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By James C. Cawley

The Bureau of Mines has empirically determined ignition probability versus current for resistive circuits in an 8.3% methane-air atmosphere. Simple ignition probability, defined as the number of ignitions divided by the total number of sparks, was determined, and the corresponding currents were recorded. The experiment was designed to minimize the probability of not observing an ignition that should occur during a series of tests. For resistive circuits in 8.3% methane-air mixtures, the experimental results indicate that ignition was not achieved below 2,000 rnA at 20 V dc, 350 rnA at 30 V dc, 150 rnA at 40 V dc, and 175 rnA at 50 V dc. The simple probability of ignition corresponding to these currents is esti-mated to be, respectively, 1.0 x 10-6, 1.7 x 10-7, 3.0 x 10-7, and 1.0 x 10-5 The ignition mechanism seems to break down below this point, implying that a threshold current value exists below which spark ignition does not occur.

Jan 1, 1987

By D. A. Wilson

A laboratory method for processing lead battery scrap has been developed that eliminates virtually all of the S02 emission that normally is produced when a reverberatory or blast furnace is used. The method employs a hydrometallurgical step to convert the PbS04 to PbO and CaS04 by mixing the battery scrap with a slurry of Ca(OH)2. The reaction is exothermic and goes to completion in 2 to 5 minutes at room temperature. The dried product is mixed with a KC1-NaC1 flux and carbon and reduced at 6500 C. A minimum charge ratio of 3 parts of carbon to 100 parts of battery scrap is required for reduction. The process produces lead reductions and recoveries as high as 97.0 and 94.9 percent, respectively. The KCI-NaCl flux is recovered using a standard counter-current water leach followed by evaporation.

Jan 1, 1976

By Robert J. Anderson

"Introductory Statement:In melting the nonferrous metals and alloys for foundry and rolling-mill work, even with the best practice, there is always a loss, due principally to oxidation. Melting losses are a serious source of financial loss in brass and bronze practice, but they are especially serious in the case of aluminum and its light alloys because of the relatively high price of aluminum. The indications are that the melting losses in many aluminum foundries of the United States are at times high, and in some plants (especially where certain furnaces are used) they are entirely too high when compared with the average practice. The fact that the oxidation losses in melting aluminum and its light alloys are high is well known, but it is doubtful whether the factors governing the most suitable methods of melting for a minimum of dross are equally well known. The metal losses involved in melting are worthy of especial attention now because of the rapidly growing importance of the aluminum industry.Factors in the operation of furnaces which affect metal and fuel losses:The essential requirements in the commercial melting of any metal or alloy are that the melting losses should be low, the melting should be rapid, and the melting cost should be low. Certainly it may not be possible to obtain these requirements in any furnace selected at random, and it follows that the design and the operation of furnaces for melting different metals are subjects that warrant the most extensive study and tests. As a general rule, in the industrial operation of furnaces, run on aluminum and aluminum alloys, an effort is made to keep the dross and oxidation losses as low as possible. In attempting to hold dross losses low, numerous factors involved in metal melting may be overlooked, or at least disregarded, and the net practical result may be that the furnace is exceedingly wasteful of fuel. In the case of aluminum and its light alloys, the effect of increasing the temperature of melting, at least in an atmosphere containing free oxygen and nitrogen, is to increase the net melting loss."

Apr 1, 1921

By E. C. Tarpley, H. M. Cooper, R. F. Abernethy

"INTRODUCTION The float-and-sink test 5/6/ is generally the first test used in determining the washing characteristics of coal. The simplest form of the test is that of using one solution of such specific gravity that the test sample is separated into ""float"" and ""sink"" fractions. In practice, however, a series of solutions is used, and the sample is separated into a number of fractions of a definite specific-gravity range. Analyses of a series of fractions of this type are often referred to as the ""specific-gravity analysis,"" and are of great value in the selection, construction, and operation of commercial washing equipment.The test is rather simple to use, provided a number of conditions are recognized and as many as possible held constant, such as:1. In laboratory testing, two types of solution are available -Aqueous solutions of calcium and zinc chlorides.Mixtures of organic liquids such as carbon tetrachloride, benzene, gasoline, bromoform, etc.2. Absorption of the solution by the coal,3. Solvent action of the solution toward the coal.4. Constancy of specific gravity during the test is affected by temperature changes, dilution, and evaporation.5. Personal technique of the test, such as the time the coal is in the liquid, rate of adding the sample to the liquid, stirring, time of draining, etc.6. Moisture content of the coal as tested."

