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By Adrian Smith, Debra W. Struhsacker

There is now overwhelming evidence that, despite concerns to the contrary, natural degradation of cyanide and cyanide attenuation by hydrogeochemical processes are capable of minimizing or eliminating potential water qua1ity impacts from heap leach systems. A1 though there was some recognition of these data by the regulatory authorities, for example the initial USEPA modification of cyanide standards to an advisory level, many states have codified standards inappropriate to the clearly site specific nature of heap leach operations. As an overview to this problem, this paper will integrate the theoretical chemical data on cyanide with the observed geochemical behavior of cyanide in the decommissioned heap leach environment. The cyanide species that are likely to exist within an abandoned heap leach system will be identified, and the relative toxicity and potential environment effect of these cyanide species will be discussed. These data will then be used to evaluate cyanide detoxification regulations for decommissioned heap leach projects in 14 states.

Jan 1, 1987

Over the past few years, the School of Mines of Paris has carried out a program of research* on the grade-tonnage relationships in the border zones of porphyry copper deposits. The initial problem was quite difficult : how does the grade vary at the border of the known orebodies? Does it decrease regularly, or do some thresholds exist, where the grade diminishes abruptly? The answer to these questions have important repercussions on the prediction of the future reserves in the fringe of the orebodies. If the grade decreases regularly, very important reserves could exist; if not, there would be strong limitations to the possible recoverable reserves. The first step of our study was a critical study of previous work done on the subject. It appeared that, following Lasky's pioneering paper (Lasky, 1950), most of the authors used what we can call an historical approach to the problem. In this, the grade-tonnage relationships are calculated from the available figures for production and reserves and the results are then extrapolated to the future. The strong limitation of this model are brought out in this article.

Jan 1, 1982

By John A. Herbst, Per-Olaf Samskog, Jan Bjorkman, Yi Chang Lo

The study described here is concerned with the development of a model for the simulation and optimization of a rod milllpebble mill circuit. A series of laboratory tests was conducted to investigate the effect of critical operating variables. The pebble mill model structure used was a population balance type which accounta for impact breakage and fines production from pebble wear. Model parameterization and verification were performed using data obtained in batch tests and in a plant test campaign. The model developed was found to provide accurate predictions of plant-scale grinding. The prediction errors are less than 21 for the product size and 31 for the mill power required to achieve that product with a mill volume scale-up of 14,000 to 1. These results indicate that accurate extrapolations from laboratory batch data to plant scale performance are poaaible using the population balance model and scale-up prediction procedures for pebble mill circuits as well as ball mills. Preliminary indications are that the new model developed here will provide vital input for pebble mill optimization and process control as well as pebble mill design.

Jan 1, 1990

By T. McWaters

In 1911, Miami Copper Co. began a block caving operation at its Miami, AZ property. A gravity mill was used to separate copper minerals from the Pinal Schist host rock. Until 1932, the mill tailings were deposited by the upstream method using perimeter launders and spigot valves in six canyons adjacent to the mill. In 1928, the larger and more distant Solitude tailing pile was developed. By 1932, it was receiving all tailings. In 1925, Miami Copper converted the gravity mill to flotation with sulfide copper recoveries. From 1934 to 1943, Miami, Copper ran a leach-precipitate float (LPF) circuit on mined ore and, in 1943, began sulfuric acid in-place leaching of a portion of the caved area formed by block caving. The pregnant solutions were collected underground and pumped to the LPF precipitating drums to harvest copper. In 1954, the company started mining low-grade ore. This led to the running an old LPF plant on select mill tailings from April 1957 to March 1959. In 1959, block-cave mining ceased. Solution mining became the only source of production using a launder precipitation plant. In the mid-1960s, Miami Copper merged with the Tennessee Corp. In the latter part of the decade, Cities Service Co. bought the combined properties. In 1976, Cities Service commissioned a 15-t/d (16.5-stpd) solvent extraction electrowinning(SX-EW) facility at its Miami copper property to replace the precipitation plant. In 1982, Occidental Petroleum Co. bought Cities Service. In 1983, the Miami operations were sold to Newmont Mining Corp. and set up as a subsidiary company, Pinto Valley Copper Corp. Finally, in 1987, Newmont Mining spun off a combined Pinto Valley and San Manuel unit as Magma Copper Co.

