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By Kotaro Ohga, Kiyoshi Higuchi

In our laboratory, a new detection system using smell detectors was developed to detect the spontaneous combustion of coal and the combustion of other materials used underground. Laboratory experiments were carried out on several kinds of coals, including South African coals, and machine oil, wood and rubber used in belt conveyers. The following results were obtained: 1) Spontaneous combustion of coal can be detected earlier by smell detectors than by conventional CO detection methods. 2) There were no differences in the results using different kinds of coal. 3) Combustion of other materials can also be detected earlier by this system than by conventional detectors for gas and smoke. 4) Use of this detection system enables one to discern the source of the combustion gases, whether it be coal, wood, oil or rubber.

Jan 1, 1995

By I. Longson

As a longwall coalface advances a caved goaf or waste region is left behind. Air flow takes place through this permeable goaf due to the pressure differentials existing across it and en route this leakage air picks up both heat and moisture. A marked deterioration in climatic conditions occurs in the face area at all points downstream of where this leakage air rejoins the main air-stream. This goaf heat source can make a very significant contribution, typically 30-40% to the rate of total heat pickup on an advancing UK longwall coalface with a VST of 40°C and hence on the climatic conditions that prevail at the return end and in the return gate of the face. The magnitude of the rate of heat collection from the goaf depends on a number of factors but it has been established that it is particularly influenced by the prevailing virgin rock temperature and the total flow rate of the leakage air. This paper proposes a model for the goaf based on a packed bed analogy and other assumptions required in order to evaluate the rate of heat pickup are identified. The outlet condition of the leakage air predicted by the model have been shown to correlate with underground measurements taken for a range of different production patterns with the face cutter at various locations on the face. The sensitivity of these predictions to variations in the input data has been tested and is commented on. At this stage of the development the capabilities and predictive limitations of the model are discussed. Further areas of investigation are suggested in order to improve the predictive ability and to extend the versatility of the model.

Jan 1, 1989

By R. D. Grove, M. F. Elliott, R. L. Weigel

The control of Florida phosphate flotation plants is largely based on the visual observations of experienced operators, both in recognizing good and bad froth conditions and in making judgments about the composition of feed, concentrate and tailing streams. Chemical analyses lag the process by at least two hours and therefore only assist in recalibrating the operators' vision when major deviations occur. An image analysis system has been developed by IMC Agrico Company (IMCA) to improve upon the accuracy and precision of the composition estimation process. It still relies upon the operator taking a representative sample, but provides a measurement in about 15 minutes after that sample is obtained. This paper describes the system and its use and presents comparative results for various process streams.

Jan 1, 1993

By S. K. Kawatra, V. Claremboux, S. Valluri

Carbon dioxide capture from coal-fired power plant flue gas and subsequent sequestration is expected to play a vital role in mitigating global climate change. To meet the growing need for CO2 capture Technology, Michigan Technological University is researching CO2 capture and Utilization. We have successfully converted CO2 into oxalic acid using an electrochemical approach. If oxalic acid can be produced in bulk from CO2, it can be used to leach rare earth minerals at low cost. Electrochemical reduction of CO2 to hydrocarbons and other chemicals is a complex multistep reaction with adsorbed intermediates. The exact reaction mechanisms leading to various products are not clear from the literature to date and will likely change over the range of conditions like pH, electrode potential, electrolyte medium, catalyst, etc. In this paper, we will present an idea of how the factors mentioned above will effect the electrochemical reduction of CO2 to Oxalic acid. INTRODUCTION. CO2 is thermodynamically quite stable, as shown by its highly negative heat of formation. Thus, it is expected that the formation of any useful chemical from CO2 will require the input of at least as much energy as geological sequestration. However, to be more effective the resulting economic value of the chemical need only pass the cost of the additional energy required beyond geological sequestration. This lends itself to two extremes: one where the quantity of energy required is low and one where the economic value of the additional energy is low. It is expected that CO2 can be reduced via electrolysis to several compounds. Of particular interest are formic acid, oxalic acid, methanol, ethanol, formaldehyde, and carbon monoxide (as a component to syn-gas). These chemicals have been reported as electrolytic products previously in literature and have considerable potential for application. EXPERIMENTAL Electrocatalytic Production of Oxalate from CO2 We are using membrane electrolysis cell to produce oxalate from CO2. A membrane electrolysis cell is a 2-chamber electrolysis cell where the chambers are separated by a selectively permeable membrane. To produce oxalate, a cation exchange membrane (which selectively exchanges cations) was used. Previous literature suggests that in the cathode chamber an organic electrolyte, such as tetraethylammonium perchlorate or tetraethylammonium bromide in dimethylformamide, are preferred3. In the anode chamber, a sodium hydroxide solution water is used. Carbon dioxide is then bubbled into the cathode chamber as a current is applied.

