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By Richard G. Sandberg

The Bureau of Mins, U.S. Department of the Interior, is investigating a hydrometallurgical procedure to conserve cobalt, nickel, and copper by recovering the metals from the matte byproducts of smelting Missouri lead ores. For want of adequate processing technology the mattes are now either unmarketable or marginally so. The procedure involves leaching with manganese dioxide and sulfuric acid to obtain copper, nickel, cobalt, lead, and manganese sulfates, and elemental sulfur as expressed by the following reaction: MS + MnO2 + 2H2SO4 ? MSO4 + MnS04 + S° + 2H2O, where M = Cu, Ni, Co, and Pb. The leach solutions, containing near theoretical amounts of sulfuric acid and manganese dioxide at 85° to 100° C, convert up to 98 pct of the cobalt, nickel, and copper in the mattes to sulfates in less than 2 hr. As they are formed, the cobalt, nickel, and copper sulfates are dissolved leaving a residue of lead sulfate, lead, sulfur, and gangue. The soluble metals are recovered from the leach solutions by caustic and sulfide precipitation, and the residue returned to the smelter for lead recovery. The manganese can be reclaimed from the spent leach liquor as manganese oxide and recycled to leaching.

Jan 1, 1979

By Walter Wood, J. T. H. Cannarella, H. F. Yancey, R. E. Zane

More than 50,000,000 tons of bituminous coal and probably about the same quantity of anthracite are cleaned annually in the United States by wet methods. The water, fine coal, and impurities from the water used for washing ordinarily are recovered by moans of various forms of settling tanks. Settling and clarification may be hastened markedly, thereby greatly increasing the capacity of clarification equipment already installed, by the addition of substances to the washery water that cause the fine particles in suspension to agglomerate and thus settle more rapidly. This phenomenon, although well known and applied in other fields, has been used at only a few coal washeries in the United States. It is widely employed, however, as an aid in the recovery or disposal of fine coal or impurities, as a means of preventing, stream pollution, and to enable reuse of washery water at many plants in Europe. Pioneering work in the United States has been done principally by two companies -- the Pittsburgh Coal Co., in Pennsylvania, 6/ and the Pacific Coast Coal Co., in Washington.

Feb 1, 1940

By Chester L. Arnold, Reinhardt Thiessen, Alexander Lowy

"INTRODUCTION Peat is the accumulated mass of plant materials that remain after partial decay under specific conditions. In the swampy peat bogs dead material which falls on the surface immediately is attacked by fungi and aercbic bacteria. Decay under these conditions is rapid, but of relatively short duration, since the constant addition of new material soon forces the older layers below the water level, in this position, without access to oxygen, the plant constituents are attacked mainly by anaerobic bacteria, and decomposition proceeds slowly. The largest part of peat is contributed by the woody tissues of plants, the chief constituents of which are cellulose and lignin, together with a small proportion of hemicelluloses. During the normal process of biological decay celluloses disappear more rapidly than lignin. The result is a complex substance known as humin, from which the humic acids may be extracted.In 1826, Sprengel 5 found that when decayed plant materials were extracted with alinnli and the resulting black liquid acidified with mineral acid a brown gelatinous precipitate was formed. To this product, which was a brown amorphous powder when dry, he gave the name ""humic acid'. Since that time, chemists have used the name rather loosely to designate products which have been isolated by very diverse means from soils, decayed woods, peat, lignite, and coal. An excellent review of the early work on humic acids was published by Baumann 6 in 1909. This publication aroused the interest of Oden, who then investigated the humic acids. An account of Oden’s work, as a good survey of the literature, is contained in his monograph “Die Huminsauren”. 7"

Nov 1, 1934

By R. E. Heithecker

The principle of determining volumes of liquid by alternately drawing in and discharging given quantities of the fluid from a confined space or compartment of known volume and mechanically counting the number of displacements is well established. This is true particularly in water measurement. For several years, oil meters employing the same basic principle have beer used for gaging oil production from individual wells, groups of wells, and in some areas for metering the entire production from a property. Especially in areas where there is town-lot drilling and space for tankage is at a premium, oil meters have been used successfully to gale the oil. This facility has obviated the necessity of installing gage tanks. Oil meters also have been used in pipe-line and refinery operations and in loading tankers. Present knowledge e of the subject shows that positive-displacement oil meters can be used for measuring crude oil in the field and elsewhere, provided the meter-counter mechanism is in proper adjustment and the oil has been studied sufficiently to determine the pro-per factor to be applied to the volume as registered by tae meter, possible the adjustment for the shrinkage of the oil caused by liberation of gas from solution.

