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By P. Cleyle, J. H. Masliyah, R. S. Chow, Z. H. Xu, Z. A. Zhou

Bubble nucleation in water under dynamic conditions was investigated using an autoclave at an air saturation pressure of 7 atm. Agitation during air saturation of water was found to be crucial in enhancing tiny bubble formation. More bubbles nucleated on hydrophobic surfaces at a higher agitation rate, due to cavity formation by the more intense hydrodynamic conditions. Flotation recovery of bitumen from oil sands demonstrated a significant role of bubbles nucleated in water: more than 50-170% increase in bitumen recovery from different oil sands was obtained by using air supersaturated than the regular water.

Jan 1, 2009

By D. R. Lentz, S. H. Mcclenaghan, J. A. Walker

"Abstract - The Orvan Brook deposit is one of several (Zn+Pb>>Cu)-rich sulfide deposits hosted by the Spruce Lake Formation (California Lake Group) in the northwestern part of the Bathurst Mining Camp. This parautochthonous deposit is hosted by a narrow band of highly deformed, locally graphitic shale that appears to conformably overlie felsic volcanic rocks of the Spruce Lake Formation, and is in tectonic contact with overlying mafic volcanic and related sedimentary rocks of the Canoe Landing Lake Formation. The Spruce Lake Formation is dominated by felsic volcanic rocks and subordinate fine-grained sedimentary rocks, and mafic volcanic rocks (Canoe Landing Lake member). The felsic volcanic rocks can be divided into aphyric and feldspar-phyric rock types. The feldspar-phyric rocks and a few of the aphyric varieties have a Zr/TiO2 ratio of 0.06, and fall into the California Lake Group field on a Y/TiO2 versus Zr/TiO2 diagram. In contrast, the aphyric felsic volcanic rocks have Zr/TiO2 ˜ 0.09 and are marked by high Zr and Th, which is consistent with highly fractionated felsic magma of Spruce Lake affinity. Major and trace element analyses of host rocks suggest that weak to moderate hydrothermal alteration developed on the south side (stratigraphic footwall) of the deposit, which is consistent with a north-younging succession. The sulfide lens strikes east-west for approximately 2.3 km, extends down-dip for at least 500 m locally, and has an average thickness of between 0.75 and 1 m, but is locally up to 5.5 m thick. The contacts of the massive sulfide lens with its host rocks are invariably sharp. Host rocks show evidence of intense ductile deformation as well as later brittle deformation. Compositional layering and sulfide breccia textures in the sulfide body are interpreted to result from deformation or tectonic enhancement of original primary layering. The deposit contains an estimated resource of 2.69 Mt grading 1.73% Pb, 5.95% Zn, 0.37% Cu, 72 g/t Ag, and 0.9 g/t Au. Similarities in bulk d34S between the Orvan Brook (+8.6‰) and the nearby Cu-rich McMaster deposit (+8.2‰) suggest a common depositional setting."

Jan 1, 2006

By J. Visman

"SummaryThis paper is presented as part of a programme to show the steps taken by industry and others interested in supplying a solid fuel of constant quality to 'satisfy a consuming market. The paper deals with the general principles underlying quality control in coal preparation plants, namely, constant quality and close adherance to acceptance limits. It also describes how control of ash content is ""generally hampered by the problem of coal sampling .and the long duration of the ash analysis and how these difficulties may be overcome.Quality control can be effected in several ways. Thorough blending wll reduce variations appreciably, except those of long trend. The latter can be detected by automatic sampling and quick ash analysis. At present, under favourable conditions, a system of half-hourly ash determinations with an accuracy of 0.5 to 1.0 per cent can be realized, to the effect that trends with a 'wave length' of more than two hours cu be eliminated within the limits of accuracy of the ash figures. The general solution of the problem is a combination of blending, accurate sampling, quick ash determination, and statistical analysis of the pattern of ash distribution.The use of statistical methods of analysis, such as the t test and F test, is •discussed at some length in order to emphasize the importance of the correct evaluation of observational data if there is to be confidence in the validity of test results.General ConsiderationsCOAL, as a fuel, is too cheap for a long haul across the country. The limiting distance depends on the price of the local competitive fuels, and, as the price depends to a great extent on quality, so does quality, to the same extent, command the market."

