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By C. J. Hartley

"Scandium oxide can be recovered as a by-product from process streams in a number of chemical and metallurgical plants including TiO2 sulphate pigment, Ni/Co laterite, zirconium oxychloride and uranium operations. The feed materials available for processing can be either mid or end of process streams containing many species in solution. This paper describes the strategies available to limit coextraction of elements into scandium containing streams from TiO2 pigment production and the removal of these elements to deliver high purity scandium oxide.A critical part of process development is to work within the constraints of the main process in terms of introducing new unit processes and producing minimal additional process intermediates and residues. This requires flexibility in designing flowsheets and plants to find novel process routes that avoid production of intermediates and/or the introduction of reagents that can compromise the main process operations.Bloom Energy has developed novel solvent extraction processes for the extraction and refining of scandium oxide that minimise impacts on core process streams within TiO2 pigment plants. The additional unit processes are designed to have minimal contact with pigment plant process streams to produce a concentrate that is refined to nominal 3N purity scandium oxide in a simple, small scale commercial plant."

Jan 1, 2016

By T. Prietl

Metallurgical vessel linings are multilayered, consisting of refractory bodies, insulation materials, joints, and additional space to control for thermal expansion. A unique biaxial hot testing press (BHTP) was installed at the RHI Refractories Technology Center Leoben, Austria to enable the three-dimensional behaviour of complex vessel lining segments to be investigated under simulated service conditions. Using the BHTP, the heat up and thermo-mechanical behaviour of magnesia chromite brick lining segments with and without mortar filled joints were examined. The results obtained during the initial heat up provided validation of CFD modelling of the lining system. In addition, after the heat up and under steady state conditions, the lining behaviour during deformation-controlled compression and relaxation was examined. These analyses generated important data regarding the stiffness, joint compressibility, and brick damage of the lining segments after cyclic loading and unloading as well as the benefits of using mortar joints in the lining. These investigations were performed in collaboration with the Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals, University of Leoben, Austria. The BHTP has been operational since November 2004 and is providing information regarding the thermo-mechanical behaviour of different lining segments.

Jan 1, 2007

By Z. Jun, L. Kerning

Jinlong copper smelter and refinery, originally designed for 100,000tpa primary copper and started up in 1997, has been expanding its capacity on the basis of operational optimization and by modifying its facilities. Currently it is producing 210,000tpa primary copper, and the new phase of expansion project with a target capacity of 350,000tpa primary copper is ongoing. This paper reviews problems and improvements made with operation and equipment in the past years. Recent plant operation is briefly described. The expansion projects completed are summarized and the ongoing expansion project is present.

Jan 1, 2007

By J. Holtzhausen

"An analysis of operating costs for underground mining operations in the current global economic climate considers the financial burden for a ventilation system to be in vicinity of 30–50%. These operating costs are often overlooked by management teams in the greater scale of things when looking to save money in the procurement phase. This oversight to operational costs can be as little as the effective delivery of ventilating air to the work zone. One of the biggest opportunities for substantial savings and improvements can be realized in the selection of a quality vent duct that is suitable and fit for purpose. The key component to the selection process for quality products is a solid selection criterion that is followed during the tender process. This allows the management team to filter out unsuitable suppliers and products. The case study identifies some of the key components that were considered in the procurement and selection process for lay-flat ducting products. These included the characteristics and strength of the materials. The selection criteria also considered a ducted performance comparison that offers the best aerodynamic performance with some of the following components. • Airflow at Duct Face (m³/s or cfm), Fan Pressure (Pa), Air Power (kW or hp), Assumed Fan Efficiency, Annual Running Costs, K – Factor or Lambda, Leakage Factor, Joining Method and available Duct Lengths with weights. • Critical components considered were the current Testing standards available for: o Bursting Strength AS 4878.5, Mass AS 2001.2.13, Tensile Strength AS 4878.6, Tensile Strength AS 2001.2.3.1, Tear Strength AS 2001.2.10, Tear Strength AS 4878.7 • Other key considerations were: o Warranty Claim, Damage claims, Local storage / operations, community engagement and relationships, current testing data, previous issues, after sales service with technical assistance, etc. Hidden costs associated with product failures and operational stoppages are often not quantified during the tender process. Buyer beware. INTRODUCTION The largest constraint underground mining operations currently face are their operating efficiencies and electrical costs. The overall cost of an operations ventilation system and its components requires more focus to identify what opportunities exist to maximise efficiency and effectiveness. This tender process may not always be clearly understood and it should be broken down into fewer components to achieve quantifiable results."

