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By G. P. Gu

The in-service 90/10 cupro-nickel tubes in a water-chiller system suffered from severe corrosion damage during their relatively short service life causing unexpected down time. In addition to downtime, the environmental risk associated with losing refrigerant was also a concern that initiated this investigation, Microstructural investigation using SEM and electron microprobe indicated that pitting corrosion had resulted in local nickel depletion, During the corrosion process, copper appeared to have re-deposited around the corrosion pits accelerating the local corrosion.

Jan 1, 2005

By V. G. Papangelakis, G. P. Demopoulos

"Recovery of gold from refractory ores and concentrates presently constitutes one of the most important, challenging, and exciting areas of R&D activity in the gold processing industry. New technologies are being tested for the treatment of refractory gold materials, some of which have been advanced to the level of commercial operation. In this paper, some recent technological developments in the hydrometallurgical processing of pyritic matrix-refractory gold ores are highlighted. Key operational steps of each of the alternate hydrometallurgical technologies are analyzed and potential advantages and drawbacks are identified. The processes which are reviewed are: hydro chemical oxidation, biochemical oxidation and pressure oxidation. INTRODUCTIONOver the years the term ""refractory"" has been applied in gold ore processing to denote situations in which straightforward cyanidation failed to yield high gold recoveries. A number of mineralogical and chemical factors may be responsible for this ""refractoriness"" problem. A systematic classification of the different options for their treatment has been discussed in a recent review paper. In this paper, the pretreatment of the submicroscopic gold encapsulated within the matrix of pyrite and arsenopyrite minerals is considered. This type of gold is the ultimate refractory material because complete breakdown by reaction of the host mineral structure is required.The method which has been traditionally applied for the treatment of pyritic-type refractory gold ores is an oxidation roast (single stage or double stage depending on the As content) of a flotation concentrate to produce a porous calcine, the latter being more amenable to cyanidation. Despite its established practice, oxidation roasting is not considered particularly attractive with today's standards for high product recovery and clean environment. Roasting is known to be very sensitive to heating parameters and feed composition and deviation from optimum conditions can result in reduction in permeability which is translated to incomplete gold liberation."

Jan 1, 1989

By J. Dufour

Although the recovery of nitric and hydrofluoric acids from stainless steel pickle liquors has been solved by several methods, such as solvent extraction, acid retardation, evaporation or pyrohydrolysis, metals (mainly iron, chromium and nickel) are usually obtained as a waste or by-product that has to be disposed. Alternatively, the treatment requires a high liquor flow to be economical, as is the case for pyrohydrolysis. A new process has been developed for metals recovery, that produces metal oxides with a low fluoride content. This new technique is based on a selective precipitation mechanism, which produces nickel hydroxide with a purity of 90%, separate from a mixture of iron and chromium oxides and hydroxides suitable for recycling. The reaction mechanism is based on the precipitation of fluoride compounds of iron and chromium, K2FeF5 and CrF3. For this purpose, free fluoride must be added as potassium fluoride. Also, solid fluoride compounds are hydrolysed, releasing free fluoride. A part of the fluoride is recycled to the selective precipitation operation and the remainder is fed to the acid recovery stage. Nickel does not react in this operation; it remains in solution giving a high separation yield.