Dec 1, 1947

By Larry D. Nichols

Poroplastic membranes containing ion exchange liquids were studied for separating cobalt from nickel-containing solutions similar to ammoniacal laterite leaches. The driving force for cobalt transport was differences in pH and composition between the leach and extraction streams. Using a diketone ion exchange liquid, a leach pH of 6.5 to 7.0, and a strip pH of 2.3, cobalt was extracted from a 750 ppm solution containing 2500 ppm of nickel at rates ranging from 1 to 10 µg/cm2 .min in single membrane cells, and from 10 to 100 in more closely spaced multiple membrane cells. Rates were variable, with evidence that cross -membrane flow pasterns were a key factor; a reproducible rate of 30 pg/cm .min would be economically viable. Loss of transport observed after several days of continuous operation was restored by flushing membranes with fresh ion exchange liquid. A major effort was devoted to preparation of thin, leak-free membranes; the resulting membranes endured operating conditions without mechanical failure.

Jan 1, 1982

By George T. Motock

The author prepared the following report as the result of a trip to Germany in the summer of 1945 for the Technical Industrial Intelligence Commitee Subcommittee on Metals and Minerals. The purpose of this committee, which functions under the Joint Intelligence Committee of the Joint Chiefs of Staff of the United States Armed Forces and of which the Bureau of Mines

Jan 1, 1946

By L. B. Pankratz

Heat contents, measured above 298.15° K, and derived entropy increments are presented in tabular and equation form for the two crystalline forms of zinc sulfide (sphalerite and wurtzite) and for four solid solutions of iron and zinc sulfides having the compositions Zno.,,6Fe0.302S, Zno.750Fe0.250S, Zno.650Fe0.3505, and Zno.498Feo.502S.

Jan 1, 1965

By Alla D. Mah

Energies of combustion of vanadium nitride (VN) and vanadium carbide (VC) were measured. Correcting to vanadium tetroxide (V204) as the final state, the heats of combustion were ?H298.15=-118,700±100 cal/mole of vanadium nitride and ?H298.15=-240,270±360 cal/mole of vanadium carbide. With vanadium pentoxide (V205) as the final state, the heats of combustion were ?H298.15= -133.440±100 cal/mole of vanadium nitride and ?H298.15=-255,020±360 cal/mole of vanadium carbide. Combining these results with vanadium oxide data, the heats of formation obtained were ?298.15=-51,880±200 cal/mole of vanadium nitride and ?H298.15=-24,350±400 cal/mole of vanadium carbide. Heats and free energies of formation of vanadium nitride and carbide were calculated to 2,000° K.

Jan 1, 1963

By P. C. Good

This Bureau of Mines report describes the preparation of phosphoric acid directly from phosphate ore, without prior beneficiation, in a small-scale, continuous process research unit, as part of an effort to improve minerals and metals recovery from domestic resources while minimizing environmental effects. Three phosphate-matrix samples, ranging in grade from 18.2 pct P20S5to 11.9 pct P205, were dry-fed at a rate of 1.82 kg/hr (4 lb/hr) to a continuous-circuit, 12-liter, single-tank digester to yield phosphoric acid and byproduct gypsum filter cake. Comparison with earlier data shows that a significantly improved filtration rate was attained in a single-tank reactor compared with that attained in a five-tank reactor train processing the same ore. Iron and aluminum impurities in the product phosphoric acid averaged about 60 pct higher than amounts reported in commercially prepared, concentrate-derived acid. All gypsum filter cakes prepared had a firm, sandy texture, rendering them physically suitable for stacking or landfill use. Introduction of dry attritioning and air classification approximately doubled the attainable filtration rate when the dry-beneficiated product was digested. In air classification, there was a 12-to 14-pct P205 loss. Depending on the technique used and the matrix grade, overall P205 recovery ranged from about 72 to 89 pct.

