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By R. M. de Carvalho

Empirical and phenomenological models of SAG and AG mills have dominated the scene for the last few decades, being used nearly every time a mill is scale-up or an attempt is made to improve its performance. However, in spite of their success, these models fail to describe the details of both the grinding environment and the breakage mechanisms. The result is a generally good track record, with a few ? but very important ? instances when these models fall short in their predictions, which can be very costly. Further, nearly all of these models require detailed calibration to industrial and pilot plant data, being costly in their application, although still with limited predictive capabilities. Recognizing these challenges, a new model framework has been proposed which overcomes the limitations of currently used models by coupling the microscale population balance model, the discrete element model and functions that describe internal classification at the mill grate. This model framework has already been applied to describe breakage in ball mills, with showing very promising results. However, in the case of SAG and AG mills a much greater level of complexity is involved in the model, given the interaction between the mechanical environment that is formed totally or, in part, by the ore itself, and the breakage response in the mill. The paper describes the model framework, demonstrating how it can address appropriately effects such as mill speed, mill filling and size distribution, on the response from the mill. Some of the advantages of the model are related to its intrinsic multi-component and dynamic nature, which allows simulating appropriately mixtures of ores of different competences in a transient manner.

Jan 1, 2012

By M. J. Merwin

Heat treated seamless tubular products are processed in a fashion that can be easily modified to produce dual phase microstructures, through the implementation of intercritical soaking prior to quenching. Dual phase steels are known to possess low yield strength compared to tensile strength. The steel line pipe market is interested in low yield-tensile ratio materials for application in reel barge pipe laying operations. In the current work compositions of commercially produced material already in use for the line pipe market were examined and dual phase microstructures were successfully developed. The microstructure and properties of the materials were found to be stable over the range of intercritical temperatures employed. Tempering temperature and, somewhat unexpectedly, small chemistry differences were found to have the largest influence on properties. Excellent toughness performance was observed in samples tempered at temperatures in excess of 550°C. Tempering in this temperature regime produced materials with strength suitable for application as API X60 line pipe. A difference in tensile strength between steels of similar chemistry was observed, and is not fully understood at this time. Welding performance was considered through simulation of three regions of the heat-affected zone. Neither intercritical temperature, nor tempering temperature, were found to have a significant influence on the heat-affected zone properties. The peak temperature achieved in the thermal cycle was the only significant factor. The hardness of the heat-affected zone was found to increase continuously with increasing peak temperature. While toughness was found to be low for both partially-transformed and coarse-grain heat-affected zones, the toughness of the fine-grained heat-affected zone was substantially better. Based on the results found in this laboratory study, a limited production trial is expected.

Jan 1, 2005

By L. C. S. Dharmasiri, S. M. Shin, A. Senaputra, J. S. Sohn, K. H. Park, J. Avraamides

Reducing agents can be applied to leach metal values from natural and secondary resources such as laterite ores and deep sea manganese nodules and recycled materials such as spent batteries / catalysts which contain high-valent metal oxides of manganese, cobalt and iron. Selective leaching of some metals can be achieved by selecting conditions to control the saturated solubility and dissolution rates of metals from oxides or mixed metal/oxide matrices. The leaching results are rationalized on the basis of chemical species, Eh-pH diagrams and heterogeneous kinetic models. The role of reducing agents such as hydrogen peroxide, sulfur dioxide and iron(II) sulphate, in acid, alkali and in the presence of complexing ligands such as ammonia for the improvement of the leaching of metal oxides and metals is discussed. Previous studies on acid leaching of metals from nickel laterites, manganese nodules and spent catalysts/batteries in the absence or presence of reducing agents show that the rate controlling step involves the diffusion of protons through a thickening product layer on the particle being leached. It is shown that the leaching of nickel and cobalt from manganese nodules and zinc-carbon batteries in ammoniacal sulphur dioxide solutions also obey shrinking core kinetics.

