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By Haydn H. Murray

The three major catalyst markets that utilize industrial minerals as raw materials are petroleum refining, chemical processing, and emission control. Because of economic, competitive, and regulatory pressures, catalyst producers are pushed to develop products with improved performance to meet changing environmental standards. Also, refiners are demanding new families of cracking catalysts that will crack residual fuels. In 1987, worldwide cracking catalyst sales amounted to $457 million (Occelli, 1988a). Recently enacted federal and state laws to improve air quality have prompted strong growth for environmental catalysts, which in 1989 accounted for more than a third of the $1.9 billion catalyst market in the United States (Farrauto, Heck, and Speronello, 1992). A catalyst is a material that promotes or enhances a chemical reaction but does not itself enter into the reaction. One of the more important mineral groups used as catalysts is clays. The first recorded use of clay as a catalyst was its use in the dehydration of alcohol (Bondt et al., 1797). Clay minerals that are used as catalysts are kaolinite, halloysite, smectite, palygorskite, and sepiolite. Minerals used as catalysts, catalyst supports, or as a raw material to make zeolites are kaolinite, halloysite, sodium montmorillonite, calcium montmorillonite, hectorite, palygorskite, sepiolite, talc, calcined kaolinite, gibbsite, chlorite, and titanium dioxide.

Jan 1, 1994

By A. C. Noble, D. E. Ranta

Orebodies with intricate three-dimensional shapes (such as porphyry molybdenum deposits) are difficult to model using geostatistics or other computer-assisted methods. The strong trends in their spatial grade distributions occur as mathematically complex shapes and prevent the customary assumption of local stationarity that is required for accurate ore reserve estimation. "Zoned Kriging", a new method developed by AMAX, solves this problem directly by using the geologist's interpretation of the ore zones as a parameter in the kriging equations. The geological basis and methods used in the Climax ore zoning technique are reviewed and discussed relative to their application in zoned geostatistical modeling. The Zoned Kriging technique is described and demonstrated using data typical of mineral deposits.

Jan 1, 1992

By Richard R. Klimpel

This paper reviews some of the factors involved in selecting amine flotation reagents used to remove silica from ores. A comparison is made between the chemical reagent design approaches used to identify flotation reagents that are used to recover silica- and oxygen-containing minerals and the chemical reagents used to recover sulfide minerals. This introduction gives practitioners who are involved with oxide- and carbonate-type minerals and who may not be familiar with sulfide mineral flotation some ideas of the chemical reagent design challenges that exist with froth flotation on a broader scale and why oxide type mineral flotation reagents are what they are. This is followed by several sections that discuss various classes of available amines. The closing sections emphasize that the optimal choice of an amine collector depends not only on that amine's specific chemical characteristics and costs but also on the operating conditions, especially the flotation feed particle size distribution.

Jan 1, 1999

By Winfield G. Wright, Philip L. Verplanck, Douglas B. Yager, Dana J. Bove, M. Alisa Mast

The upper Animas River watershed is affected by metal-rich drainage from abandoned mines and by natural weathering of mineralized bedrock. To investigate the importance of natural metal sources, surface waters were sampled in a minimally mined but intensely altered area of the watershed. Water chemistry was strongly controlled by the degree of bedrock alteration. Propylitically altered rocks, which contain calcite, produced neutral waters with low metal concentrations, whereas quartz-sericite-pyrite alteration was characterized by acid-sulfate type waters with high metal concentrations. A mass-balance approach was used to estimate natural metal sources, which accounted for 56-905 of the dissolved metal load discharging from the study area

Jan 1, 2000

By I. G. Ediz, D. W. Dixon, W. M. Fidler

In this paper a new method for the arresting of tunnel explosions is presented. In the proposed technique, the on coming explosion is detected by a pressure sensitive device by a pre-determined rise in static pressure. The sensor then triggers a mechanism which causes the explosion door to be closed in a specially constructed concrete barrier zone. The doors are of a special construction and consist of perforated steel plates that allow part of the blast wave to be transmitted but do not allow the passage of the flame. A number of design parameters have been identified, including: the likely amplitudes of the transmitted/reflected pressure waves that would govern the explosion door pressure loading; thickness of the perforated steel packages; perforation dimensions; heat transfer across the door and other factors.

