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By H. N. Mills

The glass industry is a major user of many industrial minerals in the manufacture of its product. It is the intent of this chapter to: (1) acquaint the reader with the glass industry by including a few production statistics, and then (2) cover the various aspects of the major raw materials used to make glass. Some of the items covered are: type of materials, their function in glass, their composition, cost, and the relative quantity used in glass vs. totals produced. In addition, a discussion of glass raw material specifications, some byproduct materials used in glassmaking, and comments on future prospects related to the environment, technology, and growth are included. The matter of glass compositions, properties, and batches is considered beyond the scope of this chapter which deals only with raw materials. For more details on the particular minerals and rocks, the reader is referred to the commodity chapters in this book.

Jan 1, 1975

By A. Thies, A. Mezcer

The Haile mine is situated in Lancaster county, South Carolina, twenty miles south of Lancaster. The topography of the country is characterized by low hills rising generally less than two hundred feet above the many small creeks which traverse the surface. The road from Kershaw, the nearest railroad station, 3 1/2 miles from the mines, leads through woods with sandy soil and cottonfields. In many places it lies on the bare rock and shows that the adjacent covering of soil and earth is usually not more than one foot thick, and often less. This covering is to a great extent sand. Close by a bridge, about one mile from the mine, large round boulders of diabase may be observed. The country-rock seems to be exclusively talcose slate, with a general strike varying from N. 45' E. to N. 70' E. These variations may be seen in the immediate neighborhood of the mines, the large open cuts of which present exposures favorable to such ob-

Jan 1, 1891

By Saburo Shigeno, Kunzo Amano

As shafts and tunnels move deeper levels in underground mining, development planning becomes more complex. The most serious problem is the aggravation of environmental conditions due to the imposition of higher-than-natural temperatures upon exposed strata. Since such a problem is a potential hazard to health, safety, and production, the authors have developed a system of computer-derived ambient-air temperature data for every major point of an underground mine under a given set of conditions. This system is comprised of two subsystems: 1) Ventilation network analysis, 2) Estimation of air - current temperature. The former is based on the Hiramatsu-Oka method, an improvement of the Scott-Hinsley method. The Hiramatsu-Oka method allows fast convergence and consideration of various fan characteristics. The latter subsystem considers heat radiation from strata, and the humidity. In several tests conducted at Besshi and Sazare Mines of Japan, the computer-derived data correlated with actual conditions.

Jan 1, 1969

By D. L. Martin, E. R. Parker

DURING the heat-treatment of silver specimens for tensile tests it was observed that the bars blistered and became brittle when heated in a hydrogen atmosphere. [ ] To check this unexpected result, a wide variety of commercial silvers were heated in hydrogen at 850°C, Only a few of the materials developed blisters, the most severe of which is the tube pictured in Fig. I. The microstructure of a cross section of the tube is shown in Fig, 2. The embrittlement is extremely severe at the edge; the blisters result from the severe deforma- [ ] tion of the surface material by large underlying gas pockets, The effects resulting from hydrogen embrittlement of silver have been observed by numerous investigators over a long time1,2,3 although it was only recently that a clear explanation was offered ,4 However, the damage resulting from hydrogen embrittlement has not been generally recognized; and it is of advantage to know more about this phe-

Jan 1, 1943

By R. E. Reed-Hill

Recently Levine applied the Conrad-Wiedersich17 equation where H is the activation enthalpy, v the activation volume, T* the effective shear flow stress, T the absolute temperature, and ? the strain rate, to an analysis of titanium single-crystal data. The activation energy as a function of testing temperaturs obtained from specimens oriented for single (1010) prismatic slip is shown in Fig. 12. This diagram indicates a different linear dependence of H on T in the temperature interval from 220° to 300°K than from 0° to 220°K. Levine interpreted the break in this curve as indicating a change in the thermally activated mechanism controlling the flow stress. The purpose of this communication is to point out that the data in Fig. 1 is not consistent with the concept of a flow stress controlled by a simple thermally activated mechanism between 220° and 300°K. The Conrad-Wiedersich relation assumed that the strain rate can be expressed by:

Jan 1, 1968

By A. T. Miesch, L. B. Riley

An error occurred in the preparation of Fig. 3, p. 249, of Basic Statistical Measures Used in Geo-chemical Investigations of Colorado Plateau Uranium Deposits. This figure shows the relation of the arithmetic mean: geometric mean ratio to the geometric deviation. Curves for the cases where n, the number of samples, is 100, 10, and 5 are too high with respect to the ordinate. The error is negligible at low geometric deviations, but becomes increasingly greater wi,th higher values of geometric deviation. Arithmetric mean values in Table I1 are not effected by the errors in Fig. 3. The authors will endeavor to supply copies of the revised curves on request; write to: A. T. Miesch, Geologist, Branch of Radioactive Materials, U.S. Geological Survey, Bldg. 25, Federal Center, Denver 25, Colo.

