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By R. G. L. McCready, Marco Zentilli

"Brogan coal containing mean averages of 6,93% w/w total sulphur (1.1% sulphate sulphur, 1.6% organic sulphur and 4.24% pyritic sulphur) and 16.34% mineral ash was used as the test coal in these studies.Shake-culture leaching studies on seven size fractions of the coal, ranging in size from 0.045 mm to 1.7 mm, showed that the rate of pyrite leaching was inversely proportional to the particle size. As the use of continuous stirred tank reactors would be uneconomical for the reclamation of waste coal, column leaching studies were initiated on coal sieved to >6.35 mm to < 12.7 mm, The leachate was monitored for all metal ions and the release of iron was used to monitor the rate of pyrite oxidation . Measurable amounts of Zn, Co, Ni, Mn, and V, all of which can replace iron in the pyrite crystal structure, were released during the initial stages of leaching. Further, high concentrations of AI, Ca and Sr and trace amounts of Sn, As. Se, B, Ca, Cr, Si, and Ti were detected in the column effluents.These studies suggest that bacterial leaching will remove the pyrite and qualitative amounts of environmentally undesirable trace metals from the coal if such a process is developed for waste coal reclamation.IntroductionIn 1947, Colmer and Hinkle showed that acid mine drainage was the result of an oxidative attack of the iron-mineral sulphides by Thiobacillus ferrooxidans to produce sulphuric acid . Ashmead (1955) proposed the use of these organisms to desulphurize coal , but the subsequent research effort was concentrated on the metabolism and physiology of these extreme acidophiles.A limited number of studies have been reported on the bacterial leaching of pyrite from coal (Silverman et al., 1963; Dugan, 1977). However, the bacterial oxidation of pyrite is a self-limiting first-order reaction, probably due to the precipitation of Fe(OH)J and elemental sulphur , which progressively inhibits intimate contact between the bacterial cells and the sulphide-mineral surface. Consequently, the best pyrite oxidation experiments with coal reported to date required five days to remove 97070 of the pyrite (Dugan &Apel , 1978) using mixed cultures of T. ferrooxidans and T. thiooxidans."

Jan 1, 1985

By J. Chlan

"Dryer DescriptionProctor and Schwartz Continuous Conveyor DryerThe Proctor and Schwartz Continuous Conveyor Dryer has been in operation since July 1958, and comprises six unit• - an 8• wide single conveyor with roller extruder, insulated housing, type 304 stainless steel circulating and exhaust fall system, steam heating coils, temperature controls and discharge crusher rolls. Entire dryer dimensions are 52’ x 12'0""weighing 53,000 lbs,Extruder rolls - setting is 1/8"" (Drive 3 HP 1800 RPM) clearance off the extruder screen.Conveyor - consists of 151 interlocking pans, measuring 8"" x 8' (2 HP 1200 RPM) One Exhaust Fan (5HP - 900 RPM)Steam Coils -- l"" steel pipe - with steel fins -- each coil measures 16' 2’’- 64 coils in the No, 1 Compartment- 64 coils in the No, 2 CompartmentDryer OperationThe yellowcake slurry at 28% solids is pumped to an 81 x 8' Peterson Filter. The filter media presently being used is a Neotex 4372 blanket, being 100% staple fibre nylon, 12 oz per square yard with air porosity of 9 CFM's. The cake discharge at 45 - 50% moisture falls into the roller extruder. Extrusions are formed by forcing the material by rolls through a perforated plate moving back and forth and depositing the spaghetti-like extrusion on onto the dryer-conveyor.The conveyor now carries the extruded material through the heating chamber•, The feed end of the dryer will be referred to as No. 1 Compartment, with temperature control set at 280""F. The circulating fans take the hot air off the coils and circulate the heated air through the perforated openings in the dryer conveyor pane, After passing through the set of steam coils and circulating fan in No, 1 Compartment, the material then goes through No, 2 Compartment where the temperature is set at 305'F, Final material then discharges through a set of crusher rolls set at ~"". Moisture of final dried product runs at less than 2%.The dryer conveyor load is usually run to a 3"" - 4"" depth load. Conveyor speed at approximately 90 minutes for load to pass through. Load onto the conveyor is controlled by boot level and speed of the 8' x 8' filter. The dryer steam coils are water-washed twice a month."