Jan 1, 2006

By Bruce K. McKnight

"The new H-W orebody was evaluated by considering its production at three technically feasible rates. Capital and operating costs were estimated f or each rate and production sequences were established using mining cutoff limits generated by an ore value algorithm. The viability of the project was then examined by conducting economic and financial analyses of each of the three production cases under various world economic scenarios. These analyses employing standard profitability measures demonstrated all three cases would be economically viable; the production case which maximized the Net Present Value of the project was the one selected for development and production.IntroductionWestmin Resources Limited and its predecessor company, Western Mines Ltd., has been continuously carrying out mining operations near Myra Falls in Central Vancouver Island since December 1966. The mining operation, whose current production rate is approximately 830 tonnes / day (t/d), based on ore derived from the Myra and Lynx Mines, produces copper, lead and zinc concentrates which contain significant quantities of gold and silver in addition to the base metals.In the late 1970s, with Lynx and Myra ore reserves slipping to unacceptably low levels, a major increase in mine-site exploration was initiated, with outside geological staff brought in to complement the efforts of the mine's geological staff. By the end of 1979, this program had resulted in the discovery of a significant new orebody on a deeper horizon some 300 metres below the one which hosts the Lynx and Myra deposits. Throughout the period 1980-1982, major drilling was carried out to evaluate the new H-W deposit and by the end of 1982, drill-indicated mineral inventory for the deposit compared with Myra, Lynx and Price ore reserves was as shown in Table I. During this same three-year period, a major development and evaluation program was underway comprising environmental monitoring and control programs, shaft sinking test mining, bulk sampling and mill testing, rock mechanics studies and preparation of the Stage I and II reports for the multidisciplinary Environmental Land Use Committee (ELUC).As a result of the preliminary engineering work and exploration drilling, it became rapidly apparent that the H-W deposit could support a considerably higher production rate than the current one. Accordingly, engineering studies including scheduling of development and production as well as capital and operating cost estimates, were focused on three possible production rates: 1350, 1800 and 2700 t/d. Our task was to select the optimum one of these three rates."

Jan 1, 1987

By J. W. Smith, J. G. Eacott, D. H. Napier

"Three hydrometallurgicat processes (Noranda chloride leach, B. C. Research biological leach and Sherritt-Cominco activated oxygen leach) and the Noranda pyrometallurgical process have served as the basis for design projects in the final year of the chemical engineering program at the University of Toronto. Each member of a team of five or six students devotes about 200 hours to the project and the final report is expected to include an economic analysis.None of the processes has been developed to full- scale plant, nor, in the case of the B.C. Research and Noranda processes, were pilot plant data available. Nevertheless, the designs developed provide a useful basis for a preliminary estimate of capital and operating costs and for a preliminary assessment of project feasibility.This paper discusses the approach used in the design projects with respect to engineering and economic aspects, and outlines the educational features and benefits of such a program as well as some of the problem areas that arise.IntroductionAs part of the undergraduate degree course in chemical engineering at the University of Toronto, students devote some 200 hours to a design project in their final year. Hydrometallurgical processes, not yet proven at the commercial scale, have been selected for study. The students are required to develop laboratory and / or pilot scale results into a conceptual plant design, using sound engineering principles. Capital and operating costs are then determined and a preliminary feasibility study and economic analysis are carried out."

Jan 1, 1986

"The Pierre Beauchemin Mine attained commercial production in January 1989, and went on to produce 23 968 ounces of gold for the year, 3% higher than forecast. Underground development was accelerated to prepare the way for the production of an estimated 40 000 ounces in 1989.IntroductionThe Pierre Beauchemin Mine is located nine miles west of the city of Rouyn-Noranda (Fig. I).As a result of the amalgamation with Sullivan Mines in October 1987, the mine is now entirely owned by Cambior Inc.The Eldrich deposit was discovered in 1953and began production in 1955, closing in 1962 following the decrease in gold prices and the simultaneous decrease in silica content in the ore, which was sold to the Noranda smelter for flux. A total of 717 000 tons grading 0.14 oz Au/t were produced during this period.From July 1984 to October 1987, an underground exploration program was carried out by Sullivan on the Eldrich mining concession and the nearby Flavel property. The first phase of the program included reinstallation of surface facilities and dewatering of the Eldrich Mine. Following the completion of the first phase, extensive exploration was carried out, including a major program of diamond drilling. It was then decided to deepen the shaft to a depth of 1800 ft to access a new zone called the No.5 Zone .Following the amalgamation with Sullivan in October 1987, Cambior assumed the role of operator for the project, and continued the shaft deepening work that had already been started. A feasibility study was completed in April 1988 and the Cambior board of directors approved a production decision for the Eldrich-Flavel project.The preproduction program extended from May to December 1988 and was aimed at preparing the stopes in the upper part of the mine and at developing the mine infrastructure at the bottom of the mine.The mine was officially opened in August 1988. Cambior renamed the project the Pierre Beauchemin Mine in recognition of Pierre Beauchemin's pioneer-work."