Jan 1, 1952

By J. H. Canterford

The nickel industry in Australia has followed the general pattern apparent in many other regions - lots of ups and downs, successes and failures, but always plenty of challenges. Some of these can be attributed to local geographical and infrastructure factors, others to a healthy mix of corporate good luck and management countered by decisions that, in retrospect, were less than optimum. The roles of several entrepreneurs have certainly added plenty of spice! In terms of processing technologies, there was an initial heavy reliance on the use of "off the shelf' commercially proven processes such as ammonia leaching of concentrates and mattes, and flash smelting. Over the past decade there has been an increasing dominance of plant modifications and process technologies that have been developed "in house" in order to enhance project economics and exploit lower grade and more complex resources. This presentation provides an overview of the past 40 years of the major developments in the Australian nickel industry and concludes with some guesses as to where we will be in another decade or so.

Jan 1, 2005

By M. J. Nicol, T. Moyo

Ammoniacal solutions are an effective lixiviant for the oxidative dissolution of some mineral sulphides. A detailed study of the anodic dissolution of chalcopyrite in ammonium sulphate-ammonium hydroxide solutions has been carried out using cyclic voltammetry, chrono-amperometry and rest potential measurements. The role of the copper(II)/copper(I) redox couple in the oxidation process has been evaluated. Rest potentials have been found not to be affected by oxygen but to increase with an increase in initial copper(II) concentration. Pseudo-steady-state anodic current densities measured in the absence of copper(II) ions at the rest potentials obtained in the presence of copper(II) ions increase with increasing concentration of copper(II) ions, confirming the positive effect of copper(II) ions on the rate of dissolution of the mineral. Cyclic voltametric and chrono-amperometric data show that in the absence of initial copper(II) ions, the rate of dissolution in the presence of dissolved oxygen is significantly lower. These results confirm that the effective oxidant for the mineral under the conditions of the study is copper(II) and not dissolved oxygen. Coulometric measurements have been used to establish the stoichiometry of the anodic reaction at different potentials.

Jan 1, 2014

By D. Yamada, T. Tanaka, N. Inouchi, J. Nakahigashi, H. Yoshimura, T. Nonishi

The use of cereal food materials as lubricants was investigated in an attempt to develop nonpolluting lubricants. Suspensions of wheat flour in water and other types of cereal food lubricants were prepared and their friction coefficients measured. The results indicate that a cereal food lubricant containing 30% lipids, 2% proteins, 60% carbohydrates and 0.6% calcium carbonates has the lowest friction coefficient for a sheet (cpTi-1). As example applications, the lubricant was tested with a forming press and a screw-fastening device. In both applications the cereal food lubricant performed relatively well in comparison to conventional lubricants and thereby has potential for practical applications.

Jan 1, 2006

By David Davidson

Overview- Points To Be Addressed ? Review the building blocks of a successful and vibrant industrial economy ? China?s current position in the global economy ? China?s voracious appetite for raw materials ? Distortion in import/export trends ? Areas of strategic importance for China - Steel and its components - Agriculture self sufficiency - Energy now and for the future ? Do current valuation techniques fairly value ?strategic? assets? China ? The Economical Miracle - Massive shift in population from rural to urban - ?Middle class? growing rapidly, hence strong consumer growth - China is the manufacturing center for the world ? cheap labour and - modern facilities - Infrastructure build out ?US$585b stimulus package and 5 year plan - Rail ? 30,000 kms of new track planned by 2020 - Power ? 50% capacity increase, including 35 nuclear reactors - 100 major new airports - State of the art process and manufacturing facilities - Port capacity ? 100m TEU capacity increase by 2020 Class 1 national highway ? 35,000 km?s by 2020

May 1, 2010

By Deepak Bhadouriya, Saurabh Singh, Aditya Raj Suman

"An experimental study of chemically enhanced filtration and dewatering of fine coal slurry with and without additives was carried out. The experiment involved determination of effect of slurry concentration, additives (cationic, anionic and nonionic), filter area, filtration velocity, particle size and cake resistance on dewatering and filtration using vacuum filtration cell. Finally, the rate of filtration and dewatering and optimum amount of additives used were determined under suitable filtration condition. Overall, it was found that the filtration and dewatering characteristics were enhanced by increased slurry concentration, larger filter area and larger particle size. In addition of additives, the kerosene was found to be best for enhancing the filtration which yielded cake moisture reductions of approximately 17% by weight. At optimum dosages, the final cake moisture contents were reduced by 3.6% and 5.8% by weight using the appropriate surfactant and flocculent, respectively.INTRODUCTIONFor India, it is estimated that coal constitute a principal source of energy for the next several decades. It is majorly used at thermal power plants to generate electricity and also to a great extent in steel and cement industry. It has been observed that its consumption is increasing so as to meet the energy requirements of the country. It has been found that in a coal preparation plant; approximately 20-25 percent coal is of the mined coal of the range below minus 0.5 mm (28 meshes). Generally, this fine fraction is discarded due to its high cost of processing and further utilisatisation is very minimal. But with ongoing research and development for advanced clean coal technology, various new techniques have been evolved to maximize the utilization of available coal. In recent time technologies such as column flotation, cleaning of fine size coal to lower the ash content and low pyretic sulfur is feasible at high recovery value. But in various researches it is found that one of the biggest hurdles in utilization of fine coal cleaning technology by the coal industry is the economic dewatering of the fine clean coal product. Thus, until an economical and practical solution to dewatering of fine clean coal is achieved, the efforts devoted to developing fine clean coal technology will be wasted. In this paper an effort toward enhancing and developing the optimum technique of dewatering and filtration of fine coal slurry has been made."

