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By Cyril Wells, Robert F. Mehl

THE two earlier papers in this series1,2 presented data on the rate of diffusion of carbon and of manganese in gamma iron. Apart from their scientific interest, these [] data are needed chiefly in order to treat data on carburization, on the rate of formation of pearlite, and on the rate of austenizing in a quantitative way. 1,2,9,10 In the present investigation rates of diffusion of nickel in -?-Fe over wide temperature and concentration ranges have been determined, and the effects of carbon, of impurities, and of grain size on these rates have been studied. Claussen,3 using the data of Fry,4 has calculated the diffusion coefficient of nickel [ ] in -?-Fe as 9.2 X 10-11 sq. cm. per sec. at 1200T., but had no data from which to calculate the variation of D with concentration, temperature, and percentage of carbon. METHOD AND MATERIALS Method.-Nickel was diffused along the axis of a cylindrical specimen across a concentration gradient, concentration-penetration curves were determined and D values calculated from Grube or Matano solutions.5 Details of the method are given

Jan 1, 1941

By J. Gordon Parr, G. R. Purdy

The phase boundaries of "TiNi" have been accurately determined by high-tewperature X-ray diffraction and metallo-graphic techniques. The phase (centered at 51 pct Ni) has a restricted range of homogeneity at 500°C, and a much greater range at 800°C. "TiNi" in all alloys containing less than 51 pct Ni decomposes rapidly and reversibly at 36°C to form a previously unreported phase. ThE region of the titanium nickel system corresponding to the phase "TiNi" has been the subject of several investigations.1,2,4-7 Laves and wallbaum1 reported "TiNi" as a body-centered cubic (a2) Phase, and Duwez and Taylor2 determined its para- meter to be 2.986. Duwez and Taylor also reported that "TiNi" decomposed into "Ti2Ni" and "TiNi3" on prolonged heating at 650" and 800°C, which led McQuillan3 to suggest a sluggish eutectoid reaction between "TiNis" and "Ti2Ni". Margolin, Ence, and Nielsen,' working with higher purity alloys, found no evidence of this decomposition. They showed the "TiNi" phase region extending from 49 to 54 pct*

Jan 1, 1962

At the Gateway Coal Co.'s mine, about 70 miles above Pittsburgh's Point on the Monongahela River, a battery of television cameras stands guard over what is billed as the longest conveyor belt system ever installed in a coal mine. In all, this system consists of 9% miles of 42- in. and 48-in. wide belting, and is capable of transporting 500 tph at a speed of 625 fpm from working face to the tipple located outside the mine. Gateway Coal, located near Waynesburg, Pa., is owned jointly by Jones & Laughlin. Steel Corp. (64% %), Pittsburgh Steel Co. (22lh%), and Shenango Inc. (13%). Managed by J & L, the mine is under a long-term lease from the Hillman Coal and Coke Co., which formerly operated it as the Emerald mine. Hillman produced 700,000 tons per year of metallurgical-grade coal from this mine, but since J & L et al. took over in 1962, annual output has increased to 1.7 million tons. Mine capacity will reach its peak early in 1964 when total production hits an annual rate of 3.1 million tons.

Jan 7, 1963

By R. E. Maringer, A. Schwope

IT has been recognized that oxygen in minute quantities is extremely detrimental to the room-temperature ductility of molybdenum. Early fracto-graphic studies' of the cast metal indicated that oxides are formed preferentially at the grain boundaries. Additional verification of this preferential segregation has been obtained from internal friction studies on poly crystalline molybdenum (average grain diameter varied from 0.039 to 0.065 mm) and from observations of the effect of oxygen on specimens of extremely large grain size. Specimens A, B, and C, of 0.040 in. diameter commercial molybdenum wire (Lot FW 13-40) were heat treated in the vacuum furnace described by Few and Manning according to the specifications given in Table I. Internal friction studies of these specimens were carried out using a low frequency (approximately 1 cycle per second) torsional pendulum completely enclosed in a vacuum tank. As the pressure of oxygen in the heat treating atmosphere changed, the portion of the internal friction vs temperature curves ascribed to grain boundary relaxation changed correspondingly, Fig. 1. The decrease in the damping capacity at high temperatures as the pressure of oxygen in the heat treating atmos-

