March and April 1948. Drilling disclosed that the mineralized vein did not extend over 300 feet along the strike and is probably limited in depth to the contact with the granite mylonite.

Jan 1, 1949

By K. R. Van Doren

The polynomial method for estimating virial coefficients from experimental data suffers from three serious defects: (1) There is no known relationship between the polynomial coefficients and the virial coefficients, (2) the values of the estimates depend upon the degree of the polynomial and the particular set of values used for the independent variable, as well as the random errors in the dependent variable, and (3) the variances calculated for the estimates do not represent the mean square errors of estimation. Attempts to overcome these defects have thus far been unsuccessful; these attempts have also failed to account for the fact that none of the virial coefficients are uniquely determined by the values of the dependent variable for a finite set of values of the independent variable. The conclusion is that virial coefficients cannot be reliably estimated from experimental data unless additional information about the virial expansion itself, such as its rate of convergence, is available.

Jan 1, 1969

By David Schlain

The galvanic corrosion properties of titanium in contact with commercially pure aluminum, copper, or type 302 stainless steel in some of the common organic acids were investigated. Acids used in these experiments were 10 percent formic, acetic, lactic, citric; 1 percent oxalic and tartaric; and 9 percent oxalic. Electrode-potential measurements and several types of galvanic couple experiments were carried out. Solutions were aerated by three methods: Flow of air, flow of helium, and natural aeration. Work was done at 35° C. with couples consisting of equal areas of the 2 metals. Titanium was resistant to corrosion in most of the organic acids studied, whether alone or in contact with a dissimilar metal. However, titanium coupled with aluminum did corrode in 1- and 9-percent oxalic acid solutions. Contact with titanium usually caused aluminum to corrode by galvanic action. Copper was subject to galvanic attack in 10-percent acetic acid with a flow of air. Contact with aluminum to some solutions in which titanium is ordinarily inert and noble with respect to aluminum caused titanium to corrode

Jan 1, 1956

By D. I. Bleiwas

The Bureau of Mines determined demonstrated tin resources and costs associated with tin production in order to evaluate the potential for tin production from 18 market economy countries (MEC's). Data were collected from tin producers, in most cases during on-site visits. The analyses evaluated the relative economic and resource position of 146 mines, deposits, or regions in January 1984 dollars. The demonstrated resource of recoverable tin within the nations studied is approximately 2.8 million metric tons (mt). Of this total, over 73 pct is recoverable from the Southeast Asian countries of Malaysia, Thailand, and Indonesia, which in 1983 accounted for almost 60 pct of the world's tin production. Brazil has joined the Southeast Asian countries as a major low-cost, high-volume supplier of tin and is likely to continue to expand its production. Given the 1984 market structure, over 60 pct of the tin in demonstrated resources was economically recoverable. Historically, the International Tin Council (ITC) has helped maintain relatively stable tin prices through a buffer stock and sales quotas. In late 1985, exhaustion of buffer stock funds led to suspension of tin trading on the world's major tin metal exchanges.

Jan 1, 1986

By Michael L. Clar

This volume is an annotated bibliography of published literature pertaining to the occurrence and control of surface and groundwater in underground coal mines. This literature was used to develop Volume 1 of this report, which assesses the feasibility of water diversion and overburden dewatering for underground coal mines in the Appalachian Region. Each abstract is followed by subject descriptors. the abstracts are listed alphabetically by title and are numbered consecutively. These numbers are used in the subject index to help the reader locate the appropriate articles.

Jan 1, 1981

By C. H. Riggs

This report describes the development, oil recovery, and potentialities of productive formations in the Hall-Gurney field, Russell County, Kans. It is presented as part of a general program to aid and promote increased recovery from petroleum reservoirs. The report is based on studies of well logs, drill cuttings, and oil-and water-production histories of individual wells and leases. The geological interpretations follow closely those in published literature with only slight local modifications. Oil and water analyses, made at a Bureau of Mines research center, were supplemented by many analyses obtained from oil-producing and service companies. The Hall-Gurney field, in south central Russell County, Kans., (fig. 1) was discovered in 1931 but was not developed extensively until 1941. By 1960 the rate of oil production from the field had declined to the extent that many wells were abandoned. In some areas natural productive forces have effected good recovery. However, in other areas inefficient waterflooding, both natural and accidental, has adversely affected recovery potentialities.

Jan 1, 1963

By A. C. Rice

Investigation of a variety of mines to determine efficiency for rare- earth extraction has resulted in a solvent extraction technique wherein Primene 81-R,4 N-benzylheptadeeylamine (BHDA), and Primene JM-T give favorable extraction from sulfate solutions. Extraction from chloride, nitrate, and perchlorate solutions is negligible. Distribution coefficients for 10 rare-earth elements with Primene 81-R establish an extraction sequence beginning with lanthanum and proceeding through lutetium according to atomic number. Yttrium and ytterbium are exceptions in the extract ion sequence.

Jan 1, 1962

By August J. Kwitowski

The U.S. Bureau of Mines developed and tested a teleoperating system to control a new highwall mining system. A remote operator was provided out-of-sight sensory information and control of coal extraction and haulage equipment. Surface and production testing proved that the teleoperating system supplied the operator with sufficient sensory information to operate the mining system. Details on the teleoperating system provided in this report include (1) sensor selection, (2) a description of the electronic control system, (3) equipment selection and modifications, (4) the positive test results, and (5) recommendations for system improvements.

Jan 1, 2010

During 1990-1999, a total of 458 fires occurred in all coal mining categories; 157 of those fires caused 164 injuries and 2 fatalities. The greatest number of fues and fire injuries occurred at surface mines, whch also had the highest risk rate values. A total of 66 fuefighting interventions were required. Of these, there were 25 mine rescue team interventions in underground mines, including 5 mobile equipment firefighting interventions, and 41 fire brigade and fire department interventions at all surface operations, including 19 mobile equipment interventions. In all, 50 fires destroyed or heavily damaged equipment (including 16 pieces of mobile equipment) because of failure of other firefighting methods, late fire detection, undetected fires, or fire size. A total of 1 14 fires were detected late by smoke, and 42 fires were not detected.