Jan 1, 1938

By Oliver C. Ralston

The growing popularity of perlite (sometimes spelled pearlite) as a raw material for thermal expansion into pumicelike products in the Western States has prompted a preliminary investigation of the properties of such material and the problems that want solution to put a perlite industry on a firm foundation. The Bureau of Mines is undertaking the gathering of data and the solution of these problems, and the following paper records some of the available information. and the promise of the material, with some comparisons of advantages of the various competing lightweight aggregates that can be made from siliceous volcanic glasses and rocks containing entrapped or dissolved water that causes their expansion on' quick heating to their softening points. This new industrial rock has caught the fancy of the mineral industry in the western States because it has Fume advantages over natural pumice. Chemically, it is typified as rhyolitic in composition, and one may find obsidian, rhyolite, pumice, pumicite, and perlite from the same vant and contemporaneous in origin. The material need not be rhyolite but should be a siliceous or acid lava and contain 2 to 5 percent water still in "solution" in the rock. On quick heating to the softening temperature the material puffs, due to conversion of the contained eater into bubbles of steam. Slow heating causes gradual release of the imprisoned water by decrepitation and. cracking and-results in, very little puffing. Perlite is often in the form of ovoid volcanic bombs formed by explosive eruption of large masses of lava into the air, where they, quickly cool, with escape of little of the contained water, exceptt perhaps for a hollow interior. Since they cool in layers they have an onion-type structure and a pearly luster from interference of light between the. layers, which is' the origin of the name "perlite." Perlite may occur in intruded flows that have been quickly cooled and partly expanded but retained most of their magmatic water content. Obsidian may be the same lava cooled quickly under conditions that prevented crystallization of feldspars and other minerals, leaving the volcanic glass that may or may not retain all of the original contained water.

Jan 1, 1946

By G. L. Gates

Five possible sources of water for waterflooding of petroleum reservoirs in the arid San Joaquin Valley of California were considered. Three of them (water produced with petroleum, water from a shallow saline aquifer, and waste irrigation water) were analyzed chemically; laboratory information for one (sea water) had been developed during a previous study. A series of laboratory tests made on the fifth source (fresh water) determined the solubility of calcium sulfate dihydrate in water. Laboratory analyses included the following: Chemical analyses of water produced with petroleum and waste irrigation water; solubility of calcium sulfate dihydrate in water and brines; the effect of excess sulfate on the solubility of calcium sulfate in brines; the presence of sulfate-reducing bacteria; and the permeability of cores from a petroleum reservoir to air, to water from other petroleum reservoirs, and to waste irrigation water. The results showed that most of the waters and mixtures of waters are compatible with petroleum reservoir waters and are generally suitable for injection. The calcium content of some of the formation waters is quite high, and care must be taken to prevent precipitation of calcium sulfate dihydrate. The permeability of the few cores tested was about the same to water and brines as to air, indicating that formation damage due to clay swelling will not be serious. The waters most likely to be available for injection are water produced with petroleum, water from shallow saline aquifers, and waste irrigation water.

Jan 1, 1970

By J. Dean Warner

In 1984 and 1985, as part of its critical and strategic minerals studies, the Bureau of Mines investigated lode and placer tin occurrences near Rocky Mountain (Lime Peak), in east-central Alaska. The lode occurrences consist of mineralogically complex, generally fault-controlled veins, and contain an average of approximately 0.05 pct Sn, as cassiterite. Beneficiation testing of two bulk samples of the vein material produced concentrates containing 65 and 59 pct of the total tin values at grades of 0.35 and 13.9 pct, respectively. Although as much as 30 million short tons (MMst) of mineralized rock containing up to 20 MMlb Sn may be present, the grade of these occurrences is too low to be considered economic at this time. Trace amounts of cassiterite were also identified in surface samples of glacial out-wash gravels collected along North Fork Preacher Creek, which partially drains the area of tin lode deposits near Lime Peak. Low tin grades in the samples do not account for the former erosion of a large volume of lode tin mineralization from near Lime Peak; higher tin grades may be present in gravels closer to bedrock.