Jan 1, 2014

By H. Hamza

Efficient and effective management of extraction process tailings is an essential ingredient for the continued success and development of Alberta's vast oil sands resources. Open-pit oil sands operations north of Fort McMurray recover bitumen from flotation circuits. Process tailings are managed in carefully engineered and monitored external tailings management facilities and in below-grade mine pits. In order to support reduction of production costs and improve upon established tailings management practices, CANMET has been working with the oil sands industry in a collaborative framework to assess the potential to integrate thickened tailings into oil sands extraction process flowsheets. Albian Sands has commercialized the process while others, including Syncrude Canada Ltd., continue to evaluate the suitability of the process for their operations. This paper provides an update on R&D work undertaken in recent years to assess and develop the potential of thickened tailings technology for the open-pit oil sands operators of northern Alberta. The aim of this work was to explore opportunities to optimize process efficiency and environmental sustainability by improving water and energy conservation and develop more alternatives for tailings management and reclamation.

Jan 1, 2004

By J. Kan

In order to determine the recovery functions in an oil sand circuit it is necessary to have more than a minimal determination the mass flows in the network. This over-determination is essential in order to allow for measurements within the flow matrix "to flex" according to an error function. It is then possible to identify the flows and composition at all points with maximum likelihood. These so-called full mappings are not easily obtained. However, in order to obtain an unequivocal determination of all the unit operations recoveries such a balance is needed. When databases are constructed exclusively with coherently balanced sets of data it is possible to obtain a maximally accurate process model by maximizing the probability of correctly identifying the process causality. Indeed, it is doubtful in cases of normal complexity that any sense can be made of data that is not so balanced. Coherent mass energy balancing is a tool developed by mineral processing scientists and engineers. Its rigorous application to oil sands is the subject of this paper. The additional element associated with hydrocarbon requires special considerations. It is shown that at least one currently available mineral processing tool will solve the full-mapping problem for an oil sand operation. Experimental design constraints are discussed in this paper relating to the development of databases for the development of effective process models.

May 1, 2004

By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By Ham. Y. M.

The corrosion behaviour of Al-B4C metal matrix composites immersed in 2500 ppm boron-containing H3B03, 0.5 M K2SO4, and 3.5% NaC1 solutions was investigated. Effects of B4C particle volume fraction on the corrosion behaviour of composites were studied using potentiodynamic polarization and electrochemical impedance spectroscopy techniques. Scanning electron microscopy was employed to study the surface morphology of the material before and after corrosion. Results show that all materials investigated are more corrosion resistant in 2500 ppm boron-containing H3B03 than in other solutions. No appreciable corrosion was observed in boric acid and sulfate solutions in contrast to an obvious pitting in NaC1 solution for both base alloy and composites. The preferential pitting sites are the interfaces of Al/Fe intermetallics for the base alloy, and the A1/B4C interfaces for the composites. Increasing the volume fraction of B4C particles in the composite decreases its corrosion resistance of Al-B4C composites.

Jan 1, 2011

By B. Surender Mohan

Mother Earth being a treasure of minerals, it is prime duty of the mankind to preserve this natural source to ensure steady growth of the nation. Utmost care is to be taken to see that these natural resources are explored and exploited scientifically in a sustained manner to ensure that the resource base improves and last longer. In this backdrop, the topic of ?Lignite - its resource and technology options to exploit deep seated deposits? is an apt subject to be deliberated upon in the present context, where the shallow deposits may slowly get dwindled. I shall deliberate upon the resource base of lignite, production profiles of the last five decades, consumption pattern, demand / supply projections, future available technology options to exploit the deep seated deposits, growth trends of the sector etc. in my paper. With the available resource base and future technology options, I can confidentially make a statement that ?lignite will remain as cocontributor along with coal to India?s energy generation and may well maintain its same status in the 21st century too, as it has been in the later part of the twentieth century?.

