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By M. Nduna

Surface properties of metal sulphides have a great significance in various areas of engineering and science, such as acid mine drainage, contaminant sorption, and metal separation. In various attempts at producing metal sulphide particles from synthetic solutions, prodigious quantities of nuclei that grow only to colloidal dimensions have been frequently reported. This copious nucleation is promoted by the high levels of supersaturation that characterize most precipitation reactions. Colloidal particle formation in precipi¬tation-based separation processes results in sub-optimal solid-liquid separation, which is alleviated by the production of more highly crystalline particles or agglomerates. The current work approaches this challenge from an electrochemistry perspective, by measuring surface charge potential of precipitant particles during metal sulphide precipitation with respect to the concentration of metal sulphide lattice ions in solution. Electrophoresis was used to measure the metal sulphide particle zeta potential and the settling properties were obtained by performing settleability measurements using an Imhoff settling cone. A suspension of copper sulphide particles was precipitated from synthetic solutions of copper and sulphide ions at equimolar concentrations. Immediately after precipitation the copper sulphide particles had a zeta potential of -50 mV and a settleability of about 7 ml.l-1. With the addition of copper ions the settleability increased by a factor of nearly three times and the zeta potential also increased to a maximum of -40 mV. A decrease in zeta potential to a minimum of -60 mV was observed after the addition of sulphide ions and this was associated with a settleability of 0 ml.l-1.

Jan 1, 2013

By Giuliana A. Zelada-Tumialan

Reduced workability and flowability of the concrete through the tremie tubes and drilled shaft reinforcement have been identified as the main causes of tremie-concrete drilled shaft concrete defects. This paper discusses two recent case studies of defective tremie-concrete drilled shafts. The defects (soft inclusions, aggregate segregation, and low concrete strength) were primarily caused by the combined effects of the tremie placing sequence, rapid concrete slump loss, and poor passing and blocking characteristics of the approved concrete mix design. The level of detail contained in the drilled shaft specifications varied between projects. However, even when the specifications incorporated several of the more recent recommendations for tremie-concrete placement, the case studies showed that typical provisions for concrete mix proportioning and placement can be further improved to minimize construction defects such as those described in this paper. Based on the findings of the case studies presented, recommendations for the development of more effective specifications are provided. The recommendations include requirements for mock-up testing of proposed concrete mix designs and evaluation of the tremie-concrete placement sequence. Performance of such testing and evaluation would greatly reduce the potential for drilled shaft defects and consequent time and financial burdens associated with them.

Jan 1, 2009

By Gunhild Hennum, Tewodros Tefera, Gisle Håland, Annette Jahr

"Abstract The Gudrun field is located west of Stavanger in the North Sea at water depth of 109 m. A jacket substructure was selected to support the topside and was installed in 2011. The jacket shall be able to support 16 of 0.762 m (30 in) diameter conductors and is equipped with a drilling deck to allow for pre-drilling by a jack-up rig through the jacket. In general the soil conditions below mudline comprise of a thin top layer of very loose to dense sand overlaying several layers of sandy clay, ranging in stiffness from firm to hard. Below some 30 m depth the soil consists of layers of medium dense to dense silty sand overlaying very hard sandy clay containing thick beds of sand to 100 m depth or more below mudline. The jacket is secured to the seabed by twelve 2.438 m (96 in) diameter steel pipe piles, three at each pile cluster located at the four legs of the jacket at sea floor. Different design methods were used to determine the pile penetration depth. Pile drivability was evaluated using best estimate and upper bound soil parameters. The pile driving and blow count record show that the target penetration was reached as predicted. This paper discusses the different methods used to determine the pile capacity, target penetration depth and the drivability analyses made for the Gudrun jacket piles. The soil resistance during pile driving is back-calculated from the pile installation data and compared with the prediction made.IntroductionThe Gudrun platform is located west of Stavanger in the North Sea at water depth of 109 m. A jacket substructure was selected for the Gudrun platform. The general Gudrun platform jacket configuration is to a large extent dictated by the topside layout, the requirements for support points enclosing the well slots and access for the jack-up rig. The Gudrun platform jacket is a traditional 4 legged structure with a vertical side towards the jack-up rig. At the seabed the jacket is quadratic with a base dimension of 40 by 40 metres. Figure 1 shows the Gudrun jacket during load-out from the fabrication yard to the transport barge. At the site the jacket was lifted off the barge, upended and placed on the seabed by the installation vessel. The jacket is secured to the seabed by twelve 96"" (2.438 m) diameter steel pipe piles, three at each pile cluster located at the four legs of the jacket at sea floor. The target penetration of the piles is 47 m."

