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By K. Nuttall, S. Vijayan, A. J. Meinyk, R. D. Singh

For conventional applications, there is limited demand for rare earth elements as well as yttrium and scandium. But the emergence of new high technology applications such as supermagnets, lasers, and superconductors should result in significant demand for some of these elements. This article examines the anticipated applications and demands for rare earth elements over the next decade. It also looks at the implications on the use of available resources. In the context of a growing demand, process methods are reviewed for the recovery of rare earth elements from conventional and unconventional resources. And the article also discusses the challenges facing the mining industry in meeting this opportunity. Reserves and reserve base The rare earths (RE) are a homogeneous group of metallic elements occupying the area from lanthanum to lutetium in group IIIB of the periodic table. Yttrium and scandium are also included with the rare earths because of their chemical similarities and common existence in nature. These 17 elements and their atomic numbers are shown in Table 1. The rare earths are widely distributed in low concentrations throughout the earth's crust (Hedrick, 1985). They occur in many rock formations including basalts, granites, shales, and silicate rocks at concentrations of 10 - 300 ug/g. They also occur in more than 160 discrete minerals. Most of these are rare, but may contain as much as 60% rare earth oxides (REO). More than 95% of the REO occurs in three minerals: monazite and bastnasite for the light rare earths and xenotime for yttrium and the heavy rare earths. Apatite and multiple-oxide minerals, such as euxenite and loparite, are also commercial sources of the lanthanides and yt-trium. Rare earths do not occur in nature in the elemental state. And, except for scandium, they do not occur in minerals as individual compounds. Bastnasite and monazite are the two major minerals used commercially to supply most of the rare earths (Hedrick, 1985). Bastnasite is a key raw material source for the cerium subgroup elements. The largest known bastnasite deposit occurs with iron ore minerals in China. The second largest deposit is situated in California. Typical rock analyses of the fluorocarbonate mineral bastnasite deposit in California show about 15% bastnasite. The REO content of that is about 50%. Monazite is present in beach sands in many parts of the world. This includes India, Brazil, Australia, South Africa, the

Jan 1, 1989

By Donovan F. Symonds

INTRODUCTION The selection of the optimum coal preparation plant flowsheet is a vital part of the development of a new plant or the expansion of an existing facility. Selection of an inappropriate flowsheet or individual equipment items can result in costly production losses, or needless expenditures or redundant or oversized equipment. The accuracy of the flowsheet selection process is, like most decisions, heavily dependent upon the amount, reliability, and quality of the database. A flowsheet which is based on simple borehole information from an area that has experienced little or no previous mining activity must necessarily include significant allowances for uncertainties. However, a plant which is to be built at an existing mine with good information on run-of-mine (ROM) coal quality, as well as bulk washability data and accurate projections of future quality, can be optimized. The following chapter will describe the processes which should be followed to select the most appropriate flowsheet for each unique operation. They include: 1. Examining and adjusting the washability database to reflect the ROM feed. 2. An evaluation of clean coal specifications. 3. Selection of the level of washing required. This includes no washing, if the coal is already at the desired specification, all the way through to complex total washing circuits for metallurgical grade coals. 4. Selection of the appropriate circuit such as dense medium bath vs. Baum jig. The most appropriate circuit is generally determined on the basis of economics. An approach for performing the evaluation will be desired. 5. The steps that need to be followed to develop a balanced plant flowsheet. ADJUSTING WASHABILITY DATA It is not unusual to have as many as 10 to 20 sets of washability information available for a particular mining property. These may be a combination of core and bulk samples or all bulk samples. In the latter case, they may also be face and/or ROM samples. It is necessary to reduce all of this information to a single set of washability data that is representative of the mean feed to the proposed preparation plant. This set is used to compare the clean coal yield and quality characteristics of the various flowsheet options. The term "representative" has some serious negative connotations. It is recognized that ROM coal quality will vary throughout a mine. However, over a period of 250 to 350 days per year, certain trends can be established. If possible, this "representative" sample should be close to the coal quality of the mean daily sample in terms of raw ash and sulfur contents, clean coal yield, and clean coal ash and sulfur content. If possible, this sample should be within the