Jan 1, 1955

By Ossi E. Palasvirta

The authors are to be congratulated for their interesting article, which thoroughly illustrates the variables inherent in filtration of taconite concentrate. The work and the conclusions based thereon largely parallel the test work done by the writer at the Pilotac plant* and the experience gained with a commercial size agitating disk filter in the same plant. At Pilotac, however, a thorough study was also made of the effect of depolarizing (demagnetizing) the filter feed, and it is the purpose of this discussion to comment on the merits of depolarization of the magnetite concentrate prior to filtering. The work at Pilotac was done in three phases: 1) preliminary laboratory testing with a circular filter leaf of 0.047 sq ft, followed by 2) plant testing using a 4-ft diam, single-disk agitating filter that was purchased on the basis of the pilot tests on the 4-ft model. In the laboratory tests depolarization was achieved by slowly withdrawin4 batches of thickened concentrate from a coil producing an alternating field of about 300 oersteds. In plant tests the standard Pilotac procedure1 was employed, wherein the pulp falls freely through the depolarizing coil.

Jan 5, 1958

By Harmon E. Keyes

Harmon E. Keyes (Chemical & Metallurgical Engineer, Eagar, Ariz.)-Chemical dissolution of chalcocite by acidic ferric sulfate is well known. Resulting elemental sulfur may be oxidized to sulfuric acid by heated ferric sulfate. Laboratory tests at Southwest Experiment Station, USBM, Tucson, generally confirmed stoichiometric relations of 1 part Cu dissolved to 1.750 parts ferric iron reduced, using CP chemicals, dried ore samples, and apparatus cleaned with potable water. Recirculation with open-drainage percolation to increase copper in leaching solvent was followed successfully when appropriate, both in laboratory and Pinto Valley pilot tests. Before 1924 attempts to produce ferric sulfate by aerating ferrous sulfate solution were known. Initial oxidation was satisfactory, but rate slowed below practicality as oxidation progressed and acidity increased. Also, due to hydrolysis of ferric sulfate, a ferric precipitate of hydroxide and basic sulfate resulted. Both laboratory and pilot plant tests gave similar results, regardless of whether CP ferrous sulfate or scrap iron cementation discard solution was used. Rapid oxidation of ferrous hydroxide by air alone is well known to analytical chemists. I demonstrated a process to produce acidic ferric sulfate solutions by precipitating ferrous hydroxide with milk of lime, aerat-

Jan 1, 1973

By A. U. Seybolt

DURING the course of an investigation of hot corrosion of nickel-base superalloys (combination oxidation-sulfidation attack at high temperature), it was considered possible that sulfur might gain entrance to the alloy in part, at least, by diffusion through the scale. Cr203 is nearly always observed as a prominent component of the oxide scale, and hence some experiments were carried out to examine the tracer diffusion of sulfur through Cr203 at 1000° C in the upper temperature range experienced by jet engine blades and vanes. Some hot-pressed Cr203 discs of quite high density were available from an earlier investigation1 on the rate of crf3 migration through Cr203. The Cr203 was 99.3 pct pure and contained -0.06 pct Fe as the largest metallic impurity. Additional data is given in Ref. 1. In this earlier work it was found that the rate of cation diffusion was independent of the atmosphere of thermal equilibration when using nitrogen, argon, or air, and also that the electrical conductivity of the hot-pressed Cr203 compacts was likewise independent of atmosphere in this range, thus indicating that the de-