Jan 1, 1988

By B. W. Naugle

Twenty-nine sole-heated-oven expansion teats were made on 9 different coals, and apparent specific-Brevity tests were made on 12 of the resultant cokes. The coals, which ranged in dry, mineral-matter-free fixed-carbon content from 58.7 to 81.1 percent, were tested over a rather wide range of moisture content and dry-coal bulk density to determine the separate effects of these variables on linear coal expansion. The experimental data support the follow expression relating "as-tested" coal bulk density, moisture content, and linear expansion, [ER = (1-MR) (1+Et) - 1; BDt] where ER = fractional expansion at a reference bulk density of 55.0 lb. of 1 percent moisture coal per cu. ft., Et = fractional expansion at Mt and BDt, MR = reference moisture content = 0.01, Mt = moisture content, "as-tested", BDR = reference bulk density = 55.0 lb. per cu, ft., BDt = bulk density, "as-tested", 1b. per cu. ft.

Jan 1, 1957

By Hillary W. St. Clair

This report describes a mathematical procedure for analyzing size distribution data by the method of moments. The method was applied to Andreasen's data on a variety of grinding mill products. It was found that the observed size distributions could be represented by gamma and beta distribution functions over a wide range of sizes. A computer program, written in BASIC, is described for calculating moments, distribution parameters, and the weight fraction in any size range.

Jan 1, 1969

By J. E. Hamak

This publication contains analyses and related source data for 151 natural gas samples from 19 States. Of the total samples, 138 were collected calendar year 1989. The remainder were collected earlier, but releases to were not received until 1989. All samples were obtained and analyzed as part of U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1990

By N. S. Dalal, B. Jafari, F. Y. H. Green, V. Vallyathan

"Using electron spin resonance (ESR) spectroscopy we have carried out a systematic study of the measurement of concentrations of organic free radicals in freeze-dried lung tissue. Sixty-six tissue samples were obtained from the National Coal Workers' Autopsy Study (NCWAS). The samples were characterized in terms of the concentration per gram of the free radicals, and examined in relationship to the histopathological parameters such as age, numbers of years in the mining atmosphere, the degree of disease, and smoking history. Preliminary results indicate a positive correlation between the free radicals in the lung tissue and the severity of pneumoconiosis.IntroductionThis paper summarizes our electron spin resonance (ESR) measurements of the concentration of organic free radicals in the freeze-dried lung tissue of autopsied coal miners. This work was undertaken because it is well known that most coals contain carbon-centered organic free radi¬cals,(1,2) and recent studies from our laboratories indicated that reactive free radicals might play a role in the biochemi¬cal mechanism of coal workers' pneumoconiosis (CWP) (3) Thus we obtained 144 lung-tissue samples from the Nation¬al Institute for Occupational Safety and Health (NIOSH) in Morgantown. The samples came from the data bank of the National Coal Workers' Autopsy Study (NCWAS). This selection was unique because fairly detailed histopathologi¬cal information was available for each sample.Other recent studies in this field are those of Ohta et al (4) who conducted ESR measurements on black dust deposited in autopsied human lungs, but no coal miner was included therein. Earlier Retcofsky (2) had examined one lung-tissue sample via ESR spectroscopy and had concluded that the free radicals in the lung tissue reflected simply the fusain (narrow component) ESR signals. The present study was thus undertaken to complement the earlier work (2-4) and the results indicate a positive correlation with the disease severity fairly strongly."

