Search Documents

By S. P. Holt, Robert S. Sanford

"INTRODUCTION The wartime demand for iron ore and alloy steel on the west coast revived interest in iron reserves in western United States and Alaska. Magnetite was known to have been the most abundant metallic mineral at some of the old copper mines on Prince of Wales Island. In the summer of 1942, the Bureau of Mines began a program of preliminary investigation followed by core-drilling two magnetite deposits on the island.The Poor Man iron deposit on Kasaan Peninsula, Prince of Wales Island, Southeastern Alaska, was examined in August 1942 by Robert L. Thorne, associate mining engineer of the Bureau of Mines, and John C. Reed and B. N. Goddard, geologists of the Federal Geological Survey in September 1942 the area was mapped geologically and a magnetic survey was made by the Geological Survey. In October and November 1942, a more thorough preliminary examination, which included cleaning out and sampling old adits and trenches, was made by thesenior author, Robert L. Thorne, and Aner W. Erickson, engineers of the Bureau. J. G. Shepherd, a consultant of the Bureau, spent two weeks in March and April 1943 investigating the Poor Man and other deposits on Kasaan Peninsula. Core drilling was completed in June 1943.L. A. Warner, of the Geological Survey, examined all cores and interpreted structural data revealed by the drilling."

Oct 1, 1946

By John W. Cole

As part of a general preliminary investigation of lead-zinc deposits in Stevens County, Wash., the Electric Point and Gladstone mines on Gladstone Mountain, in the Northport Mining District, were examined by R. M. Gammell, an engineer of the Bureau of Mines, in June 1946. A trenching and sampling program was executed later the same year under' the supervision of Miro Mihelich and the author. This report presents the factual data obtained from the trenching and sampling operations.

Jan 1, 1949

By L. B. Berger

Each winter brings its toll of deaths and serious accidents from the deadly gas, carbon monoxide. Newspapers carry warnings to the public of the dangers of this gas, and frequent now items retort the finding of persons dead or unconscious from the effects of carbon monoxide, yet these accidents continue. Either those warnings are not read, or they are unheeded by people who feel that "It can't happen to me." It can happen to you - carbon monoxide is no respecter of persons, as evidenced by items appearing daily in newspapers all over the country. Carbon monoxide has been a threat to human safety as long as man has used fire to keep himself warm and to cook his food. The burning of any fuel that contains carbon may produce carbon monoxide. This is true of solid fuels such as coal, coke, and wood; of liquid fuels such as oil, gasoline, and kerosene, and of gaseous fuels such as natural or manufactured gas. In the process of combustion the carbon in the fuel unites the chemically with tat oxygen of the air to form carbon dioxide (CO2), however, if the supply of air is not adequate, combustion is incomplete and carbon monoxide (CO) will be formed.

Jan 1, 1943

By J. A. Ruppert

The Bureau of Mines investigated methods of refining iron-contaminated zinc to marketable quality and developed a laboratory-scale process in which aluminum, added as a refining agent, reacted with the iron, forming solid Fe2Al which floated to the surface of the melt. Solids were separated by both filtration and centrifugation, using a unique type of "dipping" centrifuge devised during the work. Typical zinc recovery was 95 percent, and iron content of the metal was lowered from 0.37 to 0.02 percent.

Jan 1, 1967

By Robert C. Hickman

"INTRODUCTION The Big Four fault and the Sandy Creek fault, with several cross faults, traverse the Stalion-Curnel fluorspar prospect in a northeasterly direction. The Big Four mine, about three-quarters of a mile northeast of the prospect, is the only active mine in the immediate area.A resistivity survey was made of a portion of the prospect by the Division of Geophysical Exploration, Bureau of Mines, in May and June 1946. As a result of this survey, five holes were drilled by the Bureau of Mines during the period from October 8 to December 16, 1946. Two Longyear No. 12 Junior Straitline diamond drills were used for the work.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, does the actual investigative work, and prepares the final report. The Metallurgical Division, Oliver C. Ralston, chief, analyzes samples and makes beneficiation tests.The project was under the supervision of Mitchell H. Kline, chief, Raleigh Branch, Mining Division."