Jan 1, 1991

By F. L. Kadey

A discussion of fillers would not be complete without allotting adequate time to that unique and different mineral material, diatomaceous silica. Historical references to its use challenge the aesthetic aspect of man's curiosity; whereas modern scientific tools have provided a dimension of measurement that has motivated many of its more recent applications. A brief review of what is already known is in order. The diatom is a unicellular, plant-like, microscopic organism, related to the algae1. Its natural function appears to be that of a food for other marine or lacustrine organisms, The diatom's "claim to fame" from an industrial viewpoint is dependent on the fact that it secretes an opaline siliceous skeleton that must survive, chemically and structurally, the geologic processes that caused its formation in the first place; its subsequent demise, burial, consolidation, and alteration; and finally, its ultimate exploitation by man--in somewhat that order. In addition to its siliceous nature, the skeletal structure of the diatom possesses a variety of shapes, patterns, and sizes that have not only been the intrigue of microscopists for decades, but have served to set diatomite apart as an industrial mineral; and have reserved for it applications that cannot be satisfied by any other material. Its chemical inertness, its intricate structure, and its intrinsic hardness-coupled with fineness and friability-- are generally known and have accounted for its application in a wide range of filtration and filler uses. The increasing use of the electron microscope has considerably expanded our knowledge of heretofore unseen secondary and tertiary structure of submicron dimension in the diatom valve. The development of electro-sensing methods of particle size measurement which seem to supersede sedimentation and microscopic techniques has portrayed size distribution in a more realistic light. Interest in the surface chemistry of these silica structures has further strengthened our understanding for certain uses. Thus, new tools and ideas have made possible the introduction of diatomite into such sophisticated technologies as that of chromatographic supports, its improved utility in paint applications for the control of gloss and sheen, and its usefulness in the entirely new concept of "Dry Acid Concentrates." Each of these applications has been discussed elsewhere before people particularly interested in analytical chemistry, in paint, and in liquid handling, respectively, where the diatom has been a means to an end. The emphasis here, before the mining fraternity, however is on diatomite as a raw material with reference to the uses mentioned above. It is therefore toward an awareness and understanding of diatomite properties pertinent to these newer filler applications that this paper is directed.

Jan 1, 1967

By Mark E. Smith

To allow recovery of gold values from ore which cannot be economically processed by the mill, Pinson Mining Company has developed a run-of-mine heap leaching facility. In order to estimate production scale recovery rates, reagent consumption and percolation problems, a series of pilot scale tests were performed. These tests typically consisted of 3,630 metric tons (mt) (4,000 tons) leach ore at a grade of .94 to 1.56 grams per metric ton (g/mt) (.03 to .05 oz.) Au/Ton. Test heaps were loader stacked to approximately 4.3 meters (14 feet) high. Information from these pilot scale tests was employed in the design and construction of the production scale facility. Parameters such as spray rate, leach cycle, sprinkler placement, and barren solution chemistry were determined by the pilot tests.

Jan 1, 1983

By Robert Turner

Gold and silver processing techniques are some of the oldest in the mining industry. Gold mining of high grade veins and deposits has existed for centuries. However, only with the higher gold prices in recent years and heap leaching techniques have the low grade gold and silver deposits become feasible to mine and process economically. By mining and hauling 3,600,000 tons of ore per year at an average grade of 0.03 ounces/ton gold and 0.385 ounces/ton silver, the Zortman- Landusky operations became profitable in 1982. To maintain profitably, a stripping ratio of less than one ton of waste to one ton of ore, and mine run ore placed on the leach pads which will yield approximately seventy percent go1 d recovery.

Jan 1, 1984

By John H. White

As production of ground limestone increased our Company found it had an enviromental problem with limestone dust from our hammer mills. With the quarry and processing plant situated within 1 klm of a small township of 5000 people dust collection became essential. Regulations under the Clean Air Act 1972 also had to be complied with. Prior to this any demand for lime flour had been met by the use of a small drier and ball mill. Both expensive to operate. Dust emitting from the mills would amount to over 4000 tonnes per year. The cost savings were obvious. We had a better product which was essentially a by-product. Faced with a surplus of a very useful, but difficult product to handle we considered the possibility of disposing of it on the agricultural market.

