Search Documents

By V. R. Miller

The Bureau of Mines has developed a technique to separate and recover the three major components, Pb, Zn, and Cd, from lead smelter flue dust. This research was conducted as part of the Bureau's effort to reduce environmental conflicts and occupational hazards associated with mineral-processing operations and to recover valuable constituents in emissions and effluents. The laboratory process utilizes sulfation roasting of the flue dust followed by water leaching to extract over 95 pct of the cadmium and zinc. Ninety-nine percent of the cadmium was recovered from solution by cementing with zinc dust, and zinc was electrowon from the resulting solution after purification. Zinc electrolysis was carried out in a 1-liter cell at 35° C with a cathode-current density of 8 A/dm2 in a solution containing 65 g/l Zn++ and 180 g/l H2S04, Current efficiencies of 80 pct were obtained. The leached residue consisted largely of PbS04, which was converted to PbC03 and leached with H2SiF6 to produce PbSiF6 electrolyte. Ninety-five percent of the lead contained in the residue was converted to electrolyte. Lead was electrowon from solutions containing 70 gil Pb++ and 90 g/l H2SiF6 using a lead cathode, Pb02-coated titanium anodes at 28° C, and a current density of 1.6 A/dm2. Current efficiencies approaching 92 pct were obtained. Accessory minerals such as cobalt and nickel were separated into purification residues and liquor.

Jan 1, 1982

By Stephen R. Wilson

This paper is one of a series published by the Bureau of Mines on the mineral resources of the Nation. It describes briefly the occurrence of sodium sulfate in Salt Lake and Tooele Counties, Utah, presents data on sampling, and describes ex-traction and refining raw material and a mining research project that has been conducted on the deposits. ACKNOWLEDGEMENTS Acknowledgments are given to the Tintic Standard Mining Co., Salt Lake City, Utah, and Bartlett Chemicals, Inc., New Orleans, La., for permission to use data obtained by the companies. The authors also acknowledge the courtesy of J. A. Marsh and H. K. Thurber, geologists and mining engineers, for permission to use information in reports prepared by them.

Jan 1, 1957

By John A. Breslin

Three scale models of coal mine entries and mining machines were constructed by the Bureau of Mines to study the effects of ventilation parameters on dust concentrations where mining personnel would be working. A one-fifth-scale model of a coal mine entry with a drum-type continuous-mining machine and a one-sixth-scale model of an entry with a twin-borer-type machine were used as well as a one-fifth-scale model of a longwall face with a double-drum shearer. Methane was used as a tracer gas to simulate respirable dust in the models. The distance of the end of the brattice or tubing from the face was found to be more important than the airflow rate for the drum-type machine. Dust reductions greater than 90 pct were shown to be possible with a secondary ventilation system used with the twin borer and a dust collector mounted on the longwall shearer. Cutting-head speed had a significant effect on concentrations at typical positions of miners with the drum-type machine and longwall shearer but not for the twin borer.

Jan 1, 1976

By G. F. Kuncir

The funding tables included in this report were defined in support of an evaluation of the Advancing Oil Sale Mining Technology Program undertaken by The Aerospace Corporation. Because of the sensitive nature of the fiscal planning information, the tables have been separated from the main analysis report and given a limited distribution.

Jan 1, 1977

By John S. Berber

Tar produced as a byproduct from low-temperature carbonization of coal contains only small amounts of valuable lower boiling tar acids but relatively high percentages of high-boiling tar acids. These high-boiling tar acids are characterized by a high degree of alkylation and can be converted into the lower boiling homologs by catalytic treatment to remove the alkyl groups or decrease their chain lengths.

Jan 1, 1965

By P. G. Barnard

The Nation's steel industry is largely dependent on shipments of manganese from foreign sources for steel production. An adequate substitute for the manganese requirements of our present steel technology would improve our national self-sufficiency and also contribute substantially to the conservation of our manganese resources. As each of these objectives is a major interest of the Bureau of Mines, possible substitutes for manganese in steel were investigated. Titanium was selected as the most promising substitute because the published results of several investigations indicate that titanium would perform the most obvious function of the manganese in steel: The elimination of iron sulfide and its deleterious effects. The investigation involved extending the published data on titanium additions in steel to provide enough information for an accurate evaluation of the practical value of the substitute. Therefore, quantitative data were obtained on the partition of sulfur and carbon between iron and relatively small titanium additions.