Jan 1, 1979

By Elizabeth A. Johnson

Minor-element behavior and interaction in the copper matte-iron silicate slag system have been studied by the Bureau of Mines. In the present work, the possibility of interactions among the minor elements As, Sb, Bi, Se, and Te was investigated. Equilibrations of matte, slag, and one of each of the five minor elements were performed at 1,250° C under typical matte smelting atmospheres of CO, CO2, and S02 for mattes containing 40, 50, and 60 pct Cu. Results are compared with those of a previous Bureau of Mines study in which all five minor elements were present simultaneously.

Jan 1, 1984

By W. P. Yant, C. E. Traubert

"INTRODUCTION Canister-type gas masks have become an essential part of the equipment of many industries, not only for use in emergencies, but also in performing normal operations of industrial processes and procedures, particularly where ventilation is not practically or economically feasible. They are also used widely for enhancing safety of operations which previous to the development of gas masks had been performed in harmful atmospheres.Since the inception of industrial gas masks the Bureau of Mines has been actively engaged in endeavoring to increase the efficiency and safety of these devices, and this bureau has become a source of advice to manufacturers in producing devices of good quality and to industry in the proper selection and use of these devices. In order to give first-hand information and keep current with the demands and needs of industry it is necessary to perform investi-gations from time to time. This report deals with tests of certain types of commercial gas-mask canisters for protection against mercury vapor.TYPES OF CANISTERS EXAMINEDThis investigation included tests of the following types of canisters:(a) Gas-mask canister filled with 725 c.c. of granular activated charcoal, 8 to 14 mesh, and of a quality used in gas masks which meet the Bureau of Mines approval requirements 4 for protection against organic vapors."

Oct 1, 1932

By E. D. Gardner

This paper discusses prospecting for lode gold and lists the principal lags and. regulations pertaining to locating; lode claims on public lands. It is a preprint of a part of a bulletin being prepared by the United States Bureau o Mines entitled "Equipping, Developing and Operating Small Gold Mines". The increased interest in gold mining manifested during the past few years (1932-1935) bas stimulated prospecting. Many adventurers have taken to the field to search for now gold deposits. A. large percentage of them have had no previous experience in prospecting for lode gold; this paper has been written with the tope that it might assist these newcomers.

Jan 1, 1935

By Emory Smith

The Victorville cement plant of the Southwestern Portland Cement Co. is located about 1 mile from the city of Victorville, Calif. Two transcontinental railway systems, the Atchison, Topeka & Santa Fe, and the Southern Pacific Railroad, afford shipped facilities. The plant is modern and well kept, as the officials, especially the higher operating officials, take pride in the appearance of the place. Dust has been practically eliminated by the installation of dust collectors and wet grinding. The plant has a rated capacity of 5,000 barrels of cement daily.

Jan 1, 1929

By W. D. Riley

The Bureau of Mines is conducting research on methods for the rapid identification and sorting of mixed scrap metals and alloys so that domestic scrap resources can be fully utilized. One method, spark testing, is the examination of the pattern of sparks that results when a metal or alloy is ground on an abrasive wheel. This technique requires experienced sorters. Bureau researchers have shown that spectrophotometric methods can be used in lieu of the highly skilled sorter. The spectra of a mild steel, an HSLA steel, several stainless steels, and four nickel-base alloys have been measured. Differences in the spectra that are sufficient for identification are apparent.

Jan 1, 1985

By A. F. Jolly

In an effort to better predict the useful service life of friction rock stabilizer mine roof bolts in coal mine environments, the Bureau of Mines has evaluated the corrosion resistance of stabilizer steels in air-saturated and deaerated waters from seven Eastern and Midwestern underground coal mines. Accelerated electrochemical corrosion tests were used to estimate corrosion rates for the two high-strength, low-alloy (HSLA) steels used to fabricate Split Set stabilizers and for galvanized steel. Long-term static-immersion weight-loss tests were also conducted with the HSLA steels. Corrosion rates developed from the weight-loss tests (steady-state air dissolution) were roughly comparable to rates determined from electro-chemical testing in aerated waters. Although the highest rates occurred in waters with the highest chloride contents, rates in the other waters were low (<2.0 mpy) and exhibited little correlation to the widely varied chloride contents of the waters. The generally low corrosion rates are attributed in part to the tendency to deposit a protective CaC03 film, reflecting susceptibility to carbonate precipitation as indicated by positive Langelier (saturation) index values for the waters. With one exception, corrosion rates for the galvanized steel were (2.0 mpy. Rates with aerated waters were higher than those with deaerated waters. Pitting tendencies of the steels were also estimated.

