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By Alfred E. Pugsley

PAYMASTER CONSOLIDATED MINES, LIMITED, began an investigation into the economy and use of detachable bit drill-steel in June, 1937. This investigation has continued to the present time, and was made necessary by transportation and distribution difficulties that had arisen through the use of standard steel in three widely separated mine areas serviced by a central steel-sharpening shop. Detachable bit drill-steel performance was first studied in the workings of No. 2 mine, where the rock being drilled was composed mainly of porphyry or tourmaline, and where standard drill-steel transportation costs had been excessive. The results obtained in this early work definitely established the economy of detachable bit drill-steel at No. 2 mine. This conclusion was reached when the 're-grind' system of re-sharpening dulled detachable bits was 1n use. Preliminary observations on the performance of detachable bit drill-steel in the quartz-carbonate veins of No. S and No. 6 mines gave encouraging results, and warranted a large-scale investigation under practical mining conditions. All drilling operations were gradually changed over to use of detachable bit drill-steel. This change was completed by February, 1938.

Jan 1, 1939

By G. Morin, G. Marin, M. C. Parr, J. Carignan

"Investment casting offers many advantages for the near net shape production of complex geometries, however, molten titanium reacts with most of the refractories used in investment casting shelling systems, which leads to the formation of an oxygen contaminated surface layer. This layer, called alpha case, is 0.1 to 0.6 millimeters in thickness according to the casting section size and must be removed either by mechanical or chemical milling processes. Alpha case removal processes affect casting tolerances and may contaminate the part intended for medical applications (e.g. embedding of abrasive grit media in the alloy). A shelling system based on an yttria prime slurry has been developed and was found to almost suppress the mold metal reaction. Yttria is an expensive refractory, but slurry life was found acceptable for small castings using a closed container and flow coating process instead of conventional pattern dipping. Alpha case depth has been determined for Ti6Al4V by metallographic techniques and microhardness measurements on different step block casting cross sections. Alumina and yttria second prime stuccos were evaluated in this study. The shelling system minimizes finishing operations in the production of casting for medical applications.INTRODUCTIONTitanium investment castings have been in the commercial market since the beginning of the titanium era in the mid 50’s. Investment casting is a cost effective way to produce complex parts for medical, aerospace and chemical processes applications. Investment casting of titanium is difficult due to the high reactivity of titanium with air and refractories used for shell mold building especially for the face coat. Melting is done under vacuum and no shelling system has been proven effective to suppress the mold-metal reaction yet. The main issue with the mold-metal reaction is the formation of an oxygen enriched zone at the surface of the castings named alpha case (Frueh et al., 1997; Kim, 2002; Saha, 1986). The alpha case is brittle, reduce the fatigue life in service of the parts and must be removed by chemical milling.For industrial purposes, calcia partially stabilized zirconia based slurries have become widely used in titanium investment casting for primary coats due to a combination of limited metal shell reaction. Calcia stabilized zirconia slurries have an acceptable shelf life and offer an interesting production window. Our experience shows that a resulting alpha case depth is 280 micrometers for a casting section of 6.35 mm in thickness is typical with such a shelling system (Morin, 2013)."

