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By R. D. Cromarty, J. Du Toit

"Penetration of matte into tap-hole bricks causes detrimental refractory wear, which can lead to furnace breakouts. The ability of the tap-hole clay to form a protective layer on the brick, thereby limiting matte penetration was investigated by examining the interaction between platinum group metal (PGM) matte, tap-hole clay, and alumina-chrome refractory bricks on a laboratory scale.Samples containing clay and brick as well as samples containing clay, brick, and matte were heated to different temperatures to establish the clay-brick interaction and the extent of matte penetration. The greatest degree of physical contact between the brick and clay was achieved at curing temperatures of 600°C. Poor clay-brick contact was observed in the sample that was heated to 900°C.Matte displaced the clay in the clay-brick-matte sample that was heated to 1350°C, with significant matte penetration into the brick. Less matte penetration was observed when the clay-brick-matte sample was heated to 1500°C. Less matte penetration was also observed in the claybrick- matte sample in which the clay and brick were pre-baked at 800°C, and the sample then reacted with matte at 1350°C. IntroductionFloatation concentrate from ore from the eastern Bushveld Complex of South Africa, specifically the Platreef, Merensky, and UG2 reefs, forms the feed to the Polokwane platinum smelter (Hundermark, De Villiers, and Ndlovu, 2006). The ore from the UG2 Reef has a high chromite content, which requires high operating temperatures (1500–1700°C) to avoid chromium spinel build-up in the furnace hearth. These high operating temperatures lead to matte superheats in the vicinity of 500– 600°C, which put increased demands on the refractory materials (Nelson et al., 2005).Upon tapping, the matte moves through the tap-hole, which consists of an aluminachrome refractory brick-lined tapping channel (Hundermark, De Villiers, and Ndlovu, 2006). The flow of molten matte is stopped by the injection of tap-hole clay to form a plug in the tap-hole. The tap-hole clay hardens and strengthens during curing to obtain the required hardness and refractoriness against penetration, corrosion and erosion (Nelson and Hundermark, 2014)."

Jan 1, 2016

By Maggi Loubser

"In a technologically advanced era, where process control is accurately maintained within the smallest error margins, and accuracy and precision are continuously improved, sampling is still left to the lowest paid employee in the company without training him or her properly to understand the relevance and importance of the task. In this paper the objectives of sampling in a process control environment is discussed and an attempt is made to link it to the theory of sampling. Some of the practical problems associated with implementing theoretical sampling principles in an industrial environment will be elucidated and some examples given on how compromises are made. Different methods of sampling will be discussed with real life examples from different manufacturing industries."

Jan 1, 2014

By K. Sinding

This paper discusses reasons for mining company mergers that have become the fashion, the role of the ?Juniors? and asks what the motives might really be. It examines changes in company concentration over the last 20 years in key mineral segments. Data at different stages of a project are examined to attempt to elucidate the role of the ?Juniors?. Areas for further research are suggested.

