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By Leonard A. Wolff

"The 1980sfor the mining industry can be characterized as the survival of the fittest. High interest rates, low commodity prices, foreign subsidized competition and decreasing ore grades have contributed to a streamlining of the domestic mining industry in the United States, leading to the shutdown of operations or large cutback of work forces. The purpose of this paper is to look at the impact of a layoff on the employees of what was once a major uranium producer in south central Wyoming, twenty months after the final layoff and mine shutdown. INTRODUCTIONDecember 19, 1985, was the date of the final of three successive layoffs over a two-month period, leading to the complete shutdown of Petrotomics Company, a subsidiary of Getty Minerals Company. The final shutdown was due to a combination of depressed U3O8 prices and the takeover of Getty Oil Company by Texaco in January 1984.The layoffs affected 104 employees and included mine personnel, mill personnel and staff. Both hourly and salary workers were involved. The operation was considered non-union, however, a few mill hourly employees were unionized. At the completion of the layoffs. only a handful of employees remained for administrative and miscellaneous functions.For Getty employees, the terms of the merger agreement provided a generous level of separation benefits. The terms that were insisted upon by Mr. Petersen, Chairman of the Board for Getty Oil, stipulated that employees receive one month of severance pay, for each full calendar year of employment up to a maximum of two year's pay. This was the forerunner of what is now commonly known as the ""tin parachute”. All but the union employees of Petrotomics received these separation benefits. Union employees were covered by their separate, less generous, contract.Much of the literature that has been published in recent months has centred around the effects of layoffs on remaining employees, or the psychological effects on the severed employee. This study will emphasize the economic impact and ramifications due to a layoff, using the Petrotomics employees as a case example."

Jan 1, 1989

By Malcolm Scobie

"This paper reviews the evolution of Canadian surface and underground mining automation, principally relating to: advances in communications, initial development of machine teleoperation from line-of-sight remote control, and islands of automation. The eventual role of teleroboties and minewide robotic mining remains to be resolved. The progress and approaches adopted have tended to vary within each sector of the mining industry. Recent information technology advances have made possible the Digital Mine; in which information associated with all mining processes, however dispersed, would be integrated with support systems using new communications technology. The Digital Mine will provide the information infrastructure to serve as the foundation for minewide automation. This paper concludes by reviewing the issues likely to govern implementation success, relating to: mining process design, machine design, machine intelligence, and mine planning and control.IntroductionSignificant advances have recently been made in underground hardrock mine communications and teleoperation. Subsequent R&D efforts are mainly focussing on control systems for various types of machines. In underground potash mining, the realization of automated continuous mining systems appears to be imminent. Recent advances in surface mine dispatching, machine monitoring and global positioning systems (GPS) have tended to reactivate some of the initial R&D enthusiasm developed in the '70s for surface mine automation. Mines at large are approaching a major milestone: the implementation of comprehensive communications infrastructure which proves to be sufficiently reliable and economical to support the automation of routine mine production, either using teleoperated or autonomous machines. This then should motivate a deeper commitment to real time monitoring and management. The communications advances make possible the Digital Mine; in which information associated with all mining processes, however dispersed, would be integrated with support systems using information engineering. The Digital Mine will provide the information infrastructure to serve as the likely foundation for a wide range of automation scenarios. This paper surveys the status and directions of automation development in both surface and underground Canadian mines, pointing to what are seen to represent key technology development issues."