Jan 1, 1969

Servicing School Opening of a special factory training course in servicing earthmoving equipment is announced by the Euclid Road Machinery Co. Four [ ] beginning and four advanced one week training courses will be offered to representatives of distributors and customers. Circle No. 1 Core Drill The new Acker "Teredo" core drill, is named after the "boringest little animal in the world" to underline its function as a light, compact, portable core drill capable of depths to 600 ft. While light enough to be truck or jeep-mounted, it offers the combination of a three-speed totally enclosed transmission with either hydraulic or screw feed drill heads. Full 24-in. travel gives maximum footage per shift, 360° rotation permits freedom of hole location, a transmission mounted cathead winch is used in pulling rods and casings, and a power take-off is provided for a pump. Circle No. 2 Plastic Pipe Planned production of both flexible and semi-rigid plastic pipe is announced by Triangle Conduit & Cable Co. Rigid and high-impact pipe will be added to the line later. Three types: non-toxic, industrial, and suction, are being made and in sizes from 1/2 to 6 in. Circle No. 3

Jan 1, 1952

By T. V. Subrahmanyam, A. P. Rao

The adsorption behavior of chalcopyrite has been studied at different xanthate concentrations and flow rates in a column apparatus with potassium ethyl xanthate as the collector. Based upon the experiment results an equation of the type: 1/F = K3 + m3C + k2/t.Cm2.fm1 is proposed to account for the experimental data. Among copper minerals an early study on chalcocite by Gaudin and Schuman (Taggart, 1951) is well known for its research on the kinetics of the reaction by conventional method of mass balance between the products of reaction and xanthate consumed. The results were interpreted by the concept of ion exchange adsorption. Szeglowski (1977) conducted measurements on the adsorption of potassium ethyl xanthate on copper polarized to various potentials, the adsorption being measured by radio-tracer techniques. The adsorption in the range -1800 to 700 mv was found to be a reversible physical adsorption. The potential range in which the primary electrode process could lead to surface coverage with a minimum number of product layers was evaluated. The adsorption density of xanthate on sulfide surface was found to be related to the concentration of xanthate in solution and concentration of depressants as: [ ]

Jan 1, 1983

A list of publications of the United States Bureau of Mines, complete from its establishment to the end of June, 1931, may be had upon request. In addition a monthly leaflet of new publications is issued and is sent to those on the mailing list of the Bureau. Publications are separated into three main divisions: 1. Sales Publications.-Those for which a charge is made. Any orders or remittances in payment for sales publications should be sent directly to the Superintendent of Documents, Government Printing Office, Washington, D. C., and not to the Bureau of Mines. Sales publications are classified into (1) Bulletins, (2) Technical Papers, (3) Economic Papers, (4) statistical reports of the mineral resources of the United States, (5) Monographs, (6) Handbooks, and (7) Schedules. Bulletins and Technical Papers present the results of scientific and technical investigations. Economic Papers are analytical studies of production statistics, sources, resources, .distribution, and industrial flow of mineral commodities. The Annual Report, entitled "Mineral Resources of the United States," includes chapters, published separately, on the production and consumption of metals and of nonmetallic minerals. Monographs give detailed results of extensive cooperative investigations of special

Jan 1, 1933

Established as Mining, Geology and Geophysics Division, Sept. 27, 1949 Name changed February 19, 1958 Robert J Lacy, Chairman John G Hall, Assistant Chairman Vice-Chairmen Peter Joralemon, Membership J M Ehrhorn, Program John C Wangaard, Publications A W Ness, Secretary American Smelting & Refining Co 600 Crandall Building Salt Lake City 1, Utah

Jan 1, 1960

By R. C. Mahon

Operators concerned with the destruction of their piping by acid mine waters will be interested in the method by which this problem was solved at the Cardiff mine of the Homer group. Rubber lined, or acid resisting metal pipes were found too expensive. Casting concrete lining in pipe would have required a minimum thickness of one inch, thus excessively reducing the pipe's diameter, as well as taking twenty four hours per length of pipe. The Naylor Pipe Co. of Chicago, having experimented with centrifugal lining of pipe with concrete, provided information which eventually solved the problem. An experimental plant was constructed as shown, and the following procedure developed : (1) Kerosene is used to remove the interior oil coating of new pipe. Closed with blank flanges, the pipe is revolved for eight minutes at varying speeds. Stopping and starting the motor achieves a good washing action. The kerosene is then drained off, and similar washing action with caustic soda removes any excess. Swabbing in done with burlap fastened to a 1/2-in. pipe. (2) The aggregate, made of one. part quick-setting cement and two

