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By T Perera, B Fan, S Thang, T Hsia

The mining industry is currently focusing to develop and adopt sustainable collector chemistry that can efficiently recover valuable minerals from their natural state. However, a limited number of research can be seen on the design and synthesis of polymeric flotation collectors. The focal objective of this research is to synthesise a more effective polymeric collector with advanced architecture to utilise in the mineral processing industry. Reversible Addition-Fragmentation Chain Transfer (RAFT) co-polymers with cardanol derivatives have the potential to selectively trap valuable metals in the flotation process in a more efficient way. Cardanol exhibits amenability to chemical modification for making tailor-made monomers that can further produce polymers with high value. The synthesis of a series of fit for purpose copolymers in this study was accomplished by RAFT polymerisation. The ability to design complex architecture is a significant advantage in engineering polymeric collectors by RAFT polymerisation. Initially, commercially available cardanol was converted to a cardanol based monomer and copolymerised with commercially available monomers to synthesise a series of novel cardanol based copolymers with predetermined molecular weights. The side groups of the copolymer were chemically modified to incorporate functionality that can be selectively adsorbed on the chalcopyrite surface.

Aug 24, 2022

Commercial or potentially commercial deposits of coal occur in Australia in strata ranging in age from Permian to Tertiary. The coals of each period tend to show a community of petrographic character and significant differences as compared with coals of other ages. In particular- many of the Permian coals are unusually rich in inertinite whereas the Jurassic and Tertiary coals are typically very rich in vitrinite. The majority of the coals show evidence of deposition in environments subject to relatively minor marine influence. Except for some Tertiary and Permian coals the content of mineral matter tends to be high. Outcrops of coals of bituminous rank appear to be largely restricted to the eastern margin of the Australian continent. In this region vertical rank gradients are generally higher than in the other sedimentary basins and uplift and the removal of cover has occurred to a greater extent. To the west of the Tasman geosyncline, coal of bituminous rank generally occurs at considerable depths (usually in excess of 1 km and in some areas only at depths of over 2 kms), and in most areas coals at shallow depth are of sub-bituminous or brown coal rank. The controls of the distribution of coal type and rank have considerable economic significance and the unusual characteristics of Australian coals, especially with respect to coal type, make the direct application of overseas technology to Australian coals inappropriate.

Jan 1, 1975

Newmont Australia Limited has for some 15 years mined a number of large open cuts associated with the Telfer Gold Dome deposits. The principal ore body exploited has been the East Flank of the Main Dome where a very high grade gold reef deposit of mixed metal sulphides, grades in excess of 20gA Au, has been mined in conjunction with dissemi- nated mineralisation contained in the overburden material. The main ore body has been under review for some years as an under- ground mine, however due to the ore body widths of less than 1 metre and a dip generally less than 35 degrees and a very weak host rocks earlier studies all resulted in a continuation of open pit mining activities. In early 1988 it was recognised that open cast mining would not be able to mine all of this valuable resource and a feasibility study was commenced to come up with a practical and economic approach to underground mining.

Jan 1, 1991

Backfil ling of excavated Sub Level Open Stopes has been underway since March 1989 and as at December 1992 some 1 100 000 cubic metres of Cemented Aggregate Fill have been placed. During these three years significant developments in fill quantities, types and cost have taken place.Operational improvements have reduced the quantity of Cement Aggregate Fill by 40 per cent. These results have been achieved by:ò rescheduling stopes,ò designing smaller primary stope, and ò use of uncemented rockfill.Unit cost for Cement Aggregate Fill have fallen in the order of 50 per cent through:improving fill hole reli ability,simplified barricade construction procedures, reducing the cement content,ò substituting dune sand for deslimed mill tailings, ò improved maintenance at the Backfill plant, and ò renegotiated site freight agreement.This paper will review the historical developments of backfill use at Olympic Dam.

Jan 1, 1993

By M Wortley, J McKay, D La Rosa, O Guyo

It has been a generally held concept that crushing operations were, by their nature, too simple to benefit from the implementation of advanced process control. The commissioning of an OCS¬ expert control system and image-based oversize detection system, VisioRock, at the Pilbara Iron Tom Price facility are dispelling these notions. A constraint-based OCS¬ expert control system has been designed and commissioned on the high-grade crushing and screening plant along with a vision-based oversize detection system functioning on six product conveyor belts. To date, the expert control has demonstrated the ability to increase production by maximising dynamic constraint utilisation. Dynamic constraint utilisation is a concept developed by Rio Tinto Technical Services for effectively evaluating constraint-based control logic performance. The VisioRock system has been installed and configured and has been operating for a period of several months. Currently, Tom Price and Metso personnel are working to define correct oversize detection thresholds. Details of the plant implementation are discussed.