Jan 1, 2016

By Xuanxue Mo, Kaihui Yang, Steven D. Scott

Abstract -The Changning-Menglian metallogenic belt in western Yunnan, China, is characterized by the occurrences of both Pb-Zn-Cu and Cu massive sulfides in Permo-Carboniferous mafic volcanic sequences. These deposits were formed in a back-arc basin at a rifted continental margin in the Paleozoic Tethys Ocean. Pb-Zn-Cu deposits are associated with alkalic basalt, andesite, and lesser felsic volcanic rocks intercalated with limestone, which probably formed along an immature rifting segment on a continental basement. These volcanic rocks are enriched in K, Ti, LREE, and other incompatible elements, and have the attributes of alkalic within-plate basalt. An extensive unit of sulfide- carbonate-silica shale in proximity to massive sulfides contains high values of Mn, As, Mo, W, Sn, Sb, and Hg, and has REE patterns that are similar to the volcanic rocks. This, together with the graded bedding in the footwall volcanic rocks, suggests that the sulfides precipitated in a shallow, unstable, and carbonate-saturated volcanic basin. A stringer zone is traced downward for 500 m below the massive sulfide orebodies. It is characterized by an upper sericite-quartz zone and an extensive lower skarn alteration with enhanced W, Sn, and Bi. Lead isotope data show both continental basement and magmatic sources may have supplied the ore metals. Cu deposit and occurrences are hosted by tholeiitic units that represent the mature spreading segments in the back-arc basin. The tholeiitic lavas have LREE-depleted or flat REE patterns similar to MORB or back-arc mafic lavas. The cupriferous massive sulfides are overlain by an extensive unit of chlorite-magnetite or ochre, suggesting a relatively oxygenated oceanic basin. Ni and less Co mineralization is found in dolomite veins of the stringer zone. Enhanced concentrations of Ni, Co, Au, and As are found in the massive sulfides and in sulfide-rich tuffites. The geological setting and mineralization of the Changning-Menglian belt has similarities with modern back-arc basins such as the Manus Basin in the western Pacific.

Jan 1, 1999

By N. Ogbonna, D. G. Dixon

Although heap bioleaching has been recognized as an economic alternative for treating low grade mineral ores, the underlying physical, chemical and biological processes involved are complex. A detailed investigation into the dynamics of heap bioleaching processes has provided much insight into the underlying complexities, and has led to the development of a sophisticated modelling tool - HeapSim. This tool can be of great help in the design and operation of heap bioleaching processes. In this paper, the mathematical model implemented in HeapSim is examined. The model takes into account mineral kinetics, particle level effects, bacterial growth, oxidation and adsorption, gas absorption, pore diffusion, bulk advection, gas balance and heat conservation. Three case studies where the model has been applied are briefly discussed. Computational Analysis in Hydrometallurgy 35th Annual Hydrometallurgy Meeting held in conjunction with the 44th Annual Conference of Metallurgists of CIM Calgary, Alberta, Canada Edited by

Jan 1, 2005

By C. J. Edmonds

Of the gold mined in Canada over 90 percent is extracted from the ore by the process of "cyanidation". In this process crushed ore is treated with lime to provide "protective alkalinity" and cyanide, usually in the form of sodium cyanide. The gold is dissolved in the cyanide solution, which after further treatments for clarification, is precipitated by the addition of zinc dust. Wastes from the process consist of tailings which will contain cyanides. Water consumption, mill size, effluent quantity and quality are depicted in transparency (1). It should be noted that as far as the wastes are concerned it has been impossible to postulate a typical situation. Variation from the above data will occur. A summary of data from tailings pond effluents is presented in transparency (2). The figures in parentheses indicate the usual range of values for the parameter.

Jan 1, 1973

By Li. L.

Backfilling has become a popular solution in underground mines around the world. It reduces environmental impact of mining industry and improves ground stability. In most cases, backfill has a high water content so that it can be delivered by pipes from a backfill plant on ground surface to underground stopes. Upon deposition in the stope, the backfill tends to consolidate under its own weight, leading to a generation of excess pore-water pressure. To avoid excessive pressure and protect the backfill barricade installed at the base of the stope, the backfilling of the stopes is usually divided into two stages: plug pour and backfill body pour. The interruption of backfilling operation is undesirable as it slowdowns the mining productivity, and sometimes causes pipe clogging, leading to unexpected increase in manpower cost and further reduction in mining productivity. The backfilling interruption time may be reduced, even eliminated if the drainage of backfilled stopes is sufficiently improved. This paper presents an application of wick drains, a material commonly used in civil engineering, to mine backfilled stopes to help accelerating the drainage. A protocol is proposed for installing the wick drains in a mine stope to be backfilled. Numerical simulations were made, showing that the drainage of the backfill can significantly be improved by the introduction of wick drains. The application of wick drains in mine backfill can thus be considered as a promising technique and merits deeper and more detailed investigation.

