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By C J. Berry, P H. Briggs

Assessment of metal mobility, acid rock drainage production, and toxic effects from weathering of mineralised materials (ie mine-waste piles and outcropping alteration/ore zones) is key in evaluating and mitigating metal mining sites. Many metal- and acid-generating materials at these sites are sulfur minerals (sulfides to sulfates) with differing reactivities, weathering characteristics and metal contents. Our working hypothesis predicts that data on the types and quantities of sulfur minerals, coupled with comparison of their sulfur isotopic compositions to that of aqueous sulfate in the surrounding environment, can be used to evaluate primary pathways of weathering reactions at mining sites. We developed a sequential extraction scheme to separate the phases of sulfur in mineralised materials. Operationally defined phases, including monosulfides, disulfides, elemental sulfur, water-soluble sulfo-salts, acid-soluble sulfates, and resistant sulfate phases such as barite, are quantified gravimetrically and/or instrumentally. Several sets of experiments were designed to test the effectiveness of this extraction scheme. First, a variety of ore sulfides diluted in an inert matrix was analysed with the scheme. Results showed that molybdenite and arsenic-bearing sulfides do not behave as predicted from just their sulfur oxidation states, indicating that samples containing these minerals need special treatment for complete phase recovery. Second, a natural mine-waste composite standard was analysed by the scheme. The sum of the phases was equal to the total sulfur concentration analysed independently. Each phase had a similar, but distinct sulfur isotopic composition. The results were verified with a laboratory prepared æproxyÆ having the same mineralogical composition as the standard, but with each phase having a very different sulfur isotopic composition. The sulfur isotopic compositions of the recovered phases from the æproxyÆ showed that the scheme effectively separated the sulfur with only minor cross contamination of phases. The speciation and isotopic analyses were applied to both mine-waste piles and naturally occurring alteration zones at nine mine sites. A case study from one site comparing the sulfur isotopic composition of minerals in an alteration zone and dissolved sulfate in proximal streams is presented. This case study shows the application of our data to differentiating sources of sulfate in the surrounding environment.

Jan 1, 2003

By Davey KJ

Complex sulphide ores are characterised by complex texture of the valuable minerals. Any assessment of the performance of differential flotation circuits treating such ore should include analysis of the effects of poor liberation of the valuable minerals. Selected samples were taken from balanced size by size surveys of the flotation section of a concentrator treating an ore body containing fine grained galena and sphalerite in a matrix of iron sulphides which is mostly pyrite. liberation measurements were made using the QEM*SEM system on four or seven size fractions. The measurements indicated that less than 40 per cent of the galena and less than 60 per cent of the sphalerite in the flotation feed was liberated. The final concentrates were largely composed of composites of valuable minerals and iron sulphide however there was a small but significant fraction of liberated iron sulphide. Using the sized mineral flows obtained from the original balances and the liberation measurements, a satisfactory liberation balance was obtained. This enabled the effect of liberation on the flotation performance to be examined; not only for the entire circuit but also in the rougher, scavenger and cleaning sections. In the zinc circuit the effect of a regrind mill could be assessed. Recovery of galena in the lead circuit was limited by the recovery of composite lead particles. Recovery of liberated galena exceeded 95 per cent in all size fractions while the recovery of composite galena exceeded 85 per cent below 38 ¦m but fell sharply above 38 ¦m. Examination of the behaviour of the liberated and composite galena in the various sections of the lead flotation circuit revealed high recoveries of both liberated and composite galena particles in the roughing and scavenging sections but very low recoveries in the final two cleaning stages. Similar trends to those observed in the lead circuit applied in the zinc circuit although the performance of the liberated sphalerite also fell off at sizes greater than 38 pm in this case. Thus the zinc recovery was limited by the flotation of both the liberated and the composite sphalerite. The effect of regrinding was to increase the recovery of sphalerite mainly by reducing the amounts of sphalerite in less liberated sizes rather than by increasing the liberation of the sphalerite within a given size Fraction.

