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By A. Haque

"This paper describes an improved formulation of an analytical shear strength model developed by Haque & Kodikara (2012) by incorporating the failure of regular concrete/rock joints subjected to CNS condition. Sokolovskii’s analytical solutions developed for failure stress of slopes have been found to be effective in this regard. The analytical models have been validated for predicting the shear behaviour of concrete/rock joints subjected to various CNS loading conditions. The model has been found to accurately predict the dilation, normal stress and shear stress behaviour for a regular triangular saw-tooth joint up to the peak shear stress. Moreover, the peak shear stresses of concrete-rock joints with asperity angles ranging from 5 to 27.5o compared reasonably well with the available laboratory test results.INTRODUCTIONA new shear strength model for elastic regular triangular concrete/rock joints loaded under Constant Normal Stiffness (CNS) boundary condition has been developed by Haque & Kodikara (2012). The salient feature of this model is its capability of accurately estimating the normal and shear stresses of joints with shear displacements under CNS condition by incorporating the elastic deformation of asperities. However, the shear strength model of Haque & Kodikara (2012) for the elastic asperities cannot be directly employed to predict the peak shear stress of a joint experiencing plasticity under applied loads. Therefore, the model inevitability requires articulation of an appropriate shear failure criterion simulating the boundary conditions of the loaded asperity to predict the peak shear stress and corresponding normal stress and dilation behaviour of concrete/rock joints. Sokolovskii (1960) developed a set of analytical solutions for failure stress of slopes comprising c-??soils, which can be exploited effectively to simulate the failure condition as encountered for loaded regular triangular concrete/rock joints (Seidel & Haberfield, 2002)."

Jan 1, 2015

By R. Harris

The vacuum thermal route for magnesium production today accounts for roughly 80% of the global production of magnesium despite significant investment in the competing electrolytic technologies, This is up from 30% of the global production 10 years ago and is all the more significant because global magnesium production has more than doubled in the same time, A review of the sophisticated anhydrous magnesium chloride production technologies provides some explanation for this sea change in technology usage, However, an examination of the economic factors provides compelling reasons, The present review outlines some of the salient strengths and weaknesses of the competing technologies, It also offers suggestion as to where future R and D and economic effort needs to be vested to improve the sustainability of the world magnesium market in terms of its value and impact.

Jan 1, 2006

By T. -W. Hong, Y. Son, S. -J. Hong, D. Choi

The characteristics of indium-tin-oxide (ITO) nanoparticles recovered from TFT-LCD panel scraps were investigated. The ITO was separated from TFT-LCD panel scraps by dissolving the color filter layer located between the ITO layer and the glass substrate. The solution was filtered to separate the ITO from the color filter component, and the filtered ITO was dissolved in the acid solution. ITO nanoparticles were then precipitated with ammonium hydroxide and organic dispersing agent, followed by heat-treatment at 600 °C. HRTEM, EDX and XRD analyses revealed that the 20 nm sized particle were composed of 90 % In and 10 % Sn, and were well crystallized to in the (222) preferred orientation.

Jan 1, 2014

By S. Spigarelli

The creep response of the AE44 magnesium alloy was studied by means of constant load creep tests carried out at 125 and 150°C, obtaining that at the latter temperature the minimum creep rate observed under an applied stress of 100 MPa was two orders of magnitude lower in the investigated alloy than in AM50. The minimum creep rate dependence on applied stress was described by a conventional power-law, e = Aon , where A was a temperature dependent parameter and n was the stress exponent, resulting in a n value close to 30, i.e. by far larger than those observed in commercial alloys with similar Al content. This large difference in creep response was attributed to the precipitation of rare earths (RE) intermetallic phases distributed in the grain boundary zone in form of an almost continuous network of dispersoids that were observed by means of scanning electron microscopy.

