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By H. H. Schrenk

Much has been written and said concerning tables of permissible or maximum allowable concentrations of various toxic substances in air, but not enough attention has been given to their limitations and how to use them intelligently . There is a tendency to place too much reliance on figures , with little or no consideration of their real meaning . The repeated publication of a figure often adds significance to it far beyond that intended by the original author or publisher . How are these figures referred to as "maximum allowable concentrations " established? What is their real meaning? To answer these questions it is necessary first to define maximum allowable concentration . The usual definition is somewhat as follows : "The average concentration to which an industrial worker can be exposed for 8- hours daily for an indefinite period without injury or occupational disease . This definition is made up of the following items : ( 1 ) Average concentration, ( 2 ) 8 - hour day , ( 3 ) indefinite exposure period , and ( 4 ) lack of injury or occupational disease . There is some controversy regarding item ( 1 ) , items ( 2 ) and ( 3 ) are usually though not invariably accepted , and there is definite disagreement regarding the interpretation of item ( 4 ) . . To reach a more satisfactory interpretation of maximum allowable concentration , attention is directed to ( 1 ) the development of tables of maximum allowable concentrations , ( 2 ) criteria on which limits are based , and (3 ) methods used to obtain data on which limits are based .

May 1, 1948

By Thomas A. Morgan, Louis A. Panek

This report describes a method for determining the stress in rock based on a requirement for static equilibrium ; namely , that the total load on a sufficiently large area must remain constant even after a drift or stope is mined in the area . The method is based on mathematical relationships that are independent of the elastic properties of the rock and the stress distribution near the underground opening . In addition to determining the preexisting stress (before mining ) , the method described can be used to determine the change in stress due to mining .

Jan 1, 1963

By H. R. O'Brien

"During the past year, the Pittsburgh experiment station of the Bureau of Mines has been investigating methods for the quantitative estimation of carbon monoxide in blood. This work was necessary because reliable methods of analysis are of the greatest importance in the bureau's research work on prevention and treatment of carbon monoxide poisoning among workers in mines and metallurgical plants. Two of the methods considered involve color comparisons. In one of these methods, differences in tint can be noted fairly readily, while in the other, they are much more difficult to detect. The latter, however, is otherwise considerably simpler. It was decided, therefore, in studying the possibilities of this second method, to use the most sensitive eyes in the laboratory force.Preliminary trials.The method under investigation was the Haldane carmine determination of carbon monoxide in blood. The plain oxyhamoglobin of the blood in dilute solution is a pale straw color, when exposed to carbon monoxide it becomes a cherry pink. In the analysis dilute indigo carmine is added to oxyhsmoglobin until the solution matches in tint the carbon monoxide hemoglobin. The eye wanted, then, was the one most sensitive to faint pinks. But just how to select the analyst was not clear At first the Williams test scale, used in the Navy, was considered, but on con¬sultation with Dr. L. L. Thurston, bead of the Department of Psychology at Carnegie Institute of Technology, the following procedure was adopted.Instead of standard tests made up of all colors, only those occurring in the analysis were used. Solutions were prepared of the two hemoglobins, from which twenty-four different pairs were made up and placed in test tubes like those expected to be used in the analysis. One of each pair differed from the other in percentage of carbon monoxide hemoglobin by amounts varying from 2-1/2 per cent to 20 per cent. Each pair was compared in a box built in our own shop. This was 20 inches long and 5 inches square in cross section. One end was covered with ground glass. Just inside this glass cover were provided two slots, each the width of the test tubes used. The tubes to be compared were dropped into these slots through two holes in the top of the box. The device was placed before a window away from the sun, and so arranged that the light conditions were the same on each slit or opening. The person to be tested was seated before the box, and as the two tubes were placed before him side by side, he marked whether A (left) or B (right) contained the more cherry pink. This procedure was continued till he had compared all the pairs."

Jul 1, 1921

By F. S. Crawford

This report deals with the effectiveness and economy of installing mine timbers treated with preservatives in long-life service locations. Early in the present century, when mine timbers and labor were plentiful, it was not general practice to install treated timbers in such places. Because national sources of good mine timber are declining steadily, the mining industry must now conserve timber. Moreover, the cost of installing and replacing mine timbers has been rising. Therefore, even the simplest of treatments can be expected to give some return on the investment when applied to timbers that are to be installed in relatively permanent locations. Better methods of treatment will produce better returns. In a service test of maple timbers treated by the hot-and cold-bath method and installed in main haulageways of the Athens mine of the Cleveland Cliffs Iron Co., Negaunee, Mich., zinc chloride-treated timbers had an average useful life of 13.3 years; borax-treated timbers, 11.2 years; and sodium fluoride-treated timbers, 7.7 years. Untreated timbers used as controls had an average useful life of 3.8 years.