Jan 1, 1995

By K. A. Natarajan, M. K. Yelloji Rao

The electrochemistry of sphalerite and chalcopyrite was investigated under both open-circuit and applied potential conditions. Emphasis was placed on the selective dissolution of sphalerite from a mixture of sphalerite-chalcopyrite flotation concentrates as a function of applied potential, acid concentration, pulp density, and time. Morphological studies using a scanning electron microscope (SEM) were also carried out with chemically leached, galvanically leached, and unleached surfaces of sphalerite and chalcopyrite. Selective dissoulution of sphalerite could be achieved if the mixed chalcopyrite-sphalerite concentrate slurry was maintained at a negative applied potential of -0.4V (SCE). Probable mechanisms involved in the selective dissolution of zinc are disscussed.

Jan 1, 1990

By R. Hogg, E. Kaya, H. Cho

Investigations were performed on fine grinding of bituminous coal in a laboratory-scale pulverizer. The results indicated that the breakage behavior at relatively coarse sizes (i.e., greater than about 20 µm) is essentially "normal." However, at fine sizes (i.e., less than about 10 m), there is clear evidence of reagglomeration. A simplified population-balance model for simultaneous growth and breakage is formulated. Breakage rates and breakage distributions were assumed to follow the patterns typically observed in simple grinding systems. It is recognized, however, that solid particles and agglomerates may exhibit different breakage behaviors. Agglomeration rates are assumed to be determined by contact probability, i.e., by the relative numbers of interacting particles. Based on comparisons between model simulations and experimental data, it appears that agglomerate rebreakage rates and fragment size distributions are quite different from those for solid particles. The result is that product size passes through a minimum and then increases with time as agglomeration begins to dominate.

Jan 1, 1998

By Michael G. Nelson, Dot J. Helm, Edmond C. Jr. Packee

Under a Section 319 Water Quality grant from the U. S. Environmental Protection Agency, a working group of government agencies, mining industry representatives, and University of Alaska researchers undertook reclamation of an abandoned mine site on Birch Creek, near mile 101 of the Steese Highway. Stream hydrology, water quality, and the extent and nature of natural revegetation, were measured before the site was then recontoured to decrease the bedload deposition and bank erosion of the streams. Methods for stabilization of streams and rivers appear to have much in common with those for locations further south, but are subject to complications unique to the North, such as the formation of aufeiss, and to a lack of accurate climatological data. Natural revegetation appears to be possible for most northern placer mine sites. However, it may take place more slowly than required by public perception. Preliminary data indicate a surprising lack of nutrients in the floodplains of mined areas. Natural revegetation may be enhanced by selective planting of grasses and willows, which will contribute variously to soil quality, bank stabilization, and short-term appearance. Monitoring of hydrologic and water quality data, and of natural and artificially placed vegetation will continue at the .Birch Creek site through the summer of 1995,

Jan 1, 1995

By S. Chander

The advantages and disadvantages of various techniques available for controlling reagents in the mineral flotation systems are discussed. Special interest is placed on potentiometric and voltammetric sensors for monitoring flotation pulps. Different approaches to increase the sensitivity of detection and to facilitate in-stream monitoring of solution species are also discussed. The potentiometric sensors are simple to use but are limited by the availability of an electrode reversible to the species to be monitored. In some cases the response signal could be unreliable due to the presence of interfering species. In comparison, voltammetric sensors require a higher degree of instrumentation which, however, provides an opportunity to decrease interferences and increase levels of detection.