Jan 1, 2009

By T. Bednarski, L. Thomas, G. Banza, D. Muteba, P. Cole, M. Soderstrom

"In copper solvent extraction, aqueous-in-organic entrainment results in the carry-over of unwanted species into the electrowinning process with negative cost implications. The need to bleed is increased and the purity of the copper cathode is potentially compromised, depending on the impurities being transferred (Cl, NO3, Fe, Mn). In some cases, entrainment results in elevated levels of manganese in the electrolyte which can cause oxidative conditions to develop and degradation of the organic phase. Degraded organic phase detrimentally affects the physical performance of the copper solvent extraction process, contributing to even higher aqueous-in-organic entrainment. Aqueous entrainment may be minimized through good operating practices and maintenance of the organic quality, but the accurate measurement of entrainment remains a challenge. This paper presents coalescing devices designed to provide more exact measurements of aqueous-in-organic entrainment. IntroductionMany copper solvent extraction (SX) plants experience high aqueous-in-organic (A-in-O) entrainments but are unaware of the extent of the problem because entrainment is often not measured. Aqueous entrainment results in the carry-over of unwanted species into the electrowinning (EW) process and the need to bleed to maintain acceptable concentrations in the electrolyte. The costs associated with the bleed are exacerbated in copper plants where aqueous entrainment levels are high. Other than these direct costs, there are operational consequences of the build-up of certain species in the EW circuit that can have deleterious effects on plant performance.Minimizing aqueous entrainment in operating plants requires an understanding of the factors that affect entrainment levels. Both chemical and operational influences are discussed in this paper. The difficulty of obtaining a representative sample makes it challenging to obtain an accurate measure of aqueous entrainment from a continuous process like SX. Coalescing devices used to get a more precise measurement of A-in-O entrainment are useful to complete mass balances around the SX circuits. Alternatively, mass balances can be used to estimate aqueous entrainments and are helpful as a tool to troubleshoot operations with a view to improving plant performance."

Jan 1, 2016

By K. R. Noble

The planned extraction of the No. 1 shaft pillar at Blyvooruitzicht Gold Mine highlighted a number of potential problems. In spite of the relative shallowness, careful thought had to be given to stope phasing owing to the detrimental effect of the anticipated geology and the fact that uninterrupted hoisting was necessary. Extensive use was made of computer modellig to design the stope phasing, determine the influence of regional support and to predict the direction and magnitude of displacements in the shaft. The paper describes the success of this design approach, and measured displacements in the stoping horizon and shaft barrel are compared to those obtained from the original computer model

Jan 1, 1987

By D. S. Loubser

The technique of backfilling in the gold mining industry is dependent on the dewatering of slurry to form a solid support system. In many cases flocculants are added to the slurry to increase the rate of dewatering. To ensure that a stable support is obtained it is important that the chemistry, application and limitations of these flocculant additives are understood. Flocculant additives have to be added at a point where minimum shear will occur. (Shear occurs when a flocculant is exposed to excess energy resulting in breakdown, of the floc.) To ensure that optimum results are obtained it is important that personnel involved are trained to use the flocculant additives and dosing equipment correctly.

Jan 1, 1988

The optimal design of production phases and ultimate pit limit for an open pit mining operation may be generated using conventional or stochastic approaches. Unlike the conventional approach, the stochastic framework accounts for expected variability and uncertainty in metal content by considering a set of equally probable realizations (models) of the orebody. This paper evaluates the performance of a new stochastic network flow approach for the development of optimal phase design and ultimate pit limit using a gold deposit as the case study. The stochastic and conventional frameworks as considered here utilize the maximum flow and Lerchs-Grossman (LG) algorithms, respectively. The LG algorithm is restricted to considering an estimated (average-type) orebody model, while the stochastic maximum flow algorithm is developed to simultaneously use a set of simulated orebody realizations as an input. The case study demonstrates that, when compared to the conventional LG algorithm as used in the industry, the stochastic approach generates a 30 per cent increase in discounted cash flow, a21 per cent larger ultimate pit limit, and about 7 per cent more metal, while it maintains a consistency in phase size.

