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By Michael Zachariah, Art Miller, David Kittelson, Gib Ahlstrand

This report describes an investigation in which we used iron-doped diesel fuel to generate metal-bearing diesel particles and a subsequent analysis of the particles using transmission electron microscopy (TEM) and energy-dispersive spectroscopy (EDS). For this study, DPM was generated by a 1.5-L diesel engine and the fuel was doped with ferrocene to enhance the level of iron in the system. The exhaust particles were collected on TEM grids and analyzed using the Philips CM12 TEM/EDS instrument. Results show that when the iron-to-carbon (soot) ratio (Fe/C) in the engine is low, the exhaust particles have morphologies similar to those for the undoped case, but at a threshold Fe/C value of 0.013 (for this engine), homogeneously nucleated metallic nanoparticles are formed and begin agglomerating. The number and size of these nanoparticles increase with level of doping. Metal-bearing particles that span a wider size range are also formed. Agglomeration of metallic and carbon particles is observed in two distinct modes: attachment of iron primary particles (5–10 nm in diameter) to carbon agglomerates, and coagulation of iron agglomerates (20–200 nm in diameter) with carbon agglomerates. Results of this work imply that as new engine technologies reduce soot levels in the engine and/or levels of trace metals in the fuel are increased, the generation of metallic nanoparticles may ensue, creating a potential health concern. Keywords: Nanoparticles; Particulate emissions; Metallic particles; Metal emissions

Productivity in underground metal and nonmetal mines is contingent upon work methods, mine layout, and ore handling techniques. One of the most important factors impacting productivity is the efficient movement of men, materials and supplies from the surface into and throughout the mine. Various transportation systems such as man-trains, service shafts, rubber-tired diesel equipment, etc. are currently used to transport men and supplies in underground mines. In many underground mines, it is not uncommon for a worker to spend 25% of his eight-hour working day traveling from the surface to his work area and returning to the surface.

Jan 1, 1975

By R. W. Welker

A technique was developed for sampling and analyzing airborne dusts in diesel-operated, underground, metal, and nonmetal mines. Samples were taken using personal respirable samplers, operated as area samplers, and an 11-stage cascade impactor. Real-time particle size distribution and concentration measurements were made with a quartz crystal micro-balance cascade impactor and a portable electrical aerosol analyzer. The materials characterized were minerals (by XRD), elements (by XRF), particle size distribution and concentration (gravimetrically), and organic constituents (by HPLC). The method was used to characterize dusts generated at the chute pulling operations on the main haulage level of an underground tungsten mine. Analysis showed that respirable dust concentration ranged from 0.8 to 2.3 mg/m3. It consisted of silica (3-7%); organic constituents from diesel exhaust (0.11-0.31 mg/m3 equivalent airborne concentration); and mineral dust (39-100%). The remainder was diesel exhaust particles. It was concluded that size selective sampling may be used to estimate the ratio of diesel exhaust to nondiesel dusts in the respirable fraction.

Jan 1, 1982

By B. J. Moore

This publication contains analyses and related source data for 675 natural gas samples from wells and pipelines in 24 States and 5 foreign countries. The samples obtained and analyzed during calendar year 1980 are included in tables 1-4. Those samples included in tables 5-7 were collected during the years 1960 through 1979. However, permission to publish the analyses of those samples was not given until the past year when the operators were again contacted to seek release of the information. All of these samples were collected as a part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4862 and 576. The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the general public. Twenty-two previous publications have presented the results of 12,152 gas analyses made prior to 1980. The first three, Bulletins 486,' 576,5 and 617,6 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1980. The other

Jan 1, 1981

By E. P. Ferrero

Analyses of 38 crude oil samples from 25 fields in Algeria, Libya, and Nigeria are presented in this report. The 38 crude oils are listed alphabetically by country and field. Also shown are the geographic and geologic sources of the samples analyzed, the companies that supplied the samples, the general characteristics and analytical and computed data, and the production for the fields from which the samples were obtained.

Jan 1, 1966

By William N. Patterson

Drive systems for mining machines are usually sized to accommodate anticipated peak loads. Usually, the average power requirements are considerably less. Energy storage and power averaging are attractive concepts for mining machinery and could have far-reaching implications. The purpose of this program was to: ? Identify truly feasible concepts, ? Identify advantages/disadvantages, limitations, and constraints, ? Evaluate feasibility based on today?s technology, ? Identify anticipated safety problems, and ? Provide the designer with a comprehensive literature base. Concepts evaluated include flywheels, high energy batteries, gas charged accumulators, inductive storage, capacitive storage, springs and counterweights, thermal, closed cycles, internal combustion engines, trolley systems, and hybrid systems. A comprehensive reference index is provided. Included is an appendix containing abstracts of the pertinent literature.