Mar 1, 1948

By Charles Prasky

This report describes fluidized bed techniques employed by the Bureau of Mines at Minneapolis to differentially sulfatize the manganese in two samples of low-grade manganiferous ferruginous carbonate slates from the Cuyuna Range district, Minn. Suitable mechanics of operation were established. A space rate of 1.25 to 1.5 fps, a retention time of 3 to 3.5 hours, a temperature of 700° C, and a 10 percent sulfur dioxide gas in air were adequate for sulfatizing the slates by fluidization. Under these conditions the overflow product removal rate from the 4-inch-diameter reactor was 4 to 5 pounds per hour. The sulfur dioxide was used more efficiently in the two-stage treatment than in the single-stage treatment. However, approximately 80 percent of the manganese was converted to sulfate by either treatment.

Jan 1, 1963

By H. C. Miller

For nearly a score of years the American petroleum industry has faced the problem of maintaining its economic structure while oil -producing potentialities greatly exceeded the increasing market demand for oil and its products . However , the combination of maximum civilian demand with rising defense requirements caused an all - time peak in crudeoil production in the latter half of 1941 , with a daily production (as estimated by the Bureau of Mines ) of 4,139,000 barrels in December - an increase of 16 percent over the daily production of 3,573,000 barrels in December 1940. In the event of a long war , a continuing , steady, and adequate supply of petroleum and its products for military and required civilian needs is essential, and the efficiency of recovery of oil from natural underground reservoirs will have to be maximum. Whereas it may not be possible to increase production in some fields , the output from others may have to be drawn at a much faster rate than formerly . More than 10 years ' experience in operating oil fields under proration control has demonstrated to petroleum engineers that some of the efficiency of recovery of oil from reservoir sands and rocks is sacrificed if the oil and gas are withdrawn at too . rapid a rate . As petroleum is an irreplaceable natural resource for which suitable substitutes probably will not be available in desired quantities for many years , any producing method that jeopardizes the quantity of oil that may be recovered from underground reservoirs must be considered at this time of declared war against aggressor nations as conflicting with the best interests of national defense . At best, the efficient recovery of oil is a complex problem . It involves not only a knowledge and application of the fundamentals of fluid flow through porous mediums, but the sources of energy responsible for the movement of oil and gas through reservoir sands and porous rocks to wells must be known to determine the best practices for extracting these hydrocarbons . Reservoir energy is of two kinds - (1 ) water under hydrostatic head underlying the oil in the extraneous parts of the reservoir system and ( 2 ) natural gas under pressure as "free " gas in the reservoir or in solution in the oil . Inasmuch as the efficiency of oil recovery depends largely on the manner in which reservoir energy is used to move oil through reservoir sands and porous rocks to wells , optimum practices for withdrawing the oil cannot be determined until it has been established that the oil in the reservoirs is being forced to wells by an internal gas expansion, by a natural water drive , or by a combination of gas expansion and water drive . There is a fundamental difference in the performance characteristics of gas - expansion and water - drive reservoirs . In a strictly gas - expansion reservoir the energy available to move oil and gas through the porous formations to wells results solely from gas pressure , which is maximum when the reservoir is tapped by the first well . Pressures decline as oil and gas are withdrawn ; consequently, the energy available for moving oil and gas through the oil - bearing formations to wells decreases with production . Curtailing the oil - production rate or shutting in gas - expansion reservoirs entirely will not act to replenish energy previously used in the production of oil and gas ; in their operation , therefore , it is especially important not to waste reservoir energy - the production of oil with high gas : oil ratios will be reflected in lower ultimate recoveries of oil .

Apr 1, 1942

Consumption and intensity of use trends for 12 metals, by industrial end use, were estimated for 1972 through 1982 by the Bureau of Mines and U.S. Department of Commerce. The trends were then forecast through 1993 using standard statistical methods. The intensity of use measure selected is the quantity of metal consumed per constant dollar output of a specific industrial sector. The metals studied were aluminum, chromium, cobalt, copper, lead, manganese, nickel, the platinum-group metals, tin, titanium, tungsten, and zinc. Average annual growth rates for the following 4 of the 12 metals increased from 1972 to 1982 as follows: aluminum, 1.00%; platinum-group metals (consisting of platinum, palladium, and iridium), 8.83%; titanium, 7.82%; and tungsten, 6.09%. Consumption for the remaining eight metals decreased at average annual rates ranging from 0.58% (copper) to 5.37% (manganese).