Jan 1, 2012

By J. Sjöberg, P. Lundman, E. Nordlund, C. Quinteiro

Abstract In the Kiirunavaara underground mine, crude ore is transported through ore passes from the production levels to the main haulage level. Failure and stability problems have occurred in some of these ore passes, with increasing frequency as mining depths increase. In this paper, selected results are presented from a research project run by LKAB. The presentation focuses specifically on stability analysis. Numerical models were used to identify failure mechanisms, in conjunction with empirical data and engineering judgment. The most important controlling factors governing failure and damage in ore passes were quantified. A causative model was established in which failure mechanisms and failure development were described. This model was used to formulate a prognosis of future ore pass stability, and for recommending remedial measures. Résumé Le transport du minerai entre les niveaux de production et le niveau principal de transport, à la mine de fer de Kiruna, se fait par des passes à minerai. Avec la profondeur d'extraction grandissante, les problèmes de stabilité au niveau de ces passes à minerai se sont multipliés. Les résultats d'un programme de recherche sur la stabilité des passes à minerai à la mine de fer de Kiruna sont présentés dans cet article. Les mécanismes de rupture ont été identifiés à l'aide de modèles numériques, de données de terrain et du jugement empirique des ingénieurs. Les facteurs principaux controllant l'instabilité des passes à minerai ont aussi été quantifiés. Un modèle a été établi dans lequel les mécanismes de rupture et le développement des dommages ont été décrits. Ce modèle a été utilisé à fins prédictives et remédiatives. Zusammenfassung In der Grube Kiirunavaara wird das gewonnene Erz über Sturzschächte von den Abbauebenen zu der Hauptförderebene gefördert. Mit zunehmender Tiefe des Abbaus sind vermehrt Standsicherheitsprobleme in den Sturzschächten aufgetreten, die teilweise zu Verbrüchen geführt haben. In dem vorliegenden Beitrag werden ausgewählte Ergebnisse einer Forschungsarbeit des LKAB präsentiert. Dabei wird der Schwerpunkt auf die Standsicherheitsuntersuchungen gelegt. Zur Ermittlung der Bruchmechanismen wurden numerische Modelle in Verbindung mit empirischen Daten angewendet. Die wichtigsten Einflußfaktoren für das Versagen der Sturzschächte wurden ermittelt. Es wurde ein Modell zur Beschreibung der Bruchmechanismen und des Versagensablaufs aufgestellt. Dieses Modell wurde verwendet, um die Standsicherheit zukünftiger Sturzschächte zu prognostizieren und um Sanierungsmaßnahmen zu erarbeiten.

Jan 1, 2003

By C. Ringas

Pipelines are used extensively in industry to convey various products. Internal corrosion of pipelines can lead to perforation and leakage of the product. A growing problem, not often accurately recognized, is internal corrosion of pipelines caused by bacteria. Microbiologically-induced corrosion (MIC) refers to corrosion caused by a variety of micro-organisms. This form of corrosion is not widely recognized in many industries, although it is widespread and causes many corrosion problems in pipelines, both internal and external. Sulphate-reducing bacteria (SRB) are responsible for the bulk of the corrosion problems caused by MIC. Corrosion caused by SRB is found extensively in water pipelines conveying raw, potable and waste water, as well as in pipelines conveying slurries. This problem also occurs in pipelines conveying crude oil. This paper describes internal corrosion problems of slurry pipelines caused by bacteria and outlines mitigation methods to improve slurry pipeline integrity, thereby extending the life of such pipelines.

Jan 1, 2007

By L. Marais

The development of a post-mining economy is generally framed as accessible and desirable and something that mining companies, consultants, and the government can, and should, plan for. It is indeed possible. Yet, most mining regions, other than the big metropolitan municipalities, find economic diversification after mining challenging, despite their grand plans, consultant reports, and company intentions. Their efforts blind them to other ideas that are often prerequisites to diversification. This paper highlights some economic and social misconceptions about economic diversification and explains where planning goes wrong. Mistakes typically stem from ignorance and misunderstandings. Planners and policy makers fail to grasp the essential requirements for economic diversification. They underestimate the structural constraints created by mining. They do not see how mine rehabilitation is linked to economic diversification. They generally do not understand the South African space economy or the nature of new economies. The paper also proposes a more careful consideration of those economic aspects that mining cities have control over, such as land use management and infrastructure. The paper further explains how understanding long-term dependencies can help prevent governance failures. The social disruption that accompanies mine decline and closure must be recognised and dealt with. The mines must plan for decline as a way to resuscitate the economy. It concludes with a framework for assessing and developing a post-mining economy.