Jan 1, 1980

By E. P. Ferrero

Analyses of 38 crude oil samples from 25 fields in Algeria, Libya, and Nigeria are presented in this report. The 38 crude oils are listed alphabetically by country and field. Also shown are the geographic and geologic sources of the samples analyzed, the companies that supplied the samples, the general characteristics and analytical and computed data, and the production for the fields from which the samples were obtained.

Jan 1, 1966

By Edwin M. Thomasson

HELIUM SHIPMENTS in 1964 exceeded the volume shipped during the previous year for the 15th successive time. Shipments from Bureau of Mines helium plants were 667.4 million cubic feet,2 about 6 percent more than in 1963. Production at Bureau of Mines plants totaled 784.5 million cubic feet. An additional 3,193.1 million cubic feet, which was produced by private companies participating in the helium conservation program, was purchased by the Bureau and stored underground for future use. The Bureau of Mines continued to sell helium at $35 a thousand cubic feet, the price established in 1961. Substantial railway freight rate reductions for tank car shipments of helium went into effect during the year, resulting in a lower delivered price for helium. As the Nation moved ahead in the space age, it became increasingly apparent that helium would continue to play an essential role in research, in technology, in defense, and in industry.

Jan 1, 1965

By E. J. Gleim

This report describes a trip to Europe in the interest of safety in coal mines. It reviews the Eighth International Conference of Directors of Safety in Mines Re-search, which met in Dortmund-Derne, Germany, July 5-10, 1954, to discuss results of studies made in different countries to improve health and safety conditions under-ground. It also summarizes information on subjects of special interest in the United States gained by the writer in visits to mining experiment stations in Belgium, France, and England. The efforts being made to protect life and property underground were discussed, and ideas and experiences were interchanged freely, not only during the conference but also during visits to the several countries. Helpful information was obtained on many topics of interest, but time did not permit as thorough a discussion on some of them as might be desired.

Jan 1, 1956

By Virgil Miller, R. G. Knickerbacken

"INTRODUCTION The Bureau of Mines work reported by the Metallurgical Division 4/ in 1934 shows the possibility of producing artificial manganese ore by pre- ferential oxidation of manganese from spiegeleisen produced from manganiferous iron ores of the Cuyuna range, Minnesota. A three-step process is described as being capable of producing a ferrograde ore from this type of low-grade, domestic, strategic material. However, the melting temperature in the last step of the process that forms the manganese product is high, and the phosphorus content is not easily controlled. Also, the tenor of the manganese in the product is not comparable with other methods that use less process energy.Lofquist 5/ patented an improvement of the above three-step smelting method, in which sulfide was added to lower the melting point of the product.More recently, reputedly successful attempts have been made to reduce iron preferentially from manganiferous iron ores, simultaneously removing the phosphorus with the iron, by means of an unusually high temperature blast and excess coke.Anson G. Betts 6/ patented a process for the matte-smelting of manganese ores, in which the ore was mixed with pyrite and enough carbon or coke to serve as thermal energy and reducing, agent in a manner similar to the standard blast-furnace process. This process was intended to give pig iron, a manganese-iron matte, and a waste slag. Wood, Barrett, and Porath 7/ presented data on the treatment of low-grade, domestic, manganiferous iron ores and low-grade, domestic manganese ores by this Betts mattes pelting process."

Aug 1, 1942

By E. D. Calvert

Molybdenum has been successfully cast into static and rotating molds in conventional equipment used for casting titanium and zirconium. Melting was accomplished by using an arc potential of 36 to 40 volts with a current of 10,000 amperes. Pouring efficiency, after a skull had been formed in the crucible, averaged 70 percent. Techniques are described by which four successful castings were made. Tensile properties on specimens cut from one centrifugally cast tube averaged: Tensile strength, 39,800 p.s.i.; yield strength (0.1 pct. offset), 35,300 p.s.i.; elongation, nil; reduction in area, nil; impact strength, 2 ft.-lb.; hardness DPH (diamond pyramid hardness) 180. Mold reaction was not evident in shapes cast in machined graphite. This was not true, however, for rammed graphitic-base molds.