Jan 1, 1950

By Edward L. Burwell

The Bureau of Mines investigated the use of dilute polymer in brine solutions to increase the efficiency of air in gas flooding model oil reservoirs. Slugs (0.23 pore volume) of 500 ppm polyacrylamide were injected into a model, consisting of a high- and a low-permeability core, that had been previously gas flooded to residual oil. Gas flooding was then resumed. Of the total gas volume injected, the percentage entering the high-permeability zone was greatly reduced after polymer injection but remained unchanged when slugs of water without polymer were used.

Jan 1, 1970

By Daniel D. Sweeney

The United States coal mining industry has traditionally experienced difficulty in controlling dust levels below the occupational exposure limit. While improvements in face ventilation and water spray nozzles have decreased dust exposures, approximately eight percent of experienced coal miners are still developing Coal Worker?s Pneumoconiosis. This investigation tested the feasibility of enhancing existing engineering dust controls by mounting a simple barrier on a longwall shearer that separated the operators from the cutting drums. The barrier was constructed and tested above ground at the National Institute for Occupational Safety and Health Pittsburgh Research Laboratory longwall gallery test facility. A 96-percent reduction of respirable dust occurred at the headgate sampling position when tested at 2.4 m/sec (480 ft/min). The average dust level decreased from 39 mg/m3 to 1.5 mg/m3 by utilizing the barrier.

Jan 1, 2009

By R. V. Ramani, P. M. T. White, D. Sutton

1.1 General The examination and evaluation of a mineral deposit to determine whether or not it can be profitably exploited entails many factors unrelated to the physical nature and intrinsic worth of that deposit. Nevertheless, geology and geologically related factors have great bearing on the economic potential of the deposit. This is only natural because the deposit owes its existence to these factors. This is even more so in underground mines where the whole system is a geologically enclosed one. Geology plays a major role in at least four phases of a mineral venture. Firstly, it acts as an indicator of the existence of parti¬cular minerals. For example, it is inconceivable that a sedimentary coal deposit would exist in a granitic batholith or stock, or that a sandstone would host primary copper or nickel sulphides. Further, the positional relationship of different rock types may be significant in locating deposits such as replacement zinc and copper sulphides in limestones which have been intruded by igneous rocks. Thus, geology is important in the exploration phase of a mineral deposit. Secondly, once potentially valuable minerals have been discovered, knowledge of geology plays a significant role in determining the dis¬tribution, grade and extent of the mineralization. Controls on mineralization include one or all of those related to structure, rock type, sedimentary features, post-depositional redistribution, etc. Con¬sequently, in order to effectively evaluate a deposit in terms of

Jan 1, 1974

By C. J. Cohen, L. A. Dahners

"SUMMARYA method has been developed for surveying, drill holes without lowering into the hole any surveying equipment other than an etch tube. The orientation of the rods at the collar of the hole is maintained as the etch tube is lowered. The attitude of the etch ellipse in depth with respect to the rod orientation at the collar can then be observed. This relationship permits the bearing of the hole in depth to he calculated. The rod orientation is maintained during the lowering by means of a pair of alinement clamps. One clamp is fastened to the top of each rod as the rod is coupled and is removed when the alinement has been transferred to the other clamp at the top of the next succeeding rod. A particular advantage of this survey technique is that surveys can be readily made in magnetic country rock.PRINCIPLE OF THE TECHNIQUEAn axial lamina of the column of drill roes is the lamina in which one fiber would be the centerline of the rods. In the new survey technique, the rods are fed into the hole in such a manner that the axial lamina of each successive rod maintains its position at the collar of the hole. In depth, as the rods bend in following the drill hole, the axial laminae also bend. The lamina that was originally vertical will, in general, be tilted away from the vertical. The trace of this lamina is marked on the glass etch tube before the tube is lowered in the hole. The axial lamina that becomes vertical at the survey station is recognized as that axial lamina which contains the long axis of the etch ellipse. The angle between the lamina originally vertical and the lamina vertical at the survey station is thus measurable. When the vertical axial lamina at one survey station has been determined by the etch ellipse at that station, angle R between this lamina and the vertical axial lamina at the next survey station becomes measurable also. By moans of angle R, and dip angles D1 and D2 at the two stations, the change in bearing (z) of the drill hole between the two stations can be calculated."