Jan 1, 1972

"In the UK, Ireland, and Western Europe, the mineral resource and reserve reporting standard is the PERC Code, developed and maintained by the Pan-European Reserves and Resources Reporting Committee, which is a standing committee set up under the auspices of a number of professional organisations which include the Institute of Materials, Minerals and Mining (loM3), the Geological Society of London (GSL), the European Federation of Geologists (EFG) and the Institute of Geologists of Ireland (IGI) to develop a Pan-European reporting code. The PERC Code supercedes the old IMMM Reporting Code 2001 and is recognised by the UK securities regulators and stock exchanges.""FOREWORD1 The Pan European Reserves and Resources Reporting Committee (PERC) Code for Reporting of Exploration Results, Mineral Resources and Mineral Reserves (further referred to as 'the Code') sets out minimum standards, recommendations and guidelines for Public Reporting of Exploration Results, Mineral Resources and Mineral Reserves in the United Kingdom, Ireland and Europe. The history of development of this code is summarised in Appendix 4.This 2008 edition supersedes all previous editions of The Reporting Code and the IMM Reporting Code.INTRODUCTION2 In this edition of the PERC Code, important terms and their definitions are highlighted in bold text. The guidelines are placed after the respective Code clauses using indented italics. They are intended to provide assistance and guidance to users in interpreting the application of the clauses in the Code. The same indented italics typeface formatting has been applied to Table 1, and to Appendices 1 and 2 which form part of the Guidelines.3 The Code has been adopted by the Institute of Materials, Minerals and Mining (loM3), the Geological Society of London (GSL), the European Federation of Geologists (EFG) and the Institute of Geologists of Ireland (IGI), and is therefore binding on their individual members.Appendix 1 contains a table of generic terms and their equivalents, designed to avoid unnecessary duplication or ambiguity in the textAppendix 2 provides Rules of Conduct for Mineral Resource and Mineral Reserve estimators that should be considered in addition to the Codes of Ethics normally applying to members of professional institutions."

Jan 1, 2003

By B. Oraee-Mirzamani

One the most important tasks after excavation of tunnels is the implementation and installation of a support system. Tunnel collapse poses a safety hazard and can cause worker injuries. In addition, it may have a severe economic impact because tunnel collapse can stop production and ore transportation. Therefore, an appropriate and well-designed support system is necessary for collapse prevention and to help stabilize the tunnels. In this research, we suggest a support system for the Parvade1 underground coal mine. The study case is a common mining roadway tunnel in the E1 longwall panel in this mine. To design an appropriate support system, we used the finite element method (Phase2 software). The results of this research can be used to design support systems for future tunnels in this mine and any coal mine that has similar conditions.

Aug 1, 2013

By W. Grell

"In this paper, two methods of standardizing mill language are proposed; one is based on metric units and the other on English units. Tentative procedures for chemical and screen analysis based on published methods are proposed.Standard procedures for determining work index, and for leaching, flotation, and classification tests are outlined.Objects of Standardization:(1) to improve communication -(a) among gold metallurgists(b) with other branches of mineral dressing(c) with mineral dressing in other countries(d) with general scientific procedure(2) to improve mill control by -(a) standard methods of analysis (i)(ii)(iii)(b) standard methods of calcula tiort(c) standard accounting proceduresin the plantin the mill laboratoryin the assay office(3) to improve mill test work and investigationAreas of Standardization(1) Nomenclature or terminology(2) Measuring techniques(3) Test procedures(4) Accounting procedures"