Jan 1, 2019

By Mr. Peter J. Huck

Recent research has developed procedural control and geophysical test methods that can greatly enhance quality control in rock grouting. Confidence that design objectives will be made In construction requires that grout monitoring efforts be carefully designed and integrated into the overall project. Parameters that should be monitored are identified and documentation/review procedures that permit effective evaluation of the grouting effort are discussed.

Jan 1, 1980

By M. C. Fuerstenau

Flotation data indicate that sulfonate and dodecylamine adsorb physically on Mn02 at ambient temperature. Oleate also adsorbs physically if the zero-point-of-charge of the Mn02 is sufficiently high. Chemisorption of oleate apparently occurs between pH 8 and 9, and this phenomenon is enhanced considerably at elevated temperature.

Jan 1, 1966

By J. M. Mutmansky, B. Kolonja

A PC-based simulation model using the software packages SIMAN and CINEMA was developed to simulate and animate truck-shovel operations. The model is capable of simulating one mathematical dispatching strategy using linear and dynamic programming and six heuristic dispatching strategies. Data were collected from an actual operating mine through time studies and analysis of historical records. Statistical analyses were performed, and appropriate theoretical distributions were fitted for various time events in the truck-shovel cycle. The model was then applied to study overall impact of these dispatching strategies on constrained and unconstrained mine productivity. The simulation/animation model developed in this study seems to be an efficient planning tool for choosing optimal fleets and finding an optimal dispatching strategy to produce an equilibrium between the quality and quantity of production.

Jan 1, 1995

By Z. D. Hora, W. N. Hamilton

Evaporite units of the Western Canadian Sedimentary Basin are known to host native sulfur. In British Columbia, a large number of oil and gas exploration drilling holes reported intersections with native sulfur. The most important ones include 6 meters (20 feet) and 27 meters (90 feet) of native sulfur among 23 occurrences in Devonian Muskeg evaporite or adjacent Slave Point reef facies carbonates. A small Frasch sulfur deposit is known from Devonian Wabamun Group sediments near Camrose in South Central Alberta. Occurrences of native sulfur are common also in association with presently mined gypsum of Devonian Burnais Formation in southeastern British Columbia. Triassic sediments with evaporite members in British Columbia are also known to contain native sulfur showings. A widespread presence of anhydrite in many sedimentary units of Alberta and British Columbia together with oil and gas fields in the same areas and associated native sulfur occurrences point to a possibility for Frasch sulfur deposits in this part of western Canada.

Jan 1, 1992

By David Brown, Glen Hall, Ken DeVos, Frank Barone

Dredging and Flooding was completed on the Falconbridge Limited "New Tailings Area" in the period from 1996 through 1998, as part of their site closure measures. Part of the decision making process and closure planning was water quality prediction, including oxidation and diffusion modelling. The purpose of this modeling was to define the potential water quality that would result during and after dredging. A significant body of research on the geochemistry and oxidation kinetics of this site had been compiled. The results of the modeling provide practical insight on the potential water quality that may be expected. Water quality in the pond has steadily improved since flooding was completed with the exception of short term peaks during spring runoff. Aquatic vegetation is appearing through natural recovery and transplanting of local species, and colonies of minnows are now observed in the ponds.