Jan 1, 1949

By E. C. Reed

Oil was discovered in Nebraska on Nov. I, 1939, when the Pawnee Royalty Company's Boice No. I well, about 3 miles west of Falls City (NE 1/4 NE 1/4, sec. 18, T.r N., R.16 E., Richardson County) was drilled into the Hunton formation but the develop-ment of the area took place during 1940. After a pumping test lasting 18 days, the Boice well stopped producing and failed to qualify for the State bonus of $ 15,000 offered for the first oil well to produce go bbl. per day for 60 consecutive days. On May 9, 1940, the Pawnee Royalty Company's Bucholz No. I well was completed about M mile southeast of the discovery well and flowed at the rate of about 330 bbl. per day, easily meeting the State bonus requirements. In addition to the discovery well, which later was reconditioned, and the bonus well, 28 producers were drilled in the Falls City field during 1940. Of these wells, 23 are in sec. 20, two are in the northern part 'of sec. 29, two in the southwestern part of sec. 17 and three in the eastern part of sec.

Jan 1, 1941

By E. C. Reed

Oil was discovered in Nebraska on Nov. I, 1939, when the Pawnee Royalty Company's Boice No. I well, about 3 miles west of Falls City (NE 1/4 NE 1/4, sec. 18, T.r N., R.16 E., Richardson County) was drilled into the Hunton formation but the develop-ment of the area took place during 1940. After a pumping test lasting 18 days, the Boice well stopped producing and failed to qualify for the State bonus of $ 15,000 offered for the first oil well to produce go bbl. per day for 60 consecutive days. On May 9, 1940, the Pawnee Royalty Company's Bucholz No. I well was completed about M mile southeast of the discovery well and flowed at the rate of about 330 bbl. per day, easily meeting the State bonus requirements. In addition to the discovery well, which later was reconditioned, and the bonus well, 28 producers were drilled in the Falls City field during 1940. Of these wells, 23 are in sec. 20, two are in the northern part 'of sec. 29, two in the southwestern part of sec. 17 and three in the eastern part of sec.

Jan 1, 1941

By A. C. Dorenfeld

CHANGES in circuits are often made in milling operations. At the same time that these changes are being evaluated the ores are changing. Even from the same mine, the ore is usually variable as to amount and type of mineral content, degree of association of valuable and gangue minerals, amount and types of soluble salts, hardness, etc. The question then arises whether any small differences in results, after changes have been made in the various circuits, are really due to these changes or whether the variability of the ore can account for those differences. Statistical evaluation provides one method of answering the question that arises so often in beneficiation studies: Did changed results come about because of changed process, or did ore variation cause the change? In this case, data were available for statistical analysis from an operating period of 42 months, representing treatment of approximately 1 million tons of ore. During this period there had been two flowsheet changes: 1) regrind of the zinc circuit middlings was introduced, and 2) alcohol- pine oil frother mixture was substituted for cresylic acid-pine oil frother mixture. Findings are in Table I.

Jan 10, 1954

I strongly endorse Mr. Jackson's (Inland Steel Company) oral comment on the authors' paper that, as blast furnace slag is removed from the BOF charge, lime solution may be retarded. After two or three pourings, the blast furnace slag will contain some iron oxide and considerable manganese oxide, and it is hot and possibly still liquid. A few thousand pounds of this slag will speed up the slag development rate considerably and could be considered a good auxiliary flux. Although the removal of blast furnace slag from the BOF charge lowers the total sulfur load by 40 to 50%, we must have a good, quick slag development in the BOF to bring .030 to .035% sulfur hot metal to .020%, a requirement on a high percentage of our steels today. In discussions at off-the-record meetings and one not published at last year's annual meeting as well as discussions with many operators over the past 1-1/2 years, I predicted that the removal of blast furnace slag could slow down lime dissolution and that, if a shop had dissolution problems before, the problem could be quite serious.