Jan 1, 2016

By Asbjørn Solheim

The service life for aluminium reduction cells is often limited by the cathode carbon, due to preferential wear along the periphery of the cell leading to the so-called "W" wear pattern. The reason for this preferential wear is not well understood. Two mechanisms are suggested in the present paper; 1) non-stationary dissolution of aluminium carbide into a layer of sludge that periodically forms and disappears, and 2) electrochemical formation and dissolution of aluminium carbide within an aluminium carbide layer containing bath-filled pores. The latter mechanism may be related to the high local current density at the periphery of the cathode.

Jan 1, 2011

By B. C. Tripathy, S. K. Padhy, R. K. Paramguru, Pinak Patnaik

"Cobalt is regarded as technology enabling metal among the less abundant metals found in the earth crust. Electrodeposition of the metal from aqueous sulphate solutions is the preferred technology for its commercial production. Certain additives are added in the electrolytic bath during electrodeposition for the production of uniform, smooth and bright deposits of cobalt metal with higher current efficiencies and lower energy consumptions. A detailed investigation has been carried out to determine the effect of additive Sodium octyl sulphate (SOS) on the electrodeposition of cobalt. The results indicated that the additive apart from increasing the current efficiency enhanced the quality of cobalt electrodeposits. A maximum current efficiency of 98.4% was achieved at 10 mg/L SOS. The presence of SOS in the electrolytic bath did not result in any noticeable change in the crystal orientation of the cobalt electrodeposits except at higher concentrations (50 g/L) of the additive. Scanning electron micrographs indicate that smooth, compact and uniform deposits of cobalt were obtained at 10 mg/L of the additive beyond which there is detoriation in the quality of deposits. Polarisation of the cathode was seen in the presence of SOS. The effect of SOS on the electro kinetic parameters: Tafel slope (b), transfer coefficient (a) and exchange current density (I0) has also been investigated.INTRODUCTIONCobalt is recognised to be a strategic metal among the various base metals, owing to its numerous applications in various industries. Cobalt as a metal finds its use in the preparation of rechargeable batteries, as an alloying component in the manufacture of space craft and jet engines, as a drying agent for paint varnishes, ground coats for porcelain enamels and in the manufacture of the catalysts for the petroleum and chemical industries (Davis, 2000). Although there is a huge demand of the metal the supply of the metal is limited due to its scarcity in the earth crust. The metal comprises of only 0.02% of the earth’s crust for which the metal is recovered from various ores of nickel and copper as a byproduct (Hawkins, 1998). The present day techniques for cobalt production includes mostly hydrometallurgical methods which are preferred over the earlier used pryometallurgcial methods carried out for the metal production. Almost 70% of the world’s cobalt produced currently is from hydrometallurgical techniques in which electrodeposition of the metal from aqueous solutions is the final step for metal production (Verney, 1988). The most preferred route for electrodeposition of cobalt metal involves a sulphate medium (Das and Subbaiah, 1984; Lenthall and Bryson, 1997; Sharma et al., 2005)."

Jan 1, 2016

By J. C. White

This paper, after a brief introduction giving the history and geology of the area, deals with mining operations at the Copper Mountain mine of Gaspe Copper Mines, Limited. It discusses development operations, and then goes into the mining methods employed, covering drilling, grade control, blasting practice, loading and hauling, and the road and service machines used.