Jan 1, 2000

By Z. Rogovin

A Knowledge of the amount of time the material spends in a continuous mill in a closed-grinding-circuit is essential for circuit performance analysis and scale-up design. A convenient method for acquiring this information involves the use of tracers in residence-time-distribution (RTD) experiments. In a typical wet process the RTD measurements are usually done by injecting a pulse tracer into the mill inlet and detecting it in the circuit exit. In this article a simple to use mathematical method for the calculation of the closed circuit material residence time in the mill is developed. Using this method there are no restrictions on the location of the tracer injection or detection points. Any convenient location in the closed circuit can be chosen without affecting the simplicity of the method. This method also enables the calculation of the degree of mixing in the mill. The use of this method for the analysis of impulse response data obtained from several commercial grinding circuits is presented.

Jan 1, 1986

By G. Robert Guillet

Nepheline syenite is a light-colored feldspathic rock that is used primarily as an addition to the glass batch. It is also used in ceramics and as an industrial filler. Composed essentially of the soda and potash feldspars and nepheline, nepheline syenite contributes needed alkalis and alumina to the glass composition. And because it contains a higher proportion of these oxides per unit weight, it is a formidable competitor for feldspar in northeastern North America and parts of western Europe. Nepheline-bearing rocks are not uncommon on a world scale, but few are able to be beneficiated to a composition sufficiently low in iron to be used in the making of glass. Nepheline can only form in an environment deficient in silica. Hence free silica, as quartz, is always absent in the primary mineral assemblage. Biotite, hornblende and magnetite are usually present as minor accessory minerals, and zircon, garnet, muscovite, and apatite may be present as trace minerals. Nepheline syenite is produced for glass, ceramics, and filler markets by Unimin Canada Limited at Blue Mountain, in south- eastern Ontario. Unimin acquired the former Indusmin and IMC properties from Falconbridge Ltd. in 1990. Elkem Nefelin AIS commenced production of similar products from Stjernoy Island in northern Norway in 1961. Unimin acquired this company in 1992. Nepheline has also been a byproduct of apatite mining on the Kola Peninsula for many years, and in 1951 the production of alumina from nepheline was commenced in a plant near St. Petersburg (Leningrad). There are now four plants in the Russian Republic, two smaller ones based on nepheline tailings from apatite mining and two larger and more recent plants in central Siberia using other nepheline resources. All four of these plants are integrated complexes that produce alumina for the subsequent production of aluminum metal, sodium and potassium carbonates, and portland cement. Roofing granules are produced by the 3M Company from a nepheline rock in Arkansas. In 1980 and 1989, trial shipments of nepheline syenite were recorded from new sources in Brazil and western Turkey respectively. Recent interest is also recorded for deposits in China, Saudi Arabia, and British Columbia.

Jan 1, 1994

By G. Rinelli, Paul R. Jr. Smith

Preparation for flotation begins with dragline mining, pumping, washing, screening, and desliming. Slimes, nominally -150 mesh material, constitute large quantities of phosphate and water which are a disposal problem. Older techniques involve sizing at about 35 mesh for separate coarse and fine treatment. The plus 14 mesh fraction does not require concentration. Coarse treatment includes agglomerate spiralling, belt flotation, thickening, scrubbing with sulfuric acid, de-oiling for reagent removal, and cationic flotation of fine quartz. A recent trend is to screen at coarser than 35 mesh size and eliminate coarse particle treatment, sacrificing some grade of this product. Techniques for flotation concentration of the fine size fraction are discussed.