Jan 1, 1972

By J. W. Downey, M. V. Nevitt

DURING the course of the present investigation of alloy phases involving transition metals, phases were found in the systems Os-Ta, Os-W, and Ir-Ta. The (Os, W) phase was also recently reported by Raub.1 Pertinent information is given in Table 1. The approximate composition range of sta- bility was determined metallographically on arc-melted buttons that were annealed 72 hr at 1200°C and water quenched. X-ray powder patterns were obtained with a 114.6 mm diam powder camera using filtered copper radiation. The composition for (Os, W) given by Raub (66 atomic pct W) is in agreement with the composition range reported here. However, the lattice constants reported by Raub are: a0= 9.913±0.007, c/a= 0.515. The reason for the discrepancy between the lattice constants reported by Raub and those given here is not known. Acknowledgments The authors wish to thank M. H. Mueller and H. W. Knott for assistance with the X-ray diffraction work, and R. A. Morris for the preparation of the alloys. This paper is based upon work performed at the Argonne National Laboratory under the auspices of the Atomic Energy Commission.

Jan 1, 1958

By L. D. Jaffe, D. C. Buffum

EARLY papers1-' reported that temper brittleness is influenced by microstructure. This conclusion was based on room temperature impact tests, the inadequacy of which has been pointed out. Pellini and Queneau7 measured impact energy absorption at —80O to +25oC for several microstructures. On the basis of the shift, associated with temper brittleness, in the energy vs testing temperature curve they concluded that tempered martensite is somewhat more susceptible to temper brittleness than is tempered pearlite. The range of temperatures was insufficient to give complete curves covering the transition from tough to brittle behavior, so it is difficult to evaluate quantitatively the shift for the different microstructures. Also, the smaller shift of pearlite might be attributed to its already being temper embrittled at its temperature of formation. Accordingly, blanks 2 3/16 in. long were cut from a heat of SAE 3140 hot rolled steel barstock, 5/8 in. diameter, on which other work has been reported? A set of blanks was austenitized 1 hr at 900°c, water-quenched, tempered 16 hr at 675oC, and water-quenched, giving a microstructure of 100 pct

Jan 1, 1954

By I. H. Warren, E. A. Devuyst

The selective dissolution of pyrolusite (MnO2) in presence of goethite (FeO•OH) in aqueous ammoniacal ammonium carbamate solution has been investigated: various reducing agents were studied, in particular sodium sulfite (Na2SO3,) and hydrazine hydrate (N2H4•H2O). Sodium sulfite was found to be an unsatisfactory reducing agent for both goethite and pyrolusite, for the leaching rate decreased steadily with time to an impractical level because of the limited solubility of the reactions products. Hydrazine hydrate was an effective reducing agent for pyrolusite even at low temperature, whereas goethite required much higher temperatures for any appreciable dissolution. A 1-hr leach at 35°C dissolved 90% of the pyrolusite but only 0.1% of the goethite. An activation energy of 17.0 Kcal per mole was found for the dissolution of pyrolusite with hydrazine. A reaction mechanism for the leaching of pyrolusite with hydrazine is proposed in which a reduction reaction on the surface of the mineral is the rate-determining step. The application of ammonium carbamate to the beneficiation of ilmenite is briefly described.

Jan 1, 1973

By Raymond Dugdale, Fathi Habashi

There has been a recent interest in studying the action of anhydrous sulfur trioxide on ores to convert the metal values into a water-soluble form as a substitute for leaching by sulfuric acid. For example, Svenke1 converted the small amounts of uranium in slate ash into a water-soluble form by treating the material with SO, at about 600°C. Chao and Sun found that a variety of aluminum-bearing minerals could be sulfatized by SO, in the temperature range 400° to 600°C usually in the presence of a catalyst such as sodium sulfate. Kruse3 patented a process for beryllium recovery from the low grade ore in Utah by first reacting it with SO, at 560° to 750°C then leaching the product with water. In the present report, the action of SO, was examined in the temperature region 100°-300°C which was not investigated by those workers. Experimental Tests were conducted on a beryllium ore sample from Utah, the analysis of which is given in Table 1. It corresponds closely to a saponite ore type as given by Crocker et al. It was in powder form 45% passing a 400

Jan 1, 1973