Aug 1, 2013

By Carol Odell

This paper was prepared as a brief for Prospectors and Developers Association of Canada (PDAC) to guide input at a series of round tables carried out by the Federal Government in response to the 38th Standing Committee on Foreign Affairs and International Trade (SCFAIT) report, on ?Mining in Developing Countries and Corporate Social Responsibility?. This document mandate is to provide background information, analysis and recommendations on the practice of Canadian exploration and mining companies abroad. This research was based on 11 case studies of Canadian companies which have experienced conflicts or controversies overseas. All case studies were assembled through an extensive literature review of publicly available documentation and communications with representatives of the mining companies to assist in deepening the insights into the drivers of the conflicts and the needs of Canadian companies in similar situations. The case studies include both exploration and mining operations. Our analysis begins with the identification of general and case specific drivers of conflict/controversy in each case study. Company names are kept confidential and only anonymous results are presented. We make ample use of simple flow charts and schematic diagrams to explain how contextual drivers and aggravators and company drivers and mitigators play varied and interrelated roles in conflicts. The diagrams also illustrate the cumulative analysis of drivers including the linkages among drivers/aggravators/mitigators across different domains (social, governance, NGO/media and company). Finally, we discuss needs of companies and propose recommendations for addressing social responsibility and human rights concerns.

May 1, 2007

By S. A. Bradford

The twenty years before World War I was the Golden Age of copper smelting in British Columbia. In this short time, the smelters developed from small, primitive units to large, efficient operations. The first copper claims had been staked on Howe Sound and Knight Inlet in 1864, and there was extensive copper mining in the interior by the mid-1880s, but before 1895, all ore was shipped out of the country for smelting, converting and refining. The first interest in smelter construction was undoubtedly inspired by a Provincial bonus and Dominion land grants offered to smelter builders. The early smelters made use of small blast furnaces which were designed to smelt any kind of ore, but usually far too little ore was available. The first smelter seems to have been the McRae furnace on the Spillimacheen River (1883), followed by Vancouver (1889), Revelstoke (1891), and Golden (1891) (1). They each smelted a few tons of galena and then quickly closed down permanently for lack of ore. Only smelters that actually produced some copper matte are described in the following sections.

Jan 1, 1999

By Alan R. Holt

"This paper provides an overview of the use of uranium and coal in Ontario Hydro's generation program. The dynamics of available supply sources including mining and transportation infrastructures and regional considerations are described. Included is a discussion of needed procurement strategies, both in place and planned, to meet fluctuating fuel requirements while ensuring adequate supply security and cost effectiveness. IntroductionDuring the first half of this century, Ontario Hydro or the Hydro Electric Power Commission of Ontario, as it was then known substantially supplied all of the province's electricity needs from a large number of hydraulic generating stations. Although hydraulic power still provides a very significant part of Ontario energy requirements, this paper will concentrate on the role of uranium and coal in their generation program. To provide a perspective on the importance of these two fuels, Figure I shows the approximate value of each for the past few years in relation to Hydro's total operating costs. The trend toward increasing nuclear output and a corresponding decline in coal use is also clearly illustrated.Figure 2 shows the currently installed capacity of their three main energy sources, hydraulic, nuclear and coal and the 1986 production totals for each, followed by Table I which compares the average operating or running cost on the basis of dollars per megawatt hour for each type of plant. It demonstrates dramatically why Ontario Hydro base load s its hydraulic and nuclear plants, and why coal has become the swing fuel on the system. Although they have a 1200 megawatt plant in Toronto with natural gas-burning capability, and a 2000 megawatt oil-fired station near Kingston, both are presently mothballed and have not been considered in this paper.This paper starts with a user's perspective of the nuclear fuel supply situation which will be discussed in relation to the usual considerations of security, flexibility and cost."