Mar 1, 1989

By Jerry T. McLendon

The proper disposition of phosphatic clays has been the subject of research and debated for years by phosphate producers, State and Federal research agencies, regulatory authorities, and environmentalists. To date, no "universal" solution exists for the ultimate disposl of phosphatic clays. This Bureau of Mines report examines the state of conventional clay disposal technology and reviews the technical progress of innovative alternatives. Twenty impoundment sites were investigated by the Bureau of Mines using geotechnical methods and laboratory analysis of cored samples. In addition, quasi-static cone penetrometer soundings were conducted to define clay and/or sand-clay interfaces en masse. Samples of the top, middle, and bottom hole segments were obtained at each station for laboratory studies of clay densities, pore fluids, plasticity, and mineralogical properties. The results of this study support the continued use of initial clay settling impoundments but emphasize the need for "in-line" systems to reduce the initial volumes of plant-generated phosphatic clays. The effective use of sand tailings is also encouraged to promote further consolidation of clays via self-weight stressing, sand-clay admixtures, and/or surcharging sand caps.

Jan 1, 1984

By V. E. Homme

Low- and high-temperature reduction techniques were employed by the Bureau of Mines in study of conditions favorable to the formation of massive titanium crystals. '1,1,2 low-temperature method, feeding molten sodium to solidified titanium lower chloride-sodium chloride, produced higher quality and high quantity crystalline metal. The percentage of crystalline titanium was increased with increasing reactor diameter, melt depth, and titanium dichloride concentration. The high-temperature technique, feed molten sodium to melts above 8000 C, producing needle-type crystals of lower quality and with less consistent results than the low-temperature method. Layers of titanium foil, sponge, fine needles, wool, and crusts of sin-tered granules were formed during the earl, -art of the low-temperature reduction, and massive crystals were produced beneath this barrier in the latter part of the reduction. Crystalline titanium having an average hardness of Bhn 76 and representing 58 percent of the total titanium was obtained. Lamellar crystals up to 1 1/2 inches long with a hardness as low as Bhn 54 were also produced. A second-stage reduction for reclaiming titanium from offgrade sponge is described. Titanium produced by this method was comparable in quality to that from sodium reduction of titanium tetrachloride.

Jan 1, 1966

[~lis is the f'fth in a ~erieG of reports on properties of commercial motor fuels, made in accordance 1,'Vi t:h fl cooperative ae,ree-ment betwGon tho Cooperative Fuel ReRRarch (e.F.R.) Committee and the Bureau of I ines of the Dcpart~ent nf the Interior. The first report gave data on motor r-asolino~ sold during the wintor of 935-36.31 Thi~ report covers 84 brands of ga~oline represented by l,722 samples exclurling the Pacific Coast. T 3)Se J.rom th~. ?~'tcific Coast IV .ro avnrL)f:od b~r tho Pacific Coa!3t tecilnical group "bofore o8ing submi ttcd ruld arc p~.lbl:'shcd GX Gtl~r as they were submi tted. In some areas r~lJort~ . erc roceivod f~om ~ ix to eicht compD.l1ie~ on the same brands of gasoline. whoruar. in other areas only one company reported on a brond. Thut., it CU .. "! be senn that BO .. 0 uf the dnt ;.U'e more rCY>l'c entat vc thM others. The inclusion of r~0rts fro:n several ci tie. w' thin somo of tho di stricts has ir.rpr,)vcd the report by reducinc; tr.e numb~r of brand rcportel by only ono company. ]

Jan 1, 1938

[~lis is the f'fth in a ~erieG of reports on properties of commercial motor fuels, made in accordance 1,'Vi t:h fl cooperative ae,ree-ment betwGon tho Cooperative Fuel ReRRarch (e.F.R.) Committee and the Bureau of I ines of the Dcpart~ent nf the Interior. The first report gave data on motor r-asolino~ sold during the wintor of 935-36.31 Thi~ report covers 84 brands of ga~oline represented by l,722 samples exclurling the Pacific Coast. T 3)Se J.rom th~. ?~'tcific Coast IV .ro avnrL)f:od b~r tho Pacific Coa!3t tecilnical group "bofore o8ing submi ttcd ruld arc p~.lbl:'shcd GX Gtl~r as they were submi tted. In some areas r~lJort~ . erc roceivod f~om ~ ix to eicht compD.l1ie~ on the same brands of gasoline. whoruar. in other areas only one company reported on a brond. Thut., it CU .. "! be senn that BO .. 0 uf the dnt ;.U'e more rCY>l'c entat vc thM others. The inclusion of r~0rts fro:n several ci tie. w' thin somo of tho di stricts has ir.rpr,)vcd the report by reducinc; tr.e numb~r of brand rcportel by only ono company.]