Jan 1, 1966

By D. M. Bastidas

The reduction of copper sulfide and copper oxides originated during artificial tarnishing of copper was studied using potentiodynamic potential/current density experiments. Six copper surface treatments were considered: mechanical polishing; indoor exposure for 7 days; chemical etching in 1.6 M nitric acid; chemical etching and heating at 160°C; and chemical etching and dipping in a 9x10-4 M or 0.9 M potassium sulfide (1(25) solution at 70°C. Cuprite (Cu20) and chalcocite (Cu2S) were the main compounds formed. A linear relationship with the square root of the scan rate (v) was obtained by plotting the potentiodynamic potential/current density for the tarnish dissolution processes. A relationship between potential and current density cathodic peaks was not obtained, according to Müller&apos;s model, showing a proportionality factor with the dimensions of a resistance.

Jan 1, 2007

By T. Takahashi, K. Oyamada, Y. Miyata, T. Isoo

The carbonation reaction of steelmaking slag has been known for many years. However, the size of blocks manufactured from this by-product material has been limited due to the difficulty of achieving a uniform reaction throughout the block. Using newly developed conditions, large porous slag blocks (1.0 x 1.0 x 0.5 m) were produced by car¬bonation of steelmaking slag with the optimum amount of water and supplying CO2 deep into slag powder compacted in molds. The development of these blocks has great poten-tial to solve the problem of slag utilization, for example, by recycling slag in large car¬bonated blocks for artificial fish reefs and seaweed cultivation beds. This paper de¬scribes the carbonation reaction, the new process for producing large slag blocks, and the utilization of blocks in past and recent years.

Jan 1, 2004

By R. W. Thompkins

"PREFACEPart 1 of this paper, published in the September issue, covered the occurrence of uranium, radiation from uranium ores, the uranium series, radioactive theory, radioactive equilibrium and application to the radon series, the working level, the theory of emanation and diffusion, transport by thermal diffusion of radon emanating from porous rocks, and definitions.The October issue carried Part 2, which dealt with radiation theory applied to uranium ores, other radon migration factors, factors affecting the radon gas release rate, the measurement of radon gas emanation rates, the tunnel concept, variation of emanation rate with grade and estimating radioactivity from grade analysis.Part 3, in this issue, concludes the series by discussing the techniques for controlling radiation and providing some example calculations.17.0. Techniques for Controlling Radiation17.1. Altering the Factors In the Diffusion EquationIt has been noted that radon gas emanates from the surfaces of exposed ore to the mine atmosphere. The diffusion laws establish the rate of this flow. The fundamental relationship is that the rate of flow (J) is a function of the pore concentration and the distance from the surface. It is expressed as: []If any of these terms is varied, either naturally or artificially, the rate of gas emanation will be altered.Altering the Diffusion CoefficientThe literature describes many ways to lower the radon gas emanation rates which are dependent on changing the diffusion coefficient:1. A layer of ice on top of a tailings dam or on a soil.2. Humid clayey materials and swamped soils over a radon source."

Jan 1, 1982

By R. C. Hartviksen

"The Drumbo Mine is a new gypsum mine located at exit No. 32 of Highway 401 between Woodstock and Kitchener, Ontario. The flat-lying 6-foot (1.8-metre) bed of gypsum is near the base of the Silurian Salina Formation, about 380 feet (116 metres) below surface. The mine is owned and operated by Westroc Industries Limited. A shaft, 12.5 feet (3.81 metres) in diameter, was drilled and then lined with a liner-sinking technique new to this continent. The shaft was completed in the fall of 1977. Gypsum production was started in December 1978, employing a conventional room - and - pillar method of mining.Historical BackgroundA brief mention of gypsum in the Drumbo area is included in a survey of the Ontario gypsum industry by Guillet. This occurrence was discovered in 1958 when National Gypsum conducted some widespread diamond drilling. Western Gypsum Products Limited acquired leases in 1960 and concentrated a drilling program in Blenheim Township near the village of Drumbo; 79 holes were drilled in an area of 1900 acres (770 hectares). Mining rights were then acquired for 170 0acres (690 hectares). A test shaft, 44 inches (1.1 metres) in diameter, was drilled to obtain a 50-ton (45-tonne) bulk sample. This opening will be used as an emergency escape way and for ventilation.Westroc Industries Limited, a wholly owned subsidiary of BPB Industries, has its head office at Mississauga, Ontario and operates gypsum board plants at Mississauga, Vancouver, Calgary, Winnipeg and Montreal. Other gypsum mines are at Windermere, B.C. and Amaranth, Manitoba."