Jan 1, 1995

By M. C. Villeneuve, P. A. Siratovich

We present an integrated analysis of laboratory-based thermally induced fracturing and results of numerical models to give insight to the role of thermal shock fracture on geothermal reservoir rocks. Thermal stimulation is a reservoir permeability enhancement technique applied to commercial geothermal reservoir rocks to enhance fluid injection capabilities for spent power plant working fluids. The process is well known to enhance permeability but the thermodynamic and physical constraints of the process are less certain. In an attempt to constrain the interaction and the ideal conditions that lead to permeability enhancement, experimental procedures were carried out to mimic the conditions that a reservoir rock would experience during a thermal stimulation using temperature differentials ranging from 50-300°C. Samples underwent such thermal gradients under controlled laboratory conditions and were characterized for the changes to permeability, porosity, ultrasonic velocities, dynamic elastic moduli and petrological changes. The thermal stimulation was simulated in a FLAC2D thermal numerical model to investigate the nature of the thermally induced changes in the sample. The development of this model also allows us to investigate the relationship between geological characteristics and the ability to thermally stimulate any type of rock. The results indicate that numerical thermal shocking experiments are corroborated by laboratory-based results. The implication of this study is that the refined numerical models present an insight to the conditions and constraints under which thermal stimulation can prove to enhance permeability that could not be gained through purely laboratory-based studies.

Jan 1, 2015

By C. A. Biley

"A dedicated iron removal stage was installed at Anglo American Platinum’s Rustenburg Base Metals Refiners (RBMR) during an expansion project which began execution in 2010. The Pressure Iron Removal (PIR) process aims to precipitate iron from a nickel leach solution under medium temperature (145 °C) oxidative conditions using caustic for neutralisation. Since commissioning, the process has been robust in removing iron from the refinery but has shown significant variability in the residues produced. These residues, which are typically comprised of ferrihydrite, hematite or natrojarosite, have varying iron contents and different physical properties which have implications for their filtration and ultimate removal from the refinery. Since over 95% of nickel plated at RBMR passes through the PIR section, volumetric constraints caused by poor filtration performance directly influence nickel production and stabilisation of this process remains central to the continued ramp-up of the refinery to full nameplate capacity. This paper details the development of the PIR process and the journey from concept to implementation. Recent laboratory and plant scale tests have highlighted the importance of the initial phase formed in the autoclave for the ultimate residue requiring filtration and how the feed acid concentration is a critical control parameter. On this basis, a new caustic dosing philosophy was implemented which improved pH control in the autoclave. Further optimisation of the PIR process is on-going.INTRODUCTIONIn 2010, an expansion of Rustenburg Base Metal Refiners (RBMR) to increase nickel production from 21 to 33 ktpa began execution. The management of iron was pivotal in the ultimate configuration in the new circuit and one of the primary differences from the original circuit was the addition of a dedicated iron removal stage: Pressure Iron Removal (PIR). A significant drive for this new unit operation was to facilitate the separation of iron from other leach residues. Not only did this result in a significant decrease in the amount of leach residue but, without the constraints associated with iron precipitation during leaching, has permitted more aggressive leaching conditions and, correspondingly, greater throughput and efficiencies.However, as with many commercial implementations of even mature technologies, the journey from development to implementation has presented challenges for the continued ramp-up of the refinery to full nameplate capacity. Specifically, since all nickel bearing leach solution must pass through the PIR section prior to the nickel purification and recovery circuit, throughput difficulties in the PIR section can directly impact supply of feed to the nickel tank house. Since commissioning, the PIR autoclave has effectively removed iron from the refinery, but has shown significant variation in the solids phases produced in the autoclave. This variation presents difficulties for the filtration of the discharge slurry and represents a key throughput limitation which periodically impacts production. Additionally, the increasing production rates associated with the ramp-up of the refinery have resulted in a significant increase in the required volumetric throughput through the PIR process. This has placed even greater emphasis on improving the stability of the solid phase produced in the autoclave, ultimately targeting an easily filterable residue with high iron content."