Jan 1, 2019

By Frederik H. Kriel, John Ralston, Craig Priest

"Stream-based microfluidic solvent extraction offers a novel alternative to bulk-scale mixer-settler operations. However present maximum throughputs are restrictive and there are engineering challenges that need to be overcome before the technology is robust. This is especially the case for mineral processing, where circuits must be able to handle variable feed streams with long retention times and where maintenance should be minimized. This paper highlights research directed at investigating and evaluating these challenges for actual mineral leach solutions of metal ions. Molecular and particulate channel fouling is discussed. Most extraction systems studied to date show no effects that would preclude use of the technology. For rare earth elements (REE) with fast extraction rates, scale-up of volumetric throughput to 100 L/h using suitable arrays of channels, microfluidic chips and modules is shown to be achievable using a small contactor (approx. 2 m3) platform. This requires only 2–3 % of the typical aqueous phase inventory and residence time used in an equivalent mixer-settler. For a circuit with 100 contactors, the overall residence time would be less than 1 h, using an aqueous inventory of 40 L.INTRODUCTIONHydrometallurgy is of pivotal importance in many mineral processing circuits around the world, with liquid-liquid solvent extraction (SX) a key step in the separation of many base metals (e.g. Cu and Ni), radioisotopes, precious metals, and the ‘technology’ metals, such as rare earth elements (REEs) (Ritcey & Ashbrook, 1979). The standard equipment for SX in mineral processing is the mixer-settler, in which liquid dispersions are created, by agitation, to increase the surface-to-bulk ratio and, thus increase the mass transfer rate between the liquid phases. In stream-based microfluidic SX (microSX), these high surface-to-volume ratios are achieved by contacting microscopic streams (Ciceri, Perera, & Stevens, 2014), rather than forming small droplets, so that phase disengagement can be accelerated (essentially instantaneous via branching of the two streams of liquid at a channel junction). MicroSX is profoundly different from bulk mixer-settler SX operations and offers exciting opportunities for processing hydrometallurgy solutions (Kriel, Holzner, Grant, Ash, Woollam, Ralston, & Priest, 2015; Priest, Zhou, Klink, Sedev, & Ralston, 2012). Nonetheless, the advantages of using microfluidic environments are presently balanced by very significant challenges relating to throughput, process control, coupling of stages, flow stability, and fouling. If these challenges can be met using smart chip designs, process control and clever engineering, high-value/low-volume SX processes stand to benefit greatly."

Jan 1, 2016

By P. Nelson, B. Salt, J. A. Scott, H. Shang

ABSTRACT In a nickel smelting process, large amounts of off-gas emissions are generated, which can cause serious environmental and plant hygiene problems if not properly treated. With increasingly stringent environmental regulations, an enhanced understanding of well-controlled, off-gas cleaning systems is vital. In this paper, dynamic models for an industrial smelter, off-gas system tackling hazardous sulphur dioxide, carbon monoxide, and carbon dioxide are developed using mass continuity, momentum, and energy conservation laws. The effect of air in-leakage is explored under different operating conditions. The developed models provide an enhanced process understanding and a necessary basis for highperformance control analysis of smelter off-gas systems.