Jan 1, 2014

This paper provides a review of the chemical reactions occurring in the submerged arc processing of chromite ores. The excavations of industrial furnaces have shown that the charge, as it descends through the furnace, passes through a number of distinct reaction zones. Each zone is characterised by differing process conditions and reaction products. The phase equilibria, reaction steps and mechanisms occurring as the charge progresses through the furnace are examined, and the potential influences of these factors on the process outcomes are discussed.

Jan 1, 2004

By Nam-Il Um

Bottom ash contains several ferrous materials (ferrous metals, Fe3O4, Fe2O3, FeS, etc.). In particular, ferrous metals contain heavy metal because Ni and Cr are chemically attracted to iron. Likewise, Cu is used to coat Ni and Cr metals as polish or to prevent corrosion. In this study, an Fe3O4-Fe2O3 double layer (similar to pure Fe) was found to have been formed in ferrous metal during air-annealing in an incinerator (1000°C). A strong thermal shock such as one that occurs during the water-cooling of bottom ash results in the breakdown of this oxidation layer, facilitating the degradation of ferrous metals and formation of corrosion products. Therefore, Fe-ion (heavy metal) oxides may be formed on ferrous metals and may be separated from bottom ash via magnetic separation. This study sought to investigate the separation ratio of heavy metals as magnetic separation and mineralogical formation of Fe-ion (heavy metal).

Jan 1, 2006

By K H. Esbensen, K Engström

The conclusion from the debate over the last decade in the mining sector is that, for grade control, reverse circulation (RC) drill sampling gives more reliable results due to less sampling problems than blasthole samples. However, by conducting the latter with well-controlled procedures there still exist fair possibilities to counteract the major blasthole sampling problems and achieve fit-for-purpose representativeness, especially if based on minimal loss of fines. In the present PhD study, extensive replicate experiments and variographic characterisations are conducted to evaluate the performance of manual blasthole (BH) sampling and sectorial segment sampling. The experiments were performed in Luossavaara-Kiirunavaara AB (LKAB)’s Leveäniemi open pit mine in the north of Sweden. The experimental area is an apatite-magnetite iron ore deposit of the Kiruna type, with the demand to exhibit a maximum of local heterogeneity to allow the experiment the largest possible conclusion powers. Gathering and splitting the complete BH drill cutting cones (fines cone, coarse cone) served as an authoritative reference on which to assess the representativity of the two BH sampling methods.Results show that manual BH drill sampling is able to produce samples with an acceptable accuracy and precision if performed properly and with insight. Based on variographic comparison, segment sampling shows similar precision for chemical grades as the manual sampling, while the particle size distributions were more deviating for segment sampling than for manual sampling at the high and low size ranges. Possible reasons for these partly surprising results are discussed.For further investigation of the performance of BH versus RC drill sampling, a second experiment has been planned on a parallel profile. This will result in an unprecedented opportunity for a full variographic comparison between RC and BH sampling, aimed at designing specific, fit-for-purpose sampling procedures as a function of ore quality, cut-off grades and important contaminant levels.CITATION:Engström, K and Esbensen, K H, 2017. Blasthole sampling (replicate and variographic experiments) in LKAB open pit iron ore mines – fit-for-purpose representativity?, Australia, in Proceedings Eighth World Conference on Sampling and Blending , pp 85–96 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By David Bendersky

This report covers a technical and economic investigation of old electrical power systems, equipment and practices being used in the metal/non-metal raining industry. The principal sources of information were the MSHA District offices, visits to representa¬tive mines and mills, equipment manufacturers and the literature. A list of 85 mines and mills, submitted by the MSHA Districts as candidates for this study, is given and their characteristics are analysed. The electrical power systems and practices at the 10 mines and 9 mills which were visited are described. The principal areas which do not conform to standard electrical practices are discussed with emphasis on the safety aspects of these practices. The costs to update electrical power systems and practices in metal/non-metal mines and mills are given. The principal findings of the study are summarized and recommendations are submitted.