Apr 25, 2025

By K. Harlow

"Zircon is a naturally occurring radioactive material (NORM) and as such is subject to a variety of regulations around the world. The regulatory processes and their implementation are summarized and the key issues affecting zircon and zirconia highlighted. Having absorbed the activities of the former Zircon Minerals Committee, the strategy of the Zircon Industry Association (ZIA) is to be the ‘go-to place’ for information on these matters, and its activities in the NORM space are described. Chemical industry regulations such as REACH are spreading around the world, and the paper provides an update of their status in the key jurisdictions. As mineral sands are transported to market in oceangoing vessels, they are subject to the regulations of the International Maritime Organization, which are summarized in the paper. IntroductionFrom a global perspective, zircon is generally not found in high concentrations other than in placer and dune deposits where it has been deposited along with other heavy minerals such as ilmenite, rutile, and monazite. Such deposits have been sorted and concentrated over geological time by the action of tides, waves, and wind to form concentrated deposits of heavy minerals along old coastlines and in river beds and deltas. Consequently, zircon is mostly found in association with the principal titanium minerals ilmenite and rutile. These secondary concentrations in placer deposits provide the commercial sources of zircon.All geological materials contain natural radioactivity, although the term NORM (naturally occurring radioactive material) is mostly used for minerals and other materials with above-average uranium and thorium concentrations. Importantly, the radioactive nature of zircon has not changed, but the way in which radioactivity is viewed by regulators has, affecting the zircon industry throughout the value chain."

Jan 1, 2017

By G. A. Bezuidenhout

Lonmin Platinum installed a concentrated mode dual-alkali scrubber at the smelter in Marikana in 2002. The dual-alkali scrubber was the technology of choice at that time as a sulphur fixation plant, due to the perceived benefits of handling both the high SO2 concentrations of converter off-gas and the swings in SO2 concentration that are linked to Peirce-Smith operation. Owing to current and impending legislative requirements for air quality and waste, Lonmin is currently considering additions to the dual-alkali plant, but is also evaluating alternative technologies for sulphur fixation. This paper reviews the decision of Lonmin to install a concentrated mode dual-alkali scrubber and presents plant performance achieved. It also describes the important control variables and sensitivities of the plant, and the final product that is produced by the operation of the plant. The legislative requirement that drives the Lonmin technology evaluation is also discussed.

Jan 1, 2012

With the increased variability of today's large-scale mining operations, consistent flotation performance is important to improving and sustaining overall recovery through the circuit. The Newcrest Telfer Mine has implemented advanced process control technology to obtain stable level operation and consistent mass pull in the copper rougher and scavenger flotation circuits. The final result has been an overall reduction in variability, which impacts on both copper and gold recovery. This paper describes the methodology and implementation of the improvements in control at the Newcrest Telfer Mine as being an essential part of the business for minerals processing.

Jan 1, 2007

By A. Montini

The problems encountered in the design of control systems for milling cir- cuits when the model of the system and the model parameters are uncertain are discussed. Considering these uncertainty factors has led to the development of a technique that gives a quantitative assessment of real system stability, reveals the trade-offs between performance and stability and helps the designer in deciding what level of model complexity to use in the controller design. Furthermore, it allows for on- or off-line optimization of the milling circuit performance as it provides the base for the design of a controller which is stable over the plant operating range.