Jan 1, 2011

By A. D. Misener, L. G. D. Thompson

"IntroductionIt was shown by work previously reported that reliable geothermal gradients representative of various regions of the earth's, surface could he obtained from extended surveys of the rock temperatures in operating mines. These surveys showed the presence of anomalies in the isothermal levels and the existence of regions of regular behaviour. Below about 3,000 feet the temperature gradients became quite regular over the areas stud1ed. It is these regular gradients which are taken as representative of the region, wherever possible.The present paper describes the extension of this work which was undertaken to obtain further temperature gradients with a view to correlating them to other geophysical properties determined for the same regions. The additional data obtained have indicated possible reasons for the temperature anomalies. The experimental procedure was similar to that already described and was again made possible through the wholehearted co-operation of the management and the assistance of the personnel of the mines concerned. The research was entirely supported by a grant from the Research Council of Ontario.The equipment was a distinct improvement over that previously used and made it possible to take many more accurate temperature readings in a given time. Thermistor resistance thermometers were used, encased in silver sheaths and protected against damage by heavy copper casings. These were calibrated with a standard platinum resistance thermometer.The bridge used with these thermometers was one of a number designed and built by the Meteorological Service and designated M.S.C. Thermometer Indicator Type C-3. This very convenient and portable instrument operated from batteries in the instrument case. Multiple thermometer connections were provided so that rapid readings• of a number of thermometers was possible to accuracy of the order of 0.1°F. All electrical connections on the panel are covered with Dow-Corning ignition compound to prevent; electrical leakage due to moisture condensation. This, together with the high resistance of the thermometers and components of the bridge, gave much more reliable results than previously obtainable."

Jan 1, 1950

By R. Matusewicz, A. Kaye

Ausmelt Top Submerged Lancing (TSL) Technology has gained widespread commercial acceptance in non-ferrous applications, including the processing of lead and zinc primary concentrates and secondary (post-consumer) materials. TSL is highly flexible and efficient, and is one of the few technologies which can process primary and secondary feeds, and use varying fuels, to deliver high recoveries and excellent environmental performance. With the recent high value of both lead and zinc, and an escalating awareness of the sustainable use of resources, focus on the processing of secondary feed material sources has surged. Ausmelt Technology has proven to be well suited to the economic recovery of values, with twenty-two (22) Ausmelt furnaces processing lead and zinc bearing feed sources now in operation, under design or construction. This paper describes Ausmelt's progress in the fields of lead and zinc processing, and developments in new processing areas such as EAF dust processing and linking to innovative hydrometallurgical technology. Ausmelt has recently committed to the Whyalla Zinc project as the owner/operator of a facility for the treatment of zinc bearing secondary feeds. This project is due for start up in the first quarter of 2008.

Jan 1, 2008

By K. A. Mackinnon

The choice of fan type (axial flow, centrifugal or mixed flow) most suited for a mine ventilation application depends on a number of technical and economic factors. For each project, the relative importance of these factors will vary. It is worthwhile to carry out an assessment on a case by case basis. The paper, by discussing a number of technical and economic factors and their interactions, will provide the ventilation official a methodology to easily and methodically undertake such an assessment.

Aug 1, 2013

"The Upper Mannville unit commonly consists of interbedded marine and non-marine sands and shales, but in northwestern Alberta the unit consists of marine shales of the Spirit River Formation. A thick tongue of marine shale (Clearwater Formation) ex-tends eastward into the Athabasca area below sandy Grand Rapids beds. Correlation of Upper Mannville rocks to the southeast is difficult, but in the Cold Lake area a thick sandy depositional cycle (Mannville ""C"" of this paper) appears to be approximately correlative with the Clearwater Formation. In the Lloyd-minster region, tongues of marine sedimentary rock occur in the lower part of the Upper Mannville unit. Most of the Upper Mannville oil occurs in the Grand Rapids Formation at Wabasca, in the thick ""C"" unit and younger Mannville sands at Cold Lake, and in the Sparky and General Petroleums sands of the Lloydminster region (Figure 2).The Lower Mannville unit was deposited on an erosional surface of considerable relief that truncated the Jurassic and older strata of the Western Canada basin. Continental, probably fluviatile, sedimentation persisted over much of the Western Canada basin during deposition of the Lower Mannville unit, but an Arctic or Boreal sea lay over part of northern Alberta. At the end of the depositional episode, the sea transgressed southward and eastward (Figure 3) and re-worked the Bullhead and McMurray sands of northern Alberta into the glauconitic Bluesky and Wabiskaw sands. Topography on the sub-Cretaceous erosion-al surface had a considerable effect on the deposition of the Lower Mannville (Rudkin, 1965), and the highest hills on this surface were not completely on-lapped by Lower Mannville sediments (Figure 3). The coarser elastic material was derived both from a western Cordilleran region and from an eastern Canadian Shield region (Glaister, 1959, p. 620; Mellon, 1956)."