Jan 1, 1990

By Bryan C. Smith, Duane R. Skidmore

Volumetric mass transfer coefficients and gas holdups were measured in a concentric tube airlift reactor designed for the microbial desulfurization of coal. The slurries were comprised of an acidified basal salts solution containing thirteen different weight percents of coal (74 µm Ohio #1) at three temperatures. An enhancement in the mass transfer coefficient, KLa, with respect to that measured in pure solution was found at weight percents of 5 (volume fraction solids, ES = 0.035) or less, the greatest enhancement being as great as 37% at approximately 2 weight percent (ES = J 0.014). At higher solids fractions, the mass transfer coefficient decreased with further solids additions, decreasing by as much as 91% at 40 weight percent coal (ES = 0.315). KLa increased with temperature at all solids concentrations, the greatest increase being 392% at 72°C vs that measured at 30°C. Gas holdup, EG decreased with all increases in solids loading by as much as 65% and increased by as much as 67% with temperature. KLa and EG were correlated with operating conditions separately, and the separate correlations combined to yield overall correlations for the mass transfer coefficient and for the gas holdup. The correlations are suitable for inclusion in system models devised earlier for microbial coal desulfurization processes, and may be used for design, operation and cost estimation for such systems.

Jan 1, 1989

By J. E. Gebhardt, J. A. Herbst, K. Y. Lee

Benefits of proper control of reagent usage in flotation circuits are typically improved metallurgy and savings in reagent costs. Improved metallurgy can mean more consistent product quality, i.e., final concentrate grade, better recovery of product values from the feed, or higher plant throughput at existing target recovery, and grade values. Flotation performance is sensitive to a variety of process disturbances which occur in operating plants, such as changes in flow rate, percent solids, size distribution. flotability of mineral species, etc. A way to handle these variations is to fully understand the dynamic flotation responses to disturbances and to implement a suitable control strategy to compensate for these disturbances. Depending on the objectives of the control system, various types of control strategies are available which employ different levels of refinement to achieve the desired performance. Typically, variables such as collector and frother dosages and reagent addition points can be manipulated to affect the performance of the circuit. In the case of sulflde mineral flotation, manipulation of the process electrochemical potential, in flotation and in grinding, offers another degree of process control. Because of the complex and interactive nature of flotation process variables, optimized reagent control requires consideration of all, or at least the most important, interactive variables of the flotation circuit. Model- based optimizing control provides a framework to handle the complex and dynamic nature of flotation reagent process control.

Jan 1, 1994

By N. Dahotre, C. Blue, C. Zhao, B. Parekh, D. Tao, G. Engleman, R. Honaker

Equipment wear is one of the major concerns in screening of coal and minerals. Not only does it decrease the screen service life, it also results in inconsistent aperture sizes and deteriorates the efficiencies of downstream operations. In this research, a coating technique based on laser surface engineering (LSE) was successfully developed to increase the life span of raw coal screens. The microstructure and wear properties of the coating were investigated in this study. Enhanced wear resistance performance (up to 11-fold increase) of coated screens has been achieved in laboratory wear tests.

Jan 1, 2006

By Estban M. Domic

The modem copper industry presents an excellent opportunity for the application of clean, environmentally friendly techniques using currently available hydrometallurgical technologies. This paper briefly reviews key events in the development of modern hydrometallurgy in Chile. Discussion is given to those prominent events whose impact continues to be felt on most projects currently underway. Mention is also made of the foundations of heap leaching technologies, preceded by agglomeration and acid curing, known as the T.L. Leaching Process, the cornerstone of more recent developments. A review is also presented of the leading copper hydrometallurgy projects of the 1990s. A list of those projects, their tonnages and the estimated date of implementation is provided. The conclusion provides an overview of developments in research and the trends in the implementation of copper hydrometallurgy projects in Chile for the coming years.

Jan 1, 1998

By Marcel Haffen, Jean Janin

The purpose of grouting is to modify the permeability and strength characteristics of the subsoil in such a way that the planned structure can be efficiently constructed at a given location. This technique, which originally underwent considerable development in the field of dams construction is constantly evolving and it becomes more and more important in urban zones of intensive underground development for projects such as transport tunnels, stations, car parks, ect. Grouting becomes more and more indispensable whatever the natural characteristics of that subsoil ; such is the case particularly when the planned work runs through cohesionless granular soils, usually water-bearing such as alluvium, sands, disturbed ground, fill material, etc. The selection of the grouting method and the extent of treatment required at depends on two fundamental factors. 1º) nature and behaviour of subsoil to be treated. There is no need to stress the necessary of a good knowledge of geotechnical, hydrological and chemical characteristics of the ground to be treated. At the present time the specialists in these fields have available numerous methods of analysis, either laboratory or field tests, which enable to evolve a suitable treatment.

