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By N. Kacira

"Canada's largest known chromite deposit occurs in a layered intrusion in the Bird River area of Manitoba. However, numerically most of the chromite occurrences are in the Appalachians. Few, apparently minor, occurrences are also known in the Cordillera.In the Appalachians, chromite occurs as lenses and pods in dunite; they are of ""podiform"" type. The individual concentrations vary in size from a few pounds to tens of thousands of tons. Locally, chromite concentrations form discontinuous zones extending several hundred feet along strike and presumably down dip, therefore resembling boudinaged layers. Chromite layering and lineation are commonly concordant to those of the host rocks.The Appalachian chromite occurrences are thought to have been formed by fractional crystallization and perhaps also by liquid immiscibility. Their present shape and distribution are largely the result of deformation mostly prior to complete solidification of their host rocks. Therefore, the attitude of layering, foliation, lineation and other features related to deformation provide valuable guides in predicting the probable distribution of chromite, and hence are helpful in exploration.Chromites fulfilling the requirements for metallurgical, refractory and chemical grades occur in the Appalachians. Although the Appalachian deposits are similar in size and grade to some of the chromite deposits being mined elsewhere, they are unlikely to be economic, at present, in the higher wage Canadian environment. However, in case of shortages in chromite ore supply which may result, among other reasons, from increasing tendency to further processing in the producing countries, the Appalachian occurrences may become sources of ore. Such eventual shortages combined with relative abundance of electricity in Canada and recent innovations in oxide ore reduction technology may hasten the time when ferrochrome manufacture based on local chromite sources becomes economically viable."

Jan 1, 1982

By W. K. Muwais, R. G. Cuddy

"The Lower Cretaceous McMurray Formation contains the bitumen reserves of the Syncrude Mine in northeastern Alberta. This formation comprises sediments deposited sequentially in fluvial, estuarine and marine depositional environments. The Syncrude Base Mine area consists mostly of estuarine sediments, as much of the original marine sediments have been eroded away. These estuarine deposits consist of channel-fill sediments and interchannel tidal flat sediments with the channel-fills comprising most of the orebody.Channel-fills contain, among other lithologies, interbedded sand, silt and clay rich layers that often occur as sequences of inclined beds with dips up to 25 degrees or more. A detailed knowledge of the distribution of these inclined beds, their lithological characteristics and their continuity is very important in assessing the risk of mine highwall instability . Techniques used to identify and characterize adverse structures are reviewed. INTRODUCTIONGeneralThe Syncrude Canada Ltd. oil sand mine is located within the surface mineable portion of the Athabasca Oil Sands area about 40 kilometres north of Fort McMurray in northeastern Alberta, Canada (Fig. I). The company commenced large-scale strip mining of oil sands in June 1977in the area, referred to as the Base Mine, situated in the southeast corner of the company's two lease areas (Fig. 2).The mining method (Fig. 3) utilizes large electric drag lines operating on a single bench with highwall depths up to 60 metres. Feed grade oil sand (= 6 wt.% bitumen) is mined by draglines and windrowed parallel to the highwall crest. Lower grade oil sand « 6 wt. 0J0 bitumen) occurring as waste bands is selectively mined by the draglines and cast back into the mined out pit or placed on the bench and hauled by truck. The windrowed feed is delivered to the extraction plant by a bucket wheel reclaimer and conveyor system. Stripping of Recent, Pleistocene and Cretaceous overburden units is done outside the conveyor systems by mobile equipment. The 4.5 kilometre long mine is split into four quadrants for planning and scheduling purposes, with each quadrant having an individual dragline-bucketwheel-conveyor system.Surface mining of oil sand at Syncrude requires the removal of vast quantites of material. The design of the open pit mine relies heavily on knowledge of the distribution of ore and waste materials, and on the physical characteristics of these materials.The geology of the oil sand below the dragline bench at the Syncrude Mine is complex. Geological, geotechnical and hydrogeological factors play an important role in the design and operation of the mine. This paper describes aspects of the geology that impact on the design and operation of the mine. Some of the methods and procedures adopted by Syncrude to successfully overcome difficulties that the complex geology creates are discussed."