Jan 1, 1993

By Shamsuz Zaman, Barry Hansen

The major development in the evolution of the conventional subaeration flotation machine has been the steady increase in the size of the individual units. In 1950, large machines were of 1.35 m3 (48 ft3) volume capacity. In 1989 the largest volume capacity operating is 85 m3 (3,000 ft3 ) These improvements have enabled the mining industry to operate successfully in the face of declining ore grades and adverse metal prices. This paper describes the design features and performance characteristics of a number of significant flotation machine designs.

Jan 1, 1989

By C. A. Wheeler

This paper presents the initial findings of a research program to reduce the annual equivalent costs of belt conveying systems. The work utilizes models to predict the motion resistance of belt conveyors that take into consideration the influence of key conveyor variables, such as idler roll diameter, spacing, troughing configuration and belt width. Given a specified conveyor configuration, the capital and ongoing costs of the system can then be approximated based on the required belt, idler rolls, structure, drives, etc. The research provides a computational means to rapidly analyze a large number of potential conveyor configurations and to compare each on an annual equivalent cost basis.

Jan 1, 2008

By S. K. Kawatra, C. A. Hardison, J. Gurtler, T. C. Eisele, K. Lewandowski

Acid soak tests were used to measure the effectiveness of binders in highly acidic conditions to determine their suitability for use in copper heap leaching. Soak tests involved placing the agglomerates on a screen, soaking them in a solution that replicates the pH of the raffinate used in a heap leach, and measuring the quantity of fine particles that passed through the screen. A wide range of binders were evaluated which had potential for functioning in acidic solution. Only a few binders were effective, with the best-performing binders being nonionic polymers designed for dust suppression applications. The most effective binder prevented all but 1.86% of the fines from being released and passing through the screen, while binderless agglomerates allowed as much as 29% of the fines to pass through the screen. The soak test developed for this study provides a useful method for rapidly identifying promising binders at a low cost, and for examining effects such as curing conditions on agglomerate quality.

Jan 1, 2005

By Michael D. Sopko

This paper describes the project implementation from financing, through the engineering and construction phases, mine and process plant commissioning as well as operating experience realized to-date. The single line flowsheet used to process the lateritic nickel ore to a 75 percent nickel matte is presented with emphasis on the main pyrometallurgical operations. These include a rotary dryer, a unique reduction kiln, a 45 000 kVA electric furnace and two Pierce-Smith type converters. Associated infrastructure facilities and services necessary to sustain the 11 300 tonnes (12 500 short tons) per year nickel production rate are also described.

Jan 1, 1979

By Poltak Sinaga

PT Kaltim Prima Coal's 13.1 km overland conveyor was commissioned in 1991. It is of conventional 3 roller 350 troughed belt type. Cost and performance optimisation during initial design ended up with 5.4m/s belt speed, 1,000mm belt width to convey 1,350tph, and 7mtpa of coal. Despite high initial figure, the belt speed was lifted to 6.5 mps in 1996 to accommodate mine throughput increase. In 2002, new low loss ST2100 1,100mm wide belt replaced the old ST2250 due for change-out. An upgrade project was initiated at the end of 2003 to further increase the belt speed to 8.5 mps, hence to increase the OLC capacity to 30mtpa. Performance data, experience of site personnel, site observation and tests, benchmarking, and information from equipment manufacturers were major inputs to the design review. The project fast track was another challenge in addition to executing modifications on a production lifeline. The project was completed within fifteen months and the OLC was successfully commissioned at 8.5 mps belt speed in February 2005. The OLC has been to date conveying 4200tph satisfactorily.

Jan 1, 2008

By Andre Vien, Frank Laroche, David Di Sandro

Back in 1994, Claude Bazin presented a novel method for linking size data from milling models to the feed input of flotation models. It was achieved with the simple addition of a metal/mineral distribution—size distribution relationship. This allows grade and recovery predictions from a varying mine plan via product size distribution predictions. This paper presents a case study where this elegant method has been used to build a very powerful forecaster at a process plant, built from historic operating data. The methodology has been used by this operation to forecast production on a quarterly, annual, and life-of-mine basis since the late 1990s. It has been upgraded several times to incorporate new drivers as the complexity of feedstocks has increased over the years.