Jan 1, 1966

By Yoginder P. Chugh

This paper discusses an ongoing field study in southern Illinois (USA) that focuses on: 1) Identifying mechanisms of instability in the set-up rooms (SR) and their T-junctions with headgate and tailgate entries, 2) Developing alternate 3-entry and 4-entry set-up rooms geometry using 3-D numerical analyses, 3) Implementing developed geometries in cooperation with mining professionals and regulatory agencies, and 4) Demonstrating performance of implemented geometries through field monitoring. Illinois longwall mining operations typically experience ground control problems (roof falls, rib sloughing, floor heave, etc.) within SR layouts and around the T-junctions of SR. These occur around the areas where the SR for adjacent longwall face (to be mined) connect with the SR of the previously mined face, and around the tail-gate entries of the mined-out longwall face and around the T-junctions of SR. The problems manifest as highly fractured immediate roof strata, major shear zones in the roof, horizontal displacements within the excavations that result in shearing off the heads of the bolts, floor heave and severe rib sloughing. Similar observations have also been made in longwall mining in Utah.

Aug 1, 2013

By P. Bakke

Following extensive R&D efforts, Hydro Magnesium has launched a new alloy series with remarkable combinations of properties. The AE alloy family is based on additions of aluminium and rare earth elements to control mechanical properties, including elevated temperature creep strength. By combining these alloying elements with manganese additions, high purity alloys with outstanding corrosion performance are defined. A basic philosophy behind the developments has been to simultaneously approach all the critical issues related to developing a commercial material. Apart from the obvious requirements for material properties, the critical issues relate to die casting performance, as well as alloy production, recycling and environmental compatibility. Some of the important elements related to alloy production and recycling are addressed in the present paper.

Jan 1, 2006

By C. E. White

The depletion of higher grade mineral reserves will accelerate the trend toward production from progressively larger and lower grade deposits. The discovery of adequate reserves of leaner ores will require the development of improved exploration techniques with a greater depth range. The principal challenges to the Canadian mining industry are to find the mineral resources required to meet fast growing world demand and to develop mining methods and equipment to ensure production costs which will strengthen our position in export markets in the face of in-creasing world competition. The challenges cannot be met without intensive efforts to attract more technical men to the industry and to improve their training.

Jan 1, 1967

By W. B. Agocs

"IntroductionWITH THE DISCOVERY of natural radioactivity at the end of the 19th century, and the design of equipment for the detection of this phenomenon, radioactivity surveys bad their inception. Early in the 20th century it was found that almost all rocks are radioactive to a certain degree. This radioactivity is due to the nuclear disintegration of six naturally radioactive elements: potassium, thorium, uranium, rubidium, samarium, and lutecium.The radioactivity of these elements manifests itself by the emission of some concentration of alpha, beta, and gamma 'rays'. Of these, the alpha and beta 'rays' are, respectively, helium atoms and electrons, while the gamma 'rays' are short wave length x-rays generated in the nuclear disintegration by the transformation of mass into energy.The alpha and beta rays, being particles of matter, are stopped ve• easily by material barriers, but gamma rays are extremely penetrating and they will pass through a foot or more of rock or several inches of lead.The radioactivity may be detected by the causing of ionization by the radiation. The radiation detectors may be divided into four classes: ionization chambers, proportion al counters, and Geiger counters, all of which use gas for ionization, and scintillation counters, in which a solid is ionized. The basic principle of all these detectors is the same; the difference lies in the method used to measure the degree of ionization produced by the rays. Currently, the scintillation counter is displacing, the other instruments in radioactivity surveying."