Jan 1, 1980

By S. Y. Tan

As continual complementary metal?oxide?semiconductor (CMOS) scaling requirements, metal gate/high-k dielectric/Si gate stacks are expected to replace poly-Si/SiO2/Si gate stacks in the future CMOS sub-45 nm technology node. Hafnium based oxide is a promising candidate to replace SiO2 as a gate dielectric, due to its much higher dielectric constant (high-k) and stability. The key challenges of successfully adopting the high-k dielectric/Si gate stack into advanced CMOS technology mostly come from the interfacial properties. The origins of the electrical and physical characteristics of the dielectric oxide/bulk interface were studied in detail. The leakage current density-voltage (J-V) and capacitance-voltage (C-V) measurement techniques were employed to study the dielectric oxide/Si interface. The effects of the post-deposition annealing (PDA) treatment on the interface charges of dielectric oxides were studied. We found that the PDA can effectively reduce the trapping density and leakage current, and eliminate hysteresis in the C?V curves. Besides, the changes in chemical bonding features at HfO2/Si, HfSiO/Si and HfSiON/Si interfaces due to PDA treatment were evaluated by XPS measurements. The XPS analysis provides a better interpretation of the electrical outcomes. As a result, both HfSiO and HfSiON films have exhibited superior performance in terms of thermal stability and electrical characteristics.

Jan 1, 2010

By R. L. de Beauchamp

A preliminary investigation was made of the extraction of chromium from ferrochromium by low-temperature chlorination in the 3400 to 5250 C range. The objective was to devise a method for separating chromium from iron in high-carbon ferrochromium produced from domestic chromite concentrates. The majority of iron was removed as a volatile chloride; chromium was contained in the residue as a nonvolatile chloride, which was separated from carbon and unattacked ferrochromium by dissolution. A small rotary chlorination apparatus was designed, built, and used for the chlorination tests, and samples of commercial-grade high-and low-carbon ferrochromiums were chlorinated for comparison of chlorination characteristics. Low-temperature chlorination of three types of ferrochromium resulted in the removal of 81.9 to 91.6 percent of the iron content as sublimed FeC13. Recovery of chromium in a leach solution of the reactor product varied from 82.4 to 93.1 percent.

Jan 1, 1968

By V. B. Dale

San Manuel has been a modern prodigy from its inception to its present status as a block-caving operation producing 33,000 tons per day. The deposit was discovered, prospected, and developed with modern techniques, and nearly all planning was done from results of an extensive drilling program through an average overburden of 670 feet. The Federal Government had a prominent part in the discovery and primary development of San Manuel. The first 17 holes were drilled by the Bureau of Mines, and discovery of the large, low-grade, disseminated copper deposit is credited to the Bureau. A loan fund of 94 million was granted through the Reconstruction Finance Corporation to the San Manuel Copper Corp. for development of the deposit and erection of concentrating and smelting facilities. Then, while the mine was still being developed, the Defense Materials Procurement Agency contracted to buy a large amount of copper at a pegged price.

Jan 1, 1962

By G. L. Dollinger, J. P. Kindsvater, J. A. Gibson

DESIGN AND DEVELOPMENT OF A MOBILE MINING MACHINE INTRODUCTION Until recently, developing tunnels in hard rock has been accomplished either by the drill and blast method or by using large tunnel boring machines. Combining the flexibility of drill and blast with the safety, efficiency and productivity of a TBM has been the objective of mining machinery producers for many years. In 1979 The Robbins Company began developing a new type of tunnel boring machine called the Mobile Miner to meet these objectives. The development and testing of the Mobile Miner is the subject of this paper. CURRENT MINE DEVELOPMENT METHODS Both the drill and blast method and the use of a TBM have notable advantages and disadvantages. The drill and blast method, for example, allows much more flexibility, requires less setup time and has a lower initial cost than a TBM; however it requires the use of high explosives and blasting has a disrupting effect on the rock surrounding the development. A TBM, on the other hand, is safer to operate, more efficient, more productive and produces smooth tunnel walls without disturbing the surrounding rock. In longer straight drifts it will easily out distance the drill and blast method. The TBM, however, is limited to boring a circular cross section tunnel which must then be modified if a flat floor is required. It also has a higher initial cost and an extended setup period.