Jan 1, 1987

By Frederick C. Trutt

Research performed on arcing faults and their interaction; with electrical insulating materials within coal.-mine power-system enclosures is described. This work was performed at The Pennsylvania State University from 1 December, 1976 through 30. November, 1977. Results presented are interim in nature and future research is planned to integrate the simulations which have been constructed, as well as to apply developed experimental procedures to the evaluation of electrical insulating materials for use in coal-mine enclosures. The thrust of this research has been divided into several primary areas. These include the development of a theoretical procedure for computation of three-phase and line-to-line arcing fault currents as a function of time, formulation of an arc model based upon thermal-arc plasma properties so that arc voltages and energies may be computed, development of a simulation for pressure and temperature rises when an arc interacts with an electrical insulating material within an enclosure, experimental evaluation of electrical insulating materials in terms of their tendency to support an arc as well as their potential contribution to enclosure pressure rises, and integration of the above research areas to form overall procedures for theoretical and experimental evaluation.

Jan 1, 1977

By Steven J. Page, John A. Organiscak

Prolonged exposure to airborne respirable coal mine dust is responsible for coal workers&apos; pneumoconi¬osis (CWP): Furthermore, miners who show evidence of higher radiographic categories of simple CWP are at increased risk of developing progressive massive fibro¬sis (PMF). As of 1990, there were nearly 130,000 coal miners in the United States. "&apos; This excludes mines that produce less than 10,000 tons annually and the anthracite coal mines. Estimates indicate that at age 58, an average of 7/1000 U.S. workers and 89/1000 U.K workers will have developed PMF(2-1) Health research studies have iden¬tified that the risk of developing and the severity of CWP arc directly related to (1) the amount of respirable dust exposure and (2) the coal rank.,&apos;- The rank of coal is its stage of formation in the series peat, lignite, sub-bituminous, bituminous, and anthra¬cite (in order of increasing rank). The rank of coal can also be represented by the com¬mercially important characteristics specified by its proximate analysis: fixed carbon, vol¬atile matter, mineral matter, and moisture content.

By M. J. Dailey

This paper is one of a series being prepared by the United States Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. The property of the Silver King Coalition Mines Co. is situated in the western past of the Park City mining district, Utah, about 1 ½ miles southwest of the town of Park City, The elevation at the collar of the main shaft is 8,137 feet above sea-level.

Jan 1, 1930

By John B. Bennett

In this report estimates are presented of the impact of the passage of five recently proposed "acid rain" bills on electric utility costs for coal-burning utilities servicing the domestic aluminum smelting industry, and on the costs of production for affected aluminum smelters. As aluminum smelting is an energy-intensive industry, domestic increases in electricity prices could affect the industry&apos;s competitiveness. Energy costs in U.S. aluminum smelting are compared to aluminum smelting energy costs in the rest-of-the-world. Governmental policies affecting these energy costs are discussed.

Jan 1, 1988

By R. L. Handy

The goal of this research was to adapt the highly successful rock borehole shear test for use in deep, small-diameter boreholes. Operating somewhat on the principle of a rock bolt, the borehole shear test measures both the expansion pressure and pulling force to give discrete measures of rock shearing strength as a function of the applied normal pressure. A new instrument was designed and built to fit into a 2-3/8 inch diameter hole. Unfortunately the design became so complicated, the operation is nut reliable. This is attributed to constraints of the small hole, and added requirements of an in-hole anchor to push against, and a rotating shear plate cleaner for repeated tests down-hole. A clue to the d: vice complexity is its length, which is over 10 feet. Furthermore it employs concentric cylinders and one hydraulic cylinder bored into the piston of another, or it would be even longer. Meanwhile drilling technology has advanced to greatly reduce costs of drilling 5- or 6-inch diameter holes. The downhole tester therefore should be redesigned and simplified for use in a larger diameter drill hole.

Jan 1, 1982