Jan 1, 1997

By K. A. Natarajan, J. M. Modak, P. Anand

A microbial survey of Jamnagar bauxite mines in Gujarat, India, revealed the indigenous presence of a variety of autotrophic and heterotrophic bacteria and fungi associated with the ore body and water ponds in the vicinity. Among these, bacteria belonging to the genera Thiobacillus, Bacillus and Pseudomonas are implicated in the weathering of aluminosilicates; the precipitation of iron oxyhydroxides; the dissolution and conversion of alkaline metal species; and the formation of alumina, silica and calcite minerals. Fungi belonging to the genus Cladosporium can reduce ferric iron and dissolve alumina silicates. Biogenesis thus plays a significant role in bauxite mineralization. Various types of bacteria and fungi, such as Bacillus polymyxa, Bacillus coagulans and Aspergillus niger, were found to be efficient in significant calcium solubilization and partial iron removal from bauxite ore. Probable mechanisms in the biobeneficiation process are analyzed. Biobeneficiation is shown to be an effective technique for the removal of iron and calcium from bauxite ores for use in refractories and ceramics.

Jan 1, 1998

By R. A. Bergman, P. G. Thornhill

Development of the Falconbridge Ferronickel Process for treatment of lateritic nickel ores began with laboratory work in 1955, the year the Company commenced exploration of its concession in the Dominican Republic. Process development centred on selective reduction originally directed to producing calcines amenable to ammonia leaching, but later found suited to electric smelting. The reduction step of the process was developed in a 25 tpd shaft furnace pilot plant located in the Dominican Republic, to which was later added an electric melting furnace. After almost 3 years of development work on this scale the plant was expanded to 100 tpd for fixing design data for a commercial plant. This took the form of the 30,000 ton per year Nickel Ferro-nickel Complex of Falconbridge Dominicans, which started up in 1971.

Jan 1, 1979

By D. F. Watson, G. M. Philip

The article cited above reflects the difficulty that is often encountered in interpreting different aspects of kriging. Baafi et al. write: "Due to negative kriging weights, negative block grades may be obtained in some extreme situations, which makes no practical sense." Their solution to this particular problem is to constrain the kriged estimates to data values that have positive weights, i.e., reduce the subset size contributing to the estimation. As Journel (1986, p. 133) has already observed, "Negative weights are no evil." Indeed, they are an ineluctable result of the Lagrangian multipliers in the system of simultaneous equations. The fact that data distant from the estimation point may be given negative weights simply means that the influence of such distant values must be negated because their influence is contradictory to closer values (as illustrated by Baafi et al. in their Figs. 3 and 4). Of course negative kriging weights applied to distant grade values will not in themselves induce negative grade at some central interpolation point. Negative grade values, rather, seem to be a particular artifact of automatic methods of estimation involving accumulations (Philip and Watson, 1985a, 1985b, 1987b). The elimination of negative weights, suggested by Baafi et al., is likely to exacerbate a quite different problem of kriging and piecewise spline interpolation discussed elsewhere (Philip and Watson, 1987a). In interpolating large data sets of scattered observations, changing local subsets or neighborhoods must be selected automatically. Because of the mathematical formulation of kriging and spline interpolation, discontinuities then occur between closely-spaced estimation points as the subset used in the estimation changes. If this subset is reduced in number and size, the discontinuities will be amplified and more common.

Jan 1, 1988

By James S. Hanson

Existing models proposed for the bacterial leaching of metal sulfides generally fail to predict solubilization rates at times greater than a few tens of hours. The reasons for this may be that these models are empirically based and use first order bacterial and chemical oxidation rates. This type of model is satisfactory for short time predictions (on the order of 20 hours) when the bacterially catalyzed dissolution is relatively minor. However, when bacterial action becomes more pronounced, these models consistently predict higher dissolution rates than those commonly observed in laboratory experiments. The present model uses several fundamental chemically and biologically based assumptions to predict the dissolution rate of a chalcopyrite concentrate for extended leach times up to the precipitation of jarosite. The main assumptions made are that Monod growth kinetics prevail, T. ferrooxidans adsorb onto the surface of the mineral (not necessarily mineral specific), and that during periods of high growth oxygen transport may become rate limiting. The model also relies on the energy efficiency of the bacteria in fixing carbon (growth yield) and correlates this value with available surface area of the mineral particles and the bacterial growth rate.