Jan 1, 1982

By Keith Wallace

Although systematic control of ventilating air currents in underground mines dates back to the Greek and Roman empires, quantified analysis dealing with the cost of providing airflow did not appear until about 1860 when the first fans with acceptable efficiencies became available. Initially, these were introduced to avert methane explosions initiated by shaft bottom furnaces. However, discussions arose on how much coal the steam driven fans consumed in comparison with shaft furnaces in order to produce the sane amount of airflow. Ventilation economics had arrived. In 1981/82 a project was funded by the Department of Energy and carried out at the University of California, Berkeley in order to analyze and compare alternative ventilation designs from the viewpoint of economics and systems efficiency1. This paper highlights some of the results of that study.

Jan 1, 1983

By W. Linwood Haden

Fullers earth has been mined since about 1920 in southwest Georgia and the adjoining area of Florida. In 1935, the mineral was named "attapulgite" after the source of a sample near the town of Attapulgus, Decatur County, Georgia. Mining and processing of the clay was described in a 1930 publication1 at a time when petroleum refiners were the major users. In the years since then, the uses and users of attapulgite have multiplied, and both mining methods and processing methods have been changed to optimize the clay for the new uses. A comprehensive review of the properties and applications of attapulgite 2 has been published. Only a brief review will be given here to explain the properties being sought and to show how these properties are optimized by mining and processing practices.

Jan 1, 1972

By C. S. Boland

The Copper Range Company's mining properties are located in the Upper Penisula of Michigan. (Fig.). Early work indicated the presence of copper ore in a bedded deposit, confined to the base of the Upper Keweenawan Nonesuch shale, and exploitation of this deposit on a portion of the Company's property was undertaken by White Pine Copper Company. Diamond drilling of the White Pine orebody indicated that a major fault pattern terminated the values to the South-west. Further drilling Southwest of the fault zone proved a downward displacement of the ore bearing horizon some 1,500 feet and a lateral displacement of approximately 4,000 feet; and in this area an ore deposit was outlined in a large asymmetrical syncline locally plunging to the South-west. (Figs. 2 and 3)

Jan 1, 1962

By Jr. Gambrell

Support characteristics of in-cycle trusses are analyzed using a photo-elastic model loaded by tightening a truss in the sequence normally used in an underground mine. Stresses in the roof at its center point and at the junction of the roof and rib are examined. Effects of zero tension and unequal tension in the inclined anchor rods are presented. Effects of simulated subsidence on stress in the roof surface and on tension in the separate truss members are examined. Conclusions are drawn relating to (1) the effects of tension in the inclined anchor rods on uplift and compressive stress parallel to the roof surface, (2) the effects of subsidence on stress in the roof surface and, (3) the effects of subsidence on tension in the truss members.

Jan 1, 1989

By A. Dale Wunderlich

Introduction Loss prevention programs have become absolutely necessary at any precious metals producing property. In the past eight years, one security company, specializing in precious metals mine, mill, and refinery security, has been involved in investigations at gold and silver properties that have resulted in 62 criminal convictions. Of those, all but five were employees, former employees, contract employees, or vendors for the company. Several of the cases involved losses of more than $1 million. The largest number of employees prosecuted from one investigation was 17. A recent case resulted in 12 criminal prosecutions and, several years ago, one involved an additional 12 criminal prosecutions. The most serious theft problem facing precious metals mines is employee theft. Is is estimated that 95% of the dollar losses from precious metals thefts can be attributed to employees. This does not mean there is no robbery or burglary exposure. There have been successful robberies, burglaries, and extortion cases. Most mining companies, though, provide better protection against external theft than from internal theft. That is one reason employee theft has reached epidemic proportions. Any product can be stolen No product is immune to theft. Precious metals investigations have involved the theft of high grade ore, dore, bullion, concentrates, precipitates, loaded steel wool, loaded carbon, and sump cleanup. Over a period of several years, this author's security agency has documented the theft of more than 22.5 t (25 st) of load carbon. Most mining companies do not protect the number one adsorption tank or the loaded carbon screens, which frequently leads to losses. Precipitates, electrowinning tank sludge, sump material, and concentrates are usually afforded lit¬tle protection because mine management believes it is too difficult to process. There are custom mills throughout the United States that will process any form of precious metals with no questions asked. This has become a particular problem since the certificate of ownership requirement has been eliminated by most states. Due to the large number of gold mines coming on line, many mine managers are being recruited from base metal mines, where primary security problems involve the theft of tools and company property. These managers do not understand the unique security problems associated with precious metals production. Consequently, they usually forego many security needs in the interest of economy. Unfortunately, numerous cases are on file where mining companies have suffered large losses because their physical security and their security procedures were not adequately addressed when the property was in its planning stages. Properly designed and appropriate equipment The most economical time to plan alarm/closed-circuit televi-