Jan 1, 1993

By A F. Idziak

The aim of the present study was an application of coal optical property measurements for analysis of paleostress field existing in fault zones of the Upper Silesian Coal Basin (USCB) during the coalification of organic matter. Measurements of vitrinite reflectance were carried out on coal samples taken near a hanging stope of the Klodnicki fault. Other samples had been taken in vicinity of the Krzyzowicki fault. The Klodnicki fault is one of the main tectonic discontinuities in the northern part of the USCB. It is postulated that its origin is related to the deep-rooted latitudinal discontinuity in crystalline basement of the basin. The Krzyzowicki fault is located in the western part of the USCB where fold tectonic style dominates. Vitrinite, one of the basic components of hard coal is generally considered as optically anisotropic material. Anisotropy of physical properties is induced mainly by stress, which arranges vitrinite structure. Vitrinite anisotropy can be described by an ellipsoidal model called reflectance indicating surface (RIS) which is a geometrical representation of the optical anisotropy tensor. The investigation of the RIS for vitrinite was carried out on coal samples. The apparent maximum and minimum reflectance values measured for a single vitrinite particle were plotted against corresponding bireflectance to construct the reflectance crossplot. Interpretation of this plot yielded the magnitudes of the RIS three principal axes. The data obtained point to differences in optical anisotropy of coal under the study. The coal samples taken from block tectonic zone near the Klodnicki fault had mean reflectance value of less than 0.80 per cent. Their anisotropy coefficients were about 0.1. Optical properties of coal changed from the biaxial positive in the western segment of the fault to the biaxial negative in its eastern part. It suggests that past tectonic stress was greater in the western part of the zone than in the eastern one. Coal originated from a fold tectonic zone at the vicinity of the Krzyzowicki fault has mean reflectance value much greater than from previous region (ÿ1.20 per cent). Its optical anisotropy coefficient is equal to about 0.07. It suggests that paleostress field was more isotropic. The presented study shows the usefulness of coal reflectance measurements in the analysis of paleostress field existing during coalification process.

Jan 1, 2003

By C J. Ptacek, J G. Bain, D W. Blowes

The passive interception and in situ treatment of groundwater using permeable reactive barriers (PRBs) has, within the past decade, become an accepted remedial approach to the control of plumes containing dissolved organic and inorganic contaminants. Since the first applications of the technology in the early-1990s, there have been several field-scale PRBs that have provided excellent treatment of dissolved metals in groundwater. Additional commercial applications and demonstration projects continue to be developed. Three field-scale applications and supporting laboratory columns have shown that several thousands of milligrams per litre of sulfate, more than 1000 mg/L iron, and several tens of milligrams per litre of other metals can be removed from groundwater by PRBs that promote sulfate reduction. The reactive materials, which incorporate various forms of organic carbon, promote microbially mediated sulfate reduction, the generation of hydrogen sulfide, and the subsequent precipitation of sparingly soluble iron and other metal sulfide minerals. Effective performance has been achieved by PRBs installed at a mine-tailings impoundment in 1995 (Sudbury, Ontario) and at an industrial facility (Vancouver, British Columbia). These PRBs have removed iron and other metals from groundwater. Similar materials were also used to create reactive layers within test cells directly in a tailings impoundment in 1999 (Timmins, Ontario) with the objective of removing iron and sulfate from the pore water before it migrates from the tailings impoundment. Zero-valent iron (ZVI) has been shown to provide excellent removal of chromium (VI) in a PRB, which was installed at the US Coast Guard facility in Elizabeth City in 1996, by reduction and precipitation reactions. Laboratory tests have also shown that ZVI reduces As(V) to As(III), which is subsequently removed from solution by co-precipitation with iron oxyhydroxides. In groundwater containing sulfate, ZVI and mixtures containing organic carbon can promote sulfate reduction and the subsequent precipitation of sparingly soluble arsenic and other metal sulfides. A trial PRB system was installed in 2001 and was shown to attenuate arsenic and other electroactive metals in groundwater at an industrial facility in northwestern Ontario. Basic oxygen furnace (BOF) slag, a waste material generated by the steel industry, has shown excellent potential for the removal of phosphate, elements such as arsenic and water-borne pathogens from groundwater in field and laboratory tests.

Jan 1, 2003

Thank you for the invitation to this forum today. I have a hectic schedule in the Mabo legislation process but it is important not to lose sight of the bigger picture and to attend today to talk to you about the Government's role in the development of our country.More importantly, I hope over the next couple of hours to get some feedback on developments in this area from people very much involved on a day to day basis.

Jan 1, 1993

The reasons for including treatment of water in Whites and Intermediate open cuts in the overall rehabilitation strategy are given in the introduction. The target quality of the treated water also is discussed. Equipment selections are reviewed and reasons given as to why certain choices were made. The differences between this plant and an ore dressing mill are highlighted. An outline of the operating procedure is included along with a basic flowsheet. Cost estimates are briefly Discussed.

Jan 1, 1984

Direct seeding or regeneration of vegetation in Australia has been occurring in nature for about 400 million years! From the 1870's till the 1930's, direct seeding by man was used in the south-west of Victoria as a method of re-establishing native vegetation on broadacre farmland. The introduction of improved exotic pasture grasses and the wide-spread use of superphosphate from the 1930's lead to its demise as a farmland revegetation technique.