Jan 1, 2016

By L. M. Guayacán-Carrillo, G. Armand, A. Noiret, D. Seyedi, S. Ghabezloo, J. Sulem

"The main purpose of this paper is to analyze the convergence measurements in a drift excavated in the Callovo-Oxfordian claystone. The drift axis is in the direction of the major principal horizontal stress whereas the stress state is quasi-isotropic in the drift’s section. The initial geometry of the drift being circular, the anisotropic character of the deformation is taken into account by assuming that the drift shape evolves in an elliptical shape. The convergence measurement data on six different points around the drift are analyzed to identify the main axes of the deformation ellipse, following the methodology proposed by Vu et al. (2013, Rock Mech Rock Eng, 46, 231-246). Then, using the semi-empirical law proposed by Sulem et al. (1987, Int J Rock Mech Min Sci, 24, 145–154), the convergence evolution is fitted independently for each axis of the ellipse. This method permits to distinguish two effects: the face advance effect and the time-dependent behavior of the ground. The results for the two directions of the ellipse axes show very close values for the parameters describing the time-dependent properties of the ground, the distance of influence of the face, and the extension of the decompressed zone around the gallery. Such model can provide valuable insights for predictions of the convergence evolution in the long-term. INTRODUCTIONDeep disposal of radioactive waste has been studied in France for more than two decades. The French National Radioactive Waste Management Agency (Andra) began in 2000 the construction of an Underground Research Laboratory (URL) with the main goal of demonstrating the feasibility of a geological repository in Callovo-Oxfordian claystone. Several research programs have taken place to improve the knowledge of the rock properties and its response to the excavation progress. The optimization of supports design for long-term behavior is an important point to develop. A network of experimental drifts has been constructed with variations on: excavation method, structure geometry, supports system and orientations with respect to in-situ principal stresses’ directions. In each drift different sections have been instrumented to monitor the convergence evolution and the rock deformation. Continuous monitoring of the excavated zone around the drifts revealed the development of a fractured zone (extensional and shear fractures) induced by the excavation. The extent of this fractured zone depends on both the drift orientation and the in-situ stress field (Armand et al., 2014). Indeed, the fractures distribution has an important influence on the convergence of the drifts."

Jan 1, 2015

By Tamas Kekesi, Gergo Rimaszeki, Tibor Kulcsar

The efficient purification of soldering waste material can be achieved in a single operational step by the electrolytic refining in pure hydrochloric acid - tin-chloride media. The complex formation of the ionic species may offer a beneficial level of natural inhibition. Using the PCR (periodic current reversal) technology, is efficient in affecting the morphology of the cathodic deposit. In order to optimize the process, the investigation of the solution stability and the electrode reactions is essential. The natural tendency of the Sn(II) oxidation and precipitation can be overcome by properly controlling the concentration of the main components and the ratio of Sn(IV)/Sn(II) in the electrolyte solution. Polarization curves were obtained for different concentrations tin and hydrochloric acid. Conclusions referring to the electrode reaction were derived from the overvoltage - current plots. The morphology of the deposit can be correlated with the exchange current density, also determined from the polarization curves. The cathodic current efficiency and the morphology of deposited metal are affected by the distribution of tin species and the principal electrolysis parameters.

Jan 1, 2011

By Jacob Wood, Robert Matusewicz

The Outotec® Ausmelt Top Submerged Lance (TSL) Process has achieved widespread commercial acceptance over the past 40 years for the processing of copper, nickel, lead, tin, zinc and precious metal bearing feeds. The continual development and evolution of the technology during this period has resulted in a more intense smelting process with higher energy efficiency and lower operating costs. More recently, considerable effort has been invested in decarbonisation of the process through improvements such as increased oxygen usage, dry feed injection and use of low-carbon auxiliary fuels. This paper covers a number of these recent advances to the technology and highlights their impacts on energy consumption and CO2 emissions for a range of non-ferrous smelting flowsheets. INTRODUCTION Relentless demand for improvements in the profitability, safety and environmental performance of non-ferrous smelting plants has driven a continual development and evolution of processing technologies in this industry. In response to these demands, a number of bath smelting technologies have emerged over the past 40 years and have been implemented for the treatment of primary and secondary feedstocks. The Outotec® Ausmelt Top Submerged Lance (TSL) Process (henceforth Ausmelt Process) is one such bath smelting technology which has been widely adopted in a large number of greenfield projects and brownfield plant modernisations (Wood & Hughes, 2016). Emissions of CO2 from the production of non-ferrous metals represent approximately 4-5% of global totals (Rankin, 2012), comparable with the almost 10% attributed to iron and steel production. Despite significant improvements in the energy efficiency of modern smelting technologies (Coursol, Mackey, Kapusta & Cardona Valencia, 2015), primarily through increased oxygen usage, further innovation and development is still required to address their reliance on fossil fuels such as coke and coal. Transformation of the non-ferrous smelting industry to low-carbon technologies and process flowsheets is lagging behind the power and transport sectors, which have witnessed significant growth in clean/renewable energy technologies to reduce CO2 emissions and address the issue of anthropogenic climate change (IRENA, 2018; IEA, 2018).