Jan 1, 1962

By Arthur Knapp

THE economics of fuel oil must be considered in two aspects; viz., fuel oil as one of a number of competitive fuels and fuel oil as a refined product of petroleum. "Fuel Oil" is usually defined as that product of petroleum which is used in furnaces for the generation of heat by simple combustion. It is true that any product of petroleum used in an internal combustion engine is essentially a fuel oil, but such oils are not included in the class known as "Fuel Oil." FUEL OIL AS ONE OF SEVERAL FUELS For a number of years, the petroleum industry has believed that the petroleum reserves were very limited and that petroleum products would begin to become scarce within a few years. The industry has believed FIG. 1.-DAILY AVERAGE CONSUMPTION OF FUELS BY PUBLIC UTILITY POWER PLANTS. that there would be a gradual but continual rise in prices as a result of this impending scarcity.

Jan 1, 1928

THERE are two general classes of problems in connection with electric furnaces. First, those relating to the best utilization of the electrical power inside the furnace; second, those connected with the bringing of the electrical power to the point where it is to be utilized. Referring particularly to the latter class of problems, many calculations have been made, covering a wide variety of furnaces, to check the electrical capacity and power factor found from test. The following analysis, made for the purpose of determining the maximum capacity and approximate performance of a new furnace, to operate at 160 volts on a 60-cycle circuit, may be of interest. The first characteristic necessary to determine is the inductance, since this is the factor that limits the amount of power which can be put into the furnace. Inductance is calculated from the dimensions of the furnace, according to formulas of the U. S. Bureau of Standards,1 as

Jan 10, 1918

By J. F. Kemp

PAGE Introduction,............170 I. The Competence oF the Igneous Rocks to Supply the Materi als oF Veins,...........171 The Demonstrated Presence of the Metals in the Igneous Rocks,. . 171 The Presence of the Metals in the Sedimentary and Metamorphic Rocks, 173 Conclusions,...........175 The Abundance in Igneous Racks of Vapors or Dissociated Gases which will Yield Water on Emission and Cooling,. 175 The Sequence of Eruptions,. .. . 1 . • .. 78 The Sequence of Vein-Formations,.......1 79 Contact-Metamorphism,.........180 Pegmatites,............181 Frequency of Pneumatolitic Minerals in Veins,.. 183 Surface-Flows of Igneous Rock Unfavorable to Vein-Formation,. . 183

Jan 1, 1902

By Edward B. Durham

At the Richmond mecting in February, 1901, I presented for discussion the proposed rail-specifications of Committee No. 1 of the American Section of the International Association for Testing Materials, with a review of their work, and other matters relating to the heat-treatment and chemical composition of steel (Trans., xxxi., 455). In order to bring out the views of our members on the important points referred to, I offered for discussion the following questions and comments (trans., xxxi., 972): " 1. The advantages to be gained by using more metal in the flanges and web of the heavier sections of rails.

Jan 1, 1903

By William R. Webster

At the Richmond mecting in February, 1901, I presented for discussion the proposed rail-specifications of Committee No. 1 of the American Section of the International Association for Testing Materials, with a review of their work, and other matters relating to the heat-treatment and chemical composition of steel (Trans., xxxi., 455). In order to bring out the views of our members on the important points referred to, I offered for discussion the following questions and comments (trans., xxxi., 972): " 1. The advantages to be gained by using more metal in the flanges and web of the heavier sections of rails.

Jan 1, 1903

By Charles M. Brinckerhoff

When I first went to Arizona in 1925, mining was primarily an underground job. Ajo, Sacramento Hill in Bisbee and Jerome were the only open pit operations in the state. Thousands of men, however, were employed in underground mining at Morenci, Miami, Inspiration, Globe, Ray, Bisbee, and Superior. The grade of ore in the larger operations was about 1-1/2% copper while a few of the smaller ones mined ore better than 2% Cu. In Utah, the Bingham pit was doing well and growing; in Montana, the vein mines of Butte still yielded ore running 6% Cu.