Jan 1, 1983

By P. Maltby

"Smelter Feed Preparation Falconbridge Nickel Mines Limited, Sudbury Operations, operate 4 mills and a smelter to produce Bessemer Ni-Cu matte for refining in Norway. Approximately 1400 tons of Ni-Cu concentrate are produced daily which are dried from a filter cake containing 14% moisture to 7.5% moisture pellets. Concentrate drying is done by 4 rotary dryers as shown in the 'Dryer Performance Data' at four separate locations. The dryers all form part of the feed preparation stage prior to sintering.The rate at which concentrate can be produced through the Sinter Plant largely depends on the quality of the dried product which makes up the feed. A feed consisting of mostly hardened pellets will sinter much faster than a feed which consists of broken pellets and dust. Dryer products require:1. Good green strength to survive shipment and handling.2. Correct moisture content.3. Sizing within a range ideally from 1/4"" to 10 mesh in diameter.Dryer performance data is shown in Table 1. Capital costs between the two types of dryers are comparable with the Roto-Louvre producing generally a larger better-formed pellet. Dryer feeds differ in that at both Hardy and Fecunis, Ni-Cu concentrate filter cake is the only feed while at the Falconbridge slurry plant the dryer feed can consist of up to 10% by weight of smelter flue dust resulting in a combined concentrate-dust pellet for feeding to the Sinter Plant. To the Falconbridge Sinter Plant dryer, dust and limestone are added for the smelting process in addition to Ni-Cu concentrate."

Jan 1, 1972

By C. F. Harris

Following the initial development of the zinc-lead blast furnace, efforts have been directed both at increasing the scope of the process and increasing the cash return. The paper reviews the process developments which enable the process to smelt efficiently a range of material which encompasses high-grade zinc sulphide concentrates. mixed concentrates, Waelz oxide, zinc ashes and other materials blended to give a furnace feed ranging from 25 to 65% zinc and from 1 to 25% lead, with a copper-lead ratio exceeding 1 to 8. The paper also reviews the process developments which have enabled the capacity of a furnace and condenser system of standard size to be boosted from 30,000 to 80,000 tonnes/annum. The benefits achieved are used as a justification for continuation of the development of the zinc-lead blast furnace. Predictions are made of the benefits expected from further developments.

Jan 1, 1979

By C R. Evans

Whole-rock and muscovite potassium-argon dates from selected low-grade metamorphic rocks of Precambrian age in the Canadian Rocky Mountains near Jasper, Alberta, were obtained to ascertain the age of the source terrain and the age of the metamorphism. Ten argillites gave whole-rock dates ranging from 270 to 485 million years, dates which are apparently inter-mediate between the age of the source material and that of the metamorphism. "Up-dating" increases with the degree of orientation of muscovite in the cleavage plane, and with the ratio of the muscovite in the cleavage plane to that in the plane of the bedding. Detrital muscovite from four arenaceous rocks gave dates ranging from 1,050 to 1,780 million years. "Updating" increases with decreasing grain size, so that, within the range investigated, the cube of the median diameter (¢) of the muscovite is apparently proportional to the radiometric date.