Jan 1, 1990

By H. Kroog

"This contribution reports recent mineral sorting experience and lists the possibilities of the newest generation of automatic mineral sorters with a special focus on electromagnetic detection, optoelectronic technology and the latest innovative X- Ray transmission units. In industry, mineral and ore are still hand-picked and current automation potential is only utilised in a handful of specific applications. Recently a number of technological developments took place that may increase sorting potential, save mill costs and lead to lower overall tonnage costs. The mentioned technologies provide automatic dry separation of minerals and rock as an alternative for conventional processing. The MikroSort technology is environmentally friendly:•,The remaining waste is free of contaminations•,The dump volume is reduced•,The concentration of the high grade material•,at an early stage saves resources"

Jan 1, 2005

By James D. Bliss, David M. Sutphin

"On the basis of differences derived from genetic, descriptive, and grade-tonnage data, graphite deposits are classified here into three deposit types: disseminated flake, amorphous (microcrystalline), or graphite veins. Descriptive models have been constructed for each of these deposit types, and grade-tonnage models are constructed for disseminated flake and amorphous deposit types. Grade and tonnage data are used also to construct grade-tonnage models that assist in predicting the size and grade of undiscovered graphite deposits. The median tonnage and carbon grade of disseminated flake deposits are 240 000 tonnes and 9% carbon and for amorphous deposits, 130 000 tonnes and 40% carbon. The differences in grade between disseminated flake and amorphous deposit types are statistically significant, whereas the differences in amount of contained carbon are not .IntroductionIndustrial minerals, including mineral construction materials such as sand, gravel, and crushed stone, have historically exceeded metals in global production value. Today, industrial minerals are being used in new and sophisticated ways in response to the late 1980s emerging information- and service-based economies' requirements for less metal and more industrial minerals . Natural graphite is an example of one such mine ral that has been known since ancient times, and is now finding new applications. Graphite was first used as an industrial mineral in Bavaria in 1400 A.D. where it was an important component of crucibles. Traditionally, natural graphite has been used in heavy industries. New applications, such as development of carbon-magnesite bricks a decade ago and the current advancement of alumina/graphite refractories, are increasing its graphite use. Other new uses for natural graphite, such as the use of graphite powder as a thermal blanket for the continuous casting o f steel (Northern Miner, 1987) and the addition of expanded graphite to polyurethane foam where it acts as a flame retardant (Industrial Minerals, 1987), are increasing the demand for this mineral. To meet future demand for graphite and other industrial minerals, knowledge of the characteristics of the deposit types in which they are found is important. A further look at the deposit types for graphite and at construction of descriptive and grade-tonnage models is warranted .The graphite industry recognizes three basic types of graphite , distinguished primarily on the basis of grain size: crystalline flake, lump and chip, and amorphous. These naturally occurring forms of graphite are products of metamorphism and are found in schists of various types, gneisses, and marbles. Temperatures of at [east 400°C are thought to be required for graphite formation (Landis, 1971). Synthetic graphite, also known as artificial or manufactured graphite, is a man-made carbon product and offers higher purity and lower crystallinity than natural graphite. Several authors have written about graphite's unique physical and chemical properties and the uses for individual types of graphite (Krauss et 01., 1988; Graffin, 1983; and Harben and Bate s, 1984)."