Jan 1, 1986

By Karl-Heinz Frohne

This report presents the findings of a study of a portion of the Clover-Rush Run oilfield located in Roane County, W. Va. The study was made to investigate the possibilities of secondary oil recovery in the Big Injun sandstone underlying the William Kaufman lease. Reservoir properties, original reserves, and primary oil recovery are also presented. The investigation is based on a core analysis and related laboratory tests, well records, field production data, and subsurface information from the Kaufman property. A theoretical primary oil recovery of 9.7 percent of original oil in place is predicted for the reservoir. A waterflood performance prediction of a hypothetical pilot area was made by use of a computer. The prediction showed that, based on laboratory oil water relative permeability curves, the water-injection time needed to initiate oil production is excessive and that the stabilized water-injection and corresponding oil-production rates are very low. This precludes waterflooding the reservoir on an economic basis. A prediction for secondary oil recovery by gas injection was attempted but could not be completed because essential reservoir data were not available. In July 1965, the lease operator initiated, and is currently conducting, a gas-injection program, but there had been no increase in oil production up to November 1966.

Jan 1, 1967

By V. E. Erwin, W. W. Adams

"Production of explosives for industrial use in,the United States during 1934 continued the upward trend begun in 1933 from the low-level output of 1932, and the output in 1934 was only slightly less than in 1931.Reports to the United Stated Bureau of Mines from companies engaged in the manufacture of industrial explosives showed that the quantity of explosives manufactured in the United States and sold during 1934 for use within the various States was 314,767,922 pounds - 23 percent more than in 1931.Production during 1934 included 39,207,845 pounds of permissible explosives 5 206,625,027 pounds of high explosives other than permissibles, and,68,935,050 pounds of black blasting powder of which 37,192,700 pounds were in granular form and 31,742,350 pounds in pellet form. These figures represent an increase over 1933 of 15.6 percent for permissible explosives, 30.9 percent for other high explosive, and 7.4 percent for black powder.Coal-mining operations were the chief consumers of permissible explosives; 99 percent of the total output in 1934 was used, in coal mines. The proportion used by bituminous mines was 59 percent and by anthracite mines 40 percent. Coal mining was likewise the principal consumer of black blasting powder, taking 88 percent of the total sales during 1934; of this proportion, bituminous mines received 78 percent and anthracite mines between 9 and 10 percent. Consumers of high explosives other than permissibles were more varied; the reports showed that 11 percent of the total quantity sold was for coal mining, 22 percent for metal mining, 17 percent for quarrying and nonmetallic-mineral mining, 46 percent for railway and other construction work, and 4 percent for all other purposes."

Oct 1, 1935

By Suresh K. Bhatt

A mathematically simulated modeling technique is used in this U.S. Bureau of Mines report to represent a hypothetical mining operation with existing mining technology and prevalent mining costs. Mining scenarios were prepared and evaluated for potential benefits and costs available through computer-assisted mining. Base criteria, parameters, and methodology are described.

Jan 1, 1993

By Willard L. Hunter

The Bureau of Mines studied the effect of temperature upon the reduction of chromite by carbon and the relative reducibility of chromites as a function of their composition. Ferric oxide was also studied to provide comparative data. Pellets weighing approximately 1 gram and containing 70 percent ferric oxide, chromic oxide, or chromite and 30 percent graphite were subjected to closely controlled temperatures under a flow of argon for 15 minutes. The amount of CO and CO2 evolved was measured, and the reduced sample was analyzed by X-ray diffraction techniques. The reduction of Fe2O3 was studied over a temperature range of 600° to 1,400° C, while the reduction of Cr2O5 and chromite was conducted from 9000 to 1,621° C. The temperature above which appreciable reduction of Cr203 by graphite took place was 1,125° C. The temperature at which significant reduction started for three of the four chromite samples was approximately the same, indicating that there was concurrent reduction of iron and chromium oxides in the chromite mineral rather than selective reduction of iron oxides followed by reduction of chromic oxide. Rhodesian chromite appeared to dissociate at a lower temperature with concurrent reduction of iron. Based on the temperature at Which chromite was 50 percent reduced in 15 minutes, Transvaal chromite reduced most easily, followed by Mouat, then by Kampersian, and finally by Rhodesian DFC material. Statistical analysis of test results indicated that the ferric iron content of chromites affects their reduction behavior more than any other constituent.