Jan 1, 1989

By L. C. Galloway, G. L. Tiley

"Mine hoist brakes must meet the following statutory performance criteria:- There should be two independent braking systems; at least one should act directly on the hoist drum.-If one brake fail s, the others should be able to retard and stop the hoist safely before the descending conveyance, carrying the rated load, reaches any obstruction.- When all brakes apply, decelerations should not be so violent that men travelling in the conveyance are injured.- The brakes shall not overheat and fade during an emergency stop.This paper discusses design principles and capacities of caliper and disc type brakes, when applied to double drum and friction hoists of equivalent capacity.IntroductionThis paper is about the brakes that are used on mine hoists; their functions, especially in emergencies, typical design, and how they are operated, controlled, tested, and adjusted.There are two basic types of mine hoists:1. Drum hoists, where the ropes are attached to, and coil on drums. The simplest system has only one drum. Most such hoists, however, have two drums, attached to a common shaft. Ropes are wound on each drum in opposite directions, so that when one conveyance is being raised, the other is lowered. The conveynaces may travel in vertical or inclined shafts. In the latter case, the hoist s are referred to as slope hoists.2. Friction hoist s, where the headropes are not attached to the wheel, but are in contact with it for an angle of lap of, typically, between 180 and 195 degree s. Forces are transmitted from the hoist wheel to the head ropes by friction.The lower ends of the conveyances are connected to balance ropes , approximately the same weight per foot as the headropes."

Jan 1, 1986

By Steve Forgeron, Brendan MacKenzie, Kevin MacPherson

"The geological composition of strata immediately adjacent to coal seams has a significant effect on the safe and efficient extraction of coal from underground mines of the Sydney coalfield. Geological features such as paleo-sandstone river channels, seam splits, floor rolls, paleo-soils and stone-filled rupture features can rapidly alter the competency of immediate roof and floor strata, significantly reduce the height of the coal seam, cause rapid variations in seam gradient and influence the in situ and run-of-mine quality of the coal.The impact of these features on the over-all mining operation can be significantly reduced if mine management can be for-warned of their impending occurrence. Using the information acquired from boreholes, geological mapping, x-ray diffraction analyses, microscopic studies, geophysical logs and seismic surveys, sedimentary models have been constructed which enable the mine geologist to predict, with increasing accuracy, the future occurrence of deleterious geological features ahead of the working face."

Jan 1, 1986

By T. Lamb, T. Aston

"The Gays River Mine is located within a complex hydrological regime and underground mining environment. Early in the mine history, the operation was' affected by an inability to control mine water inflows. More recently, the reopened mine operation had been unable to maintain consistent drainage of groundwater to the mine workings and sustain low groundwater levels.In 1992, a series of investigations were completed, which in part Were funded under the Canada-Nova Scotia Mineral Development Agreement. The studies undertaken included: hydrochemical and drainhole well screen assessments, an air photo study of sinkhole features, numerical modelling studies and a major piezometer installation and overburden soil study. The results indicate that the water draining to the underground workings is comprised of two distinct components: precipitation over the drawdown cone catchment area and seepage from the nearby Gays River. In addition, a third ""balance"" component was' also found, which represents uncertainties in the areal extent of the drawdown cone and river seepage components.After outlining the history of the groundwater problems experienced at the Gays River Mine, this paper examines the various studies undertaken during 1991-1992 and concludes that control of groundwater levels in the mine area is achievable. A number of recommendations are also proposed for future study ."

Jan 1, 1993

By M. P. Brameld, R. H. McCorkell

"Overburden covering bedrock uranium deposits was sampled to depths of 29 m and Rn concentrations measured at the same depths. Total-alpha activities, V concentrations and Rn emanation (J) of the samples were measured. The U-flux into the overburden was greater in the past: oxidation and dissolution has since removed most U, leaving decay products which indicate the presence of U deposits when U itself does not. Distributions of U and decay products and their ratios to each other reflect U-migration and degrees of U-removal. Rn distribution in overburden is related to the J of overburden samples and the presence and movement of groundwater. Simple, rapid methods of total-alpha and J measurement are described.IntroductionThe overburden drilling apparatus developed by Bondar-Clegg and Company makes possible sampling and radon measurement in overburden from the surface down to about 50 metres. This apparatus was used here to study the diffusion of uranium and its decay products from ore deposits into over lying overburden at the N deposit of the Amok Ltd. property (Cluff Lake, Saskatchewan) and on the Imperial Minerals Ltd. property at Gooderham, Ontario. These ores are enclosed in bedrock; the overburdens were deposited by glaciers or streams. The migration of uranium and its decay products in such situations and the factors which affect it have been little studied in the past, as readily usable techniques for mapping it in three dimensions have not been available. The results reported here are somewhat sketchy and preliminary, but they indicate the value of the methods used and some of the patterns to be expected. Surface and subsurface sampling and measurements were carried out on 3-line grids crossing known zones of mineralization. The lines were 60 metres apart at Gooderham and 40 metres apart at Cluff Lake."