Jan 1, 1987

By J. O. Roux

The Impala Platinum Limited Base Metals Refinery in Springs, South Africa, refines convertor matte containing base metals and PGM?s (platinum group metals) using a hydrometallurgical process. In addition to a PGM-rich concentrate that is further refined, the Base Metals Refinery produces nickel (in powder or briquette form), copper cathodes and cobalt powder. Five leaching stages are utilized to remove the base metals and impurities from the PGM concentrate. The project described in this paper involves a radical redesign of the second stage leach autoclave with the aim of reducing maintenance costs and downtime, increasing throughput and ensuring a safer working environment. The second stage leach process at the Base Metals Refinery, produces a PGM-rich residue through the extraction of copper and any remaining base metals from the first stage leach solid residue material. Leaching is performed in an autoclave operating at a pressure of 600 kPaG and a temperature of 140°C to 150°C. Concentrated H2SO4 is added to the feed to produce a solution with a free acid content between 10 and 30 g/L and a pH of less than 2. Oxygen is passed into the 1st and 2nd compartments of the autoclave. As a result of the aggressive, highly oxidizing conditions within the autoclave, the original design utilized a heavy wall carbon steel shell with lead lining and two layers of acid bricks. The bricks acted as a wear resistant material and ensured a low surface temperature at the skin of the lead lining, whereas the lead lining acted as a corrosion barrier to protect the steel shell. These brick lined autoclaves were heavy, maintenance intensive and prone to catastrophic failure. A radical autoclave redesign was needed to reduce the high costs of manufacturing, installation and operation. Finite element modelling was used to optimize the design and various high alloy materials were investigated for the application. Based on extensive test work, the carbon steel shell was replaced with duplex SAF 2205 stainless steel in the new design. The use of this highly corrosion resistant material, eliminates the need for the lead and brick linings and reduces the wall thickness requirements substantially, resulting in an increase in the available volume for the same external shell dimensions. The vessel is welded in circular sections to form an elongated, impermeable, cylindrical body, with several agitator nozzles and compartments. The first new duplex stainless steel unit has been in continuous operation for more than 24 months and its performance has exceeded the highest expectations. The design was so successful that a patent has been registered. The major benefits of the new stainless steel design include increased throughput, improved performance, less downtime and a safer working environment. Lead has been eliminated and replaced with a more environmentally safe material, and the total lifespan of the vessel has been extended. In addition, the autoclave project has made significant developments in advancing the field of welding and optimizing the integrity of welding quality standards in South Africa.

Jan 1, 2009

By M. Frenzel, K. Bachmann, M. Rudolph, R. Tolosana-Delgado, E. Schach, M. Buchmann, L. Pereiraa, K. G. van den Boogaart, N. Kupka

Geometallurgy - the science of predicting the behaviour of ores along the value chain based on their geological and mineralogical characteristics - has barely moved beyond process minerology studies. These studies typically link process behaviour to the mineralogical and microstructural characteristics of pristine or processed ores in a qualitative or semi-quantitative manner. Eventually, a trial-and-error optimisation of the operation is achieved. However, to deliver on its promise, geometallurgy should progress beyond this current approach to a fully quantitative understanding of process behaviour, including the various uncertainties involved, namely predictive geometallurgy. One of the barriers currently hindering this development is the neglect of most ore characterisation data obtained in geometallurgical studies. This is mostly due to the large extent of this information exceeding the capacity of conventional software. To address this challenge, we developed a data mining platform consisting of an SQL database, an R front-end in-house package, and back-ends to interpret data from several analytical instruments. This platform enables the use of the statistical and data mining power of the R open-source environment for any geometallurgical study. Potential applications range from ore characterisation to process understanding and forecasting, and from geostatistical prediction to operational control and optimisation. The scripting abilities of R allow for the: 1) processing of many streams in loops, thus freeing the user from repeating tedious click-and-drop tasks; 2) computation of virtually any derivate or aggregate quantity from the data; 3) distribution of the work among several processor clusters; and 4) keeping of a log file for the calculations done. This contribution presents the building blocks of this platform, and illustrates with several examples its potential to enable predictive geometallurgy. Keywords: Data mining, entropy, kernel methods, LASSO regression, predictive geometallurgy

Jan 1, 2020

By A. Cambitsis

We show that the prioritization of business improvement and performance management decisions may be significantly improved by taking into account the systemic effects of changes made in a single process area. To do so we build a model of a mining value chain, taking into account consequential downtime that arises from downstream and upstream starvation and choking effects of each activity. Introducing the concept of internal capacity, this approach yields insight into the relative importance of key metrics such as loading and hauling rates. We suggest that a holistic view of this type should be a core component of business improvement and performance management decisions.