Jan 1, 1988

By Yuki Tsunazawa, Shuji Owada, Sho Fukui, Chiharu Tokoro

"Since the amount of e-waste has been rapidly increasing all over the world, there is a desire to develop the effective recycling process. E-waste has various kinds of electronic components with valuable and/or hazardous materials. Recycling of them is an important subject from the viewpoint of both the recovery of valuable materials and waste treatment. In common with all mineral processing, the comminution of e-waste is a key process because the liberation states after comminution determine the overall efficiency of metal recovery. Since some of useful critical metals are concentrated in a specific component, a special and selective grinding is expected to be effective. However, the knowledge about the mechanism and the effectiveness of the selective grinding is still limited and unclear.To better comprehend the mechanism, in this study, the investigation of comminution process using the particle-based simulation was conducted. Especially, this study focused on the comminution performance of printed circuit boards (PCBs), which are major components of e-waste. The behavior of PCBs and airflow in a drum typed agitation mill having flexible chains was simulated by the discrete element method (DEM) coupled with computational fluid dynamics (CFD). To model the shape of PCBs, the particle based rigid body model was introduced into the DEM. Since this model could not directly simulate the breakage phenomena, collision energy was calculated to qualitatively evaluate the comminution performance. In addition, the simulation results were compared with the experimental comminution tests using simulant PCBs where some capacitors were solder-mounted. These results indicated that comminution performance was affected by the rotation speed of the agitator. It was also demonstrated that the comminution performance was qualitatively evaluated using the particle-based simulation and this particle-based simulation made it possible to investigate the mechanism of e-waste comminution."

Jan 1, 2016

By Victor Maksaev, Marcos Zentilli

"Abstract - The Domeyko Cordillera, the westernmost uplifted crustal block of the composite High Andes of northern Chile (20°S to 28°S) hosts a narrow N-S trending belt of Late Eocene-Oligocene giant porphyry copper deposits, which include Collahuasi, Chuquicamata, El Abra, La Escondida, and El Salvador. These deposits are spatially and genetically associated with the closing igneous activity along this range, prior to a 30 km eastward jump of the magmatic front in response to tectonic plate interaction. The porphyry copper deposits are also spatially associated with a major intraarc strike-slip shear system, the Domeyko Fault System. Although the tectonic uplift of the 3000 m to 5000 m high range has generally been assumed to be mostly Miocene in age, field relationships suggest that the Domeyko Fault System and tectonic uplift were active as early as the Eocene, coinciding with porphyry copper emplacement between 41 Ma and 30 Ma. Apatite fission track (FT) thermochronology provides both age data and a time-temperature history for rocks since they cooled below a temperature of ca. 125°C (equivalent to a depth of 4 km to 5 km under normal geothermal gradients) on their way to the surface during exhumation, or after a heating event. Apatite FT data from the Paleozoic crystalline basement of the Domeyko Cordillera indicate that at least 4 km to 5 km of rocks were eroded during exhumation of this tectonic block between ca. 50 Ma to 30 Ma (Middle Eocene to Early Oligocene), a time that immediately precedes and overlaps with the emplacement of giant porphyry copper deposits. The FT data constrain the age and duration of a period of crustal thickening and extensive erosion known as the Incaic compression, an event recognized in the Andes of Chile and Peru. Assuming that cooling was due to denudation alone, modelling of the FT data allow estimation of denudation rates between 200 and 100 m/My during this period. In contrast, exposures of pre-porphyry Paleocene intrusives on the western edge of the Domeyko Cordillera reveal apatite FT ages that are concordant with biotite 40Ar-39Ar dates, indicating shallow emplacement, fast cooling and negligible exhumation. The apatite FT ages of the Chuquicamata and El Abra porphyry copper deposits are only marginally younger than their 40Ar-39Ar dates, implying fast cooling/exhumation of shallow mineralizing systems (ca. 2 km to 3 km). Their FT time-temperature history is compatible with extremely low rates of exhumation (ca. 50 m/My) since about 30 Ma (Early Oligocene). This limited extent of erosion, due to exceptional aridity, has greatly contributed to the preservation of rich supergene enriched blankets above some of the porphyry copper deposits.A model is proposed, which is consistent with field relationships, geochemical, and geochronological data. High relative velocities and intermediate-angle oblique convergence between the Nazca and South American plates in the Eocene-Early Oligocene led to intra-arc transpression partitioned into reverse faults of opposing vergence and a right-lateral shear system (the Domeyko Shear System) localized along the magmatic front. Crustal shortening and thickening led to uplift within the Domeyko Fault System and to erosion of at least 4 km to 5 km. Crustal thickening deepened the zone of magma generation, and magmas accumulated in the lower crust, allowing small volumes to rise rapidly to shallow levels along transtensional domains of the regional shear system. A similar model of crustal thickening and shortening before and during porphyry copper emplacement in zones of transtension may also apply to the Miocene-Pliocene giant porphyry copper province of central Chile."