Jan 1, 1976

By Michael L. Maniocha

Most magnesia (MgO), whether of natural or synthetic origin, is used in the dead-burned or periclase form as refractory linings for the production of steel. Continued research in refractory science, combined with good refractory maintenance and improvements in steel-making processes, have resulted in decreased use of magnesia. To make up for this loss of business, producers of synthetic magnesia have started to manufacture a variety of magnesium-based chemicals that are used in many industries. There are three primary methods of producing MgO. The first involves the calcination of naturally occurring minerals species. Most of the magnesia produced by this method uses the rhombohedra1 carbonate mineral magnesite, MgCO,. To a lesser extent, the mineral brucite, Mg(OH), is calcined to magnesia. Magnesia produced by the calcination of minerals is called natural magnesia. The second production method uses magnesium-rich brines, or sea water reacting with lime or calcined dolomite to produce magnesium hydroxide. The magnesium hydroxide is subsequently calcined to magnesia. Material produced in this way is called synthetic magnesia. The third major method of production uses saline lake brines to produce magnesium chloride. Magnesium chloride brine is sprayed into a reactor where it thermally decomposes into MgO and HCl. The magnesia is purified by slaking to magnesium hydroxide followed by calcination. Magnesia produced in this manner is also know as synthetic magnesia (Duncan and McKracken, 1994). The degree to which the magnesium minerals or the synthetically prepared magnesium hydroxide is calcined governs the physical properties of the resulting MgO. It is the physical properties that dictate the end use for the product. The terms used to describe magnesia vary along with the degree of calcination. Table 1 summarizes the terminology used when discussing the various forms of magnesium oxide.

Jan 1, 1997

By M. P. Saunders

A comprehensive, site specific water management plan is of primary importance to the successful implementation, operation and decommissioning of any mining project. Formulation of a plan requires an orderly planning process consisting of identifying problems, establishing planning criteria based on the guidelines and requirements of regulatory agencies, and an iterative procedure of identifying, investigating, and evaluating plan elements and alternative plans. A typical uranium surface mine operation consists of a mine pit or pits, spoil pile areas, crusher, processing plant, and tailings disposal area. A water control plan addresses the problems of diversion of natural runoff from undisturbed areas around the mine; and diversion, collection, and treatment of runoff from within the mine area. A water control plan is required to determine the location and size of appropriate control and detention structures; their cost; and the schedule for permit activity, design, and construction. The plan must be formulated to meet the requirements of both the State and Federal regulatory agencies.

Jan 1, 1981

By S. B. Castor

Proceeds from industrial mineral mining in Nevada were approximately equal to those from metal mining during the barite boom in the late 1970s and early 1980s; however, since then the economic importance of industrial minerals has been overshadowed by gold mining (Fig. 1). The total value of industrial minerals mined in Nevada increased by about 60% during the 1980s, reaching an estimated $306 million in 1990 before falling slightly in 1991. The state's most important industrial mineral commodities, in order of estimated value, are aggregate, lithium carbonate, diatomite, lime, cement, gypsum, barite, clay, silica, and magnesia (Fig. 2). Industrial minerals produced on a smaller scale are colemanite, dimension stone, dolomite, perlite, salt, and zeolite. In 1991 industrial mineral commodities other than aggregate were produced at 39 operations in Nevada. Most of these operations are located near the two major metropolitan areas of the state, or along the major transportation routes (Fig. 3).

Jan 1, 1993

By P. Bevilacqua, G. Ferrara, M. C. Williams, T. P. Meloy

Tabling is an old environmentally friendly separation unit operation. This paper models shaking tables and explores the action and design of riffles on shaking tables. By reassessing riffle shape and riffle patterns, significant improvements in tabling performance appear feasible. While table sales appear at their nadir, a high-tech environmentally friendly table may have a significant market in the coming decade. Riffles on a shaking table impact particle separation. Particles are affected by riffles and their exit position on the table is dramatically changed, Riffle shape determines how much the riffle will influence a given material. Moreover, riffle patterns influence the concentration of a given material and its exit points on a table. This effect of riffle placement and design is modeled in a spreadsheet. Major performance and separation improvements may he expected by improved table design. Two physical laws of tabling have been derived. These laws aid in the design of sophisticated high-tech tables.