Jan 1, 2006

By C. Zangerl, H. Lechner

"Large scale rock slides in deeply incised Alpine valleys are common hazards that can endanger human life, settlement areas and critical infrastructure such as highways, railways and reservoirs (Bonzanigo et al., 2007). In order to perform reliable forecasts of the behaviour of rock slides influenced by large dam reservoirs the geometry, the kinematics, the deformation behaviour and the hydrogeological situation need to be understood profoundly. Based on generic rock slide models the influence of the rock slide geometry on the stability as well as the impact of the buoyancy forces and water load of the reservoir at the toe of the slope are the main focus of this study. Various assumptions of hydraulic conductivity, groundwater conditions of the rock slide and impoundment depth of the reservoir are analysed using limit equilibrium approaches.Generally, deep seated rock slides are characterised by deformation along one or multiple shear zones where most of the measured total slope displacement localizes. Many large rock slides, especially those observed in foliated, mica-rich crystalline rock masses (e.g. paragneisses, mica schists, phyllites), do not fail suddenly or reach high velocities. Instead, many of them move slowly and reach velocities of centimetres per year or even less. Some show episodic accelerations, sometimes reaching alarming levels, but then subside to non-critical levels again. However, there is a potential that deep-seated rock slides fail rapidly, develop into far-reaching run-out rock flows, and cause catastrophic events. Whereas the role of triggers in promoting phases of acceleration is often understood, the same cannot be said regarding the kinematics and dynamic processes by which the rock slide mass decelerates, re-stabilises or accelerates to a catastrophic degree once the trigger impetus has been removed. Thus key questions of the presented work concern the geotechnical, geometrical and hydrogeological conditions under which a slowly moving rock slide is triggered to accelerate to irreversible, maybe dangerous velocities. The development of the sliding zone is generally influenced by pre-existing discontinuities such as brittle fault zones, shear and tensile fractures, foliation and bedding planes. These geological structures determine the geometry of the sliding zone which can either be rotational or translational. During the gravitationally induced failure process the geometry of the rock slide undergoes a change.Several observed post-failure geometries in metamorphic rocks show a concave topography in the middle to upper part of the rock slide and a typical convex or bulge-like topography at the toe of the slope (Zangerl et al., 2012). Whereas the sliding zone of the upper part of such a rock slide mass is rather steep and planar, the inclination of the sliding zone at the toe can be close to zero and act against the driving forces (Alonso et al., 2010). A shear zone that meets alluvial deposits at the foot of the slope encounters a stabilizing impact on the mechanical behaviour. This buttressing effect of alluvial sediments has a remarkable influence on the slope stability."

Jan 1, 2015

By B. A. Peppley

The current most common method of hydrogen production for fuel cell systems, including SOFC systems, is autothermal reforming. Autothermal reformers have a number of advantages including fast start up and load following and ease of control. However, there are a number of problems inherent with the addition of air into a system connected to the anode feed such as dilution of the fuel with nitrogen and the potential for oxygen to reach the anode chamber directly. Pure steam reforming, which does not involve air addition, provides a richer fuel mixture to the SOFC anode and is inherently safer than autothermal reforming. Although in theory pure steam reforming can be shown to provide these advantages, a number of technical problems need to be overcome before such a system can be practical. In particular, issues such as catalyst degradation due to poisoning and thermal sintering, coking, as well as fuel-steam mixing need to be addressed. Experimental results from a prototype reformer will be presented to illustrate a number of these points. This paper will compare differences in system efficiency, safety and complexity between autothermal/SOFC systems versus a steam reformer/SOFC system. A system simulation will be utilized that is able to account for material and energy balances for a SOFC power generator operating on diesel fuel. The requirements for improved catalysts will be discussed and an analysis of the potential benefits of sulfur tolerance and lower temperature activity will be considered.