Jan 1, 1960

By Louis H. Berkelhamer

"INTRODUCTION ""Free silica"" includes all free forms of silicon dioxide, such as quartz, chalcedony, tridymite, cristbbalite, opal, diatomaceous earth, and lechatelierite. The term, has been used rather loosely however, as synonymous with quartz, as quartz is the most abundant form of free silica. ""Combined silica,"" on the other hand, has been reserved to denote silica combined with other elements as silicates.Improvements in methods for the determination of free silica, and quartz in particular, have been the subject of considerable interest during the past decade, owing mainly to the accented and increased knowledge concerning quartz as a causative factor in silicosis. Analysis for quartz, however, is of importance in many other fields, including the determination of quartz in ceramic raw materials, such as feldspar and clay; the evaluation of a beneficiation procedure by the ore dresser, such as in the concentration of iron ore; control studies of a manufactured product, such as silica brick; and routine analysis of rock, mineral, and ore samples by chemists and petrographers."

Jul 1, 1944

By Eldon Keith Stanek

This annual report deals with four distinct tasks related to research on the safety and reliability of mine electrical power systems. Task one is to develop tests and the associated instrumentation to detect incipient faults on a mine or any low-voltage power system. Task two is a dual effort related to the digital prediction of electrical transients on mine power systems and laboratory testing of transient suppression devices. Task three is also a dual effort. This task consists of both theoretical and laboratory work to assess both the reliability and the fail-safe characteristics of several items of protective equipment used in mine power systems. Task four consists of an effort to use programmable calculators and/or computer terminals to check overcurrent protective device coordination.

Jan 1, 1976

By K. K. Kershner

The purpose of this investigation was to develop methods, on a laboratory scale, for recovering tin from Bolivian metallurgical slimes. Petrographic and chemical analyses were made of slime ore fractions from several well-known tin operations. High percentages of the total tin were volatilized as chlorides at temperatures below 600° C. Under optimum conditions reaction rates were relatively rapid, and the chloridizing reaction approached completion. Owing to the low temperatures involved and the high yields of tin, the process was considered to have possibilities for treating Bolivian slimes on a commercial basis. ACKNOWLEDGMENTS Appreciation is hereby extended to the Patino Mines and Enterprises, Inc., of Bolivia, for supplying slimed tin ores that were used in the experimental work. This company has since been nationalized.

Jan 1, 1959

By O. Q. Leone

A processing unit was developed for the complete cleaning of titanium alloy chips. The process uses solvent degreasing, magnetic separation, and anodic solution of nonmagnetic impurities in 10 weight-percent sulfuric acid. Vacuum arc-melted ingots weighing approximately 10 pounds each were prepared from cleaning chips according to ingot specifications.

Jan 1, 1973

By Thomas J. Peters

In 1979 and 1980, the U.S. Bureau of Mines and U.S. Geological Survey conducted a mineral survey of the 15,600 acre (6,310 ha) Freel Peak RARE II area (No. 5271) in the Lake Tahoe Management Unit. This study by the Bureau of Mines indicates that potential for economic mineral resources in the area is slight. The only mineralized structures in the area consists of two quartz veins. One quartz vein, at the Mountain Top Mine (fig. 1), located by Fred Denner in 1932, is estimated to contain 2,000 tons (1,800 t) of silver and copper-bearing resources. Chip samples from the vein averaged 0.61 oz silver per ton (20.91 g/t), and 1.59 percent copper. The narrow vein is not economically mineable. The other quartz vein is poorly exposed and contains traces of molybdenum. A second reported molybdenum occurrence could not be substantiated.

Jan 1, 1982

By Herbert H. Einstein

Instability of rock slopes often occurs in the form of excessive movement of bodies that are bounded by discontinuities. The well known limit equilibrium analysis for wedges and blocks suffer, however, from procedural simplifications and from the basic deficiency of limit eguilibrium analysis--the rigid body assumption. Thus, stability analysis for 2-and 3-plane wedges with a wide range of additional features regarding failure modes and external forces have been developed. The deficiency, due to the rigid body assumption, was corrected by an approach that includes the effects or the in-situ stress field and of the stiffness of discontinuities. The final step in making limit equilibrium approaches more valid was achieved with the method of artificial supports which makes it possible to identify among all possible failure modes the critical one and to determine the corresponding factor of safety. The analytical development includes the creation of appropriate computer codes and routines for programmable pocket calculators.