Jan 1, 2005

By Sano S, Ishikawa T, Nagaoka H, Hayashi Y, Hasegawa M

The stirred mill is regarded as one of the most efficient devices for micronising materials and has come to be actively used for preparation of fine particles. Recently, the demand for ultrafine particles was increased in many kinds of industries. In this paper, autogenous grinding to get submicron particles based on mutual friction feed material has been carried out using a stirred mill. The mill used was made of stainless steel and its volume was about 5.5 litres, and has 12 impeller blades. Sample used was limestone. In the present work, two operating parameters such as stirring speed and feed size of limestone were considered. The ground products were sieved in the size range from feed size to 325 mesh (45 lun), and from 45 to 0.17 pm the size distributions were measured by a laser diffraction and scattering method. The progress of grinding was evaluated by the increasing amount of submicron particles in products. As a result, the rotational speed of impeller with the minimum energy consumption to produce submicron particles was observed. It was found that the autogenous grinding with a stirred mill is an effective method for producing submicronized limestone.

Jan 1, 1993

Cyanide-extractable gold is far more meaningful in the definition of ore, and control of extraction, than fire- assayable or aqua regia digestible gold. The use of cyanide- extractable gold addresses the significant problems of over- as well as under-assaying by fire and aqua regia digests. The problems of conventional control or diagnostic cyanidation extractions: lengthy extraction, and masking by pregrobbing in cyanidation extractions for assay purposes; are surmounted with a novel activator - Leach WELL. Full extraction of liberated gold, insignificantly affected by preg-robbers, can now be achieved within 30 minutes. This can assist in reducing common gold losses presently often hidden by inappropriate mine call factors, and/or high grade cut values. This paper includes a discussion of fundamental mechanisms of cyanidation, preg- and assay-robbing, which underlie the phenomena Involved.

Jan 1, 1992

In recent years, the. art of electric steelmaking has received a great deal of attention, and naturally, much controversy has existed from time to time regarding the relative merits of different practices and tywes of furnaces. Nevertheless, at the present time, the basic principles of the process are reasonably well established, and by far the greatest percentage of electric steel is a product of the basic lined, direct arc type furnace. Ferro alloy manufacture has demanded the development of furnaces having very different characteristics to those used for steel. Some special alloys, however, require conditions of manufacture which are more closely approached in the steel type furnace, and thus the latter has been adapted where necessary for the production of these alloys.One such alloy, low carbon ferro-manganese, is manufactured at Whyalla, South Australia, in a basic-lined, direct arc furnace, which is used alternatively for the production of alloy steels.BRIEF HISTORY OF THE ELECTRIC FURNACEThe principle of melting by electricity was first applied to the melting of iron in 1879 by William von Siemens, whose equipment consisted of a small crucible into which were introduced two carbon electrodes. Very little practical development took place in the next 20 years, although in 1890 a Frenchman named Heroult designed a direct arc furnace for the production of ferro alloys. At the beginning of the 20th century, several types of furnaces were patented for steel melting, the most important of these being the Heroult, using a direct arc, the...

Jan 1, 1951

By G Brooks

The control of phosphorus in steelmaking is one of the famous challenges of pyrometallurgy. It is well established that highly basic slags, the presence of FeO in the slag and lower temperatures (less than 1650°C) are favourable for phosphorous removal. The thermodynamics of this reaction have been extensively studied under laboratory conditions and the general trends confirmed through industrial trials. However, in general, phosphorus slag/metal distributions measured in industry are far from equilibrium and quite specific to the oxygen steelmaking technology being used. This variability was quantified by Urban, Weinberg and Cappel (2015), who found that the phosphorus partition ratio measured in plants varied with blowing practice, stirring intensity and even converter life. Some recent kinetic studies by Gu, Dogan and Coley (2017) have shown how the kinetics of these reactions vary with FeO content and dissolved sulfur at the droplet scale. A global kinetic model by Rout et al (2018) provides meaningful predictions of where dephosphorisation occurs in an industrial basic oxygen furnace (BOF) and some recent heat transfer modelling by Madhavan et al (2021, 2022) implies that temperature difference between droplets and slag has a role to play in explaining why equilibrium is not achieved. This paper will review the current state of knowledge and provide suggestions on predicting phosphorous removal for industrial operations and how greater removal could be achieved.