Jan 1, 1969

By R. R. Song, Q. Li, H. Xing, X. C. Wei

Geomechanical modelling of fault stability is an important part of CO2 capture and storage (CCS) research program to ensure its viability and long-term safety. Storage of CO2 in deep subsurface reservoirs requires estimates of sustainable fluid pressures that will not induce fracturing or fault reactivation which could cause fault slip. More importantly, fault slip gives rise to seismic waves, which inflict severe damage to the cap rock of the reservoirs and may result in leakage pathways for the buoyant plume and thus compromise the integrity of seal formations. In this study, we generated a numerical model tuned towards conditions usually encountered in the Shenhua CCS demonstration project in Ordos basin. In particular, with the purpose of evaluating the sensitivity of the parameters as well as their relationships with the moment magnitude of the seismicity, a variance-based sensitivity analysis was adopted for importance ranking of the uncertain input parameters of the given model. However, such flow models could involve one or several spatial inputs, for instance, fault dip, distance between fault and the injection well, friction angle of fault, permeability of fault, Young's Modulus of fault, injecting pore pressure and the stress field. Studying the sensitivity to each of these spatial inputs motivated the present work. The results led to the following conclusions: fault depth and fault dip significantly affect the behavior of the fault and the fault slip becomes violent with the fault depth increasing and fault dip decreasing. Furthermore, the results indicate that slip time increases with the fault dip decreasing and decreases with permeability of fault increasing. In addition, the calculation of seismic moment and moment magnitude of an earthquake demonstrates that it rises significantly with the decrease of fault dip and the increase of fault depth, and it decreases with the rising stress field. The results show that variations of the only controllable parameter injection pressure do not show great influence to the fault behavior compared with other geological factors, which imply site selection is extremely important for the CCS projects.

Jan 1, 2015

Background ArcelorMittal?s (formerly QCM?s) Port Cartier iron ore pelletization operations 2 side-by-side induration furnaces each producing 578 t/h of cured pellets Firing No. 6 fuel oil and coke breeze (in bed) Very large heat losses to be addressed primarily by gas recirculation

May 1, 2011

By V. I. Ryaboy, V. P. Kretov, I. V. Ryaboy, E. D. Shepeta

This paper studies the features of known and newly synthesized dialkyldithiophosphates and reagents with thioamide groups when separating copper-containing and arsenic-containing minerals in the flotation of skarn-scheelite-sulphide ore at the Primorskaya concentration plant. The optimization of dialkyldithiophosphate collectors was based on the study of their surface activity at the liquid-gas interface and estimated hydrophobic abilities. The flotation experiments show that the selectivity of action of the reagent increases with an increase of its surface activity and a reduction of hydrophobic ability when separating chalcopyrite and arsenopyrite. IMA-225-5 was proposed as a more efficient dialkyldithiophosphate collector, which increases the recovery of copper by 2.8% compared to the industrially used collector IMA-I413. Selection of the optimal structure for reagents with thioamide groups (derivatives of thionocarbamate and thiourea) was carried out according to their acidity and the presence of hydrophilic particles in their structure. Calculations were performed depending on the pH of the solution of chalcopyrite to determine the optimum reagent sorption and to further optimize the structures of these reagents. The tests with reagents with thioamide groups show an increase in copper recovery by 3-4% together with a significant increase of arsenic content compared to IMA-225-5. As a stronger collector with thioamide groups, it was recommended to use sample 234, which belongs to the thiourea derivatives. IMA-225-5 was recommended for industrial tests at the Primorskaya concentration plant. Thus, this study has shown that using dialkyldithiophosphate is more appropriate if it is necessary to increase the selectivity of separation of copper-containing and arsenic-containing minerals, and using reagents with thioamide groups, or their combinations with dialkyldithiophosphates, is more appropriate if it is necessary to increase the recovery of copper or the quality of copper concentrate with less selectivity of the process.

Jan 1, 2016

By J. C. Hampton, L. A. Matzar, C. R. Gamwell

In geomechanics, conducting uniaxial or triaxial compression tests require samples to be prepared to a certain length-to-diameter ratio. This ratio is typically defined as 2:1 (length to diameter) and is accepted as a common standard for all materials on which mechanical properties testing is performed. Variations in sample length can cause changes in measured strength properties across multiple material types, such as cement, rock, or soil. Within the oil and gas industry, it is not uncommon to receive samples for technical services work that are slightly under or exactly the length requirement before surface grinding and sample preparation. Many of these samples are discarded from uniaxial and triaxial compression tests and used in another manner; therefore, it is necessary to study the length-to-diameter ratio in efforts to understand the limits and validity of testing samples that are slightly out of the 2:1 ratio. This paper discusses uniaxial compression tests performed using Berea sandstone and a standard cement mixture of 2.54-cm diameter to study changes in rock strength and properties. Compressive strength for each lengthto- diameter ratio over a range of 0.5:1 to 2.2:1 was measured. The investigation was extended to study near-end effects, where the sample length is near, but not exactly twice the diameter. It was discovered that the cement samples conformed reasonably well to the suggested ASTM correction factors. The sandstone did not conform to the correction factors and further analysis is required to develop a correction factor unique to the material. Near end effects, in both the cement and Berea, were found to increase compressive strengths, especially when the L/D of the samples was increased slightly over a 2:1 L/D.