Jan 1, 1962

By David R. Hanson

Experimental work performed by the Bureau of Mines in a laboratory environment has shown that the formation of failure zones within certain rock types is accompanied by the emission of significant amounts of radiofrequency (RF) electromagnetic (EM) energy. This radiation was detected using nonresonant, "electrically short," broad-band antennas. Rock types for which emission was observed include granite, quartzite, and taconite; sandstone and marble did not emit measurable radiation. Amplitude spectra of the radiation showed the energy to be concentrated between 10 and 40 kilohertz. These data indicate that emission is directional, but this has not yet been proven. In addition, amplitude of RF emission increases with increasing crack size. Since emission was observed only for brittle quartz-bearing rocks, it appears the formation of piezoelectric fields is a necessary condition for RF radiation. Plausible mechanisms for emission include rapid decay of piezoelectric fields accompanying the sudden stress release at failure and/or the acceleration of an "exoelectron plasma" through the intense local piezoelectric fields. Since emission appears to increase with the scale of failure, and since antennas do not need to be coupled directly to rock surfaces as with conventional geophones, the possibility of developing a portable system to monitor seismically active areas exists.

Jan 1, 1981

By D. R. Tesarik, R. W. McKibbin

Material properties affecting slope stability were measured in a large 50-year-old, partially consolidated rockdump located in an active open-pit mine. Field tests included single-ring infiltration and density. In addition, a nuclear depth-moisture gauge was used to measure water content in six stainless-steel-cased drill holes on the crest and an upper bench of the rock dump. Precipitation, evaporation, wind speed and direction, and temperature data were collected at a weather station installed on the dump’s crest. Laboratory tests included particle-size distribution, specific gravity, Atterberg limits, and water content. By measuring material properties of a rock dump presumed to be stable, the safety of miners working on or at the toe of old rock dumps constructed of similar material and located in a similar climate can be assessed.

Jan 1, 1999

By Norwood B. Melcher

This report describes preliminary experiments by the Federal Bureau of Mines on the practicability of adding raw pellets of taconite concentrate to blast furnace feeds. The usual industrial practice is to harden the pellets by heating before they are charged to the furnace. The Bureau research demonstrated that raw pellets could be successfully smelted in an experimental furnace with no significant change in coke consumption and only a moderate increase in dust losses. The dust loss was 43 pounds per ton of metal for an all-pellet charge, compared with 7 pounds per ton for an all-sinter charge. Raw taconite pellets undergo only slight degradation during charging to the furnace if 1 percent bentonite is used as a binder. INTRODUCTION Fines and concentrates must be consolidated or agglomerated into larger masses before they can be smelted in a commercial blast furnace. Such agglomeration is usually done by sintering, pelletizing, nodulizing, or briquetting. Sintering has been the more common practice, but with the advent of taconite concentrates pelletizing is increasing in importance.

Jan 1, 1960

By John J. Mulligan

Ear Mountain is an isolated mountain mass that rises abruptly from the coastal plain on the northwest shore of the Seward Peninsula. Geologically it resembles the more accessible Brooks Mountain and Cape Mountain areas to the southwest, being composed of a granitic core surrounded and partly capped by metamorphosed sediments. The occurrence of lode- and placer-tin deposits in this area has been known since the early 1900's, when the Seward Peninsula region was prospected extensively for both gold and tin. The Federal Bureau of Mines investigated the tin deposits in the Ear Mountain area during the 1953 and 1954 field seasons. The objectives were to delimit the areas in which tin minerals occur, as a guide to future prospecting, and to determine the amount of tin in the known prospects. Work by the Bureau of Mines included both placer and lode sampling.