Aug 1, 1944

By A. F. Colombo

Laboratory-scale tests were conducted by the Bureau of Mines on an argillaceous Michigan copper ore and mill tailing to determine the feasibility of leaching with acidified ferric sulfate solutions. The ore and tailings, containing 1.24 and 0.24 percent copper, respectively, were from the White Pine Copper Co., Ontonagon County, Mich. The investigation showed that ferric sulfate leaching of the ore and tailings followed a predictable pattern. Thus, with 4 hours of leaching, up to 58 percent of the copper in the ore was extracted, but prolonged leaching (2 to 3 weeks) was required to dissolve more than 90 percent of the copper. Similarly, about 50 percent of the copper in the mill tailings sample was dissolved in a few hours, but 8 days or more were required for extractions of over 90 percent.

Jan 1, 1962

By John D. Sullivan

The present article is one of a series which is being prepared by the Southwest Experiment Station of the United States Bureau of Mines in cooperation with the Department of Mining and Metallurgy, University of Arizona, Tucson, Ariz., of papers dealing with factors involved in the leaching of copper ores. A knowledge of the time required to dissolve the various copper minerals present in ores, as well as of the consumption of leaching reagents is very desirable, because with the decrease of the Nation's total tonnage of sulphide ores increasing attention is being given to the recovery of copper by leaching methods from low-grade disseminated ore containing both oxidized and sulphide minerals. As leaching has already been applied with success and profit, this study was undertaken to determine certain fundamental characteristics that are applicable to all ores suitable for leaching.

Jan 1, 1929

By Kenneth Lipman

Auxiliary equipment was assembled around a purchased oscillograph to permit observation of the current and voltage characteristics of low-energy, capacitance-discharge sparks having durations of at least 10 mµ-sec. Circuit details of the assembled apparatus, performance characteristics of the complete system, and some preliminary data from representative self-initiated sparks are given in this report. INTRODUCTION One of the subjects of continuing research by the Federal Bureau of Mines Division of Explosives Technology is the ignition of explosive-gas mixtures by means of low-energy capacitance sparks. Quite early in these investigations it was recognized that understanding the gas-ignition phenomena would be facilitated by detailed information about the performance of the ignition source (spark) under the actual conditions of interest; however, the sparks of practical interest are nonrepetitive transient phenomena whose duration could reasonably be estimated to be in the time range of 1 mµsec. to 1 µsec. As such, the only feasible method of obtaining detailed information was and is oscillographic representation of the pertinent current and voltage transients. It was not until 1947 that a suitable, commercial, dual-channel oscillograph could be obtained as the basic instrument for these studies; the instrument specified in 1947 was delivered in 1950. This paper describes the auxiliary

Jan 1, 1959

By R. A. Guereca

The Bureau of Mines conducted an analysis to determine criteria for steady-state, laminar flow boundary conditions for a coiled-tube gas viscosimeter by comparing experimental data from a thick-walled, stainless steel capillary in a horizontal, straight-tube condition, with similar data taken after the same capillary was formed into a helix. Overlapping volumetric f10wrates and pressure drops are covered for both configurations at pressure levels of 28, 225, and 1,000 psia at 3000 K. Friction factor, Reynolds number, and Dean number correlation plots show conditions where the coi1ed-tube flow deviates from straight-tube flow. The coiled-tube data indicate departure from Poiseui11e steady-state laminar flow at a Reynolds number close to 390 and a Dean number of about 15. Below these conditions and consistent with the data reported, Dean's circulation appears negligible. For the particular coil used, a conservative upper limit of 10 is chosen for the Dean number corresponding to an upper limit of about 250 for the Reynolds number.

Jan 1, 1967

By L. C. IlsLey

"Nearly every piece of electrical equipment used in mines ""breathes."" In other words, motors, controllers, rheostats, switches, and other similar equipment, even though encased in seemingly tight compartments, breathe in the atmosphere that surrounds them.As the apparatus is used, the temperature of metallic parts is changed generally in positive direction through the heat by friction and the heat due to the electric current. When the apparatus is idle it gradually cools down to the temperature of the surrounding atmosphere.This increase of temperature during operation and return to normal temperature when operation stops alternately raises and lowers the temperature of the atmosphere within the compartments which, in strict accordance with Charles' law -will expand or contract in proportion to any given temperature change.As compartments are not gas-tight, such expansion and contraction will force the atmosphere out of the compartment =on expansion and suck the surround¬ing atmosphere into the compartment during contraction, hence the term ""breathing.""Investigators2 of explosion-proof equipment have recognized that such an interchange would take place and have designed their equipment to safeguard possible explosions within the compartments."