Jan 1, 2012

By G. Poropat, A. R. Guest, H. P. Grobler

At the De Beers Consolidates Mines operations it is common practices to perform Geotechnical mapping of the newly exposed faces in the waste and ore rock. The purpose of Geotechnical mapping is to quantify the in-situ fracturing of a rockmass that in turn is required during the planning and application of a mining method. Whether it is to determine slope angles, caveability, impact of blasting or support requirements. This mapping involved a cumbersome and time consuming procedure that requires individual examination and description of the natural inherent fractures exposed by mining. During highwall mapping in an open pit this can be a safety concern due to the duration of time spent below a highwall. The advantages gained through the recent introduction and application of SiroVision® allows safer mapping, an increase in statistical fracture population, archiving of rock faces and the more accurate reflection of the true mapping. This paper aims to describe in detail the application of the recently developed SiroVision®, photogrammetry software, to replace conventional face mapping. A De Beers Consolidated Mines, il est pratique courante de faire une cartographie géotechnique des tailles récemment exposées dans le rocher stérile ou minerai. Le but de la cartographie géotechnique est de quantifier la fracturation in-situ d’une masse rocheuse, qui sera nécessaire lors de la planification et application d’une méthode minière, que ce soit pour déterminer les angles des galeries inclinées, les possibilités de foudroyage, l’impact du dynamitage, ou les besoins en supports. Cette cartographie nécessitait une procédure longue et compliquée qui demande l’examen individuel et la description des fractures naturelles propres exposées par l’opération de mine. Pendant la cartographie de parois dans une exploitation à ciel ouvert, cette opération peut être dangereuse à cause du temps passé sous la paroi. Récemment, le lancement et application de Siro Vision apportent l’avantage d’une cartographie plus sûre, une augmentation des statistiques de population de fracture, l’archivage des tailles de roches, et le reflet plus précis de la cartographie. Le but de l’étude présente est de décrire en détail l’application du développement récent de Siro Vision, logiciel de photogrammétrie, pour remplacer la cartographie de taille conventionnelle. Bei den De Beers Consolidates Mines Operationen ist es gängige Praxis geotechnische Aufzeichungen des Taub- und Erzgesteins neu geöffneter Abbaustellen zu erstellen. Zweck dieser geotechnischen Aufzeichnungen ist die vor-Ort-Quantifizierung des Bruches der Gesteinsmasse, welche im Gegenzug während der Planung und der Anwendung einer Abbaumethode erforderlich ist, sei es um einen Neigungswinkel festzustellen, Abbaubarkeit, Auswirkung von Sprengungen oder Anforderungen an Unterstützungen. Die Aufzeichnungen waren mit umständlichen und zeitaufwendigen Prozeduren verbunden, die eine individuelle Prüfung und Beschreibung der durch den Abbau freigelegten natürlichen inhärenten Brüche, verlangten. Dies kann auf Grund des Zeitraumes der unterhalb einer Flözoberschicht verbringt wird zu einer Frage der Sicherheit werden wenn die Aufzeichnung einer Flözoberschicht im Tagbau erfolgt. Die Vorteile auf Grund der jüngst erfolgten Einführung und Anwendung der SiroVision® gestatten sichereres Aufzeichen, eine Zunahme in der statistischen Menge an Gesteinsbrüchen und eine akkuratere Reflektion der tatsächlichen Aufzeichnungen. Diese Arbeit hat zum Ziel im Detail die Anwendung der kürzlich entwickelten SiroVision®, eine photogrammetrische Software, die die konventionelle Abbauortaufzeichnung ersetzen soll zu beschreiben.