Jan 1, 1959

By John J. Henn

Two lime sinter processes for recovering alumina from clay, the double-leach process and the single-leach process, are evaluated in this Bureau of Mines report. In both processes, clay and limestone are mixed and sintered to form calcium aluminate from which alumina is extracted as sodium aluminate by leaching with a dilute solution of sodium carbonate. The pregnant liquor is desilicated, then carbonated to precipitate alumina trihydrate which is recovered and calcined to a,-alumina. The fixed capital costs for plants producing 1,000 tons per day of alumina are $85 million for the double-leach process and $86 million for the single-leach process based on a Marshall and Stevens chemical equipment index of 240.0. Because plant locations are variable with respect to the proximity of clay and limestone deposits, a nomograph is included to determine operating costs at various delivered costs of clay and limestone. For plants at which the delivered cost of clay containing 30 percent A1203 is $2 per ton and the delivered cost of limestone is $1 per ton, the operating costs are $81.04 and $89.87 per ton of alumina for the double-leach process and single-leach pro-cess, respectively.

Jan 1, 1969

By John J. McClelland

The Bureau of Mines conducted a study of longwall plow operations to identify dust sources and existing control technology. Three longwalls employing either the high-speed overtaking or conventional method of mining were surveyed. Principal operating parameters and on-site dust control technology at the time of each survey are described. Short-term gravimetric and instantaneous sampling results are discussed in detail. The relationship between longwall dust levels and dust control technology was examined.

Jan 1, 1988

By L. Garner McDonald

The U.S. Bureau of Mines tangentially impacted potential coal-cutter bit shank materials against sandstone to investigate the potential of the materials to ignite natural gas by a friction-generated hot streak. The shank material samples were mounted in a 24-in, 550-lb flywheel, which was rotated at surface speeds of 400 to 900 sfpm. The sandstone was advanced toward the rotating flywheel at feed rates of 1 mil per impact. The atmosphere mixture was 7 vol pet natural gas in air. Three grades of polycarbonate resin, an ultra-high-molecular weight polyethylene, and a zinc alloy (ZA27) were among the potential materials. None of these materials caused ignition of the methane at any of the three test speeds (400, 600, and 900 sfpm), but the above materials do not have sufficient strength to hold a carbide tip during coal cutting. Of the materials having sufficient strength to hold a carbide tip, three nickel-based alloys proved less likely to cause a natural gas ignition than did iron-based alloys such as 4340 (a commonly used shank material for coal cutters).

Jan 1, 1992

By M. M. Fine

This report describes a Bureau of Mines technical feasibility study of simultaneous reduction and induration of pelletized iron ore to make a product with superior qualities as blast-furnace feed. Highly reduced, physically competent pellets can be made from magnetite and specularite concentrates that contain small additions of bentonite as binder. In batch tests, pellets were dried, surrounded with solid fuel in crucibles, and heated to the reducing temperature. Total iron content of the best products was higher than 80 percent and crushing strength of 1/2-inch metallized pellets ranged up to 600 pounds or more. Comparative tests of several commercial oxide pellets showed a wide range in crushing strengths, but most values were less than 350 pounds. Continuous tests in a rotary kiln resulted in the same degree of reduction, but the pellets had lower crushing strengths because of the limitations in the maximum operating temperature of the small kiln.

Jan 1, 1962

By Kung-Lee Wang

FOLLOWING the rapid recovery of previous years, the U.S. economy continued the upward trend and moved forward moderately and sporadically during the first half of 1962. There was a slow-down in the recovery rate, which was especially notable in the third quarter. The economy recovered in the fourth quarter, and by the end of 1962 the gross national product amounted to $555 billion, a new high, 7 percent above that of 1961. Production, employment, personal income, and corporate profits all achieved new peaks, but unemployment continued high and the prospects for improvement remained poor. The economy again failed to us~ its full potential; 1962 was a good year, but not good enough. During 1962, all industrial production climbed from the low in January to a high in late summer which lasted through the fall, and declined slightly at yearend. Mining production followed this pattern closely and most sectors were approaching record highs. Most minerals gained in value and volume of production. The steel-associated minerals group was the only exception, and it sustained a small net loss. The nonfuel minerals industry opened the year at a high level, maintained this high level until late summer, with the peak in May, and drifted downward toward the end of the year. The gains recorded by nonferrous metal mining partly offset the loss of ferrous metal mining, resulting in a small gain for metal mining as a whole. The upsurge of construction material minerals output was primarily responsible for the substantial increase in production of nonmetals other