Jan 1, 1985

By R. Switalski, M. Schafer, R. Pintabona, M. Kritzer, B. Lukajic, S. Janosko

Methane gas caused an eight-month shutdown of mining operations at the Mill Creek, Phase 3, Tunnel. The gas-related shutdown occurred as the tunnel was advanced to an approximate distance of 2,700 feet, which constitutes approximately18% of the total tunnel length. The construction of an emergency ventilation shaft, a comprehensive program of de-gassing wells and an expanded gas monitoring system were used to mitigate the gas condition. When complete, this tunnel will be utilized to convey and store combined storm and sanitary sewage collected from a portion of Cleveland, Ohio and ten suburbs. This paper will provide an overview of gas related remedial measures and explain how these measures were integrated into the project to ensure safe tunneling conditions.

Jan 1, 2007

The safety of mining operations is significantly influenced by the in situ stress fields in which the mining excavations are created. From the point of view of planning of mining operations, the in situ stress field is a most important input parameter for valid modelling of excavations. Many in situ stress measurements have been carried out for mining and civil engineering projects in southern Africa over the past 30 to 40 years. A database of in situ stress measurement results and observations has been compiled. This paper presents results extracted from the database which are considered to be of particular interest to mining areas in South Africa. The database will permit the estimation of likely stress conditions in new areas of mining, provide a basis for evaluation of results from future in situ stress measurement programmes, provide a basis for comparison of observed behaviour with expected behaviour, and provide a source of data on which realistic design and layout analyses can be based. The information contained in the database indicates that horizontal to vertical stress ratios in the Carletonville, Klerksdorp and Rustenburg areas are significantly higher than the value of 0,5which is commonly used in mine layout planning.

Jan 1, 1998

By E. K. Stanek

This research study was performed on a case study basis and can be divided into two parallel thrusts: electrical and thermal energy conservation. Energy consumed annually in mining and refining operations represents about 6% of the 80 quadrillion Btu's consumed nationally. In the electrical portion of the study, five areas were addressed: optimal dispatching of on-site generation, high-efficiency motors, conductor selection, power factor correction, and high efficacy lighting. In the case study mine which has a multiple unit on-site generation system, optimally dispatching units can save significant energy. The other four methods are difficult to justify on a retrofit basis due to capital costs. In the thermal portion of the study, a thermodynamic analysis was performed on the reverberatory smelting process possible areas of energy conservation were identified as radiation and convection heat losses from the furnace arch and the dumping of high energy content smelting slag. It has been shown that materials currently available can provide the means of reducing heat loss from the reverberatory furnace. It has also been shown that a significant amount of energy may be recovered from the slag. However, these are both subject to further study and validation.

Jan 1, 1982

By Rainer Kahrger

During the last decade, advances were made in solvent extraction/electrowinning (SX/EW) technologies. Combined with heap leaching, these technologies made it viable to exploit large, low-grade oxide copper deposits. The El Abra Mine is a good example for such a deposit. The deposit is situated in northern Chile at an elevation of about 4,000 m (14,000ft), 70 km (45 miles) north of Calama. Codelco sold 51% of the El Abra to Cyprus Minerals in June 1994, with Codelco retaining the balance. In 1993, Cyprus and the engineer on the project began discussions withinternational companies regarding the materials-handling system requiredfor the project. These early discussions were considered critical for this fast-track project.

Jan 1, 1996

By Adrian Coombs, Paul Magowan, Derek Zoldy

Continued development and intensification are fuelling the urgent need for new trunk infrastructure within The Regional Municipality of York and throughout the Greater Toronto Area. Permitting of these projects is increasingly subject to public scrutiny to severely restrict dewatering through construction technologies and the requirement for a comprehensive and effective Environmental Management Plan. Three current projects: one on the York Durham Sewage System and two in the City of Toronto 1.Conventional Design, Tender, Award: 4,150m (13,600 ft.) 2.7m (9 ft.) finished interior diameter soft ground tunnel for York Region’s YDSS Interceptor Trunk Sewer 2.Negotiated Contract: 3,800m (12,500 ft.) 3.5m diameter (11.5 ft.) rock tunnels for Enwave’s environmentally sustainable and innovative chilled water system in downtown Toronto 3.Conventional Design, Tender, Award: 2,200m (7,200 ft.) 3.3m diameter (10.8 ft.) rock tunnel for reinforcement of Hydro One’s primary hydro feed in the downtown core of Toronto These projects exemplify issues such as: EPB tunnel and sealed shaft technologies Substantial permitting requirements associated with dewatering Mitigation of rock creep Congested downtown rights-of-way Deep shafts and confined working compounds Unique scheduling and cost benefits when Owner, Contractor and Consultant can work together cooperatively.