Jan 3, 1972

By A. M. Gaudin

THE large increase in the use of selective flotation as contrasted with the collective flotation of a few years ago has focussed attention on the desirability of achieving accurate control of the pH of mill circuits. Although it is well-known that alkaline circuits result in dropping pyrite and that acid circuits conversely float it, but drop the gangue, there is little that is known, beyond question, ass to the action of the acidity or alkalinity of the circuits. A complete answer is not available at present but experiments -are now in progress at the University of Utah, whose aim is to find out what the effect is on recovery of a change in hydrogen-ion concentration and how this change is brought about. Broadly speaking, a change in hydrogen-ion concen¬tration seems to affect either the mineral surface, as was suggested by A. W. Fahrenwald in his paper "Surface Reactions in Flotation"1 (TRANS. 70, 647) or the attachment of the collecting agent on the mineral surface.

Jan 1, 1929

By E. Ryba, D. J. Michel

SAMPLES of REZn2 (RE = rare earth) intermetallic compounds prepared by a variety of techniques have been shown to exhibit an extensively twinned micro-structure.1-4 We have recently conducted compression tests at room temperature on specimens of HoZn2 prepared by a powder metallurgy technique.' The microstructures of specimens before and after testing are shown in Fig. 1. The "before" specimen, Fig. l(a), shows the basic twin structure of this material. Fig. l(b) shows the microstructure of the "after" specimen just below the fracture surface and reveals considerable cross-twinning as well as additional

Jan 1, 1970

Engineering Experiment Station, Ohio State University, Columbus, Ohio For publications, send requests and remittances to The University Press, Ohio State University, Columbus, Ohio. A few of the Bulletins of the Engineering Experiment Station will be of direct interest to mining engineers and geologists Bulletin 29, Coal losses in Ohio (1925), 25 cents, 33, A plan of a cooperative sliding scale of wages as applied to bituminous coal mining (1926), 10 cents, 46, The carbonization of Ohio coals (1928), $1; 63, Ohio coal investigation- pt 1, Hocking Valley coal (1931), 50 cents; 67, The Lawrence clay of Lawrence County (1932), 50 cents

Jan 1, 1933

By E. Northcott, F. N. Oberg

High-grade concentrates from Florida pebble phosphate deposits have long been recovered by wet methods. When work was begun in the field, only the coarse pebble (generally +1 mm) was recovered. In the 1920's a froth flotation process was developed to separate quartz from the finer phosphate fractions, but this method proved unsatisfactory for treating the intermediate fraction (-1 mm +35 mesh). Consequently various other processes were adapted, including agglomerate tabling and spiral separation of reagentized feed. Today the three processes are used-washing and screening for coarse pebble, tabling or spiraling for intermediate sizes, and flotation for -35 mesh material.

Jan 10, 1958

By N. A. Parlee, A. E. Lord

Measurements of the solubility of lead in liquid iron were made at 1550°, 1600°, 1650°, and 1700°C using two different methods, i.e., 1) liquid iron-liquid lead equilibration and 2) liquid iron-lead vapor equilibration. LEAD was long considered insoluble in liquid iron1. Today steels containing 0.15 to 0.35 pct Pb are used. One laboratory has found a solubility of about 0.5 pet in the 1600°C range. Recently Miller and Elliott2 gave 0.60 pct as the result of one determillation at 1540°C. Because these findings resulted from the

Jan 1, 1961

By N. A. D. Parlee, M. T. Utine

ThE kinetics of absorption of oxygen by induction-stirred liquid silver (at constant Po2 and T) has received some study here.''2 This paper describes a study of the kinetics of effusion (non-bubble-forming), and some additional work on absorption. A Sieverts type of apparatus was used. The kind of reaction tube assembly has been described.4 The same 25-kw, 450-kc induction unit was used as in earlier absorption work1'2 but the "coupling" was different. The runs were made under the following conditions: i) saturation at 1 atm, effusion at 0.81 atm;

Jan 1, 1969

By R. Haynes

ON the basis of compositional changes of a phase observed in a eutectoid Cu-Al alloy1 it has been suggested that mechanisms for the decomposition of the ß phase proposed by earlier workers2-5 were incorrect. These data are reinterpreted in conjunction with lattice parameter data obtained on an alloy containing 12.2 pet Al, whose isothermal transformations have been reported elsewhere.5 The a Lattice Parameters of a 12.2 Pet A1-Cu Alloy—~iffraction patterns of completely transformed specimens were obtained in a back reflection camera using copper Ka radiation. Lattice parameters of