Jan 1, 2005

By N. Dahata

B206 aluminum?copper alloy has a potential for wider use in the automotive industry due to its light weight and relatively superior mechanical properties as compared to aluminum-silicon alloys. The possibility of casting this alloy via Lost Foam Casting (LFC) has not been investigated in detail. Therefore, the effects of foam types (T170B standard untreated EPS and T175-brominated EPS), coating types (Styro Shield 5553 and Styro Shield 5554), copper level (4.5 wt % and 5.0 wt %) and titanium levels (0.5 wt % and 0.25 wt %) were related to fillability, microstructure and microporosity. The metal velocity in T175 EPS pattern was higher than that in T170B EPS pattern. For T175 EPS pattern, the total solidification time was 3% higher and the loss of temperature for decomposition of EPS was lower than those in the case of T170B EPS pattern. The grain size, porosity level and maximum pore size were quantified using Light Optical Microscopy (LOM) and image analysis. The casting with T175 EPS pattern showed larger grain size relative to that with T170B EPS pattern. The porosity level and the maximum pore size decreased significantly when the titanium level was increased from 0.05 wt % to 0.25 wt %.

Jan 1, 2007

By A. C. Hatton

Doped SrCoO3.8 was found to be a promising material for use as a cathode component in intermediate temperature SOFCs. In this work, strontium cobaltite ceramics doped with 10 mol% to 90 mol% samarium were synthesized using the glycine nitrate process in order to study the electrical conductivity and thermal expansion at temperatures of up to 800°C. As-synthesized powders were deagglomerated, pressed and sintered at temperatures ranging from 1100-1250°C. The effect of temperature and composition on electrical conductivity and thermal expansion are presented and discussed.

Jan 1, 2005

By A. Valenzuel

Arsenic is a common impurity in copper sulfide concentrates treated pyrometallurgically, which inevitably during the smelting-converting process reports in the final copper product affecting its properties, but also it is a very toxic occupational hazard. Arsenic recovery or disposal from concentrates or arsenic-containing copper smelter dusts have been practiced in the metallurgical industry for many years. It has been recovered principally as arsenic trioxide by roasting or leaching then precipitated. On the other hand, several hydrometallurgical processes have been developed and implemented in smelters to remove it from arsenicbearing dusts and stabilize it prior to disposal in the form of a solid compound, either as calcium arsenate, arsenic sulfide or ferric arsenate. This paper reviews the methods implemented for arsenic recovery worldwide and arsenic disposal in the metallurgical industry.

May 1, 2001

By R. A. L. Drew, C. A. Rodríguez González, Caleym W. F.

This work addresses the need of new refractories for copper converters. Technological improvements and environmental regulations for chromium containing refractories have generated this need. Chemical interactions, mechanism of penetration and the effect of oxygen potential and temperature in the system Cu2S-FeS-SiO2-O2 are presented for two refractories: a burned magnesite chrome brick (typically used by the copper industry) and a chrome-free spinel direct bonded brick. The main difference determined in the refractory performance was the blister copper penetration resistance; burned magnesite chrome brick is penetrated while direct bonded brick is not. These results are very promising since blister copper penetration has been reported as the major cause of refractory wear. The results are explained in terms of refractory porosity and wetting characteristics.

Jan 1, 2004

By R. A. Nemchek

Over the years, concentrator plant design has evolved from a large number of small grinding mills to a small number of large mills. In many cases, all of the tonnage runs through a single mill (typically a large SAG mill), so that the plant’s performance hinges on the productivity of this one machine. Industry specifications attempt to address the critical nature of today’s grinding mills in a manner that is often overly complex, neglects economics, and is not clearly focused on the end user’s goals. This paper surveys current industry practices, and proposes an improved approach to standards writing recognizing that product design, procurement, manufacturing, and quality are all inter-related in contributing to a project’s success. The lessons learned here can be extended to specifications for all types of machinery.

Jan 1, 2012

By Chih-Huey Lin

The Au/?-Al2O3 catalyst prepared by AuCl3 impregnation is subjected to the influence of residual chlorine after an oven drying. A post-impregnation NH4OH treatment was able to eliminate chlorine, and to reduce the cluster size of Au moiety. However, the CO oxidation activity was not increased by this post-impregnation NH4OH treatment. This suggests that certain metal-support interaction (MSI) is the determining factor for the activity of Au catalysts. Thermal treatment under H2, O2 or He was attempted to increase MSI of the prepared catalyst with or without the post-impregnation NH4OH treatment. No significant activity enhancement was found but the TPD analysis suggests that a H2 treatment has a higher chance to induce MSI.