Jan 1, 2015

By O. Espinoza Ortega, S. Song

A process scheme has been devised to improve the silver recovery and the grade of concentrates from the scavenger concentrate of a silver ore flotation circuit. Based on modal analysis studies it was found that silver sulfide minerals in the scavenger concentrate were associated as simple binary particles and finely disseminated in sulfide and non-sulfide gangues. Fine grinding of the concentrate improved the grade-recovery curve of silver to a very limited extent owing to heterocoagulation between liberated fine silver sulfides and coarse particles of gangue. This heterocoagulation phenomenon was prevented by grinding the concentrate in the presence of the dispersing reagent sodium hexametaphosphate. The silver grade-recovery curve was improved by practicing. before the conventional flotation step, a selective aggregation step for the fine silver sulfide particles using the non-polar oil kerosene, the sulthydryl collector Aerophine 3418 and conditioning the pulp under strong agitation conditions.

Jan 1, 2004

By E. A. Roux

As the first mine-to-metal zinc operation utilising atmospheric leaching, solvent extraction and electrowinning, Skorpion Zinc faces unique challenges and opportunities. One of these challenges is found in the solvent extraction circuit, in which di-ethylhexyl phosphoric acid (D2EHPA) is used as the organic extractant. Although D2EHPA is an excellent extractant for zinc, it suffers from the co-extraction of ferric iron, which is produced during leaching and by the corrosion of the grinding media. This situation is partially mitigated by iron precipitation in the neutralisation step prior to solvent extraction. Unfortunately, some ferric iron still reports to the solvent extraction process. This leads to a slow build up of iron in the organic phase. Chemical stripping is used to maintain the Fe concentration at an acceptable level. In this paper, the efficiency of the iron removal process is discussed.

Jan 1, 2006

By Agbo Chima

Low-lying sections of open-pit mines accumulate water, especially during the rainy seasons, preventing access to resource-bearing areas. To sustain mining operations, the water must be lifted out of the flooded pits at a high flow rate using pumps. These pumps need to be mobile so that they can be removed during drill-and-blast operations. Most mobile pumps rely on diesel engines with high maintenance requirements. A special pump design was developed to address the unique needs of open-pit mining while making the dewatering process more sustainable. Using the target flow rate and head data, an efficient pump was designed, encased, and deployed in the open pit. A variable speed drive (VSD) was installed in a protective skid so that the pump could be tuned to match the preferred flow rate at any point during its operation. This system was tied to the national electrical grid instead of being powered by diesel pumps, which reduced the carbon intensity per kilowatt-hour. The high availability, low maintenance requirement, and greater reliability reduced the use of spare parts, the fuel consumption, and the logistics associated with operating the pump. This further reduced the carbon footprint of the dewatering process. This paper provides some of the two-year performance metrics for a deployment in West Africa. With a focus on availability, maintenance costs, average cost per volume lifted, and carbon footprint, this encased pump system is compared to the diesel-driven pumps that it aims to replace.

Jan 1, 2023

By Oleg G. Tovmachenko

We have studied optical properties of fluorescent nanoparticles. These particles consist of a metal (gold/silver) core, an empty and a dye labelled silica shells. The different dye molecules with moderate quantum yields (about 0.3) has been used. Almost all of types of nanoparticles show fluorescence enhancement. This enhancement is strongly dependent on the degree of the overlap between the surface plasmon band of the metal and the absorption/emission band of the dye molecules. The results are interpreted in terms of competition between local field enhancement and quenching of fluorescence by the metal surface.

Oct 1, 2003

By P. W. A. Mayer

"As the push toward the northern regions of Canada steadily increases to exploit the rich mineral reserves, interest is steadily rising in respect to accessibility and climatic conditions and the problems posed thereby. In twelve years of operation, the Iron Ore Company of Canada, and associated companies, have found, through advanced technology, ingenuity and, most of all. need, some of the answers to the running of a profitable year-round open-pit mining operation."

Jan 1, 1966