Jan 1, 1999

By Jiuhua Xu, Shuiku Jia, Weiren Sun

"The Jinqingding gold deposit, situated in the east Jiaodong Peninsula of Shandong province, is typical of the pyrite-quartz vein gold deposits in the Muping-Rushan gold belt of China. The gold deposit is controlled by a great NNE fracture zone and is composed of several lenticular orebodies within the fracture rone occurring in the Kunyushan granite massif. The Kunyushan granite massif was formed by the replacement of the Archean Jiaodong group.The main minerals associated with gold are pyrite, chalcopyrite, galena and sphalerite; the gangue minerals are dominated by quartz, sericite, microcline and calcite. The mineralizing event can be divided into four stages: (1) pyrite-quartz; (2) quartz-pyrite; (3) siderite-polymetallic sulfides; and (4) calcite-quartz. Gold occurs mainly as native gold and electrurn in stage I and stage II. There are some evident differences between pyrite from major stages of gold mineralization and that from minor stages; these include differences in crystal forms, size and composition of fluid inclusions.Wallrock alterations consist of sericitization, silicification, pyritization and potash-feldspar alteration. Five alteration zones can be distinguished from unaltered granite (zone 0) to vein lodes (zone IV). Au and Ag increase rapidly from zone 0 to rone IV, Cu increases continuously, while Pb and Zn increase slowly. R-type geological factor analysis indicates that the Au, Ag, Cu, Pb and Zn bear a close relationship to wallrock alteration."

Jan 1, 1994

By A. B. Parsons, P. G. Howes

"This article discusses how recent changes in the federal and Quebec .income tax laws have contributed to an improved investment climate for mineral exploration in the Province of Quebec. Individual investors who are resident in Quebec and who are in the highest tax bracket (1984-60.4% marginal rate) may obtain tax benefits that result in only nine cents of each invested dollar being at risk.IntroductionIn a recent submission by the Mining Association of Canada to the Royal Commission on the Economic Union, it was stated that the mining industry ""is no longer discovering and opening new mines at rates sufficient to offset the depletion of existing orebodies and to maintain pre sent output"". With world metal prices still in a depressed state following the prolonged 1981-82 recession, moreover, the continuing success of Canadian mining in world markets will depend on this country's ability to compete in a new environment characterized by subsidized Third World production . For the most part, this new competitive environment will encourage the development of cost-efficient mines that are better equipped to withstand the troughs and valleys of international metals prices."

Jan 1, 1984

By D. Thibault, A. Akhiate, M. Brochu, E. Braud

Cast martensitic stainless steels, 13%Cr-4%Ni, having carbon contents between 0.018 wt% and 0.067 wt% were normalized, air quenched, and tempered at two different temperatures (550°C and 610°C). Their microstructures were characterized by optical microscopy and X-ray diffraction (XRD). Macro and microhardness, tensile strengths, and impact resistance were quantified for each material and condition. Results show that the prior-austenite grain size is constant through the materials but the percentage of reformed austenite, contained in the martensitic matrix, depends strongly on the material chemistry and on the tempering temperature and on its duration. It is observed that, independently of tempering conditions, an increase in carbon content increases the material hardness and tensile strengths, whereas the elongation remains constant. In contrast, the results of Charpy type impact toughness tests show a different trend. The material containing the average carbon content (0.034 wt%) is significantly tougher than the two other alloys. Surprisingly, the toughness of the steel containing 0.034 wt% carbon was found independent of the reformed austenite content. It is thus concluded that carbon and reformed austenite contents are not the only parameters affecting the toughness of these steels.