Jun 19, 2024

By Laros T, Schoenbrunn F

Deep paste thickeners have been proven capable of consistently producing medium to low slump material for disposal without the need for filters. However, proper design of the entire system is critical for a paste project to he successful. Some of the factors that must be carefully considered in design of a paste system include thickener sizing, tailings inipoundineni design, underflow pumping, and control system.

Jan 1, 1998

By T Y. Ko, Y S. Kang, S J. Park, J H. Hwang

The lunar subsurface, particularly the lava tubes formed by ancient volcanic activity, presents a promising environment for establishing safe and sustainable human habitats on the Moon. Tunnel Boring Machines (TBMs), widely used for excavating tunnels on Earth, offer a potential solution for developing these subsurface spaces. However, the unique lunar conditions, including extreme temperatures, high vacuum, radiation, and the extraordinary strength and abrasiveness of lunar rocks, necessitate significant adaptations to existing TBM technology. This study investigates the feasibility of utilising TBMs for lunar subsurface exploration and base construction, addressing the challenges posed by the harsh lunar environment. We review previous conceptual designs for lunar TBMs, highlighting their strengths and limitations in addressing these challenges. Additionally, we explore innovative excavation methods, such as microwave-assisted rock weakening and undercutting techniques, to enhance the efficiency and effectiveness of lunar TBM operations. By evaluating the geological characteristics of the lunar crust and analysing the potential of lava tubes as launching points for TBM operations, this study provides a comprehensive assessment of the technical requirements and operational considerations for lunar TBM implementation. The findings of this research contribute to the growing body of knowledge on lunar base development and pave the way for future human exploration and utilisation of the Moon’s subsurface resources.

Sep 1, 2024

AT Broken Hill, N.S.W., where flotation is tbe final stage in concentration, the gangue minerals are discharged as an aqueous pulp, and water recovery from the pulp being essential, provision must be made for the clisposal of the solids and for the return of the clear water to the cemcentrating mill circuit. This water also contains an appreciable quantity of flotation reagents, and is more effective for flotation than supply water.In the development of a scheme for the disposal of large quantities of residues, several of the more important factors for consideration are:(a) Tonnage to be handled.(b) Grain size of residues and pulp density.(c) Dewatering of residues and return of clear water to mill circuit.(d) Possible uses of residues.-A varying proportion of sand residues is used for underground filling, and to a limited extent for yoncrete making and other engineering work.(e) Choice of a suitable dumping area. - Before deciding upon this area consideration will be given to possible future operations so that the dump will not be likely to interfere with any development which may be necessary. Again, residues dumped at the present time as worthless or...

Jan 1, 1927

By M D. Urbani

HiTec Energy Ltd has been conducting research since 1996 into novel process routes for the treatment of low-grade and waste manganese sources for the production of high value and high quality electrolytic manganese dioxide (EMD) for the alkaline battery market. HiTecÆs approach is to treat previously unsaleable manganese deposits and mine site tailings using a novel sulfur dioxide leach route, followed by purification and electrowinning to generate the sought-after EMD product by an environmentally superior processing route to those presently practiced throughout the world today.HiTec Energy Ltd expects to be in commercial production with its Stage 1 facility in Kalgoorlie in the last quarter of 2004 for the production of 12 500 tpa EMD. With this production facility being adjacent to a laterite nickel producer with available waste manganese units, the opportunity arose for HiTec to combine its existing technologies with processes (that will be discussed in this paper) to turn two waste by-products into products that are used for high-tech purposes.HiTec Energy Ltd and the Parker Centre have had a collaborative research relationship for a number of years in areas involving EMD and battery related technologies. Meanwhile the solvent extraction (SX) group of the Parker Centre (CSIRO Minerals) has developed SX processes to separate manganese from nickel and cobalt. A project was initiated by HiTec Energy to recover manganese from waste laterite leach solutions using SX technology. Batch tests were conducted to select a suitable organic system for the extraction of manganese in terms of selectivity and extraction and stripping kinetics.A total of eight organic systems were tested by determining pH isotherms of metals using a laterite nickel process waste stream. Two organic systems, the Versatic 10 and Versatic 10/synergist systems, were chosen for further test work with Shellsol D70 chosen as the diluent for both systems.The Versatic 10/synergist system would be advantageous over the pure Versatic 10 system because fewer SX stages are required, resulting in a smaller organic inventory and lower capital costs. The risk of gypsum formation is also significantly lower with the synergistic system.