Jun 1, 1927

By F. N. Kissell, C. D. Litton

This study ranks the factors impacting survival during a coal mine fire. It bas already been established that reducing time delays is the most important factor in saving lives. Consequently every event during afire is measured in terms d its duration, and the effectiveness d any action taken to improve survival is measured in terms d the time it saves. By ranking actions according to time saved these authors found that a comhination d actions was most effective. This combination was: • installing lifelines. • moderately decreasing air leakage and • decreasing the fire growth rate. Changing ventilation leakage alone was much less effective, as was altering the CO (carbon monoxide), sensor alarm threshold. These results confirm an earlier fault-tree study on escape from mine fires. The fault-tree study bad shown that, with the exception d delays, single factor changes have minimal impact. Significant reductions in fire fatalities only take place with multiple factor changes.

By H. O. McDonald

Solutions containing Cr6+ and sulfuric acid are used in a number of surface-finishing operations. Substantial quantities of chromium and copper are lost and pollution problems are created when the spent solutions are discarded. To minimize the undesirable environmental effects while improving secondary resource recovery technology, the Bureau of Mines is conducting research to detoxify and recover metals from these solutions. Spent etchants are treated to remove copper and reduce Cr6+ to Cr 3+ in an electrolytic cell. The anodes and cathodes are granulated coke. The spent solution is continuously pumped through the electrodes. Hexavalent chromium is reduced to trivalent chromium, and copper is recovered at the cathode. Reoxidation of Cr3+ at the anode was not observed. The removal and recovery of copper reduction of Cr6+ lessen chemical demand and increase efficiency in waste in treatment operations associated with the use of these solutions.

Jan 1, 1980

By R. L. Grant

The Bureau of Mines applied automatic computational methods to analyze the degree of correlation between sound transmission and atmospheric conditions. Statistical analysis of data collected over a 5-month period indicated that the following weather variables, listed in order of decreasing importance) have a significant effect on the transmission of sound in the atmosphere: 1. Wind velocity and wind direction. Winds in the direction of travel of the sound wave increase the sound intensity and duration. 2. Barometric pressure. High pressures are related to low sound intensities and durations. 3. Atmospheric temperature. High temperatures are related to low sound intensities and durations. Inversion of the atmospheric temperature did not appear to affect sound transmission under the conditions of this study.

Jan 1, 1967

By J. C. Franklin

The Bureau of Mines substantially reduced shale degradation in a coal mine by two spray coat applications of a water-base epoxy sealant. More than 12,700 square feet of passageways were treated, and in 18 months only one failure occurred. This failure was due to improper spray application, Material costs averaged 13 cents per square foot, and labor costs were 7 cents per square foot. Labor included moving all materials into the mine, the setup time for each of the areas coated, and application of coatings.

Jan 1, 1977

By R. W. Stahl

A survey of firefighting facilities and practices in coal mines conducted by the Bureau of Mines3/ showed such variations in equipment and apparent attitude toward fire protection that a comparison with other industry seemed advisable. Although other industry is confined generally to surface operations and the hazards probably are not as great, the same general methods of extinguishment are employed, so that the cost and protection at least should be comparable. An investigation of industry other than mines revealed a generally greater emphasis placed on fire-combating equipment, fire-brigade training, fire-fighting facility inspection, and fire-hazard elimination, as well as a greater average expenditure for fire protection.

Jan 1, 1959

By Alla D. Mah

No experimental heat-of-formation value has been reported in the literature for cerium sesquioxide. The heat of formation of bismuth sesquioxide has not been determined in recent years, and the older value was subject to large uncertainty. Accordingly, the heats of combustion of cerium sesquioxide and bismuth metal were measured by the Federal Bureau of Mines. The heats of formation were: ?H°298.15 = -427.01 ± 0.70 kcal. /mole for cerium sesquioxide and ?H°298.15 = -137.16 ± 0.30 kcal./mole for bismuth sesquioxide. The free energy of formation was estimated for cerium sesquioxide and accurately calculated for bismuth sesquioxide. The data were compared with values in the literature.

Jan 1, 1961

By Raymond M. Stateham

Climatic conditions are compared with roof fall occurrence from April 1, 1972, to December 31, 1975, by the Bureau of Mines. These comparisons indicate that humidity has a strong influence on roof fall occurrence rates. Cubic regression techniques are used to develop best fit curves. Statistical analysis of these curves indicate that both are sinusoidal and exhibit positive correlation with each other. The sine waves have a period of 1 year with maximum and minimum inflection points in August and February.

Jan 1, 1978