Jan 1, 2019

By S. C. Cohen, A. F. Mikkelsen

"This paper describes the improvements made to the operation of a liquid phase, 300°C, heat transfer system in the paste plant of an aluminum smelter. These improvements were achieved by replacing the original heat transfer fluid, a synthetic aromatic, with a new technology, petroleum-based product. This new fluid, Calflo HTF, provided better thermal stability, with lower toxicity, and improved plant working conditions.The procedures for fluid selection, changeout and performance monitoring are described along with a summary of control analysis over the last three years."

Jan 1, 1993

By D. G. Cerigo, D. M. Bryce, P. H. Jennings

This paper summarizes the results of an experimental and economic study undertaken to evaluate the feasibility of treating an oxidized orebody of about 10 million tons, grading about 0.75 per cent copper, by agitation leaching and by percolation leaching.

Jan 1, 1968

By P. A. Verhey

"This paper describes a series of wear-resistant ceramic materials which have been successfully used in the mineral processing industry in Canada. Applications include use with metallic ores, coal, potash and asbestos, and in other processes where wear degradation is of major concern. The paper will also deal with considerations involving the selection of the different ceramic materials available. It will cover the installation of ceramic materials on support structures under varying process ' conditions, as well as the other physical and chemical factors which have to be taken into account.IntroductionIn the mineral processing industry, large volumes of ores tailings and other materials are handled. The abrasive nature of most of these materials results in extensive wear to both handling and processing equipment.Wear ratios versus cost, production losses due to down time and wear-resistant material suitability for a given application all demand particular attention when viewed against the need for increased efficiencies in existing processes. As a consequence, a very active continuous search for materials with improved wear resistance has been carried out for many years.In this search, starting about 20 years ago, dense ceramic materials were tested and evaluated in certain applications, notably in the iron ore and asbestos operations in Eastern Canada. As a result of substantially better performance both in continuous extended life and ultimate economics realized , wear-resistant ceramic applications developed progressively in many other processing applications, replacing traditionally used materials.In the vast majority of wear-resistant ceramic applications, considerable extended life over previously used materials was established. This invariably was not just a fractional increase but, in most cases , in factors of double, triple and often all the way up to 18 and 20 times the life of alternative materials used previously. In certain applications, extended life could not be measured and appears to be indefinite.Obviously, as a result of such experiences, the progressively wider use of wear-resistant ceramic materials is now an established trend."

Jan 1, 1981

By Technische Universität Braunschweig, K. Saksl, J. Furste, P. Eschenbacher, F. Brunke, D. Wolter, M. Kohnke, C. Siemers, J. Kiese, M. Schlemminger