Aug 1, 2013

By Ifeanyichukwu Nweke

"Aluminium rolling processing from ingots to cold rolled coils comes with a lot of challenges especially in controlling defective products in casting, hot mill and cold mill operations. Hence this study focused on reducing defects at mills and cast-house using six sigma approaches. The use of six sigma approach will help the production experts to determine the gap between its operation and world class process. Practical data from First Aluminium Rolling mills were presented and analysed and mini improvement projects were proposed based on organisation need to achieve excellence. This study encourages aluminium alloy industries to pursue process improvement projects on the basis of analysis on data obtained from their shop floor, hence ensuring that through this, recovery is improved and cost of poor quality is reduced.INTRODUCTION Engineer Bill Smith while working at Motorola in 1986 introduced a new concept in which a set of techniques and tools are used for process improvement by controlling variations (defects). These tools and techniques are explained by an acronym DMAIC. D DEFINE the problem M MEASURE the variables in the problem A ANALYSE the variables of the problem I IMPLEMENT and verify the solution to the problem C CONTROL the solution to sustain it Most times in six-sigma approach, variations in the process that results in defects and customers’ dissatisfaction are targeted at 3.4 defects per million opportunities. There are numerous methods six sigma application use to achieve quality results and innovative strategies. Improving the quality of process through these methods helps identify and reduce variations which paves way for organisational excellence. In this study, it is encouraged to use six sigma techniques to improve aluminium rolling operations and other aluminium processing activities, the benefits of such improvement concept include: • Satisfy the voice of the customer (VOC) • Minimise costs • Maximise Profits • Build Good Team • Implement Profitable Project"

Jan 1, 2018

By J. A. Finch, M. Mimezami, M. S. Hashemi A.

The adsorption of magnesium and calcium ions on sphalerite and pyrite is discussed. These ions are common in process water and often considered be detrimental in sulphide flotation. The study attempts to characterize the adsorption mechanism, which has been less studied than the oxide system. Generally for oxides metal ion uptake occurs when cations are hydrolyzed. Our findings reveal that magnesium and calcium adsorb on sulphides at pH below hydrolysis, but adsorption is not chemical. At higher pH, charge reversal occurs that does correspond to presence of hydrolysis products. Advances

Jan 1, 2009

By Syamujulu. M

Subsequent to the unbundling of the Zambia Consolidated Copper Mines (ZCCM) and the privatization of its constituent parts, the Konkola Copper Mines (KCM) represents a third of the original conglomerate. Now run by private hands as a sub group of Vedanta Resources Plc of India, KCM is strategizing on how best to deal with the operational issues of the organisation to resolve some of the difficult, logistical, environmental, mineralogical and metallurgical problems being encountered to tum them into opportunities as the company turns around. This paper reviews the options being put in place to provide appropriate solutions and strategies including the treatment of the highly siliceous low energy copper belt concentrates in its mining operations in Zambia.

Jan 1, 2007

By Jonathan Matthews

Efficient and effective management of mine tailings is essential for continued successful development of Alberta?s vast oil sands resources. Syncrude Canada Ltd. continues to research novel tailings management techniques in an effort to improve production efficiency and environmental sustainability. During the summer months of 2001, Syncrude Canada Ltd., in collaboration with members of the Canadian Oil Sands Network for Research and Development (CONRAD), conducted field-scale trials of thickened tailings technology at Syncrude?s Aurora mine, north of Fort McMurray, Alberta. This paper provides an overview of the test program including discussion of objectives, test configuration, and program observations. 0Data collected during the field trial indicate that substantial swings in feed slurry composition challenge effective thickener operation. When coarse mineral solids dominated slurry composition, thickener rake torque rose to unmanageable levels. It was determined that the end-of-pipe depositional characteristics of thickened oil sands slurry were generally consistent with present understanding of oil sands tailings slurries. After shear, thickener underflow product exhibited very shallow beach angles and a limited capacity to keep coarser particles in suspension indicating that stacking of ?paste-like? thickener underflow product from a conventional thickener is not practical in an oil sands setting unless process adjustments can be made to increase the underflow density and/or preserve the initial high yield stress of the underflow during transport and deposition. These technical challenges notwithstanding, Thickened Tailings technology offers considerable promise for recovery of warm water from oil sands process tailings.