Jan 1, 1990

By E. M. De Souza

"The mining industry has developed a strong need for monitoring underground openings since bulk mining, used for increased productivity, has become the dominant mining method industry wide. The large stopes associated with bulk mining methods generally have to remain open and stable for several months, and monitoring is essential to provide an indication of ground response to mining and stope stability. The instrumentation data is also important during design optimization, which is used to maximize recovery, to minimize the dilution of ore and to minimize costs. Monitoring is essential to implement safety and is also critical in stope and mining sequence designs. The safety related aspects of monitoring include the protection of underground workers and the prevention of accidents by providing early warnings of the onset of any ground instability. The design related aspects of monitoring involve the development of data bases used for stope dimensioning and mine sequencing and timing and the monitoring of ground behaviour as a result of mining to verify the validity of the design thus allowing for remedial action during operation.Manual instrumentation data collection is, in a number of cases, economically unfeasible and, in many situations, dangerous as instrumented areas become inaccessible or extremely unstable. Also, because more and more complex instrumentation is being installed in underground operations, in several cases it becomes practically impossible to collect readings manually. The design and development of low-cost acquisition systems for mine wide monitoring would thus constitute an important step toward automation in excavation instrumentation. A unique menu-driven automatic 32-channel analog data acquisition and analysis system with a built-in rock failure warning mechanism has been designed and developed. This low cost acquisition system is capable of receiving, processing, displaying and storing the transmitted instrument data remotely and automatically. Computer software has been designed to provide data reduction and analysis immediately in the field and to automatically display results in graphical form for quick interpretation. Automatic data interpretation is used to show trends in rock mass behaviour and the system can be used to provide early warning of rock failure to the mine personnel working in there so that immediate remedial action can be safely taken."

Jan 1, 1992

By T. Alan O'Hara

"The decision to invest capital in developing a mine and constructing a mineral processing plant and services is usually made after a feasibility study shows 'that the estimated future cash flow from mine operations will yield an adequate return on the estimated capital expenditures.The actual return on investment may differ substantially from that estimated in the feasibility study, because of the probabilities of errors in estimating capital costs, ore reserves, operating costs, mineral revenue and operating productivity. This paper outlines the R.S.S. (root sum of squares) risk analysis procedure of computing the overall probability of the actual project D.C.F. (rate of discounted cash flow), differing from that estimated in the feasibility study.Variation in Project D.C.F.It is assumed that a feasibility study of the project has been completed which has defined the estimated values for all the project parameters, such as ore reserve tons and grade, capital cost, concentrate recovery, metal revenue, daily milling capacity and operating costs.The financial analysis of the mining project will have determined that the cumulative cash flow will yield an expected D.C.F. on the capital cost if all project parameters attain the estimated values. If, however, the actual value of any parameter varies from that estimated, the actual project D.C.F. will vary from the estimated D.C.F. Risk analysis methods attempt to determine the overall effect of probable variations in the estimated values of all project parameters on the D.C.F. of the mining project. This overall effect is expressed as a probability profile, which shows the likelihood of actual D.C.F. values greater or less than that estimated.Thus, a completed risk analysis of a mine project, with an expected D.C.F. of 15.51%, would display the characteristics shown in the preceding diagram."

Jan 1, 1982

By E. Ghali, B. Arsenault

Aluminum alloys play an important role in the manufacturing of air and ground vehicles. However, with such alloys, corrosion damage is often found on structural components subjected to fatigue loading. The alloying provides large benefit in terms of the high specific tensile strength (ultimate strength/density ratio) to the aluminum alloy but causes the aluminum alloy to be more sensitive to localized corrosion due to complex microscopic heterogeneities such as secondary phases. This paper investigates thermal spray coating namely arc spraying to evaluate the protection against environmentally assisted cracking (EAC) and localized corrosion on Aircraft structural 7075 T651 aluminum alloys. In particular, EAC and pitting corrosion at the interface coating-substrate are a challenge for thermal spray protective coatings on aluminum alloys under cyclic load and immersion. To address these issues, different surface preparation techniques prior to arc spraying were considered such as chemical de-oxidation, laser ablation, shot peening and grit blasting. Results indicate that surface preparation and improved coating process parameters play an important role to provide a coating conferring a protection against both localized corrosion and EAC.