Jan 1, 1964

By Z. -E. Nakagawa, O. Yamamoto

After the formation of a concentration gradient of SiC within C-C composite, either zircon or mullite thin films were coated on the surface by sol-gel process. Oxidation resistance tests of as-prepared composites with a couple consisting of a ceramic thin film and a SiC-gradient were then carried out in air at the temperature range from 600 to 1600°C. By the coating of zircon with a thickness of 1.5 µm, a pronounced oxidation resistance was observed; the mass loss by oxidation was almost negligible at 1000°C and one hundredth of original composite at 1400°C. In the case of the coating of mullite with a thickness of 1.0 pm, the marked improvement in oxidation resistance over the whole temperature range examined, from 600 to 1600°C, was found with the combination of a SiC-gradient and a mullite thin film

Jan 1, 2004

By L. Avramovic, B. Han, R. Jonovic, Z. Stevanovic, K. Haga, S. Dimitrijevic, A. Shibayama, L. Godirilwe, Y. Takasaki

Pyrite (FeS2) and chalcopyrite (CuFeS2) which could not be recovered, are present in mine tailings discharged from Bor copper mine. About 0.3% of copper (Cu) is contained in these tailings, therefore it can be considered as a useful copper resource. At the same time, pyrite is known to promote acid mine drainage, therefore it is necessary to detoxify the tailings. An efficient method has been proposed to recover copper and reduce the environmental impacts of tailings by a combined hydrometallurgical process of high pressure leaching (HPL), solvent extraction (SX) and electrowinning (EW) process. HPL process yielded high copper leaching rate (>95%) when water (H2O) was used as a leaching media. On the other hand, pyrite contained in the tailings was converted to iron oxide by high pressure leaching. Stability evaluation of the residue obtained from high pressure leaching, confirmed almost no elution of metal ions. The percentage of copper extracted and stripped from the Cu-loaded organic phase reached 97.4%. Moreover, it was confirmed that a low iron concentration in the electrolyte of copper electrowinning, resulted in the improvement of current efficiency of copper electrodeposition. INTRODUCTION Mine tailings are a by-product obtained from the flotation process and there are billions of tons of already existing tailings all over the world. Moreover, several billion tons of additional copper tailings will inevitably be produced in the coming years (Onuaguluchi & Eren, 2012). With the declining average copper ore grade, alternative sources of copper are highly sought, mine tailings have a comparable copper grade to that of low-grade ores (0.2–0.3%) therefore, it can be said that copper mine tailings present a very important source of secondary raw material for copper production (Antonijevi´c et. al., 2008). Consequently, it is necessary to confirm the possibility of the valuable metals (such as copper) recovery from mine tailing in which copper content is about 0.2–0.3%. Our group investigates the flotation and high pressure leaching processes for recovering of copper from mine tailings. Previous work on related samples include copper and nickel flotation tailings from Botswana, and a low–grade copper ore sample from Chile. Impurities, which are associated metals in mine tailing such as iron (Fe) and aluminum (Al) co-dissolve into the solution during the HPL treatment process. Therefore, separation of copper from impurities is necessary for selective extraction of copper from mine tailings and upgrading the copper concentration in the leachate to enable further purifying of Cu by electrowinning. Thus, it is important to investigate the possibility of applying solvent extraction for concentration of copper from leachate solutions of mine tailings (Onuaguluchi & Eren, 2012; Antonijevi´c et. al., 2008). In this study, LIX-84I was used as an extractant of copper from the leachate of high pressure leaching of mine tailing. As a fundamental solvent extraction investigation, the extraction behavior of copper was studied using a simulated solution of the leachate from the high-pressure oxidative leaching of mine tailing. The effects of; solution pH, extraction time, extractant concentration and phase ratio on copper extraction and sulfuric acid (H2SO4) concentration on stripping were investigated.