Jan 1, 2014

By Sarah R. Hindle

Carbon capture and storage has jumped to the forefront of climate change mitigation efforts for its capacity to sequester large amounts of carbon. Mineral carbonation is one prominent option, mimicking and accelerating the natural weathering process of certain silicate minerals. This has the ability to produce stable carbonate minerals that can store carbon on geologic time scales with little to no risk of leakage. Commercialization of this process is ideally suited for integration into the proposed mining operations at the Turnagain Nickel site in Northern BC. This is due to the abundant supply of suitable ultramafic feedstock material, as well as the economic benefit of sharing costs while reducing net emissions and bringing value to otherwise valueless and costly waste rock. While studies have shown this process to be technologically viable on a laboratory scale, assessing the economic and financial viability of such a process on an industrial scale is necessary. An evaluation of the financial feasibility of integrating mineral carbonation into the mining cycle at Turnagain under a proposed cap-and-trade system is presented.

May 1, 2010

By Robert B. Parsons

"In all likelihood, Canada's mining industry would be adversely affected by corporate tax reform proposals actively being considered by the Department of Finance in Ottawa. When the next set of proposals for lax reform is released later this year as promised by Finance, the mining industry had better be prepared 10 take a hard look.IntroductionTwo federal budgets ago, in May 1985, Finance Minister Wilson tabled budget papers that were more massive in terms of volume than most federal budgets. Buried in this mass of documentation is a discussion paper entitled ""The Corporate Income Tax System-A Direction For Change"". When the discussion paper was tabled over one year ago, reaction from the business sector was almost nonexistent. By and large, the paper was regarded as nothing more than one more federal publication of mild academic interest.But, recent events suggest that this discussion paper for corporate tax reform could be the cornerstone for a series of changes to the tax laws which would have more profound and widespread effects for all sectors of the economy than any reform since 1971 . No industry in Canada can afford to ignore the movement afoot in Ottawa for corporate tax reform."

Jan 1, 1986

By Z. Bibak, S. Banisi, A. Ghasemi, E. Nematollahi

"The major importance of liners in grinding is their role in providing an appropriate trajectory for the charge. Since it is not possible to study the charge movement by direct observation in operating industrial mills, this task is accomplished by physical (laboratory), and/or, mathematical (software) methods. Because of the high cost and a longer time required for a physical analysis, mathematical simulations have become more common. Simulation of the effect of liner shape on the charge movement has provided a means to select a proper design based on the operational objectives and conditions. Furthermore, the liner shape changes due to wear and impact during operation, which will influence the charge trajectory. This adds more of an incentive to use simulation. These changes in liner could be predicted through liner profile measurements during operation and/or simulation. In this research, an inhouse developed DEM software called KMPCDEM © was used to simulate the charge movement in industrial plant SAG mills. A geometrical method of implementing the shell liners on SAG mills at the Sarcheshmeh (9.75×4.87 m) and the Gole-E-Ghohar (9×2.05 m) operations facilitated the software simulation. Point by point implementation of the measurements of liner profiles of these mills enabled the study to trend the change in the charge movement as the liners wear. Comparison of the simulation to a laboratory mill (1 m diameter) showed that the difference between the measured and predicted charge impact point, shoulder angle and toe angle were 6, 4 and 3°, respectively. INTRODUCTIONComminution is the most energy intensive operation constituting the major portion of operating and capital costs of a mineral processing plant. In the last decade, a vast number of research was aimed at studying various aspects of grinding with the aim of performance improvements (Davis, 1919; Mishra & Rajamani, 1990; kalala, Breetzke, & Moys, 2008). Mill liners transfer the input power to the charge and play a significant role in affecting the motion of the charge (Mclvor, 1983; Mishra & Rajamani, 1990; Radziszewski, 1997; Van Nierop, Glover, Hinde, & Moys, 2001; kalala et al., 2008). Lifters are usually used with mill liners to extend their life and to enhance the grinding and impact breakage efficiency. Mill lifters are used to raise the grinding media and ore to transfer the energy from the mill to the load (Rezaeizadeh, Fooladi, Powell, & Weerasekara, 2010)."