Jan 1, 2006

By G. K. Rutherford, G. W. Van Loon

"Tailings in the mining and smelting industry are reject products of the refining process which are deemed too deficient in native are to warrant smelting. They are essentially finely ground rock materials which have been moved by alluvial suspension from the site of crushing to a deposit site. It is realized that components of flotation chemicals used in specific gravity separation may become part of the tailings and also that sewage sludge or other materials may be added at some stage to the tailing deposits.It would seem, then, that as tailings have a similar parent material to soils, namely rocks, and that they have also been comminuted to similar size fractions, they would react in similar ways to soils. There is an increasing body of evidence and experience which both supports and negates this supposition. It is the object of this paper to point out similarities and contrasts between these two materials which may influence the vegetation and rehabilitation of tailings.Soil-Formlnq FactorsThere are considered to be six soil-forming factors which impart the particular and unique properties harboured by a soil at any site. It is .relevant to consider each of these in turn, as each provides an historically based parameter with which to judge tailing properties.Parent MaterialsAlthough all mineral soils have originally come from rocks, for most soils the route has been rather circuitous. Soils may be formed directly from underlying rocks, as in some parts of tropical and semitropical regions today; these are sedentary soils. However, most soils of the world have been formed by materials which were transported to their present site by ice, water or wind, or as volcanic ash. Virtually all soils in Canada have been transported by ice or water and deposited on an extraneous rock surface during the last glacial retreat. Ice-deposited materials are extraordinarily heterogeneous in their size components and may range from very bouldery and gravelly to predominantly clay-sized materials. Water deposited sediments are usually homogeneous, but nevertheless these also show considerable level variations. In many parts of Canada, clay-sized materials deposited in ephemeral post-glacial lakes form the parent material for soils."

Jan 1, 1982

By Deni Pageau, Deni Caron

"This paper describes the operations of the open pit and emphasizes particular aspects of Les Mines Selbaie. The open pit as well as its related services were incorporated into a complex which includes an underground mine and a concentrator. The equipment was chosen with the objective of auto-sufficiency during each phase of mining. The paper outlines the organization and the methods used in each step of mining, notably: drilling, blasting, loading, transporting and crushing. The responsibilities of the Engineering Department are also outlined from the conception of the open pit to the latest follow-up methods. A short resume of the results which have been obtained as well as suggestions for improvement are provided.Layout in Consideration of Main SiteThe A-I zone deposit is located I km from 8 zone. Open pit mining of A-I zone required the regrouping of different services to those already existing.I. The crusher was placed in an area close to the concentrator in order to minimize the length of the conveyors and to provide space for the crushed ore reserves (50000 tonnes).2. The location of the service building (warehouses, mine offices, maintenance, engineering and geology) raised a few problems. Because of the multiple services provided therein , it was impossible to fulfill all the requirements, and the garage in itself is located a fair distance from the pit. Added to this inconvenience is the fact that heavy equipment regularly travels throughout the main yard.3. The storage of explosive magazines has been changed to obtain more surface space and meet government regulations.4. A space has been provided for minor repairs in the garage used during exploration. A trailer was installed next to the garage to provide a lunch room for the employees working at the open pit."

Jan 1, 1990

By Leonard A. Wolff

"The 1980sfor the mining industry can be characterized as the survival of the fittest. High interest rates, low commodity prices, foreign subsidized competition and decreasing ore grades have contributed to a streamlining of the domestic mining industry in the United States, leading to the shutdown of operations or large cutback of work forces. The purpose of this paper is to look at the impact of a layoff on the employees of what was once a major uranium producer in south central Wyoming, twenty months after the final layoff and mine shutdown. INTRODUCTIONDecember 19, 1985, was the date of the final of three successive layoffs over a two-month period, leading to the complete shutdown of Petrotomics Company, a subsidiary of Getty Minerals Company. The final shutdown was due to a combination of depressed U3O8 prices and the takeover of Getty Oil Company by Texaco in January 1984.The layoffs affected 104 employees and included mine personnel, mill personnel and staff. Both hourly and salary workers were involved. The operation was considered non-union, however, a few mill hourly employees were unionized. At the completion of the layoffs. only a handful of employees remained for administrative and miscellaneous functions.For Getty employees, the terms of the merger agreement provided a generous level of separation benefits. The terms that were insisted upon by Mr. Petersen, Chairman of the Board for Getty Oil, stipulated that employees receive one month of severance pay, for each full calendar year of employment up to a maximum of two year's pay. This was the forerunner of what is now commonly known as the ""tin parachute”. All but the union employees of Petrotomics received these separation benefits. Union employees were covered by their separate, less generous, contract.Much of the literature that has been published in recent months has centred around the effects of layoffs on remaining employees, or the psychological effects on the severed employee. This study will emphasize the economic impact and ramifications due to a layoff, using the Petrotomics employees as a case example."