Jan 1, 1992

By J H. Kyle

Cyanide is a significant cost in gold processing, as well as an environmentally sensitive issue. It has been suggested that precipitation of cyanide from leach liquors as copper-iron-cyanide compounds such as Cu2Fe(CN)6 may account for part of the total cyanide consumption. This may be especially true for ores that are rich in both copper and iron minerals. Ammonia addition has been shown to decrease the cyanide consumption by copper. Cu2Fe(CN)6.xNH3 precipitates have also been postulated to form during conventional cyanide detoxification processes, using oxidants such as SO2/air, with ammonia arising as a breakdown product from the oxidation of free cyanide. The present work has examined the conditions under which such precipitates may form, particularly in gold plant process and detoxification liquors. Ammonia and pH were found to have a large effect on the extent of precipitation. The compounds that were formed were found to comprise mainly Cu2Fe(CN)6.7H2O, as well as a range of NH3-bearing variants. The stabilities of the various precipitates are important from an environmental perspective. The long-term stability of copper ferrocyanide precipitates in tailings dams may be a problem under alkaline conditions and when some free cyanide is present, elevating the measured total cyanide in solution significantly. Case studies including data from actual plants are also considered, and the importance of these effects is reaffirmed from these results.

Jan 1, 2000

By Leigh G, Gottleb G, Wilkie G

The estimation of particle liberation is important in the study of mineral concentration. With simple systems, where the densities of the components are low, the liberation can be studied directly by density fractionation. For most practical systems, and particularly for the dense, complex sulphides, the only method known is by measurement in polished section. There are two major difficulties with such measurements. Firstly, the measurements themselves are difficult and considerable care is needed before reproducible results can be achieved. Secondly, a well known stereological problem arises which gives the estimates an inherent bias. The paper discusses both aspects of the problem. The practical features of measurement are treated in detail and a method described which has been developed and proven to give reproducible estimates of the liberation in the section. This discussion relates to automated measurements by QEM*SEM and presents a way of estimating the confidence limits within which measurements lie. Comparisons are shown between measurements made by the traditional manual optical technique and automated equipment. Stereological reconstruction is also discussed briefly. Several methods have been presented in the literature but all are complex and none is yet widely accepted. Area measurements are less biased than linear estimates so a practical approach is to use area measurements in uncorrected form. The topic is still being actively researched so it is expected that one method will soon emerge as the standard technique.

Jan 1, 1993

THE writer of this paper well realizes that the majority of engineering and metallurgieal works have from time to time evolved mechanical devices which are of great value as regards application in an operating plant.Many of these deviees would not be apparent to an individual making a brief inspection of works such as these, and it is for this reason that the writer proposes to outline a few of the devices which have been evolved by the engineering department of the Broken Hill Associated Smelters Pty. Ltd.NOVEL METHOD OF MACHINING A SPHERICAL JOINTFig. 1 represents one half of a casing for a ball-joint coupling. In the ordinary methods of boring an external spherical casing, that is with a radius bar attached to the tool rest of a lathe, there is always an error in the bore. It has two flat sides, and this error is inherent in the ordinary orthodox method and cannot be corrected. The engineers of the Broken Hill Associated Smelters Pty. Ltd. undertook a job that had to be extremely accurate, and the tool shown in Fig. 2 was evolved. The tool is not exactly fool proof, but in the hands of an average mechanic an absolutely perfect FIG. 1. sphere can be bored. The casing has to be held in the lathe in such a manner that one half can be removed without affecting the setting of the work. The business end of the tool is then placed inside the...

Jan 1, 1922

By C Fountain

It is commonly known that copper smelter terms include penalties if the concentrations of elements, such as arsenic, mercury and fluorine, exceed stipulated limits. It is less commonly known that the behaviour of these elements in the smelters can depend on the processes used to treat the concentrate. The principle behind the penalties is to compensate the smelters and refineries for additional costs caused by the presence of the penalty elements, but these costs will vary depending on the process used and the location of the smelter.The issues caused by the minor elements include effects on the occupational health of smelter workers, increased environmental disposal costs, increased operating costs and reduced cathode copper quality.The effects of minor elements can be surprising. High levels of arsenic in concentrate are considered undesirable, but some smelters add arsenic to anode copper to improve the performance of the refinery.Excess concentrations of some elements will result in rejection of concentrates by smelters. China has blanket import bans on copper concentrates with concentrations of lead, arsenic cadmium, fluorine and mercury exceeding specified levels.This paper will review the behaviour of minor elements in smelters and refineries, explaining the deleterious effects of each of them, to provide a greater understanding for people and organisations wishing to market copper concentrates.CITATION:Fountain, C, 2013. The whys and wherefores of penalty elements in copper concentrates, in Proceedings MetPlant 2013 , pp 502-518 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