Jan 1, 2016

By Robert B. Parsons

"Investors in flow-through shares are going to need an expanded road map to find their way through a growing maze of tax rules affecting such shares. At the end of 1985, no fewer than three new sets of important tax amendments were tabled which could have a significant effect on flow-through share issues. This proposed legislation is discussed this month in Tax Notes.IntroductionIn a flurry of legislative activity at the end of 1985, the federal government tabled legislation which includes the introduction of new rules which will have a notable effect on investors in flow-through shares and on companies that issue such shares.First, on November 26, 1985, Bill C-84, the legislation to implement most of the changes announced in the May budget, was introduced in Parliament. This legislation includes the rules for the $500,000 capital gains exemption, a matter of considerable interest to flow through share investors.Next, on December 2, 1985, the government tabled a Notice of Ways and Means Motion which would extend the time horizon for spending flow-through share funds to include the 60-day period following the calendar year. But all news was not good news. On December 4 the government released its proposals for a minimum personal income tax, which would include rules that would catch an investor's CEE expenses and capital gains."

Jan 1, 1986

By Ursula M. Franklin

Old iron nails are one of the most common objects which entice the general public to ask questions about the history of metallurgy. There is a lot of history in old nails - history of the manufacturing industry, and social and economic history. Nails, therefore, are fine teaching tools; whether students have to acquire metallurgical skills or explore the structure and properties of wrought iron, whether they want to look into the history of inventions and the development of machinery, studying nails tells a story better than any teacher or any book. I have used this approach often and the following note is based on several student projects, particularly the work of Carmina Herrero and Vicky Marchant. Nails, those essential metallic fasteners, have long been with us. Their size, shape and design is basically a compromise between the makers' ability to control and manipulate material and the demands of the intended application. There were copper and bronze nails in antiquity, but in this paper I want to deal only with iron nails. In Rome, iron nails were common, and Cleere carried out the fine metallographic investigations on a large stock of nails recovered from a Roman fort site in Scotland. Those nails were hand forged; sorting them at the site on the basis of length, shape of head and shape of shank (in cross section) indicated that there seemed to have been some nail standardization. It appears that the Roman smiths used a series of heading dies starting with a 1/s-in. size. Each successive size increased by approximately 1/16-in. The metallographic inspection of the microstructures of the nails showed that the smaller nails were made in the one operation; i.e. both the tapering and the formation were accomplished on the heated rod without reheating. However, in the case of the larger nails, the nail had to be reheated for the tapering after the head had been forged. Most nails were tapered on all four sides of the shank and the shanks were square in cross section; only one group had rounded shanks. Most heads were flat disks, but in one group the heads were pyramids and another group had conic heads. Figure 1 shows the procedure used to produce the pyramidal heads. Obviously, Roman nail making was sophisticated and each nail design was meant for a particular use.

Jan 1, 1999

By Joseph Carlston

With environmental regulations continuing to restrict the discharge of phosphorus from wastewater treatment facilities, traditional methods of phosphorus removal are proving inadequate. To achieve the phosphorus control necessary, a new coagulant used for phosphorus removal, cerium chloride, has been studied in several municipal and industrial wastewater treatment facilities that must meet a phosphorus discharge limit of 0.5 mg/L or lower. These studies demonstrated the high phosphorus removal capabilities of cerium chloride, with the results illustrating the ability for cerium chloride to reduce phosphorus to low concentrations in the effluent using a lower volume of product as compared to traditional coagulants, such as ferric chloride. This reduction is due to the unique ability of cerium chloride to remove phosphorus as cerium phosphate, whereas iron- and aluminum-based coagulants rely on adsorption and co-precipitation.

Jan 1, 2014