Jan 1, 2007

By J. H. Zietsman

It has previously been observed that industrial high-titania slags display a compositional invariance, remaining close to stoichio-metric M3O5. The present study focuses on this invariance and the phenomena which may cause it. The invariance was studied using thermochemical calculations and a mechanism is proposed for the observed behaviour. The mechanism suggests that a combination of thermochemical equilibrium and transient slag solidification and melting results in the observed compositional invariance. The proposed mechanism provides new insights and prompts questions about other mechanisms in the smelting process.

Jan 1, 2004

By S. Kelebek, E. Yalcin

"Two composite samples of a gold-bearing ore from North Western Quebec (Barry Township) were tested to assess their grindability, recovery by flotation and Knelson concentrator as well as extraction using cyanidation.Work index values (BWi) for two composites were found to be 10.4 and 11.0 kWh/tonne, respectively. Flotation tests involved feed samples for which the particle size ranged from a P80 value of 205 ?m to 53 ?m, which resulted in gold recoveries of 91.8% to 95.8% (at gold grades of 130 to 140 g/tonne). Cyanidation tests indicated gold extraction levels ranging from 94.2 to 97.5%. Higher, recoveries were obtained at finer grind sizes and higher cyanide strengths. However, the grind size had a bigger impact on gold leaching. Gold grade and recoveries obtained with the Knelson concentrator device were lower than those obtained by flotation. Mass recoveries to concentrate products strongly depended on the fluidization pressure used. High gold recoveries can be obtained generally at low water pressures of 3 to 4 psi. Higher water pressures produced more selectivity at the expense of higher gold losses.It can be concluded that the gold ore samples tested have good characteristics due to moderate levels of energy requirement, high gold recoveries and extraction rates attainable.INTRODUCTIONBench scale testing of ore samples is an important step in the long series of metallurgical and economic studies involved in bringing new ore bodies into production (Coleman, 1980). Through a laboratory testing program, the behaviour of an ore in a particular process on a larger scale can be established. In an exploratory manner, this testing can be helpful for classification of ores in terms of “good ore” or “problematic ore” by providing preliminary information on recoverability of target minerals. Potential problems if any can be assessed by further investigation of products (e.g., middlings) obtained as a result of testing. A detailed bench scale experimental program in the metallurgical laboratory can also provide the background work for flowsheet development. Depending on the simplicity or complexity of the ore to be tested and type of details required from a testing program, the amount of samples required in the mineral processing laboratory can vary from several kg to more than one hundred kg depending on how detailed the metallurgical testing program is."

Jan 1, 2008

By Kevin Connor

During 1986, the Government continued with efforts to ease the country's almost total reliance on coffee exports for trade revenues by allocating 45% of the Government's budget to commerce and industrial projects. The collapse in coffee prices in 1985 continued to exacerbate the country's growing trade deficit, weakened currency, and dwindling reserves of foreign exchange in 1986. Amoco Burundi Petroleum Corp., a subsidiary of Amoco International Oil Co., continued with plans to drill at least two exploration wells in Lake Tanganyika in 1987. Both offshore and onshore drilling exploration was planned by Amoco Burundi. Any oil or gas finds were expected to have substantial impact on the Burundian economy, as a major portion of the country's trade deficit was directly attributable to petroleum and gas imports.

Jan 1, 1988

By J. J. Bouillon

"Located in the northwestern portion of the Abitibi greenstone belt, Les Mines Selbaie is a copper-zinc (silver and gold) producer. Felsic tuffs host three are zones. Composed of sulphide veins and breccias, they are not exhalative massive sulphide deposits, except, probably, for the massive pyrite (fragments and lenses) localized close to the top of the volcanic sequence.The total of all (mineable and mined) ore in the three zones presently outlined on the property, is of the order of 29.9 x 106 tonnes with average grade of 0.63 g/t Au, 37.02 g/t Ag, 1.21% Cu, 1.91% Zn.The ore reserve calculations and the daily production procedures are computerized to various degrees. The data handling process is highly computerized.Various geophysical methods are, and have in the past, been successfully used on the property. The ""mise-à-la-masse"" surveys were used to perform the geological interpretation of an underground deposit (A-2 zone). Presently the PULSE-EM surveys are performed in all surface and underground exploration drill holes."

Jan 1, 1990