Jan 1, 1989

By R. A. Walker, G. Scheltgen, T. Javorsky, G. Blackwell

"Recent engineering advances in open pit rock mechanics have resulted in improved pit wall slope design and improved operating procedures in the event of a major wall instability. At the other end of the spectrum, on the scale of single bench failures, considerable discretion is left to the mine operators as to how potential problems are handled. The usual alternatives are either to operate with caution beneath potential hazards, or try to bring the unstable rock down. In specific cases it may be advantageous to attempt to stabilize rock structures for reasons of access and operating safety.A t the Brenda Mines open pit a prominent structure on the north wall had caused recurring bench-scale wedge failures when exposed on each mining level. In spite of operating precautions a shovel was hit by a rockfall causing significant damage. The first section of this paper describes the investigative, design, and stabilization methods which permitted subsequent mining beneath the structure to proceed without incident. Emphasis is placed on the personnel and equipment resources available at the mine site which were used to minimize costs and which would be available at most operating mines.The second section describes an ongoing research project that utilizes radio telemetry to transmit slope monitoring data. As part of this project the wedge structure was instrumented so that it could be continuously monitored with the aid of a computer. The application demonstrated the potential of 'micro- chip' technology to remote data collection and processing as related to rock structure monitoring, slope stability and safety."

Jan 1, 1989

By Grant L. Anderson, Richard C. Rice, Richard L. Jentgen

"Data for underground mine-hoist ropes determined in the Ontario Special Rope Tests were obtained, encoded and analyzed statistically. Prior 10 refined statistical analyses, these data were subjected la characterization studies and preliminary analyses to allow trends to emerge that could be used to guide and facilitate the refined analysis. The data were characterized by determining distribution s for a wide range of variables including remaining strength, service life in terms of lime and hoisting cycles, outer-wire torsion values, elongation during tensile testing, diameter reduction, location of strength loss and the strength lasses associated with corrosion rating and lubrication rating , This paper describes the more important relationships between remaining strength (or, conversely, strength loss) as the dependent variable and some of the principal independent variables mentioned above.IntroductionBoth productivity and safety in underground mines could be improved if mine-heist rope Iife and reliability could be predicted more accurately . As a result, hoist-rope failure processes and their effects on rope life and remaining strength need to be quantified and related in such a way that improved retirement criteria can be developed. This is true whether the failure is incipient or actual or whether the failure mode is by corrosion , wear, fatigue or a combination of these factors."

Jan 1, 1984

By F. Hassani, J. Peck, D. J. Lucifora

The performance of a rotary blasthole drill is heavily dependent on the material being drilled. This material is a microcosm of the in-situ geology that makes up the surface mine in which the rotary blasthole drill is deployed. The performance metrics that are influenced by the in-situ geology are penetration rate (distance drilled per unit time), rotary torque and to a lesser extent rotary speed and vibration. For simulation and testing purposes it is useful to have a validated plant model based upon the application of study. Once validated, a plant model can be used to perform simulation based testing as a supplement and possibly in place of more expensive and logistically complex field testing. Previous studies in the field of rock mechanics have supplied proven models that relate the performance of a rotary blasthole drill to the material being drilled for a given rock type with a given drill bit. In this study, field based experiments were conducted in an active surface mine on a working rotary blasthole drill and the corresponding monitoring while drilling (MWD) data was recorded. Data analysis was then performed on the collected field data. The techniques used successfully fit the collected MWD data to the previously proven rock mechanic models. This paper explores the theory relating rotary blasthole drill performance to the material being drilled, illustrates the required data collection and data analysis techniques, and demonstrates the ability of these techniques and the known rock mechanic models to provide a simulated plant model for the drilling process that can then be validated. This validation is also discussed.