Jan 1, 1938

By J. E. Matta

The Bureau of Mines made laboratory absorption measurements on oil shale samples, which showed that the amount of methane absorbed is proportional to pressure and oil yield, and can be much larger than would be predicted based solely on porosity. Oil shale cores collected in the field were also measured for their gas content using the Bureau of Mines direct method. Cores taken from deep locations and far from outcrops yielded more gas than cores from shallower locations or at outcrops, when taking into account variations in oil yield, and all data indicate that oil shale mines that are both deep and far from an out-crop will emit low levels of methane gas.

Jan 1, 1977

By D. A. Paice

A portable calibrator to check tie trip setting of dc circuit breakers within an accuracy of +5% has been developed for the Bureau of Mines. It operates from a 300 volt dc trolley wire to provide controlled current pulses of 120 milliseconds duration and continuously adjustable from 1400 to 3600 A. These current pulses enable a breaker dc trip current to be determined and subject the contacts to full current rating. The equipment is simple to use and weighs 86 pounds. Connections are made with protected, clamp-on leads which are separately connected and weigh about 22 pounds. An accurate calibration procedure takes less than 5 minutes to complete.

Jan 1, 1978

By James F. Neill, O&apos

Investigation of the Gilley fluorite deposit was based upon examinations made by several of the Bureau's mining engineers. Fluorspar was found in the dump talus of sloughed and water-filled trenches and shafts, and there were indications that faulting or other dynamic distortions favorable to deposition of this mineral in minable quality and quantity might exist. The inference was based upon a field study of the area and its comparison with fluorspar deposits in Kentucky. The proximity of this deposit to the iron furnaces at Gadsden and Birmingham was a factor that influenced its investigation, as the demand for metallurgical grades of this critical mineral is acute. The present supply for the district is obtained from out-of-State sources, and the value of any local deposit would be enhanced by the saving in freight charges. The Gilley fluorspar deposit is 17 miles east of Gadsden and 50 miles northeast of Birmingham, Ala. Mineral deposits occur as thin veinlets and small bunches of fluorite in upturned bode of siliceous limestone. The ore-bearing structure is a reverse fold, and the mineral deposit appears as a replacement along crumbled zone fractures of the contorted limestone.

Jan 1, 1950

By P. M. Gruzensky

A survey of the literature has been made covering the extraction of bismuth from raw materials, its separation from lead, and its subsequent refining. The use of aqueous, nonaqueous, and fused electrolytes in electrolytic refining is reviewed. This literature survey has been prepared preliminary to some proposed investigations concerning the electrometallurgy of bismuth, and, although an effort has been made to cover a majority of the applicable references, a critical review was not attempted and no assertion is made that this manuscript is exhaustive in nature. Titles of publications in parenthesis are translations from the language in which the reference was originally published.

Jan 1, 1954

By R. A. Friedel, J. L. Shultz, A. G. Sharkey

The purpose of this investigation was to study the primary materials associated with the coal structure . Mass spectrometric techniques can be useful in studying the chemical structure of coal and various high- molecularweight materials derived from coal . Investigations of pyrolysis products and extracts of coal , and also whole coal , showed : 1. Aromatic hydrocarbons obtained by the vacuum pyrolysis of coal below 300 ° C possibly were sorbed material rather than decomposition products . 2 . 2 . Thirteen structural types having molecular weights from 78 to 400 were identified in pyridine extracts constituting one - quarter or more of the coal by weight . 3. Material extracted at room temperature with a methanol - benzene solvent and a vacuum pyrolysis condensate obtained at 450 ° C contain similar components . The extract and the condensate have approximately the same average molecular weights ( 200-300 ) . 4. Material extracted from coal at room temperature is altered even by mild thermal treatment . 5. Changes in various alkyl series occurring in thermally treated coal extracts can be followed quantitatively . 6. Similarities in the spectra of coal and graphite were indicated in an investigation using a mass spectrometer equipped with a spark source . Determinations on a coal - ash sample by this technique showed good agreement with data obtained by emission spectroscopy .

Jan 1, 1963