Jan 1, 1963

By B. J. Scheiner

As part of its mission to reduce pollution associated with mineral production, the Bureau of Mines is developing a dewatering technique for phosphatic clay waste that uses a flocculant, polyethylene oxide (PEO). This flocculant forms strong, stable flocs, which can be partially dewatered on a static screen and dewatered further on a rotary screen. Using this technique, a field test unit (FTU) was operated at a nominal 100 gal/min. Consolidated phosphatic clay material containing 20 percent solids was produced when feed slurries of 3 percent solids were treated with 0.69 pound of PEO per ton of feed solids. Pit and column tests indicated that the PEO-treated material continued to dewater; compacted products containing 40 percent solids were obtained after 45 days.

Jan 1, 1981

By L. J. Prosser, G. Esterhuizen, A. T. Iannacchione

The potential for roof fails in underground mines remains a clear and present danger for mine workers An investigation of ground conditions in nearly 50 percent of the nation’s underground stone mines fold that the slate of roof stability is primarily determined in a limited and subjective manner. These large-opening mines with roof heights typically 7 m (23 ft) or more, make physical observation difficult. Although some mines use monitoring techniques to gain additional information an roof stability, this practice is usually short term and localized to address ground conditions in a particular section or part of the mine. A roof-fall hazard-assessment techniques was development based on engineering judgment acquired from extensive underground stone mine experience and on exanimation of the related literature. This technique utilizes observational processes to determine roof fall likelihood Case-study scenarios offer a realistic picture of model implementation. Providing the mine level decision-maker with an accurate assessment tool to ascertain the level of ground fall hazards is expected to reduce mint worker injuries and fatalities Moreover; the presences of danger can be overcome with a clear picture of quantified ground conditions.

By T. T. Campbell

This report describes the development of new electroplating baths from which tin-nickel alloy plate was deposited. Although tin-nickel plate can be deposited from an aqueous ammonium bifluoride bath, the corrosive nature of this bath has served as a deterrent to its use. The Bureau of Mines felt that more general acceptance of this new alloy plate would follow if neutral or alkaline baths could be developed. Promising results were obtained from electrolytes containing both tin and nickel chlorides dissolved in triethanolamine-hydrochloric acid or in ethylene glycol hydrochloric acid baths. Current efficiencies close to 100 percent were obtained with these baths. Research revealed that tin-nickel plate could be produced from organic solvents or from mixed aqueous-organic electrolytes. The composition of the alloy deposit - 65 percent tin and 35 percent nickel - was found to exhibit the same single-phase structure that is obtained from the commercially accepted fluoride-type bath.

Jan 1, 1959

By John R. Shattuck

Preliminary examination of the McCormick chromite property was made by the Federal Geological Survey and the Bureau of Mines during the spring and summer of 1943. In October 1943 an exploratory project was undertaken by the Bureau in cooperation with the Survey and was completed in February 1944.The urgent need during the war for high-grade lump chromite such as produced at the McCormick mine, was one of the pertinent reasons for the project. The McCormick mine is situated about 12 miles southwest of the town of Sonora, in the foothill belt of the Sierra Nevada Mountains, Tuolumne County, Calif. The chromite occurs as irregularly shaped lenses in masses of dunite contained in a steeply dipping, sheared, serpentinized zone of peridotite, near a contact with granodiorite.

Jan 1, 1949

By Raymond M. Kacmar

This report presents the Bureau of Mines research on the hardware reliability prediction for two Bureau monitoring projects. The basic concepts of reliability predictions are introduced along with the reliability models and assumptions used for this particular evaluation. The results of the reliability predictions are for ground-fixed and naval-sheltered environments.

Jan 1, 1986