Jan 1, 1966

By GEORGE S. POPE

The Government of the United States annually expends approximately $8,000,000 for coal. Prior to 1906, this coal was purchased mainly on its reputation, or trade name, rather than under contracts specifying the heating value of the coal, its contents of ash and moisture, and other characteristics. In recent years the Government and other large consumers have appreciated more and more the desirability of definitely determining by chemical analyses and tests the character and quality of coal deliveries. Studies of engineroom and boiler-room efficiencies and economies point forcibly to the necessity of devoting more thought to the improvement of the boiler-room end. This calls for an intimate knowledge of the character and quality of the fuel used. The analyses and tests of delivered coal furnish such data, whereby the power-plant results can be comprehensively studied and a continuous check maintained on the coal and on the conditions of plant operation. Under authority of acts of Congress making appropriations for analyzing and testing fuels belonging to or for the use of the United States Government, a laboratory is maintained at the headquarters of the Bureau of Mines, 'Washington, D. C., where samples representing deliveries of coal purchased for Government use are analyzed and tested. The Bureau of Mines has been active in promoting the purchase of coal by the Government under specifications,a that is, by contracts that make definite requirements regarding the heating value of the coal expressed in British thermal units, and the composition as shown by proximate analysis. Under many of these specification contracts the bidders guarantee the quality of the coal offered, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled and analyzed to determine whether the coal is of the quality guaranteed by the contractor, and if it is not, the price to be paid is decreased in proportion; but if the coal is of higher quality, the price is proportionately increased. The analyses of coals or the guaranties offered by the bidders may in some cases be used for determining the award of a contract, but if the coals offered are of widely different characteristics, it may be difficult to determine which would prove the cheapest fuel, without having their relative evaporative efficiencies. Hence, it may be necessary to conduct evaporative tests under service conditions in order to determine which coal is particularly adapted for successful and economical use in the plant. But once a particular coal is selected, regardless of the procedure of determining the award of a contract, then the greatest advantage of the specification method is realized, in that it guarantees to the purchaser coal of uniform character and quality, thereby insuring the best results in the plant. The cost of purchases, under such specifications, of fueL for the use of the Government now aggregates approximately $4,100,000 per annum, and the cost of additional fuel for which samples are taken and submitted to the Bureau of Mines for analysis in order to determine the character and quality of the coal furnished aggregates some $3,000,000 per annum more. In fact, information is now obtained regarding the quality of fuel purchased on almost all contracts large enough to warrant sampling and analysis and heatingvalue tests. It may be said that the purchase of coal under specification is still in the stage of evolution and development, and that experience and time will be required to develop fully standard specifications and methods of sampling and analysis that may be used universally. The success of the specification method for the purchase of coal and the reliability of analysis now rests almost entirely on sampling.a Improper sampling leads to controversies, with resulting condemnation of the specification method in general and the value of laboratory analyses and tests in particular. A number of bulletins b have been published showing the results of the purchase of coal by the Government under specifications. This bulletin is a compilation of the results of coal analyses by the Government, including those made in the fiscal years 1908-1910, which have been previously published, and later analyses representing coals analyzed during the fiscal years 1911-1915. The preceding bulletins gave individual analyses or average monthly analyses, whereas this bulletin gives the average analyses only for the entire contract. It is hoped that this compilation of a series of comparable analyses of the coals purchased by the Government will be of value alike to coal dealers, to Government engineers, to purchasing agents, and to all users of coal.

Jan 1, 1916

By G. R. Hopkins

[A new record in fuel efficiency at petroleum refineries was established in 1939, when a the average e B.t.u. requirements per barrel of crude oil processed declined to a new low of 557,000 B.t.u. (see fig, 1).]

Jan 1, 1941

By G. L. Neumann

"INTRODUCTION Mining in this area is inactive. The entire region is now comprised of small farms. Because approximately 1,500,000 tons of magnetite ore had been shipped from this area between 1855 and 1915, it was deemed probable that geophysical surveying and core drilling might indicate other ore bodies or sizable extensions of the previously mined ore bodies.ACKNOWLEDGEMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has, as its primary objective, the most effective utilization of our mineral resources, thus fortifying our national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual investigative work and prepares the final report. The Metallurgical Branch, Oliver C. Ralston, chief, analyzes samples and performs beneficiatien tests.The chemical analyses and beneficiation tests included in this report were performed at the Eastern Experiment Station of the Bureau of Mines at College Park, Md., under the general supervision of J. B. Zadra, chief, College Park Division, Metallurgical Branch, and the immediate direction of Dr. Alton Gabriel, head of the laboratory service unit.The Mineral exploration Was under the general supervision successively of G. D. Jermain, district engineer, C. B. White, district engineer, and McHenry Mosier, chief, College Park Division, Mining Branch.The geophysical section of the exploration was performed by G. B. Botsford, engineer of the Bureau of Mines. Assistance was given by the Division of Geophysical Exploration of the Bureau of Mines, Dr. F. W. Leo, chief."