Jan 1, 2004

By J C. de Vries

When times are tough in the mineral industry û as they have been for some time û typical responses by mining companies are to cut costs and/ or increase production. The latter is seen to spread fixed costs, thereby also reducing unit costs per tonne mined. However, most mineral deposits respond to increased production rates by lowering ore grades, so the reduction in cost per tonne of ore does not necessarily result in a reduced cost per unit of metal produced. The authorsÆ experience is that this process often leads to a mine plan that is a long way from optimal. Producing to the point where marginal cost equals marginal revenue may work well in a manufacturing operation, but it is not necessarily the best strategy for a mining company with a depleting resource. Variations in tonnage and grade with depth, ore reserve optimism and a variety of other factors conspire to produce variations in production rates and grade that often result in suboptimal outcomes and potential mine failure. Added to this is the focus of industry analysts and senior corporate management on such measures as unit costs and ounces in reserves. This is perceived to have the perverse effect of driving the share price down when strategies are adopted that actually improve the value of the mining operation, and vice versa! Many mine failures can be prevented by a close examination of the tonnage grade curve and an understanding of how margins, net cash flows and resulting business risk change with cut-off grades and rates of production. A few relatively simple analyses early in the evaluation of a project can demonstrate the tradeoffs between the main decision parameters, leading to right-sizing of the operation. Once major commitments to major capital items have been made, and reserves have been publicly reported, optimisation of the operation becomes much more difficult than if it had been done earlier. Such investigations can also identify the upside potential and downside risks associated with factors outside the companyÆs control. Many strategies that may enhance value in the good times significantly increase the downside risk in the bad times. What is often called risk analysis typically looks at superficial issues, and does not evaluate the major factors leading to the potential for financial disaster. This paper illustrates some of these major risks, and demonstrates how they may be fully evaluated so that corporate decision makers can make fully informed decisions that take account of the real risks.

Jan 1, 2003

By Kapoor M. L

EMF measurements were performed in the temperature range of 933-1095 K to determine the thermodynamic properties of oxygen dissolution in liquid lead and lead-tin alloys with tin in the dilute concentration range of 0 to 6 atom per cent. The oxygen in the Pb-O system was varied by equilibrating with (PbO) slag, and that in the Pb-O-Sn system was varied with the addition of lead oxide. Wagner's interaction parameter approach was used to evaluate the self interaction parameter and ternary interaction parameters at different temperatures, to yield: E8(pb) = 97.35 - 113.27 x 103/t Eo(pb) = 139 - 20.616 x104/1' Quasichemical formulation was employed to yield Inf to reveal the effect of tin on oxygen in lead. Results have been predicted on the basis of classical models and those obtained using the QCT approach of Alcock and Richardson at Z=2 have been found to agree with the experimental Data.

Jan 1, 1992

By B G. Lottermoser

Field and laboratory data combined with computational modelling have been used to predict the pit water quality for the Highway Reward mine. Open pit mining of the Highway Reward copper-gold deposit has produced a final mining void with a diameter of 600 m and a depth of 280 m. This void will be left to fill with ground and surface water once pumping of pit water ceases. Several leaching tables were constructed to simulate weathering reactions and surface water run-off in the major pit wall units during a 200-day leaching experiment. To date, about three-quarters through the experiment, combined run-off from these cells has reached a pH

Jan 1, 2003

To finalise the arrangement and details of the headframe to be erected over the new No. 3 Shaft, the haulage and winding equipment requirements were first determined, then tentative designs were prepared to cover the needs of general shaft servicing work for men and materials, mullock and ore handling, and the probable requirements of a breaker station to be built adjacent to the headframe, which would provide for the crushing of the run-of-mine ore down to a size which would be suitable for feeding on to the concentrating mill.