The Writer's knowledge of this region began in 1912, while he was with the Geological Survey of South Australia, and, investigated the principles governing the occurrence of fresh and saline ground waters in the area then being opened for closer settlement by the railways under construction from Port Lincoln.These field investigatons for water were extensive rather than intensive, but other examinations covered certain mineral aspects. The Writer also has' had the benefit in the preparation of this paper, of later work done by others, as well as of the monumental earlier work in South Australia by the late H. Y. L. Brown.AREAThe area dealt with, approximately 21,000 square miles, lies to the south of the latitude of Port Augusta.TOPOGRAPHYAs a whole the region is one of low relief, but the Olinthus Range, west of Cowell and north of Cleve, reaches an elevation of 2,000ft., while there is als0 a high area west of Port Lincoln and Tumby Bay. At the north end of the region the Gawler Ranges are formed by the dissection of a thick sheet of felspar porphyry extending over two degrees of longitude, by a width of 20 to 70 miles, with fairly uniform maximum elevations of the undissected portions of the order of 1,000 ft. above sea level. South of the Gawler Ranges are many isolated ridges up to 1,000ft. in height, generally sedimentary and trend...

Jan 1, 1951

By S Johnston, L Howe, S Stevens

Regulators have an important role to play in fostering and enabling reliable, effective, environmental management. Given this, it is perhaps surprising that there has been relatively little debate on exactly how regulators can enhance their own approaches, in order to promote improved outcomes overall. The authors argue that applying research on High Reliability Organisations, as well as the University of Pennsylvania’s Penn Program Framework for Regulatory Excellence, to regulators has the potential to facilitate positive environmental results across the mine life cycle.

Aug 2, 2023

Mining engineering, metallurgy and minerals-related geology have proud traditions and are essential professions to support a safe and sustainable minerals industry. However, the future of these professions is under threat. The courses that produce such graduates are disappearing worldwide and the number of graduates available to enter the industry has been falling in English speaking countries for at least a decade. It is unlikely that this problem will be remedied by æsupply and demandÆ. Instead, some active intervention is required.

Jan 1, 2004

By F

Ore reserve estimation has been described as the most individualistic, the most prickly and even the most controversial of all the technical aspects of the mining profession. This symposium is a great opportunity to look at the present state of the art and full marks must go to the Sydney Branch for organi- sing it at this time. The first essential of good ore esti- mation is probably an awareness of the uncertainties involved, and the possible impli- cations of these uncertainties.

Jan 1, 1979

In the wake of the United Nations Conference on Environment and Development (UNCED) held in Rio de Janeiro in June 1992, evolved AGENDA 21. This document which was adopted at the Conference, provides a global action guideline for sustainable development into the 21st century.Sustainable mining requires a complete understanding of the `mineral cycle', including government legislation, mineral exploration, mining operations, rehabilitation, product use, re-cycling and waste disposal that takes into consideration associated social and environmental considerations and achieves economic objectives.

Jan 1, 1993

By Middlebrook PD

The problems of education and research in the extractive metallurgy area are being tackled by the University of Melbourne through activities centring on the Department of Chemical Engineering. The establishment of the G.K. Williams Laboratory and the enhance- ment of the teaching of material relevant to extractive metallurgy in the Chemical Engineering course aim-at providing graduates and experienced researchers for the industry and at providing a strong research group carrying out industrially significant research in the area of pyrometallurgy.

Jan 1, 1986

By Hamilton LH, Campbell PB

Since fundamental research in applied coal petrography is carried out mostly on polished surfaces, backscattered electron microscopy is most applicable for studying coal in the SEM. By employing this technique coal macerals can be easily identified , and information on the relations between maceral groups, mineral matter and trace elements are highlighted by grey level contrasts. This type of information is valuable in coal technology and cannot by normally revealed by the light microscopy (e.g. the distribution of inherent mineral matter).

Jan 1, 1989

By Tilyard P. A

Pasminco has tested a Valmet ES1 ceramic disc vacuum filter at its Broken Hill concentrators. On lead and, particularly, zinc concentrates at the ZC Mine the filter performed well but on North Mine lead concentrate problems were experienced with deposition on the disc, which resisted both ultrasonic and acid cleaning. A preliminary financial analysis showed that the application of the filter at the ZC concentrator was worth pursuing. Accordingly an ES30 machine has been hired for plant evaluation.

Jan 1, 1989

The BHP Steel Group embarked on a Total Quality Control (TQC) programme in 1984 in response to enquiries from a major customer regarding procedures for quality in materials supply.The TQC initiative has been adopted by all seven Divisions of the Steel Group and covers a broad and comprehensive range of management and workforce improvement initiatives.The development of the TQC initiative in the Collieries Division of BHP Steel over the past eighteen months has resulted in important experiences and leanings.

Jan 1, 1991