Jan 1, 2003

By Y. Sagawa

The Hishikari Gold Mine consists of epithermal vein type Au-Ag deposits, each of which has several veins standing almost in parallel each other and inclining 70 to 90 degrees. The veins have 1 to 3m widths and are extracted mainly by drifting and bench stoping with waste rock fill. The Hishikari has tried to optimise the stope dimensions by the Potvin’s Stability Graph Method, which is well known as an easy and effective tool to design appropriate stope dimensions. The method, however, has some limitations of application due to its simplicity so that it has been used only in limited cases. The authors developed a new numerical approach, based on 2D FEM solu-tion for the stability analysis. As a result, it has been possible to solve the Hishikari situation. The authors also introduce the concept of the design approach and compare the results obtained by us-ing the approach with the database of the Stability Graph Method for validation. La mine d’or Hishikari se compose de gisements d'Au-AG avec des types de filons épither-maux dont chacun a plusieurs veines qui sont presque parallèle les unes par rapport aux autres et sont inclinées de 70 à 90 degrés. Les veines ont de 1 à 3 m de largueur et elles sont principalement extraites en creusant et en abattant des bancs de roches encaissantes. Hishikari a essayé d’optimiser les dimensions du chantier d’exploitation avec la méthode de graphique de stabilité de Potvin, bien connue comme un outil facile et efficace pour avoir des dimensions de chantier d’exploitation appropriées. Toutefois, la méthode a certaines limites d’application dues à sa sim-plicité de sorte qu’elle a été utilisée seulement dans des cas limités. Les auteurs ont développé une nouvelle approche numérique, basée sur la solution 2D FEM, pour l’analyse de stabilité. Par conséquent, il a été possible d'expliquer la situation de Hishikari. Les auteurs présentent le concept de l'approche et ils comparent les résultats donnés en l'employant avec la base de données de la méthode de graphique de stabilité pour la validation. Die Hishikari-Goldmine besteht aus Au-Ag-Ablagerungen mit epithermalen Adern, die jeweils mehrere Adern aufweisen, die mit einer Neigung zwischen 70 und 90 Grad nahezu parallel zueinander verlaufen. Die Adern haben eine Breite von 1 bis 3 Metern und werden überwiegend durch Vortrieb von Stollen und Bergversatz abgebaut. Hishikari hat versucht, die Abmessungen des Abbauorts durch das Potvins Stabilitätskurvenverfahren zu optimieren, das als einfaches und effizientes Mittel für die Erzielung angemessener Abmessungen des Abbauorts bekannt ist. Das Verfahren weist jedoch aufgrund seiner Einfachheit einige Anwendungsbeschränkungen auf, so dass es nur in einigen Fällen benutzt worden ist. Vor diesem Hintergrund haben die Autoren einen neuen numerischen Ansatz entwickelt, der hinsichtlich der Stabilitätsanalyse auf der 2D-FEM-Lösung beruht. Dadurch wurde es möglich, das Problem von Hishikari zu lösen. In diesem Dokument stellen die Autoren die Grundlagen des Ansatzes vor und vergleichen die erzielten Resultate durch Benutzung der Datenbank des Stabilitätskurvenverfahrens zur Validierung.

Jan 1, 2003

By M. Lange

The postulation that primary platinum group metal (PGM) matte will chemically react with magnesia-chrome bricks when temperatures exceed 1500°C was tested. Magnesia-chrome brick samples were heated in contact with matte at 1300°C to 1750°C for 30 minutes, after which the refractory samples were analysed using reflected light microscopy and scanning electron microscopy. The samples were all completely penetrated by matte. As the temperature increased the matte also penetrated the fused aggregate grains and disintegrated them. The chromium concentration of the matte inside the refractory samples was found to be slightly higher than that of the bulk matte. At temperatures of 1500°C and higher, MgO, FeO, and magnesium-rich silicate crystals could be identified in the matte directly adjacent to the refractorymatte interface. Phase relations clearly indicated that chemical reactions take place between primary PGM matte and the magnesiachrome refractory material at temperatures above 1500°C, but that these reactions are more complex than expected from FactSAGE® calculations.

Jan 1, 2014