Jan 1, 1957

By Lawson E, Purkiss S. A R, Van Ashwegen p C

It is only in the past decade or so that industrial exploitation of biological resources and techniques has become regarded as a distinct discipline. Commonly referred to as Biotechnology, it embraces biochemistry, microbiology and the engineering sciences and is mainly aimed at the biological conversion of suitable raw materials into desired end products. The catalytic agents are more often than not bacteria although other micro-organisms such as fungi are used. The range of micro-organisms used is wide and the choice depends upon the desired end product, which in turn depends upon the metabolic attributes, genetically engineered or otherwise, of the cells. The metabolic diversity of micro-organisms has been applied to processes such as antibiotic production, food processing, brewing and chemical production, and of course extraction of metals from ores. Metabolic diversity is, to a certain extent, based on nutrition, which, in its simplest form, can be divided into energy source, carbon requirements and nature of the electron donor producing reducing power to the cells. The source of energy may be light, in which case the organisms are phototrophic (eg green plants, algae). The carbon requirements and reducing power may come from organic sources. These organisms are then called heterotrophic (eg man and most bacteria, including the well known Escherichia colt). However, there is a group of bacteria whose energy metabolism depends upon chemical redox reactions, use inorganic carbon (CO2) and obtain their reducing power from reduced chemicals such as metal sulphides. These are known as chemolithotrophs. They play an important role in mineral recycling in nature and are also ideal for extraction of metals from ores. This is because they are extremeophiles being acidophilic (grow at very low pH) and sometimes also thermophilic (grow at very high temperatures). These bacteria operate in such hostile environments that competition, or contamination, by other organisms does not occur. Extraction of metals from ores by chemolithotrophic bacteria is commonly referred to as biohydrometallurgy. Other related areas are bioadsorption of metals from dilute solution,- microbial treatment of metal contaminated wastes and removal of toxic chemicals produced or used during mineral processing. This paper basically reviews the work that Gencor has undertaken in the field of biohydrometallurgy and the advancements it has made in commercialising the technology, but also touches on certain long-term areas of research that are currently under investigation.

Jan 1, 1995

By Tumilty JA, Douglas WD

With a view to characterising activated carbons with respect to their ability to adsorb gold from cyanide solutions, an attempt was made to establish correlations between the equilibrium capacity constant of the activated carbon for gold (k value) and five other parameters. These parameters were percentage ash content, iodine number, methylene blue value, surface area, and pH respectively. Twenty four different proprietary brand activated carbon products were examined, the correlations being established by means of linear regression analysis. It was shown that a significant correlation only existed between k and pH value. This was interpreted in terms of the presence of oxide complexes on the activated carbon surface. Further test specifications as developed at the Anglo American Research Laboratories are also outlined with a view to the selection of activated carbons suitable for use in' a carbon-in-pulp operation. Methods for assessing both the capacity and the kinetic response of carbons for gold adsorption are presented, while the measurement of attrition resistance, particle size distribution and moisture and solubles content is also outlined. The measurement of the capacity constant for gold adsorption together with attrition resistance are considered to be necessary in the initial selection of a suitable carbon.

Jan 1, 1982

By A Whaanga, A Doecke

The internal stratigraphy of the Marillana Creek palaeochannel Tertiary channel iron deposits (CID) in the Hamersley Province of Western Australia was initially defined in the 1980s and redefined as the Marillana Formation in the early 2000s. Recent drilling, open pit mining and field observations in the Western deposits at BHP Billiton Iron OreÆs Marillana Creek tenements have revealed some additional details on the extent and detail of some units of the Marillana Formation stratigraphy in this area. The drill hole data at Western 1 South has identified a number of features either not previously documented in this area or whose significance has not been adequately recognised, including a denatured zone at the base of the Upper CID of the Barimunya Member, and variations in the lithology within the Munjina Member at the base of the channel. Additionally, the Western 4 pit walls show evidence of a significant near-surface clay horizon and overlying CID, which are suggested to be the equivalent of the Iowa Eastern Member in the Eastern deposits. The deposition of this unit was most likely driven by a regional climatic disruption rather than a change in sediment source area alone. The nature of the Weeli Wolli Formation-derived goethitic peloids in the Western deposits may explain the more extensive denaturing in the Western Lower CID of the Barimunya Member. In contrast, the more robust nature of the haematitic-cored pelletoids in the Central and Eastern deposits has resulted in a less denatured Lower CID in these areas. Such work reveals the value of and need for geologistsÆ ongoing face mapping observations and detailed drill hole logging, and cautions against not querying previously accepted interpretations.

Jan 1, 2007