Jan 1, 1979

By G. B. Clark

One portion of this project was to test a blast shield and to design some features for a novel tunneling method termed the Automated Drill and Blast System (ADBS). The ADBS tunneling concept was developed for the design of an excavation system of greater efficiency than conventional drill, blast, and muck (DBM) systems by minimizing the down time and approaching the non-cyclic efficiency of continuous tunneling by means of small charge blasting. Small charge blasting uses simultaneously detonated, small light charges (less than 200 grams per hole) in four to eight shallow (24 to 36 in. deep) holes usually in a line. Limitation of the total explosive per blast reduced air blast overpressure, fly rock velocity, vibration, and noise. Thus, shielded equipment can remain at the face and a tunnel shield permits support personnel to work outby the shield at all times. The ADBS equipment will be composed of five components: (1) a chassis, upon which is mounted automated mucking equipment, and a frame which carries (2) the hydraulic drill(s), (3) load/blast system(s), and (4) control cab(s). The blast shield may have its own mounting. Ventilation, horizontal, and vertical alignment controls are incorporated in the system. The blast sheild, which protects personnel outby the advance equipment from air blast overpressure, fly rock, and gases, was tested with full scale small charge blasting. A blast shield was designed, fabricated, and tested under conditions anticipated for a working model. The shield was designed to expand to fit the tunnel shape, to seal itself to the tunnel periphery, and to contain air blast, fly rock, and gaseous explosion products. In addition, the shield, which was lined on the inby side with rubber belting, reduced the blast noise level outby the shield to 113 dBA or less, which is very near permissible levels. The test results show conclusively that the shield concept is viable. Based partially on the shield tests, a blast resistant control cab was designed to be located on the equipment chassis inby the blast shield to protect operators during blasting, and to contain all the controls necessary for system operation and safety. The economics of tunnel driving using the ADBS were compared with those of DBM. Four rock types, which determine advance rate, and four cost categories were examined. The results of this analysis are as follows: 1. ADBS advance rate is faster because equipment remains at the face and operation procedes semi-continuously. 2. ADBS bit and explosive cost (which accounts for 4%o of the total advance cost) is higher than for DBM. 3. ADBS equipment cost, on a per foot basis, is lower than for DBM. 4. Due to a reduced labor force, ADBS labor cost is lower than for DBM. 5. Because of the overbreak reduction due to controlled blasting, ADBS tunnel support cost is lower than for DBM. 6. On a per foot basis, total ADBS advance cost is from 17% to 20% lower than for DBM, depending on tunnel diameter and rock type. The small charge method greatly reduces ground vibration, increases personnel safety by limiting excessive fracture, and decreases tunnel support requirements by reducing overbreak. The overall analysis, tests, and results to date show that the Automated Drill and Blast System may be developed into a viable tunnel excavation method. The method also may be adapted to use in the mining of ore. For some types of mining operations, the cyclic nature of conventional drill and blast methods may not be a disadvantage, either where the drilling and mucking may proceed simultaneously or where the operations are carried out in adjacent working faces. The proposed method would find application where continuous methods of excavation are desirable.

Jan 1, 1979

By Michael Rieber

Commodity transportation by barge is possible on about 25,000 miles of navigable inland waterways in the contiguous 48 states. Barge operations are used chiefly for the movement of bulk raw materials ranging from farm products to iron ore, coal, and other bulky semi-finished as well as finished products such as steel, chemicals and petroleum [3,p.7-9]. The barge industry, unlike other transportation industries, is largely unregulated. This is because all liquid bulk commodities most dry bulk commodities transported by for-hire carriers and companies engaged in private transportation of their own commodities are exempted from Interstate Commerce Commission regulations. As a result, about 15 percent of the total ton-miles of barge traffic each year is under Interstate Commerce Commission regulation [13,p.14-25].

Jan 1, 1977

By C. E. Julihn, Lowell B. Moon

"INTRODUCTION To increase the supply of ore needed to produce steel the Bureau of Mines has explored 187 mineral deposits containing chromium, iron, manganese, cobalt, nickel, fluorspar, tungsten, vanadium, or coal during the fiscal years. 1940-44, the deposits thus explored were selected from several thousand that were first examined to appraise their possibilities. The objective of the exploration was to determine the tonnage and grade of ores upon which mining, operations might be based, and the metallurgical processing that was most suitable for their utilization.Most of these deposits were sub-marginal by pre-war standards; hence there had been no incentive for their exploration, yet many such deposits were known to exist that probably contained ore sufficient in grade and amount to be utilized as war reserves.Some of the Bureau's exploration projects have disclosed substantial or even very large amounts of ore, much of which is fairly high in grade. In a few of them bodies of high-grade ore have been found, though in others the tonnage has proved to be too small or too low-grade for utilization."

Mar 1, 1945