Jan 1, 2019

By A. A. Lavrinenko, N. I. Gluhova, L. M. Sarkisova, D. V. Makarov

"The investigated sulfide Cu-Ni ores are characterized by low PGE contents and emulgated impregnations of pentlandite and palladium minerals in the main ore-forming mineral pyrrhotite, which hinders their selective separation, requiring a collective flotation of sulfides to concentrate, and hydrometallurgical processing. As revealed by studies of floatability of Pt-Cu-Ni ore in a mixture of butyl xanthate and chelating phosphorus containing reagents, the most effective additive is Aerophine 3416 (a phosphinates mixture) manufactured by Cytec. Using collective flotation with a butyl xanthate – Aerophine 3416 composite in the ratio of 1:3 has afforded to enhance the Pt, Pd, and Ni recovery by 13.6 %, 9.2 %, and 9.4 %, respectively. The optimal ratios of Aerophine 3416 to butyl collector for the collective flotation are the following: 1:1 for Pt and Pd and 3:1 for Ni. The effect of these reagents on the electrode potential and surface hydrophobicity of pyrrhotite, pentlandite, and platinum black has been investigated. The extraction UV spectrophotometry experiments demonstrate that DIBDTPI exists on the pyrrhotite surface mainly in the form of disulfide in weak acid medium and in the form of compounds with Fe on the mineral surface in minute amounts. There appears some disulfide and few amount of (DIBDTPI)2Ni on the surface after interaction of DIBDTPI and pentlanditeINTRODUCTIONXanthates are widely used in flotation of copper-nickel ores containing platinum group metals (PGM) as sulfides collectors which can concentrate the most part of PGM connected with the sulfides. Though xanthates are hardly efficient for flotation of free PGM, the latter are floated more slowly compared to the sulfides of base metals. The reasons for poor floatation of free (mineral) forms of PGM are under-researched, however the key accepted reasons are: fine disseminations of free PGM, insufficient interaction with xanthate and negative influence of blue copperas and sulfur-containing ions which are sulfides oxidation products (Penberthy et al. 1999; Shackleton et al., 2007). That’s why an additional collector, normally dialkyldithiophosphates, is used during flotation of PGM-containing copper-nickel ores. A reagent DP-4 is used for recovery of PGM at Norilsk mining and metallurgical plant. The reagent represents a slightly-soluble organic calcium sulfonate which is given to flotation pulp in the form of water emulsion of 5% - solution in automotive diesel oil."

Jan 1, 2016

By G. Sedelnikova, D. Kim, N. Ibragimova

"The object of this study was three samples of sulfide old tailings, which were obtained after Cu- Zn ores processing. Fine metal dissemination in sulfides as well as fine mineral intergrowth determine the refractory nature of material and low metal extraction using simple methods: gravitation 1-6%, flotation 32-48%, cyanidation 10-37%, and cause the need to use sulfide bio-oxidation to liberate gold and to recover it by heap leaching. The gold is the main valuable metal in the tailings with content 1-1.5 g/t. Heap bio-oxidation with mesophilic and moderately thermophilic bacteria was used for pre-treatment of tailings before gold heap leaching from bio-oxidation solid residues. The tailings have a low permeability < 0.3-1.2 m/day, which is caused by migration of fine particles, decreases recovery rates, and is poorly suited to heap bacterial leaching. Therefore, preliminary gold sulfide tailings with permeability < 0.3 m/day were pelletized using copper containing flotation tailings of converter slags and calcium oxide. The most gold extraction was obtained for pelletized tailings. The base metals (copper and zinc) were precipitated from bacterial solutions. Experiments have demonstrated effective bio-oxidation of all third gold sulfide tailings samples and enough high gold extraction 60-82%.INTRODUCTIONIn Russia, as everywhere, there is a trend toward deterioration in the quality of mineral resources, including non-ferrous and precious metals, manifested in lower grade and higher complexity of ores. The proportion of refractory ores is increasing, characterized by fine dissemination of metals in sulfides, intergrowth, and poor liberation of minerals during concentration, resulting in loss of base and precious metals to flotation tailings.Over the operation period, huge reserves (hundreds of million tons) of ore processing waste have been accumulated at mining and concentration operations. Because of the imperfections of the previously used ore concentration technologies, the content of precious and base metals in flotation tailings is comparable with the grades of the ores being currently processed. Therefore, old tailings can be viewed as an additional reserve of non-ferrous and precious metals. The works (DEN, 1997; Lyman, Johnson, & Guerney, 2000) demonstrate that, tailings containing sulfides (sulfur, copper, zinc, and other metals) are a potential environmental hazard since they produce acid drainage water containing toxic components. Processing those tailings would require designing an effective technology for recovering useful components and protecting the environment."