Oct 1, 2003

By S. Xu, A. Ramesh, F El-dabbagh, Z. Fang, A. Sobhy, J. A. Kozinski

Waste remediation is a goal that will be driven forward by economic conditions. As the cost of waste disposal increases, new methods of waste reduction will become economically attractive, and will be implemented. It is difficult to imagine, however, a time when there will be no waste generation. For the foreseeable future, despite effective reduction practices, there will still be hundreds of millions of tons of waste that must be destroyed or controlled to protect the public health and the sanctity of the environment. To remain faithful to environmental covenants, the mineral and metallurgical industries will face these new challenges. This paper discusses novel waste remediation approaches and techniques focusing on hazardous wastes and thermal remediation. Aspects concerning technological and environmental importance are examined. Solutions for neutralization of environmentally hazardous compounds are proposed.

Jan 1, 2004

By R. R. Rogers

Introduction The subject of cathodic protection is not new. In 1824 Sir Humphry Davy, in publishing the results of his investigations for the British navy, pointed out that copper could be protected from sea-water corrosion by connecting it electrically with zinc or iron. Since that time much work has been clone in this field, particularly in the protection of metals from the action of sea water, neutral brines, and treated and untreated waters. Special mention should be made of the successful protection of underground pipe-lines which formerly were badly corroded by the water in the ground. So far, magnesium alloy and zinc anodes have been the most popular. However, fairly recent work has indicated that aluminium anodes will give good service under certain conditions. The principle of cathodic protection has been applied extensively in coating steel articles with zinc and in cladding aluminium alloy sheet with pure aluminium. A valuable discussion of the fundamentals and applications of cathodic protection recently was presented in the Corrosion Handbook. A useful list of references was included in the article.

Jan 1, 1949

By Bert Taylor

"The Mining concessions of Quemont Mining Corporation, Limited, are located at 48°16'N latitude, 79°00'W longitude, in Rouyn township, northwestern Quebec. Six hundred and forty acres in area, they lie directly north of, and contiguous to, the Horne mine of Noranda Mines Limited. The north arm of Osisko Lake covers a large area of the southern part of the property. The orebodies lie below the Jake with one body extending through to the bedrock surface.The property was staked in 1922, and was originally known as the Murray Claims. The group attracted interest from numerous exploration companies because of the proximity of the Noranda orebodies.The United Verde Extension Company, of Arizona, optioned the claims in 1926. They sank a shaft to a depth of 235 feet, at a short distance from the Noranda boundary. From a level established at a depth of 215 feet they completed 3000 feet of exploratory driving from which 6000 feet of diamond drilling was done. Only a small body of siliceous gold ore was found before they dropped their ·option.In 1928, The Mining Corporation of Canada purchased a 90 per cent interest in the property. An operating company, later named Quemont Mining Corporation, was formed. An electrical survey was carried out on a portion of the property, followed by deepening of the shaft to 922 feet. Levels were established at 500 and 900 feet, and 4,800 feet of driving and more than 3000 feet of diamond drilling were carried out from them.Geological knowledge at that time recognized that a major break, the Horne Creek fault, lay not far inside the south boundary. Striking north 80 degrees east, the fault dipped south at 85 degrees. The rock on the north side of the fault was massive rhyolite; to the south, meta-diabase and a little rhyolite. A left-handed movement was indicated by a 600-foot offset on a north striking diabase dyke. The small body of siliceous gold ore, referred to previously, was confined to the 215 level."

Jan 1, 1949

By Katherine (Kate) Bruce

Aurora College ? Yellowknife Campus, in partnership with the Northwest Territories Mine Training Society and industry partners, has developed a 6 ? week program on Underground Mining for delivery in Northern communities. The goal of the program is to inform and connect Northern residents to the career potential at existing and future mining operations throughout the Northwest Territories. The program content includes an introduction to the mine life cycle, basic underground mining methods, the use of technology in training via desktop simulators for underground mining equipment, safety in the workplace, and essential skills training (Ready to Work - North) and assessment. Students completing the short program may then choose to continue into a long (12-week) program to be offered at the Yellowknife Campus. This program expands upon the initial introduction and includes modules on NWT geology, environmental studies, underground mining processes and underground mining equipment operation using the larger enclosed cab simulator for a variety of equipment being used at northern mining operations. Success of both programs will depend upon a variety of factors, many of which are outside of the control of the developers of the training modules. These will be investigated throughout the presentation. Connecting northern employers with northern employees is a major concern. It is hoped that through the development and implementation of a program such as this, that the connection can be made and sustained allowing continued employment for the life of northern mining operations.