Jan 1, 1989

By I. Iwasaki

As the world tension relaxes and as the interest and taste for consumer products change, complacency is beginning to prevail over the needs of minerals and primary metals. The current trend towards resources and energy conservation calls for miniaturization of consumer goods, and lowers the demand for virgin materials to produce goods and services. Challenged by the third world countries with high grade ores and low labor costs, industrialized nations with lower grade ores are being pressed into more efficient operation through technological innovation, while protecting the environment. In many countries, domestic mines were forced to close since the oil crises due to rapidly rising energy and labor costs. Research in conventional mineral processing needs to be directed towards breakthrough technologies in order to maintain the competitive edge in the global marketplace. Research activities will provide new challenges in the processing of solid waste and waste water for environmental remediation as well as for resource conservation, in the preparation of new functional materials of extreme purity and/or unique properties for high technology applications and in the development of such future resources as deep sea minerals and extraterrestrial materials.

Jan 1, 1995

By P. L. Padgett, J. C. Hower

Five coals blended at a Midwestern United States power station were subjected to detailed analysis of their Hardgrove grindability. The coals, representing four distinct coal beds, are a low-sulfur, high-volatile A bituminous Upper Elkhorn No. 3 coal (Pike County, Kentucky); a medium-sulfur, high-volatile A bituminous Pittsburgh coal (southwestern Pennsylvania); a low-sulfur, subbituminous coal from the northern Powder River Basin (Montana); and two low-sulfur, subbituminous Wyodak coals from two different mines located in the eastern Powder River Basin (Campbell County, Wyoming). All samples that were processed in the Hardgrove grindability tests were also analyzed for their maceral and microlithotype content. The high-vitrinite Pittsburgh coal and the relatively petrographically complex Upper Elkhorn No. 3 coal exhibited different grindability behavior. The petrographic compositions of the Pittsburgh raw feed, the 16 x 30-mesh fraction (HG! test fraction) and the -30-mesh fraction (HGI test reject) are similar, suggesting that the HGI test fraction typifies the whole feed. The eastern Kentucky test sample is not as representative of the whole feed, with the HGI test fraction having lower vitrinite amounts than the rejected -30-mesh fraction. The Powder River Basin coals are high in vitrinite content and show behavior similar to the Pittsburgh coal.

Jan 1, 1998

By John C. LaScola, Gerald L. Finfinger, Michael A. Trevits

Methane gas is an ever-present problem facing the underground coal mining industry. Mine operators are mandated by law to maintain safe concentrations of methane gas within the mine environment. Ventilation is the method of choice used by all mine operators to reduce gas concentrations. When gas emissions are such that ventilation alone cannot control the gas, methane drainage methods must be applied. In the 1970’s, there was a concern that unprecedented gas emissions would be experienced as mine operators began new developments in the deep and gassy Blue Creek and Pocahontas No. 3 Coalbeds. Such concern was well founded as significant gas volumes are being emitted as these mining operations mature. In 1971, the U.S. Bureau of Mines began to tabulate and track the change in mine emissions. These data were extracted from the underground coal mine quarterly air quality-quantity inspections performed by the Mine Safety and Health Administration. At that time, approximately 6560 Mm3/d (231.7 MMcfd) of gas were emitted from 430 underground coal mines. It was determined however, that the mines emitting less than 2832 m3/d (100 Mcfd) contributed only 2.1 percent of the total daily gas flow. In 1988, underground coal mines emitted 8350 Mm3/d (294.9 MMcfd) from 487 mines. This report evaluates the changing nature of U.S. mine gas emissions over the last 18 years.