Jan 1, 1955

By Paul Hammond

Abstract The Allard Lake ilmenite deposits, which are currently being developed on a large scale, occur as a series of dykes or lenticular, flat-lying bodies within the northeastern part of a large, oval shaped anorthosire mass of Precarnbrian age which lies with its long axis paralleling the gulf of St. Lawrence. The Lac Tio deposit, discovered by Kennco Explorations, Limited, in 1946, is the largest body of titanium ore of its type now known in the world. It contains upwards of 112,000,000 short tons of ilmenite ore averaging 32 per cent TiO2 and 36 per cent Fe. The ore is an aggregate of ilmenite with oriented microscopic blades of hematite. The deposits appear to be high temperature, late magmatic injections containing only a small amount of volatiles, and bear a genetic relationship to the anorthosite rocks in which they occur. * * * Introduction Recent developments on the ilmenite deposits in the Allard Lake district of Quebec indicate the probability of a major industry, and one which may make Canada the world's greatest producer of titanium pigments and, ultimately, of titanium metal. The presence of ilmenite in this district was first reported by the Quebec Department of Mines following a reconnaissance shore-line geological survey in the year 1941. The ensuing report by Retty describes the occurrence of a number of small ilmenite lenses about the shore of Allard lake and' along two smaller lakes in the vicinity. These showings were later staked by Toronto and Montreal interests who carried out a certain amount of development work, and were described in more detail by Longley for the Quebec Department of Mines. The claim groups were later optioned by Kennco Explorations, Limited, Canadian subsidiary of Kennecott Copper. None of the deposits in themselves constituted a sufficiently large body of ore to warrant the major construction expenditures necessary for their exploitation on a profitable basis. The surrounding anorthosite areas, however, were considered favourable for the possible occurrence of other ilmenite deposits

Jan 1, 1949

By G. V. Theja, V. B. Maji

Large infrastructure projects like tunnel excavations, underground constructions face innumerable risks. For successful completion of these projects, it is essential that we foresee and understand risks that could occur during different phases of the project. One of the risks affecting underground excavation projects is the inaccurate performance prediction of TBMs. As this could severely affect the project, resulting in lower advance rates and could also result in changing the excavation machine or method, due to difficulties in excavation, thereby increasing the overall cost of tunnelling. This makes performance prediction of the TBMs as one of the crucial aspects in tunnelling, as a precise estimation of its performance is required for planning and estimation of time and cost of the tunnelling projects. This performance prediction of TBM is a challenging geotechnical problem that is intricate and complex in nature, this is possibly due to the fact that TBM performance prediction involves understanding the rock fragmentation process in wide range from micro-scale (i.e. the interaction of surface of rock material and cutter tip) to macro-scale (including the interaction of rock mass and TBM). Thus in order for the performance prediction model to be efficient, parameters of both TBM specifications and ground conditions have to be considered. Various models have been proposed by researchers since the early phases of TBM application, these studies resulted in the development and improvement of numerous penetration prediction models. Most of these models consider the geotechnical parameters that are input to the model to be consistent along the TBM drive and neglect the uncertainties in parameters that occur. And so to improve the predictive capability of these models and to incorporate the above uncertainties, the penetration rate is modeled as a stochastic variable depending on the geotechnical and TBM parameters, its statistical distribution is determined and is used to characterize the penetration rate instead.

Jan 1, 2015

By A. J. Oliver, C. E. O’Neil, I. J. Itzkovitch, V. A. Ettel

A new solvent extraction process for the separation of cobalt, copper and zinc from nickel sulphate process streams has been developed. It involves selective extraction of these elements with a quaternary ammonium thiocyanate dissolved in an aromatic diluent. The chemical principles of this process have been investigated and are described, together with background physico-chemical data relating to the use of this solvent. Long-term testing in a continuous "mini-plant" circuit gave high-purity nickel and cobalt products (Ni/Co —200011 and Co/Ni ~1000/1 respectively).

Jan 1, 1976

By G. F. Vander Voort

Over the past twenty years, steelmakers have introduced improved practices for reducing the inclusion content of steels. The success of these practice changes can be monitored in a variety of ways. Chemical analysis of the bulk sulphur and oxygen contents provides a relatively simple means to assess the impact of these changes. However, microscopical test methods are still needed to assess the nature of the inclusions present. Traditional chartbased measurement methods have wide acceptability, and their data are well understood by both purchaser and producer for heat acceptance purposes. However, these methods do have inherent weaknesses which limit their usefulness for quality control, SPC, and database applications. Image analysis-based chart measurements are an improvement over manually generated chart ratings, but the data still do not lend themselves to databases and statistical comparisons. ASTM Committee E-4 on Metallography has developed a stereologicallybased image analysis standard test method, E 1245, which provides the necessary data in a form which is easily databased and analyzed statistically. This paper describes E 1245 and shows how data from different heats and melting practices can be compared statistically to ascertain valid test differences.