Jan 1, 2015

By R. M. T. Raja Ismail

Shipping and stevedoring industry is going to witness a massive increase in the amount of containers to be handled while land constraints become more critical. Offshore transfer operations hence offer a preferable solution to deal with the surge in cargos rather than to expand the port outwards. Recently, there has been increasing research interests on offshore crane automation. Suspended cargos in a ship-mounted crane system are caused to swing due to the vibratory motion of the ship induced by ocean waves, which can lead to collision between cargos and deck. Therefore, it is vital for offshore crane systems to satisfy rigorous requirements in terms of safety and efficiency. This paper presents the modelling and control development for offshore boom crane systems. A second-order sliding mode control law is proposed for trajectory tracking and sway suppression control, making use of its capability of actuator chattering alleviation while achieving high tracking performance and preserving strong robustness. The asymptotic stability of the closed-loop system is guaranteed in the Lyapunov sense. Simulation results indicate that the proposed controller can significantly reduce the effect of disturbances coming from gusty waves and other dynamic loadings.

Aug 1, 2013

The mixer that is commonly encountered in hydro metallurgical operations consists of a single turbine and tank combination. However, it would be advantageous to examine some common solvent extraction mixing systems in the light of the fundamentals of chemical reactor design. The basic concepts of reactor design are commonly used in the chemical industry, and it should not be too difficult to apply them to solvent extraction. The factors that affect the engineering design of a reactor are: the reacting system; the type of reaction; and the configuration of the reactor. The reaction system in solvent extraction consists of a heterogeneous liquid phase, involving two immiscible liquids. It is essential f or the process that the reactor product can be separated efficiently in the subsequent settler. The type of reaction in solvent extraction system may be quite complex, and the picture is complicated by the presence of competing and side reactions. The reactors themselves have been generally continuous stirred tanks, and the nature of the mixer-settler makes it unlikely that the pumping mixer can be dispensed with. However, it appears that there should be some definite advantages to a system of stirred reactors in series. The kinetic experiments which are carried out should have the definition of optimum reaction conditions as one of their goals. The data obtained from these experiments must also be applicable to the design of reaction equipment. Reactor selection and design is often a unique problem for each chemical process, and does not lend itself to a systematic general approach. However, the application of chemical and physical principles to mixer design in solvent extraction should result in practical, more efficient plants.

Jan 1, 1979

By Jeffrey D. Oke

While significant progress in underground construction engineering has occurred in the past few decades, a number of fundamental deficiencies persist regarding the recognition, prediction, and mitigation of underground construction hazards associated with complex geological conditions in rock and soil works, such as tunnelling. Many of these shortcomings could be addressed by improving geomechanical models which, in turn, would provide more realistic frameworks for determining input parameters for design analysis. This would improve predictions of construction efficiency for tunnelling and the formulation of more accurate modelling techniques (2D, 3D and 4D) required to optimize the design of engineered rock structures. This research focuses primarily on the issues related to forepole temporary tunnel support within weak rock masses. This research attempts to determine how best to numerically model forepole support. The behaviour and mechanics of forepole support has not been quantified and/or optimized. As well, there is a lack of in-situ and/or laboratory forepole and weak rockmass interaction parameters available. In terms of numerical modelling, there is a lack of understanding of the use of proper interaction parameters associated with the forepole and the rockmass. The parametric study that has been conducted by the authors demonstrates the influence of each of the forepole-rockmass interaction parameters and their sensitivity. Introduction

Jun 1, 2012