"In general, titanium alloys combine outstanding mechanical properties with corrosion resistance and biocompatibility and are, therefore, used in many challenging applications. Nevertheless, for special products, well-tailored properties are required which might not be achievable by a specific design so that new or modified alloys are needed. In this overview paper, alloy development strategies performed at the Institute for Materials of the Technische Universitat Braunschweig are discussed at different examples, namely, (1) oxidation-resistant, microstructural-stabilized and cold-workable alloys for exhaust applications, (2) aluminum- and vanadium-free, medium-strength and cold-workable alloys for implants and osteosynthesis applications and (3) free-machining alloys by the addition of particles with low melting points for non-safety critical light-weight constructions to replace heavier steels, e.g. in automotive applications. A special focus is set on the alloy development techniques and the analyses carried out to achieve well-balanced properties by the optimization of the alloy compositions. INTRODUCTIONTitanium belongs to the allotropic metals and can therefore exist in two different equilibrium lattice modifications. Pure titanium crystallizes at 1668°C in a body centered cubic (bcc) structure called ?- titanium which at 882°C transforms to a hexagonal close packed structure (hcp), the a-titanium. A martensitic ?-to-a-transformation is possible at large cooling rates. This thermally induced hexagonal martensite is called the a'-phase. The transformation temperature named ?-transus-temperature (T ?) can be influenced by alloying elements (Peters & Leyens, 2002).For titanium alloy production typical alloying elements are aluminum (Al) and oxygen (O), both a-stabilizers shifting the ?-transus temperature to higher temperatures, whereas tin (Sn) and zirconium (Zr) only show a limited influence on the ?-transus temperature. The ?-stabilizing elements are subdivided into two groups: Niobium (Nb), molybdenum (Mo) and vanadium (V) stabilize the ?-phase between the melting point and room temperature and are therefore called isomorphous -stabilizers. Elements like copper (Cu), iron (Fe) or silicon (Si) also stabilize the ?-phase to lower temperatures but undergo a eutectoid reaction during cooling. ?-titanium then dissociates to a-titanium and an intermetallic compound. Consequently, these elements are called eutectoid ?-stabilizers (Boyer, Welsh & Collings, 1994)."

Jan 1, 2016

By R. Noriega, M. Suazo, V. Murariu

Current AG and SAG mill circuits have continued the trend to larger, fewer mills. These large mills place a significant additional load on the discharge systems and it has become imperative that the designs of these mill discharge systems are evaluated carefully to ensure maximum efficiency and have the capacity to be able to handle the increased mill discharge volumes. The current generation of multiphysics modeling tools allow a detailed analysis of AG and SAG mill discharge performance. The combination of Discrete Element Method modeling and Computational Fluid Dynamics allows the designer to model in detail all aspects of a mill discharge performance. This includes a detailed description of the build-up of solids and slurry in a mill discharge, the recycle of material back into the mill through the grates, the relative wear rates and the occurrence of overloading at the pinch points. These tools allow intelligent decisions to be made regarding the type of discharge arrangement, pan lifter geometry, and discharge cone design, so as to ensure that the discharge is capable of handling the duties required for a specific installation. This paper details the current state of the art in these modeling tools, and provides an overview of some recent applications.

Jan 1, 2012

By Michael L. Free, Shukla. Abhijeet

The short-circuiting tendency of a copper electrowinning cell (EW) based on the roughness of cathode deposits was investigated with varying parameters such as Cu concentration, guar concentration, current density, and temperature. A bench scale EW cell was set up to produce copper under conditions similar to industrial Cu EW. In addition, a statistical analysis and finite element analysis were performed to analyze the deposited thickness, surface roughness and maximum feature height. Interaction data for the cathode deposits suggest that current density and Cu concentration together affect the roughness of deposit more than the combined effect of guar and temperature. Model predictions of roughness were similar to experimental values. The predicted time to short-circuiting was similar to the measured time. This study provides an industrial relevant baseline against which new operating parameters can be compared.

Jan 1, 2014

By K. Sun, S. A. Argyropoulos

The assimilation and the exothermic behavior of Zn-Zr metallic powder compacts into molten aluminum was studied by measuring simultaneously the temperatures inside at the centerline of the compact, at its surface, and inside the molten aluminum bath, as well as the net downward force acting on the compact. In addition, the exothermic behavior of these compacts was also investigated in an argon protected atmosphere. The temperature rise inside the compact increases significantly with the mass ratio of zirconium in the compact and to a lesser degree with the aluminum bath temperature. Experimental results on the recovery of these compacts in molten aluminum will also be presented.