May 1, 2003

By James R. Hein, Jane Reid, Robert W. Embley, Se-Won Chang, Randolph A. Koski

"Abstract - This is the first reported occurrence of an active hydrothermal field in an oceanic fracture zone setting. The hydrothermal field occurs in a pull-apart basin within the Blanco Fracture Zone (BFZ), which has four distinct mineral deposit types: (1) barite mounds and chimneys, (2) barite stockwork breccia, (3) silica-barite beds, and (4) silica, barite, and Fe-Mn oxyhydroxide in sediments. All deposit types contain minor amounts of sulfides. In barite stockwork, silica-barite beds, and mineralized sediment, Ba, Pb, Ag, S, Au, Zn, Cu, Hg, Tl, As, Mo, Sb, U, Cd, and Cu are enriched relative to unmineralized rocks and sediments of the BFZ. Fe and Mn are not enriched in the barite stockwork or silica-barite beds, but along with P, Co, and Mg are enriched in the mineralized sediments. Silver contents in deposits of the hydrothermal field range up to 86 ppm, gold to 0.7 ppm, zinc to 3.2%, copper to 0.8%, and barium to 22%.Mineralization occurred by diffuse, low to intermediate temperature (mostly <250°C) discharge of hydrothermal fluids through pillow lavas and ponds of mixed volcaniclastic and biosiliceous sediments. Bacterial mats were mineralized by silica, barite, and minor Fe hydroxides, or less commonly, by Mn oxyhydroxides. Pervasive mineralization of bacterial mats resulted in formation of silica- barite beds. Silica precipitated from hydrothermal fluids by conductive cooling and mixing with seawater. Sulfate, U, and rare earth elements (REEs) in barite were derived from seawater, whereas the REE content of hydrothermal silica deposits and mineralized sediments is associated with the aluminosilicate detrital fraction. Fe-, Zn-, Cu-, Pb-, and Hg-sulfide minerals, Ba in barite, and Eu in all mineralized deposits were derived from hydrothermal fluids. Manganese oxides and associated elements (Co, Sb, Mo, W, Cl, and Cu) and Fe oxides and associated elements (Be, B, P, and Mo) precipitated as the result of mixing of hydrothermal fluids with seawater."

Jan 1, 1999

Building off the enthusiasm generated by Credit Suisse First Boston on the potential benefits of an industry-wide effort to market gold jewellery, a group of gold producers, led by Randall Oliphant, CEO of Barrick Gold, decides to investigate the long -term impact of launching a significant marketing initiative to stimulate demand for gold jewellery. The group establishes an international Steering Committee representing producers of differing sizes, members and non-members of the World Gold Council. This Committee comprises representatives from AngloGold, Barrick, Gympie Gold, Kinross, Randgold, and Sons of Gwalia and is supported by the Australian Gold Council, the Gold and Silver Institute, and CSFB. The Steering Committee hires McKinsey to assist it by conducting an independent review of whether investment in a large-scale marketing initiative for gold jewellery would be effective in increasing demand for gold, and ultimately of significant economic benefit of the gold industry. Based on McKinsey?s review* and its own discussions with key stakeholders across the industry, the Steering Committee strongly believes the case for marketing is compelling and sufficiently proven to persuade the industry to undertake a major initiative over the next few years. The Steering Committee, supported by McKinsey, conducts briefings with a range of gold producers to share its findings and to understand producers? perspectives on an industry-funded marketing campaign. The Steering Committee is asking for your support to bring this industry-funded marketing campaign to life.