May 1, 2008

By Sadan Kelebek, S. O. Fekete, Gerhard W. Heinrich, Peter F. Wells

"For many years, rejection of pyrrhotite at the milling stage has been a viable method for sulphur dioxide abatement. Pyrrhotite rejection options have included the use of selective pyrrhotite depressants in flotation; a depressant which has recently come into use is diethylenetriamine (DETA). This reagent has been the subject of recent research and development efforts in the processing of nickel-copper sulphide ores.In the present study, adsorption trends for DETA have been monitored under the dynamic conditions of flotation using a spectrophotometric method which has been adopted for this purpose at Falconbridge Limited. The results indicate that the adsorption of DETA is quite fast and in the majority of cases, accounts for the disappearance of 75-95 % of this reagent from pulp's liquid phase. The adsorption decreases linearly with an increase in the DET A dosage from 100 git to 600 git. The tailings produced in flotation tests were subjected to washing with deionized water at 60 °C to examine the desorption of DET A. These results indicate that the amount desorbed increases with increasing DETA dosage used during flotation but is less than 7 per cent of that adsorbed. It was found that adsorption of DETA alone, even at relatively high levels, does not always cause depression of pyrrhotite. A new combination of reagents identified in the metallurgical laboratories of Falconbridge Limited utilizes sulphur dioxide with DETA. These reagents together are capable of efficient depression of pyrrhotite on a consistent basis."

Jan 1, 1995

By S. Amira

In the last two decades, many new creep-resistant magnesium alloys have been developed for high temperatures applications. Their mechanical performance and corrosion behaviour were reported for various experimental conditions. However, these conditions often led to uneven comparison basis. In the present study the microstructure, mechanical properties and corrosion performance of four of these newly developed creep-resistant magnesium alloys were systematically compared. Specimens were obtained from experimental box-like components that were die-cast and thixocast in comparable conditions. Their mechanical and corrosion properties were compared using similar testing conditions. Results show that the creep resistance, strength and impact resistance of specimens are comparable but systematically lower compared to specimens cast under optimized conditions. The reduced concentration of elements such as Al, Ca, Sr and Ce lead to a decrease of the corrosion resistance of the magnesium alloys in 3.5% NaCI solution.

Jan 1, 2007

By D. Letzig

Wrought magnesium alloys are of special interest as lightweight structural components as a result of their more homogeneous microstructures and improved mechanical properties compared to cast components. Extrusion as a shaping technology offers the possibility to produce a wide variety of magnesium alloy profiles. In this contribution we describe the role of extrusion parameters such as extrusion speed, ratio and temperature as well as the type of extrusion process on the microstructural development of AZ-series magnesium alloys and the resulting mechanical properties. The effect of microstructure on the tensile/compression deformation behavior of the alloys has also been investigated. Aspects of process optimization designed to overcome technical and economic limitations and thus establish magnesium alloy profiles for industrial applications will also be discussed.

Jan 1, 2006

By C. Hu

A MOS capacitor hydrogen sensor array is reported for hydrogen gas distribution mapping. Si(100) was used as substrate for film deposition. After silicon oxide growing on the silicon surface with dry thermal oxidation, palladium film was sputtered on silicon oxide as hydrogen-sensitive gate material in MOS structure. The 3x3 sensor array was patterned on silicon substrate and packaged in one chip. Sensors' response was test with impedance analyzer. The sensors in array were calibrated in the hydrogen concentration range from 10ppm to 10000ppm. The 2D hydrogen concentration distribution was obtained with the calibrated sensor array.

Jan 1, 2005