Jan 1, 2008

By Andrew Cormier

"The Early YearsThe Grand Lake coal fields in New Brunswick undoubtedly can claim the distinction of being the first part of North America from which coal was mined and exported. The diaries of the Governor of Massachusetts during the first half of the 17th century clearly establish this fact. There is also a reference in the Massachusetts Colonial Records which indicate that coal exports to New England were carried on as early as 1639.It has generally been believed that Cape Breton mined and exported the first coal; but no account has yet been found to show that this took place earlier than 1676. Both at Grand Lake and Cape Breton the coal was near the surface and removed by hand.When the country passed entirely into British control, Joseph Garrison, a grantee of Maugerville in 1765 moved to Jemseg. While surveying the north side of Grand Lake he discovered outcroppings of coal on the shore of the lake and further inland along the banks of streams. It was he who named Newcastle Creek in reference to Newcastle in England, which was widely known for its coal mines. Joseph Garrison died in 1783, the same year that an influx of United Empire Loyalists increased settlement in Newcastle Creek in the area now known as Minto. Many Loyalists also settled on the shores on both sides of Grand Lake.At a number of points where streams cut channels through the overlying strata, the coal seams were exposed and it was at such outcroppings that the early operations were carried on. A tunnel was driven in the seam from the foot of the bank, affording both an outlet for the coal and natural drainage from the workings. The coal was loaded into boxes and wheeled over wooden tracks to a point on the surface where it could be dumped into wagons and hauled either direct to destination or to where it could be loaded into boats and conveyed via Grand Lake, Jemseg and Saint John river to points of distribution.In the latter part of the 18th century and first years of the 19th century, farmers were undisturbed by mining the coal found on their lands. This was soon to change and resulted in many years of contention between landowners and the Legislative Assembly.New Brunswick became a separate province from Nova Scotia in 1784 and the seat of government moved from Saint John to Fredericton in 1788. The new province had its first priorities; the establishment of counties, the building of roads, and the development of its natural resources. From 1805, records of coal and land development are fairly complete. These records show the increasing interest of the Province in developing the coal fields. This interest resulted in the granting of coal leases to many friends of the government, without any regard for the wishes of the farmers who owned and had occupied the land for many years. The farmers fought back with lawsuits and other forms of dissension but with little success. By the end of the 19th century there were very few farm operators left in the area."

Jan 1, 1992

By J. -M. Bosgiraud, G. Armand, S. Dewonck, L. Richard-Panot

"The Meuse/Haute-Marne Underground Research Laboratory (URL) is located on the eastern boundary of the Paris Basin. The URL started to be built in 2000 (shaft sinking operations) in the framework of ANDRA’s (French national radioactive waste management agency) research program aimed at determining the feasibility of a reversible deep geological disposal of high-level and intermediate-level long-lived radioactive waste (HLW, IL-LLW). Its underground drifts are used to study the Callovo- Oxfordian claystone layer between 420 m and 550 m in depth.The ongoing research program (started in 2006) following the “Technology Readiness Level” (TRL) Scale is more dedicated to technologies improvement and demonstration issue of the different disposal components, even if characterization and monitoring studies are still ongoing.In rock mechanics, at the main level of the URL (located at 490 m), construction and evolution of disposal cells of different size are studied for HLW and IL-LLW packages. A step by step approach, started in 2006, is carried out based on comparison of HM behavior of parallel drifts excavated/supported by different construction methods. These various configurations give insight of the influence of construction method on the EDZ extent and evolution and on the progressive loading of the support, which are key issues to design the Cigéo disposal drifts and excavations.The concept of disposal cells studied for HLW consists in horizontal steel lined micro-tunnels 80 m long and 70 cm in diameter. Several campaigns of tests have been carried out since 2009 in order to demonstrate the feasibility of excavating such micro-tunnels and study their behavior under different conditions (with and without back filling the annular gap between the rock and the casing, watertight or not casing). A full scale demonstrator representative of the benchmark concept has also been excavated, to study its behaviour under thermal loading with heat produced by electrical heaters."