May 1, 2002

By A. Mykytiuk, I. E. Puddington, W. D. Macleod, F. W. Meadus

"A laboratory-scale continuous procedure for the up-grading of naturally occurring tin ores, based on the principle of spherical agglomeration, is described. High recoveries are indicated. A proposed second stage suggests useful fractionation steps.IntroductionA LABORATORY-SCALE batch process for the upgrading of a tin ore using the principles of spherical agglomeration has already been described (1). This procedure consisted of milling, for about an hour, a precrushed ore with at least 200 per cent water, 0.2 per cent of a reagent such as tall oil (to render the de-sired ore particles hydrophobic) and about 3 per cent of a viscous petroleum oil. The feed material passed an 8-mesh Tyler sieve, and the percentages of re-agents are based on the dry weight of the feed. Du-ring the grinding, the hydrophobic particles transfer into the oil phase to produce coherent semi-solid bodies while the gangue stays preferentially in the aqueous phase. The concentrate can be separated from the gangue easily by a mechanical operation. Using an ore containing about 0.3 -0.5 per cent tin, grades of from 1.5 to 7.0 per cent were obtained by varying the pH of the system. Recoveries fell from about 80 per cent to as low as 50 per cent as the grade in-creased."

Jan 1, 1966

By Gema Ribeiro Olivo

The hydrothermal Au-Pd deposits are hosted by the jacutinga in the Lake Superior-type iron-formation of the Itabira Group, Minas Supergroup. Jacutinga is a highly sheared, metamorphosed, hydrothermally altered iron-formation composed of hematite, magnetite, quartz, talc and phlogopite (Cauê) or muscovite (Conceição) and minor tourmaline, palladian gold, arsenopalladinite, mertierite II and palladeisite (hydrothermal) and native gold, native palladium Pd-Cu-oxides, and kaolinite (weathering products). The highest concentrations of Pd-Au occur in quartz and hematite veins parallel to the S1 foliation (Corpo Y, CorpoX, Aba Leste and Central orebodies, at Cauê and a single orebody at Conceição) or parallel to the S2 foliation (Aba Norte). The average ore grade is 30-40 g/t Au+Pd. The characteristics of the Au-Pd ore favor an epigenetic model for gold and palladium concentration in the iron-formation. During the D1 deformation and peak metamorphism, the oxiziding, acid and hot hydrothermal fluids transported Au and Pd preferentially as chloride complexes. The reaction of the fluid with the dolomitic carbonate (the probably protolith of the jacutinga) would have dissolved carbonate and K-feldspar to form muscovite or phlogopite and tourmaline, resulting in an increase in solution pH and a decrease of Cl concentration and subsequent deposition of gold and palladium minerals.

May 1, 2003

By G. J. Hamilton

"THE Royalite-Canada Southern Coleville No. 1 gas strike of August 15th, 1951, and the closely following low gravity black-oil strike of August 23rd, were the first of a series of recent oil and gas discoveries in western Saskatchewan. They are in what is now known as the Coleville field, 25 miles north and west of Kindersley and 30 miles east of the Alberta-Saskatchewan border (Figure 1).Gas flows have been recorded in the Viking sand at daily rates of between 5 and 10 million cubic feet, and black oil of 15° A.P.I. gravity is produced from Mississippian sediments of Banff age at a daily rate .of 50 to 100 barrels on pump.Development drilling was carried on during the winter months, with very little attempt at step-out exploratory ventures. This year, however, a step-out programme to the northeast (Figure 2) is •being carried on in order to determine the position of a possible truncation of Mississippian sediments in that direction. Section 30 of the Coleville area has been fully developed on a 20-acre wellsite basis, and structural information is restricted to local rather than regional interpretation. No attempt will be made in this paper to interpret the Coleville area with respect to the regional geology in any but a general manner."