Jan 1, 2016

By Weimin Fu

Chondrite-normalized rare earth elements (REEs) profiles and high field strength elements (HFSEs) in rocks and minerals represent important tracers of geological processes. Of these the birdwing-shaped profile with negatively-sloped light REE ((La/Sm)N >1), positively-sloped heavy REE ((Tb/Yb)N <1), and strong negative Eu anomalies is commonly associated with large-scale hydrothermal systems or granitic intrusions. In a different way, severe deviation of Nb/Ta, Hf/Sm ratios from those of chondrite may also indicate hydrothermal signatures in the rocks involved as these ratios are generally stable and chondritic in normal magmatism as a result of their nearly identical ionic radii and charge. In this study, we present a typical setting where birdwing-shaped REE profiles together with Nb/Ta, Hf/Sm ratios unusually higher than those of chondrite, are systematically developed in a series of garnetite, quartzofeldspathic gneiss, Fe- or Mg-rich aluminous gneiss, and sulfides and magnetite. These units and associated Cu-Au mineralization form a VHMS-style hydrothermal system in the granulite-facies 1.4 Ga -1.35 Ga volcano-plutonic, arc-related Bondy gneiss complex (BGC), western Grenville Province, Canada. Outside the recognized hydrothermal system of the BGC, such REE profiles are not observed. Instead the surrounding felsic and mafic gneisses display primary trace element characteristics of island-arc magmas, suggesting that granulitefacies metamorphism did not modify significantly the trace element signatures of the protoliths. Although magmatic fractionation of accessory minerals can produce birdwing-shaped profiles, it cannot explain the extreme fractionation of isovalent trace elements (Nb-Ta) and the high Zr content of the hydrothermal rocks. Neither is it compatible with the lack of significant Nd depletion that would normally incur during this process. Following our study, we demonstrate that F-rich fluid and mineral phases enriched in LREEs and HREEs respectively must have been involved in the main hydrothermal alteration and REE fractionation process in the BGC. Preferential removal of REEs from the interstitial glass of the volcanic protoliths together with dissolution of plagioclase and subsequent external influx of HREEs and HFSEs can produce birdwing-shaped REE profiles. In turn, such profiles and/or unusual Nb/Ta, Hf/Sm ratios can be used as a sensitive marker of hydrothermally altered rocks in targeting mineral exploration.

May 1, 2003

By R. V. Hopper, M. E. Wilson, L. S. Trenholme

"The Company known as Rouyn Merger Mines, Limited, was formed in 1943 to take over the ownership of claims in Rouyn and Joannes townships formerly held by East Rouyn Mines, Limited, O'Neil Thompson Mines, Limited, and the Hosking-Cockeram Prospecting Syndicate. The NorandaSenneterre branch of the Canadian National railway passes in an approximately east-west direction through almost the entire length of the property. Since 1937, sixty-three diamond drill holes have been drilled from the surface to cross faults on the contact of the Timiskaming sediments with the Abitibi ( Keewatin) volcanics, along which ore has been found to occur. Late in 1945, the sinking of a 3-compartment inclined shaft in the andesite agglomerate beneath the ore zone was commenced. On January 17th, 1947, this shaft had a depth of 944 feet; cross-cuts have been driven north-northwest from the shaft at 150-foot intervals from depths of 200 to 800 feet on the shaft (Fig. 2).GEOLOGYThe western or East Rouyn part of the Rouyn Merger property in which ore is being mined adjoins the area owned by McWatters Gold Mines, Limited, on the east and is underlain by the eastern continuation of the McWatters formations. As at the McWatters, the rocks belong structurally to three areas: (1) the territory north of the Cadillac-Bouzan Lake fault, occupied almost wholly by Abitibi ( Keewatin) volcanics; (2) the area along the south boundary of the property, underlain by Timiskaming conglomerate and greywacke; and (3) the synclinal belt of McWatters volcanics and sediments between areas 1 and 2.1Bouzan fault of Hawley."