Jan 1, 1995

By Craig M. Sams

Phosphate mines in Florida are continuing to encounter higher dolomitic content host rock with the phosphate pebbles(1) necessitating a change in grinding conditions and/or circuits, One of these changes is to install hydrocyclones and close circuit the mill as opposed to the traditional open circuit grinding plant. Close circuiting of the grinding mill with hydrocyclones allows one to take advantage of reduced process mill power requirements by circulating the coarse mill discharge back into the mill for multiple chances of particle breakage. Additionally, as in this case, the hydrocyclones de-slime the pebbles, allowing for more efficient use of grinding power by reducing the amount of dolomitic material recycled to the mill.

Jan 1, 1986

By William J. Shampine

This map shows general trends of the chloride concentration of water in the upper part of the Floridan aquifer. Below this part of the aquifer, high chloride water can be found everywhere in the State. The accompanying cross section shows the depth to salty water across central Florida. In the center of Florida, fresh water may be found as deep as 2.000 feet, whereas, along the coast it may extend no deeper than about 200 feet. Chloride concentration in small local areas may deviate from the values represented on both the cross section and the main map. This map shows general trends of the chloride concentration of water in the upper part of the Floridan aquifer. Below this part of the aquifer, high chloride water can be found everywhere in the State. The accompanying cross section shows the depth to salty water across central Florida. In the center of Florida, fresh water may be found as deep as 2.000 feet, whereas, along the coast it may extend no deeper than about 200 feet. Chloride concentration in small local areas may deviate from the values represented on both the cross section and the main map.

Jan 1, 1966

By Velu Annamalai

In-situ uranium solution mining involves the injection of a lixiviant (leach solution) through appropriately placed wells into the underground ore zone. Upon contacting the uranium minerals, this solution will dissolve the uranium. The uranium containing solution is then pumped out of the wells into a processing plant where the uranium values are removed, typically in ion exchange columns, and the stripped liquor is recycled back into the field. The lixiviants may be acidic or basic. Where the ore zone mineralization contains appreciable carbonate, as in the South Texas fields, acid consumption would be excessive and the typical solution is ammonium carbonate bicarbonate at about 5-10 g/l and a pH of 7-9. Because the usual uranium minerals, uraninite or coffinite, contain uranium in the insoluble tetravalent state, it is necessary to add an oxidant to increase the valence to the hexavalent state where the uranium is soluble. Oxygen dissolved in the lixiviant has been shown to be quite effective for this purpose. It is also much more economical than other oxidants. Of concern is the possibility that (1) its solubility may or may not provide concentration levels adequate to give an economically attractive uranium level in the extracted liquor, and (2) the addition of oxygen in excess of the saturation level so as to increase the uranium grade in the lixiviant may cause gas blockage of the typical fine-pored ore formations.

Jan 1, 1981

The exploitation of mineral deposits for economical recovery of the contained minerals has many aspects differing from other industrial or manufacturing operations. However, generally accepted principles of good organization and management applicable to industrial plants are similarly effective for mineral processing plants. A more detailed coverage of organizational structures and management techniques than is possible in this section can be obtained from many good books devoted wholly to these subjects. A few of the more readily available examples are included in the general references at the beginning of this section. The field of mineral processing encompass a wide variety of minerals, processes, flowsheets, equipment, and end products. Mineral deposits, mines, and related beneficiation plants are found in all parts of the globe, often in remote locations with no nearby support for supplies and maintenance. Available labor is frequently unskilled, sometimes primitive, and often untrained without machine and hand tools or heavy equipment experience. Such situations call for well- planned and conducted training programs covering the full range of mining-type job skills. Climates can range from arctic to tropical and from arid to extremes of rain or snow, and the mine and plant sites can be almost anywhere. However, it is often possible and sometimes necessary for

Jan 1, 1985