Jan 1, 1959

By W. F. Hosford, E. W. Kelley

By testing polycrystalline specimens from textured plates which had Previously been used to provide materials for growing single crystals, it has been possible to relate the plastic anisotropy of textured materials to the deformation behavior of single crystals. The deformation studies have been conducted at room temperature on textured polycrystalline magnesium and binary Mg-Th and Mg-Li alloys. Variously oriented specimens of the textured materials were deformed in plane-strain compression and in uniaxial tension and compression. The stress-strain curves are similar in their general jorm of anisotropy and stress levels to those obtained on single crystals of the same alloys. The degree of anisotropy is lower, however, in the polycrystalline materials and correlates with the intensity of the basal texture. Yield loci for the textured materials appear reasonable in terms of the deformation mechanisms, and deviate sharply from the form predicted by the Hill analysis for aniso-tropic material. A N earlier study1 of single crystals has shown that magnesium and magnesium alloys with thorium and with lithium deform at room temperature primarily by basal slip, {10i2) twinning, and (1011) banding. The (10i1) banding mode is a combination of {10ll) twinning followed by (1012) twinning and basal slip within the doubly twinned material.2, 3 Magnesium with lithium can also deform by {1010)(1210) prism slip.1'4'5 Still other deformation modes have been reported for magnesium6-11 but these are considered to play a minor role in room-temperature deformation. In a polycrystalline material, plastic deformation must occur in the individual grains through the operation of one or more of the various deformation modes. Because the critical shear stress for basal slip is very low compared to the activation stresses for the other deformation modes,' basal slip accounts for much of the deformation in the polycrystalline aggregate. However, since there are only two mutually independent basal slip systems, and because five independent systems must be active for an arbitrary shape change in any material,'' modes other than basal slip must account for some of the strain. The deformation of textured magnesium, like that of other hcp metals, must be controlled by the same mechanisms observed in single crystals. In strongly textured material, the form of the anisotropy should be similar to that of single crystals, and the degree of anisotropy should depend on the intensity of the texture. EXPERIMENTAL PROCEDURE The anisotropy of deformation was investigated through the use of plane-strain compression tests, as well as uniaxial tension and compression tests. Materials. Test specimens were cut from the three textured plates of magnesium which had previously been used to provide material for single crystals.' These plates, furnished by Dow Chemical Co., had been reduced about 80 pct during the process of being hot-rolled to their final 1/4-in. thicknesses. The plates had the three respective compositions, pure magnesium, Mg-0.5 wt pct Th (0.49 pct Th by spectro-graphic analysis), and Mg-4 wt pct Li (3.84 pct Li by chemical analysis). Impurities other than iron were less than 0.0005 pct Al, 0.01 pct Ca, 0.001 pct Cu, 0.0006 pct Mn, 0.001 pct Ni, 0.003 pct Pb, 0.001 pct Si, 0.001 pct Sn, and 0.01 pct Zn. Iron was 0.001 pct in the pure magnesium, 0.002 pct in the Mg-0.5 pct Th, and 0.014 pct in the Mg-4 pct Li. The textures of the three plates were determined by X-ray diffraction utilizing only the reflection technique out to an angle of 50 deg from the sheet normal. The resulting basal pole figures are presented in Figs. 1, 3, and 5. Grain sizes in the plates were ASTM number 4 in the pure magnesium and number 7 in each of the alloys. Plane-Strain Compression Tests. Plane-strain compression specimens approximately $ in. thick by 4 in. wide by $ in. long were prepared for each of the three compositions. These specimens were prepared in a manner similar to that used for the single-crystal specimens of the earlier study.' All polycrystalline specimens were stress-relieved at 500°F for hr as the final step in their preparation for testing. The testing procedure was identical to that used for the single crystals, involving compression in a channel and using 2-mil Teflon film as a lubricant. The specimens were tested in six orientations of interest, these being the six combinations of the rolling, transverse, and thickness directions of the material serving as loading, extension, and constraint directions in the plane-strain compression test. Each of the six orientations was assigned a two-letter identifying code. These are combinations of the letters (thickness direction), R (rolling direction), and T (transverse direction) with the first letter signifying the loading direction and the second letter the extension direction. For example, ZR specimens were compressed in the thickness direction while extension was permitted to operate in the rolling direction of the textured material. To facilitate comparison of the present work with that of the single-crystal study1 the orientations used for single crystals are given in Table I along with the polycrystalline orientations that most nearly correspond. To insure reproducibility, at least three duplicate

Jan 1, 1969