Jan 1, 2015

By Gary M. Bone

The autonomous control of vehicles interacting forcibly with their environment, such as dozers and tractors, is an unsolved and challenging problem. Forces and motions are inherently coupled between the tool and the means of vehicle propulsion. Furthermore, they are often operated within uncertain and unstructured environments, such as those encountered in underground mining. There is a growing industrial interest in the development of robotic vehicles to improve productivity, efficiency and safety in mining and construction. This paper focuses on the modeling and control of autonomous robotic dozing for a material removal operation. A dozing process model has been developed based on observations of both a fullscale dozer and a scaled-down version. The model characterizes the dynamic interactions between the blade position, material accumulation on the blade, material distribution in the environment, and the motions of the dozer. The dozing control objective is to remove the loose material as rapidly as possible by driving forwards at full power while automatically raising/lowering the blade in response to sensor measurements. Two different controllers were developed to meet this objective. The first controller is based on a set of heuristic rules, and the second is an optimal controller based on the dynamic model. An instrumented scaled-down robotic dozer and dozing environment, designed to emulate the full-scale operation, are used to implement the controllers and compare their performances over multiple dozing passes. Experimental results are presented showing that the model-based controller increased the material removal rate by 33% compared to the rule-based controller. Lastly, technologies for full-scale implementation are discussed, followed by proposed future work and conclusions.

Aug 1, 2013

By Chandrakala Kari, Divyang Shah, Lakshmi Kanth Reddy, Kaushik Vakil, Sanjay Sarkar, Bhavin Desai

Gases rich in sulfur dioxide generated as a by-product of smelting and converting operations of copper concentrate contain selenium apart from zinc, lead, copper, cadmium, bismuth, antimony, and arsenic. The gaseous stream is heat exchanged in waste heat boiler, dust collected in electrostatic precipitator followed by cleaning in reverse jet scrubber to remove fumes, halogens and fine dust before passing to DCDA Monsanto catalytic converter to produce commercial grade sulfuric acid. The gas cleaning section of the acid plant uses water to scrub the smelting gases. During scrubbing, precipitated solids, known as sludge, settles at the bottom of the reverse jet scrubber containing 30 to 40 wt% copper and selenium up to 40 wt% selenium. In the existing process, the sludge collected during scrubber cleaning process is directly recycled to the smelter for copper recovery. However, the selenium is expected to again vaporize due to high oxidation potential during smelting and converting, causing accumulation of selenium in sludge. In present investigation, a roasting process has been developed to recover the selenium from acid plant sludge before charging it to smelter for copper recovery. Selenium is associated with copper in acid plant sludge as copper selenide, as determined by X-ray diffraction and electron microscopy. Thermodynamic and thermo-gravimetry study revealed that the copper selenide phase present in the sludge was amenable to oxidation at 600°C forming oxides of copper and selenium (Cu-Se-O). However, the dissociation of selenium from the copper oxide was made possible by sulfatation using sulfur dioxide between 450°C to 600°C, resulting into the formation of CuSO4(s) and SeO2(g). Lab scale experiments were carried out in vertical tubular furnace to determine the optimum roasting conditions with respect to roasting time, temperature and molar ratio of O2:SO2. Using these optimum conditions, selenium up to 90 wt. % in the form of SeO2 vapors could be recovered from the acid plant sludge in a large scale commercial roaster. Roasted sludge free from selenium and containing oxides and sulfates of copper could now be recycled in the smelter for copper recovery. INTRODUCTION There is an increasing demand for minor metals due to their use in innovative technologies. Similarly, the increase in demand for selenium is expected due to disruption in sectors related to renewable energy and photovoltaic battery. Selenium is a chalcogen and a non-metal with black or red crystalline appearance. Selenium is used in the glass industry to decolorize glass and to make red-colored glasses and enamels. It is also used in solar cells and as a photographic toner. Selenium is used as a brasses in stainless steel to improve its machinability. Selenium sulfide is used in anti-dandruff shampoos. In spite of the toxicity of its compounds, selenium is also an essential trace element for humans and animals. Selenium occasionally occurs free in nature, but more often occurs as selenides of iron, lead, silver and copper. There is an urgent need for the development of new methods for selenium recovery from the existing resources. Commercially, selenium is obtained only from anode mud produced during electrolytic refinery of copper.