Jan 1, 1954

By S. M. Bulatovic, D. M. Wyslouzil, K. R. Rawlings

"The suitability of a new organic reagent DS20 as a depressant for oxidized and carbonaceous pyritic lead-zinc ore from Nanisivik Mines Ltd. has been evaluated in the laboratory and in the plant.The depressant DS20 is a mixture of Lignosulphonate-Dextrin-Quebracho and was developed specifically for depression of highly oxidized and carbonaceous pyrite.The laboratory test work indicated that the poor metallurgy resulting from the oxidized ore could be improved to normal plant performance by the addition of the DS20 depressant with the existing plant reagents. The laboratory data suggested that lime consumption could be reduced when using DS20.In this paper, the development work and the plant trials with DS20 are described.INTRODUCTIONNanisivik Mines Ltd. treats approximately 2000 tonnes per day of lead-zinc massive sulphide ore, containing currently 1% Pb and 9% Zn. The concentrator operations have been described previously (1,2) and typical metallurgical performance is detailed in Table I.The concentrator flowsheet (Figure No. 1) and the standard reagent scheme (Table No. 2) demonstrate the relative simplicity of treatment of this coarse grained ore.A recently discovered satellite orebody - Area 14 - containing 2% Pb and 12% Zn was brought into production in October 1983. This ore had been oxidized to varying degrees by ground water; the pyrite mineralization was found to be very fast floating and a carbonaceous constituent present in higher than normal proportion also affected flotation. The simple high lime addition could not control the pyrite, and very low grade lead concentrates resulted; zinc metallurgy was also affected by this oxidized condition (Table 3)."

Jan 1, 1986

By O. S. Perry, G. H. Charlewood, K. Griffin, S Ogryzlo, H. Hopkins, G. MacIntosh

"The gold mines of Kirkland Lake are in Teck township, Timiskaming district, Ontario, latitude 48°9'N. and longitude 80°3'W., at an elevation of 1,038 feet above sea-level.There are seven contiguous producing mines in a length of 3;1/2 miles along the general east-west strike of the deposits. The seven mines are, in order from west to east, Macassa, Kirkland Lake, Teck-Hughes, Lake Shore, Wright-Hargreaves, Sylvanite, and Toburn.The first discovery of gold in the zone was made by W. H. Wright in 1911 on the east claim of the Wright-Hargreaves property, and the following year the Tough brothers and H. Oakes found gold in what is now the No. 1 vein_ at the Toburn. Production began at the Toburn in 1915, followed by Teck-Hughes in 1917, Lake Shore in 1918, Kirkland Lake Gold in 1919, Wright-Hargreaves in 1921, Sylvanite in 1927, and Macassa in 1933.To the end of 1946, 31,938,350 tons of ore had been milled at the Kirkland Lake mines, from which 16,132,700 oz. gold, having a value of $498,517,600, were recovered. The bullion varies from mine to mine between 800 and 900 fine, the average for all the mines being 853. The average fineness of the native gold is 941.The workings of some of the mines are more than 6,000 feet deep and sinking to depths below 7,000 feet is now in progress.GENERAL GEOLOGYThe regional structural geology of the area in which the mines of Kirkland Lake occur is described in a preceding paper in this volume by J. E. Thomson."

Jan 1, 1954