Open pit optimization and mine design depend upon a realistic estimate of the grade-tonnage dis¬tribution. The estimate should reflect what can be reasonably recovered and processed. The McCoy/Cove operation in central Nevada is a gold and silver mine. Recoverable reserve estimations of gold and silver were made using indicator kriging and the indirect log normal variance correction to construct the grade- tonnage distribution. Optimal pits were generated using this distribution, and the results were compared to the pits generated by ordinary kriging and indicator kriging block mean methods. The results indicate that the proposed method for multimetal recoverable reserve estimation shows an improvement in terms of predicting the recoverable tons and grades. The optimal pits generated from the recoverable resource model are larger than those generated by the ordinary kriging and indicator kriging block mean methods. This model maximizes the overall recovery of the mineral resource.

Jan 1, 1999

By B. E. Dindsale, P. B. Altringer, R. H. Lien

The Bureau cf Mines, U.S. Department of the Intericr, is investigating biolcgical and chemical deccntaminaticn of cyanide- containing leachates and residues. Biolcgical cyanide cxidaticn, using bacteria isolated from a precious metals tailings pond, destroyed >85 pct of the cyanide in several prccessing solutions containing up tc 280 ppm CN. Reaction time varied from about 4.5 hr in a trickling reactor using quartz as a bacterial substrate to 2 mo in unagitated, covered flasks. Chemical techniques were used to destroy the remaining complexed cyanide down to 1 ppm. Exploratory tests were also conducted using spent ore from heap leach operations as the bacterial substrate to determine if biological cyanide oxidation could be used to destroy the residual cyanide in spent heaps.

Jan 1, 1991

By James J. Guesk, Robert W. Reisinger, Timothy C. Richmond

A high-altitude (2,900 m [9,500 ft]) historic underground copper mine in Wyoming is discharging copper-laden water with a neutral pH into an otherwise pristine creek. The Wyoming Abandoned Mine Land program is reclaiming the site under a CERCLA deferral agreement. The clean-up goal is to reduce copper in the mine discharge so that the creek can eventually support a trout fishery. A pilot-scale passive treatment test utilizing sulfate-reducing bacteria has been conducted at the site beginning in summer 1997. Test results show significant reduction in copper concentrations in near-freezing mine water at flow rates ranging to 19 liters per minute (5 gpm)

Jan 1, 2000

By Edward Donovan, Bryan Knott, R. E. Melley, O&apos

South Bulga Colliery, located near Singleton in the Hunter Valley region of Australia, began longwall production in late 1994. The mining conditions there are conducive to high productivity with good roof conditions and a shallow seam with production areas located close to the portal. When the longwall was commissioned, the low capacity and availability of the conveyor system greatly curtailed the mine's productivity. A number of changes were made to the conveyor system culminating in a drive change out to improve the system. Using South Bulga as a case study, this paper aims to demonstrate the absolute necessity of a reliable, high performance conveyor system for the viability of a mine, and some of the factors that are needed to ensure a conveyor system performs as intended. These factors include a thorough understanding of the individual components and how they influence and interact with each other; a system design that is tolerant of variations in component performance and the necessity of robust and reliable communications and PLC programming.

Jan 1, 1996

By John G. Reid

Geologists, employed by the Australian Company, Metals Exploration Limited, discovered nickel laterite enrichment at Greenvale in 1967. A joint venture was arranged with the Freeport Minerals Company who had gained early experience with nickel laterite ores when building and operating the Nicaro and Moa Bay Treatment Plants in Cuba. A 5 tonne/day Pilot Plant at the Freeport research facilities at Belle Chasse, Louisiana, verified the amenability of the ore to treatment by the reduction and ammonia-ammonium carbonate leaching process used at Nicaro. A 5 800 tonne/day Treatment Plant was constructed on the coast at Yabulu, North Queensland. This paper describes the ore body, the mining operation and the stages of treatment required to produce nickel oxide products and a mixed nickel/cobalt sulphide product at Yabulu.

Jan 1, 1979