Jan 1, 1952

By H. Nakano

The codeposition behavior of impurities such as Ag, Bi, Fe, Ni, Pb and Sb with Cu was investigated galvanostatically at 5-3000 A/m2 using a Pt cathode at 60 °C in acidic copper (I) chloride (cuprous chloride) solution at pH1-2 containing 1.0 mol/L of Cu+ and 4.9 mol/L of Cl-. The impurities were classified into two groups: Group I (Ag, Bi) which codeposits with Cu as a metal, and Group II (Fe, Ni, Pb, Sb) which is slightly involved in the deposited Cu in nonmetal form from the electrolyte. Silver and Bi in Group I behaved as more noble metals than Cu, and significantly codeposited with Cu, showing typical features of regular-type codeposition. When Cu was deposited dendritically, the Ag and Bi content in the deposit increased with increased duration of electrolysis as a result of decreased net current density caused by increased cathode area. The current efficiency for Cu deposition in impurity-free solution was 95-100% over 100-1000 A/m2, but it abruptly decreased at above 1000 A/m2 when the limiting current density of Cu was attained. Although Fe, Ni, Pb and Sb in Group II were involved to 0.01-0.02 mass% in the deposit, they had no influence on the current efficiency or morphology of Cu.

Jan 1, 2007

By Alan S. Lock

Large scale feasibility studies for the establishment of oil-seed and cellulose producing crops on mine tailings have been successfully conducted over 1 growing season with the purpose of these crops to be used as feedstock to the biofuels industry. An acid sulphide tailings impoundment in Copper Cliff, Ontario and a near neutral pH goldmine tailings impoundment in Timmins, Ontario were both tested by amending half hectare plots to approximately 1 m thick with residual biosolids from the pulp and paper industry and growing canola and corn on these plots. Full scale agricultural equipment was used to cultivate seed and harvest the plots to prove the full scale feasibility of farming on these biosolids. The vegetation development, growth, yield, quality and composition were assessed to identify the best species that would maximize biomass development for feedstock to the biofuels industry and carbon credits for the mining industry. Groundwater, biosolids and tailings chemistries were investigated to identify potential deleterious impacts of degrading organic matter on tailings metal mobility. Preliminary hydrologic investigations using moisture sensor profiles elucidate potential conservation of water in amended plots. Tailings amended with biosolids have the potential to provide the mining industry with carbon credits and supply feedstock to this new industry while reclaiming brownfields to a new level, utilizing industrial and municipal organic waste material.

May 1, 2009

By Karl J. C. Harries

"14.1. INTRODUCTION1The boilerplate of an agreement is not a single provision, but a series of provisions that are expected in “every agreement”. They are sometimes also referred to as the “lawyer’s provisions”. Many businessmen consider the boilerplate to be superfluous and, to some extent, window-dressing by the lawyers – even legalese. They will often offer advice to the effect that it can “pretty well be ignored”. Such advice could not be more wrong.Most boilerplate provisions are essential parts of every agreement. Some may be part of a “standard package” and may have little relevance to the agreement at hand, but these are the exception rather than the rule. The exceptions should not be treated as justification for giving all these provisions short shrift. The boilerplate should receive the same review, consideration, and negotiation as the provisions that set forth the business deal. It is often these provisions that make the deal work or that are turned to at the time of disputes. If they are inadequate, as they sometimes are (unfortunately, some draftsmen are also loath to review or update their standard boilerplate provisions or to tailor them to the deal at hand), they can create problems, rather than offer solutions. Such problems can be costly and time-consuming for the parties to address. Inadequate or incomplete provisions may ultimately be one of the reasons for the parties to turn to the courts to settle their differences. On the other hand, good boilerplate provisions can help keep them out of the courts.One of the principal objectives of an agreement should be to provide procedures, or mechanics, for implementing agreed principles and for the parties to follow to settle their differences, real or perceived, without going to the expense and disruption of a lawsuit. An agreement should aim to keep the parties away from the courts, not serve as a springboard to the courts. It must nevertheless be acknowledged that, if there is a major falling-out among the parties to an agreement, the chances are that, however carefully the provisions of that agreement have been negotiated and drafted, the parties will end up before the courts or some other adjudicating body."

Jan 1, 2003