Jan 4, 1988

By Paul L. Russell, Charles O. Hook

While the oil shale resources of the US are becoming increasingly known, few people in this country are aware of the extensive worldwide occurrence of this resource. Two recent international conferences* confirmed the growing worldwide interest in oil shales, both as future and current energy sources. The 1981 conference noted the difficulty in characterizing worldwide oil shale resources because of lack of common terminology in reporting both assay value and resource potential. Assay value is variously reported as: •US gallons per short ton; •Imperial gallons per metric ton; •Liters per metric ton; •Liters per cubic meter; •Weight percent oil; and •Volume percent oil. Oil shale resources are variously reported in barrels, short tons of oil shale, metric tons of oil shale, and cubic meters of shale oil. Worldwide petroleum shortages sparked interest in alternate energy resources including oil shales. While petroleum supplies appear to have stabilized, at least for a while, high costs are affecting the balance of payment index of many countries, resulting in a continued search for local energy resources. Kerogen is the organic constituent of oil shale and may be the most abundant form of hydrocarbon on earth, possibly exceeding coal occurrences and far more abundant than naturally-occurring petroleum resources. Oil shale, by one name or another, is widespread and is known to exist in more than 38 countries (Table 1). Oil shale industries have existed in at least 14 countries at one time or another. Many predated the Drake oil discovery in Pennsylvania in 1859, and most were unable to compete with natural oil; these operations either converted to its use or closed. At the present time shale oil is being produced on a commercial scale only in the USSR and in China. Only very rough estimates of grade and quantity are available for most of the worldwide shale occurrences since only a few deposits have been thoroughly explored. The Green River Formation of Colorado, Utah, and Wyoming is an exception. For many years this oil shale deposit has been described as the largest single concentration of hydrocarbon material in the world. With increasing world interest, larger deposits may yet be found. In 1965, the US Geological Survey published an in-place world oil shale estimate. This study, while made some 16 years ago, is still a reasonable order-of-magnitude estimate. Although exploration and evaluation are underway and a few oil shale deposits have been appraised, information on which to evaluate most worldwide oil shale occurrences has improved little since 1965. Table 2 presents an order-ofmagnitude estimate of in-place world oil shale resources. Total US resources and Green River Formation

Jan 1, 1982

By A. P. Massmann

Design for economical operation, minimum operating labor and minimum maintenance for labor and supplies are virtually inseparable. Each consideration has a vital bearing on the other. Let us assume that we have the design complete for the most economical operation with a minimum of operating personnel. This means, in addition, that we have the fewest number of operating units consistent with the product requirements for a team or metallurgical coal which we are called on to produce. The number of units will vary greatly, being influenced by design, washability characteristics, tonnage and degree of quality control necessary by reason of producing a product for metallurgical, steam or domestic use. The units involved most ordinarily for any type coal preparation plant will number as a minimum the following: 1. Hoppering R.O.M. Coal 2. Feeding

Jan 1, 1959

By E. J. Peuraniemi, J. T. Yli-Penttilä, A. Jokilaakso, K. M. Riihilahti

Dust formation and the reaction mechanisms of copper matte particles were investigated in simulated flash-oxidation conditions. The granulated and ground matte consisted of 72% Cu, 4% Fe and 21 % S (by weight). Experiments were conducted by using a laminar flow furnace with a reaction-gas composition ranging from 20% to 75% O2 (by volume) in nitrogen. The particle feeding was carried out by a single-particle method, and samples were quenched after a specified reaction time ([~] 0.05 to 0.4 s) in a cold water film. Experimental temperatures ranged from 800o to 1,300o C. Chemical analysis was used to determine the degree of oxidation, and optical and scanning electron microscopes, combined with energy dispersive analysis, were used for characterization of the reacted particles.

Jan 1, 1999

By Chris Mills

El papel de la separacion gravimétrica en la industria minera es brevemente considerado en perspectiva. Las pruebas e intentos de laboratorio y mineralógicas para el diseñio de los procesos gravimetricos son examinados poniendo especial énfasis en la selección de la tecnologia del proceso. Es tratado y comentado el material disponible en equipos para pequeña escala y trabajo de pruebas-piloto, particularmente en relación a la escalacion y a la adquisición de datos precisos y fiables. El transporte del comportamiento de los datos desde la planta piloto a la planta a escala es igualmente explicado. Son resefiados todos los tipos de equipos a escala total existentes para la separacion gravimétrica, poniendo de relieve las unidades de alta capacidad. Es considerada la disposicion de la planta y la seleccion de 1os equipos auxiliares.