Jan 1, 1998

By E. Hardwick, K. C. Sole, Y. Jurrius

"The Luilu cobalt plant at Kolwezi, Democratic Republic of Congo, has been operating since the late 1950s, using a conventional precipitation flowsheet for removal of impurities from the cobalt process stream. Most impurities are, however, incompletely removed using this technology. Copper and zinc, both of which quantitatively deposit at the cathode in the cobalt electrowinning process, are two of the main impurities contaminating the cobalt metal product. Ion exchange offers a modern approach to removing these impurities from the cobalt advance electrolyte.Following a laboratory testwork programme to identify a suitable ion-exchange system, an on-site pilot-plant trial, treating 1500 to 3000 L/d of electrolyte, was operated for a period of six weeks to optimise the operating conditions and to determine full-scale design criteria. Copper removal was carried out using a fixed-bed lead-polish configuration with the Lanxess iminodiacetic acid resin, TP 207. Zinc removal was subsequently carried out in a similar configuration using the Lanxess aminophosphonic acid resin, TP 260. The optimised system proved capable of removing both copper and zinc from 20 to 30 mg/L to <1 mg/L from plant electrolyte containing ~20 g/L Co. Selective elution allows co-loaded cobalt to be returned to the main circuit and value to be obtained for the copper impurity. The process shows operational and economic advantages over the traditional flowsheet. Full-scale implementation of the developed process is in progress and some design considerations are discussed."

Jan 1, 2014

By Corrie Pitzer

Safety performance in many companies and even industries has stalled in the last decade. Accidents rates are improving but more slowly and yet, serious accidents and fatality rates are not: in fact, these rates of more serious incidents have plateaued or deteriorating. In more dramatic cases, organizations that had ?exemplary? safety statistics, suddenly had a catastrophic or multi-fatality event occurring. Popular books such as In Search of Excellence of Peters and Waterman or Good to Great of Jim Collins created many delusional ?secrets? or recipes, to achieve great performance and yet, most of those ?great? or ?excellent? companies have now declined in their performance, some dramatically and some have fallen from grace, like Fanny Mae, a company Jim Collins identified as a ?great? one, that had to be bailed out in the latest financial crisis. These organizations share several ?delusions? about managing a business, and often, these delusions are created by academics, consultants and authors of popular books about (safety) management. More damaging however is that safety management is defined by a set of key practices or axioms: a focus on human error, compliance to rules and regulations, creating consistency of systems and actions, reacting to accidents and incidents and on prevention of those, measuring safety with performance metrics and rewarding employees on those measurements. All of these axioms contain the seeds of destruction, and they create conditions and dynamics that precede the disaster - and ironically, they are all &apos;good things&apos; we do in safety management. For example, a mere focus on safety in the business, and the measurement of it, create a culture of repression of mistakes and incidents, leading to a situation where the organization knows incrementally less and less of risks and risktaking behaviour - until the day it all coincides destructively! This paper discusses seven such safety delusions and how they impact on the views and safety management approaches. They are: ??The delusion of (risk) control, that risks can actually be identified, analyzed and mitigated. ??The delusion of compliance, that mere compliance to rules will safeguard the business ??The delusion of consistency, that standard operating procedures will ensure safe operations ??The delusion of predictability, that accidents and trends tell us everything about the risks of the future ??The delusion of human error, that people are the weakest link and that it can actually be dealt with through discipline and enforcement. ??The delusion of statistical trends, that safety is measurable with statistics ??The delusion of invulnerability, that we have achieved high levels integrity and capability to deal wit risks. Organizations that suffered catastrophes all share some or all of these delusions and this paper traces how these played a role in many disasters, ranging from the Titanic, Challenger, Piper Alpha, Bhopal, BP Deepwater Horizon and many more.

Aug 1, 2013