Dec 1, 1947

By G. L. Cook

The design of a dual-inlet system for a Consolidated model 21-103C mass spectrometer is described in detail. The system permits both high-mass and low-mass samples to be run by using a single instrument. The difficulties of using a single instrument for both purposes are given and a method of minimizing these difficulties through the use of the present design is discussed, After examining the experience of five years of use, the conclusions are that the bimodal operation is practical and the low-mass analyses had nearly the same precision as before the modifications to the instrument were made. In 1951, O'Neal and Wier.5/ published the first description of the modifications made to a mass spectrometer so that the spectra of hydrocarbons with molecular weights up to 600 could be obtained. Further discussion of the equipment of O'Neal appeared in 1953.6/ Also, Brown, Melpolder, and Young7/ described a parallel inlet system designed to reduce sorption effects at room temperature.

Jan 1, 1960

By H. H. Schrenk

There is a need for a method of determining benzene vapor in air which is simple and accurate and suitable for making industrial hygiene surveys. The most widely used method in this country is the Smyth modification of the Elliott and Dalton procedure. This depends on the nitration of the benzene to m-dinitrobenzene, reduction to phenylenediamine with an excess of standard titanous chloride solution, and back titration with a standard ferric ammonium sulphate solution. This method has the disadvantages of being somewhat time-consuming and cumbersome; it requires considerable apparatus, and a special modification is necessary in the presence of toluene. Recently Cook and Ficklen have published a method based on the oxidation of benzene with hydrogen peroxide in the presence of iron salts. This method requires the use of solid carbon dioxide to freeze out the benzene. The reaction Which produces the color is complex; and only approximate quantitative estimations can be made, except in a very narrow range.

Jan 1, 1935

By Harry H. Ku

In December 1975, a report entitled "An Evaluation of the Accuracy of the Coal Mine Dust Sampling Program Administered by the Department of Interior" [1] was prepared by the Analytical Chemistry Division of the National Bureau of Standards (NBS), in response to a request by Senator Harrison A. Williams. Chairman, Committee on Labor and Public Welfare. The report attempted to evaluate the adequacy of (1) the personal sampler unit used to measure the coal dust concentration in the mines, (2) the procedures used by the Department of Interior (DOI) to analyze the dust samples obtained from mine operators, and (3) any recent studies made by the Department or private industry concerning the coal dust sampling equipment. Recommendations in the report of NBS included continued research efforts by the appropriate organization to correct the personal sampler deficiencies and to consider the use of area or stationary samplers as a supplement to the personal samplers. Concurrent with the NBS report cited above, the General Accounting Office (GAO) also issued a report in December, 1975 [2], suggesting that improvements are still needed in coal mine dust sampling programs and procedures relating to penalty assessments and collections. Among recommendations made by GAO, the following paragraph specifically called for actions by the agencies involved:

Jan 1, 1979

By H. H. Schrenk

[There is a need for method of determining: benzene vapor in air which is simple and accurate and suitable for making industrial hygiene surveys. The most widely used method in this country is the modification of the Elliott and Dalton6/ procedure. This depends on the nitration of the benzene to reduction to phenylenediamine with all excesses of standard titanous chloride; solution, and titration with e standard ferric ammonium sulphite solution. This method has the disadvantages of being what time consulting: and cumbersome it requires considerable apparatus, and a special modification is necessary in the presence of toluene.]

Jan 1, 1935

By Leland E. Paulson

This investigation examined the feasibility of altering the inorganic component of North Dakota lignite by ion exchange. Lignite of specific size consist was washed with various ionic solutions and examined for evidence of exchange. Ions of higher valance substituted preferentially at equivalent concentrations. Results indicate that a major portion of the inorganic material associated with lignite is combined in exchangeable form with the organic component. Particle size of the treated coal is a critical factor in determining the rate of exchange. The data indicate that monovalent ions are easily replaced by divalent and trivalent ions, and the presence of ionic material in slurries containing finely divided lignite significantly increases filtration rates.

Jan 1, 1968