Jan 1, 1982

By J. Duarte Neto, V. M. Torres, A. Viana, G. S. P. Pereira, P. M. Andrade

There are technical and commercial limitations to using high fluorine copper concentrates in industrial copper smelters. The presence of more than 1,000-ppm fluorine affects the sulfuric acid units generally integrated to copper smelters. Price penalties are normally applied to copper concentrates with high fluorine contents. Several process alternatives to resolve this issue were studied at the Companhia Vale do Rio Doce (CVRD) Technology Center, Santa Luzia, Brazil. These alternatives included modifications to conventional sulfuric acid plants so that they can use high fluorine concentrates; removal of fluorine-containing minerals by flotation using depressants; selective leaching of fluorine minerals; and sulfuric acid leaching of the copper concentrates. As a result of this research, a hydro¬metallurgical process to remove fluorine and upgrade copper concentrates was developed by the CVRD.

Jan 1, 1999

By Russell. A. Smith

This paper describes some recent work on the identification and development of new chemical reagents aimed at improving the industrial processing of phosphate ores by froth flotation. In particular, three chemical product families which will be discussed appear to offer enhanced flexibility by: 1) utilizing a small amount of a silica control reagent which can significantly reduce the amount of anionic (carboxylic) collector required for a given P2O5 recovery level; 2) utilizing a new anionic collector family which offers high P2O5 recovery and selectivity versus standard carboxylic collectors; and 3) utilizing another new anionic collector family which has, in some tests, allowed for selective removal of dolomite from apatite. Examples and use characteristics of each of these new chemical ideas will be presented.

Jan 1, 1993

By C. E. Zebula, F. F. Aplan, R. S. Datta

The hydrophobicity of oil shale was found to follow the sequence R-5 > Mahogany >> Eastern. Further, hydrophobicity was found to correlate with the total organic carbon (TOG) content, decreasing with increasing specific gravity of raw oil shale pieces. Differences in hydrophobicity from piece to piece indicate that gravity preconcentration would be much more effective for Western than for Eastern oil shales. Purified kerogen concentrates and low specific gravity fractions (<2.0) of raw Western oil shale samples show critical surface tension of wetting values of [y]c = ~35 mNm -1, and for a kerogen concentrate from an Eastern oil shale [y]c = ~46 mNm-l. This infers that dust from oil shale mining operations can be suppressed by surfactant solutions similar to those used to suppress coal dust.

Jan 1, 1988

By Feng Dingwu, Chen Jin, Sun Zhongyuan, Peng Shiying

The recent development of rare-earth permanent magnets has impacted the field of magnetic separation. The permanent magnets technology led to the advent of various magnetic separators particularly designed for application in mineral processing. In this paper, a new type of rare-earth PHGMS possessing a higher magnetic field strength in the working zone was developed using finite element analysis techniques. The NdFeB permanent magnets used had properties of 38 MGOe stored energy, and magnetic material flux levels exceed 1.2 T, The combination of scientific and engineering design and suitable matrices can offer an effective separation of industrial minerals, such as kaolin, feldspar, etc. Compared with conventional high intensity electromagnetic separators, the equipment can reduce electrical energy over 80% with lower operation and maintenance costs, and less installation space.

Jan 1, 1995

By Hassan El-Shall, Abbas A. Zaman, Brij M. Moudgil

The addition of organic and inorganic dispersants to aqueous suspensions of heterogeneous particles (kaolin) was found to significantly affect the solubility of metal ions from kaolin particles and stability of the dispersion. In most of the industrial applications of kaolin, highly concentrated slurries of controlled stability and fluidity are required. The solubility of kaolin particles in terms of aluminum and silicon ions and its effect on the stability of the slurry was investigated. The main objectives of this study were (1) to study the effect of the extracted metals on the properties and performance of the slurry, (2) to understand the reaction mechanism of dissolution of metals from kaolin, and (3) to understand the interaction mechanism of dispersants with kaolin particles. The controlling variables were dispersant dosage, slurry pH, solids loading, and aging.

Jan 1, 2003