Jan 1, 1991

By Charles H. Jacoby

Introduction Although, in general, the openings created in domes or diapiric type salt deposits during mining operations are larger than those created in bedded deposits, the openings in bedded salts are of significant lateral extent. Thus, this paper will deal primarily with the dome deposits of the Gulf Coast and more specifically with the Avery Island dome operated by the International Salt Company where recent development activities have materially increased the sizes of previously standard openings. Geology The geology of salt deposits is the governing factor in the rock mechanics associated with the opening which is being created in the salt. Bedded salts are customarily characterized by having experienced solution along the interface between the top of the salt and the overlying bed. Thus, as the salt slowly dissolves there has been left behind a layer of laminated insolubles which is often incompetent. In most cases, this incompetent rock must be supported by a thickness of bedded salt which is left in the roof as support. Where this salt is of secondary deposition (recrystallized halite) with included moisture, additional thicknesses of roof salt are necessary to achieve stability. The salt which forms the domes of the Gulf Coast regions is from the Louann formation of the Jurassic period. These formations are dipping toward the Gulf of Mexico so that the upper tier of domes which have formed across northern Louisiana in an east-west direction into Mississippi and Texas have a salt source some 10 to 15,000 feet

Jan 1, 1976

By J. F. T. Agapito, J. B. Page

This paper describes part of a geotechnical study based on stress determinations and convergence measurements conducted to assess the long-term stability of an experimental room-and-pillar oil shale mine. A rock mechanics program was initiated in 1971 at the Colony Mine as part of a large study conducted for the design of a commercial operation. The Colony Development Operation is a joint venture currently consisting of four active members; Ashland Oil Inc., Atlantic Richfield Company (Operator of the project), Shell Oil Company, and The Oil Shale Corporation. Although oil shale commercialization plans are presently suspended, rock mechanics instrumentation has been continued as part of Colony's policy in maintaining readiness to proceed with a commercial shale oil plant when national energy policies became better defined. The property is located in the southern edge of the Piceance Creek Basin in northwestern Colorado, approximately 200 miles west of Denver. Experimental mining operations were conducted from 1965 to 1972 with one of the major objectives of the pilot mine being the assessment of opening and pillar sizes for the determination of extraction ratio and life of the property. Mining was conducted in a 60 foot thick portion of the Mahogany Zone in the Parachute Creek Member of the Green River Formation, at depths of 600 to 850 feet by a one-bench system. Pillar dimensions were 58 feet by 58 feet and rooms were 55 feet wide.

Jan 1, 1977

Controlled-blasting experiments in small development drifts were conducted at CANMET's Experimental Mine in 1992 and 1993. The objective of these experiments was to develop suitable controlled-blasting techniques for small development headings that are drilled by jackleg with 32-mm-diam holes. The experimentation was also aimed at providing insight into blast-damage mechanisms. Particular attention was given to the physical-mechanical properties of the rock and the rock-mass structural data. The drift faces were approximately 2.4 by 2.4 m (7.9 x 7.9 ft) in size with 36 to 43 holes drilled to a depth of 2.4 m (7.9 ft). Cartridged water gels, emulsions and semigelatin dynamite were used in the cuts and as primers, ANFO was used as the main explosive and decoupled 19-mm (0.75 in.) diam semigelatin dynamite charges were used in the perimeter holes. Smooth-blasting techniques and presplitting were tested in the underground mine. All of the blasts were monitored with a multichannel blast-vibration monitor, to which was attached sets of high frequency geophones and accelerometers. These experiments demonstrated the efficiency of controlled-blasting techniques for the reduction of blast damage and also demonstrated the need to improve the safety and efficiency of using explosives.

Jan 1, 1997

By Z. Eisenstein, H. Heinz

INTRODUCTION Contemporary underground transit systems often require cross sections which are not adaptable to shield tunnelling. Due to the frequently large dimensions of these cross sections, which are normally situated at shallow depths and in soft ground, full face advance is not feasible because of ground control and construction requirements. Ground deformation and face stability are controlled by "staged excavation", which consists of sequentially driving smaller, specially arranged, individual headings hence avoiding full-face excavation. Shotcrete is normally used for initial support and these tunnels are frequently described as applications of the New Austrian Tunnelling Method (NATM). Figure 1 illustrates the relative size of large cross section tunnels with respect to conventional shield tunnels. Within the scope of this paper, 'large' cross sections are defined as those whose continuous (i.e., without intermediate pillar support) cross sectional excavated area exceeds 60m2. This definition includes most double track highway, railway and subway tunnels, subway stations and some single track railway tunnels. Excavation schemes which have been more frequently used for continuous cross sections (i.e., with no intermediate pillars) are presented in Figure 2. This classification is an extension of that presented previously by Eisenstein et al. (1986). The symbols used for classifying the excavation schemes are formed by the letter T (for "type"), followed by a number, which represents the number of excavation stages fully embraced by a shotcrete ring, termed "cells" by Lessmann (1986). The numbers inside the cross sections in

Jan 1, 1989