Jan 1, 2019

By J. P. Aiello

"INTRODUCTIONWhile this paper deals specifically with potential coal use at the Cold Lake Project of Esso Resources Canada Limited, a majority of the technical aspects of coal conversion could apply to any oil field and industrial boilers or stearn generators. In 1962, Imperial Oil Limited's production arm (the forerunner of Esso Resources), began examining methods of extracting bitumen from a 50 m thick layer of oil sand buried 450 m below the surface in the Cold Lake area. Almost two decades of research followed to develop an in situ oil sands recovery technology that made commercial production feasible.A $13 billion mega project that would have produced 22 000 m3/d (141 000 barrels/day) of synthetic crude oil (160 000 bpd of bitumen) was shelved in 1981, and ultimately replaced by a phased development strategy, involving smaller production units, to bring blended bitumen production on stream as markets and prices permit.The first two phases came into production in 1985. There are currently a total of six phases in production with four more in the construction stage. Each phase has 130to 140production wells (initially) and a central plant with water treatment, crude treatment and stearn generating facilities capable of producing 150 m3/d (9500 bpd of raw bitumen). The stearn generation section for each phase consists of three 180millionBtulhour oil fieldsteam generators.In its natural state, the bitumen is too thick to be recovered using conventional oil recovery techniques. At the Cold Lake Project, bitumen is recovered by a method called cyclic stearn stimulation. Water is pumped to the central plant where it is treated and heated to produce high pressure, high temperature steam. During the steam cycle, this steam is transported in insulated pipelines to the wells for injection into the oil sand formation. This cycle lasts from 30 to 50 days, heating the formation and causing the bitumen to flow. Following an initial flowback period, a surface based artificial lift system pumps the heated liquid bitumen, mixed with water and gas, out of the well and back to the central plant. The water and gas are separated from the bitumen, with the gas being used to provide some of the fuel for the stearn generators and the water being treated and recycled. Approximately 5% of the water cannot be recycled and is disposed of by injection into deep formations . The bitumen is blended with a diluent and shipped by pipeline to market."

Jan 1, 1989

By A. C. Gagnon, H. Saroglou

"The focus of this paper is on the analysis of geometrical discontinuity properties for the rock mass located within an open pit mine located in Western Africa. Discontinuity data were collected using various techniques including oriented core logging, borehole televiewer surveys, surface pit wall mapping and photogrammetry. The geological setting was initially studied prior to the data analysis to produce threedimensional ground models of the regional and mine site geology along with block diagrams illustrating predicted fracture patterns. Stereographic and statistical discontinuity data analysis of the geometrical properties of the rock mass was subsequently performed to identify unique structural domains throughout the open pit area. The discontinuity data collected throughout the studied open pit area were primarily discontinuity orientation, frequency and spacing and the investigation focused on the reasons for observed differences between the various data collection techniques. Stereographic analysis was used to assess the preferred geometry of discontinuities filtered by lithology, data collection technique, borehole, discontinuity type and pit wall (footwall or hanging wall). The observed fracture pattern is explained adequately by the geological setting. The need for accurate ground models for the design of open pit slopes is highlighted.INTRODUCTIONThe Tasiast Mine is an open pit operation located in north-western Mauritania, approximately 300 kilometres north of the capital Nouakchott. The Tasiast mine, which is owned and operated by Kinross Gold Corporation (Kinross), began commercial operations in 2008. The Tasiast mine is located in an area characterized by flat desert terrain within the western reaches of the Sahara Desert region. The current mine site includes mill buildings, shop facilities, waste dumps, tailings facilities and two main open pit operations (Piment and West Branch). The West Branch pit is the focus of this paper. The current open pit plan for West Branch indicates a final pit measuring approximately 2.5 km long by 1.4 km wide and 510 m deep."

Jan 1, 2015