Jan 1, 1982

By L. A. Homeniuk, R. Bonnar

"The Fond-du-Lac uranium deposit is located on the northern rim of the Athabasca Basin. The uranium mineralization is, for the most part, confined to the Athabasca Group, which is underlain by pre-Helikian metamorphic rocks of the Western Craton.The deposit is characterized by a remarkable train of mineralized glacial erratics which led to the original discovery. The mineralization is present as a ""high-grade"" core and a diffuse ""low-grade"" aureole. The ""high-grade"" core occurs as a stockwork of steeply dipping pitchblende veins which strike N 50°E. Hematite, siderite and secondary silicate are also abundant. The ""low-grade"" aureole contains uraniferous goethite, argillaceous material and rare carbon buttons. Recent alteration to coffinite has taken place along the margins of pre-existing ore minerals.The ""high-grade"" core is 390 m long and 10 to 40 m wide, and is surrounded by an irregularly shaped zone of ""low-grade"" mineralization with a similar length and a width of up to 350 m.Comparing the Fond-du-Lac deposit to other unconformity-type deposits, several important differences can be noted:1. Ninety per cent of the ore is above the unconformity, in the Athabasca sandstone.2. The deposit is not associated with underlying graphitic rocks or a major structure.3. The clay-rich alteration zone is not extensive around the Fond-du-Lac deposit.Although there are differences with other Athabasca unconformity-type deposits, the high-grade portion below the unconformity suggests a common origin.The ore deposit is postulated to have been formed from uranium-bearing solutions which entered the stockwork of fractures. Following the reduction in part of these solutions by pre-existing carbonaceous matter and pyrite and/or chemical reaction with pre-existing hematite, deposition continued as a result of decreasing temperature and pressure. Subsequently, minor supergene redistribution of the uranium has taken place."

Jan 1, 1982

By Rene A. Morin, John K. Kebe

"As explosives become more widely used in urban and other congested areas, governmental regulations pertaining to their use are becoming more pervasive and stringent. This is forcing the blasting industry to review its entire spectrum of operations. Greater attention is now being paid not only to the design and layout of blasts, but also to the monitoring and recording of their after-effects for both legal and business reasons.Current PracticesThe major users of explosives in urban areas are quarry operators and construction companies. A characteristic of both of these industries, at least in recent years, is a relatively low margin of profit. This, coupled with the fact that their use of explosives is relatively intermittent, prevents them from having the kind of professional consulting services that blasting operations really warrant in today's regulatory environment. When such services are obtained, they tend to be directed more at the design and execution of the blast than at the recordkeeping function. The records that are kept tend to be more in the form of a summary of the consultant's design data as opposed to the kind of after-effect detail that is necessary.The more experienced consultants and operators now realize that at least as much attention must be paid to the record-keeping as to the design work. Regulatory bodies at all levels of government are insisting on the availability of such records.Unfortunately, the instrumentation in use today for taking such measurements does not lend itself to the practice of intermittent consulting. Current monitoring and recording instruments are based on so-called analog technology of the type that has traditionally been applied to the monitoring of earthquakes. They require set-up and calibration procedures which must be repeated each time the instrument is moved, or the blasting parameters are changed, as well as complex total analysis of the recorded data. This can lend to confusion and a dilution of responsibility for anything other than the design work and possibly some summary reporting."

Jan 1, 1985

By Bradford P. Simser

Increasingly sophisticated rock mechanic tools are becoming more and more available for today?s ground control specialist. However many problems are still beyond our ability to explicitly calculate or measure. There is often a gap between the ?art? and the ?science? of rock mechanics. This paper focuses more on the ?art?, giving relatively simple examples of underground observations and micro-seismic records to help explain ground control issues. Ground support techniques such as in cycle shotcrete with high pressure water scaling, mesh and bolting, pumpable resin bolts/cablebolting, and yielding bolts with load spreading straps are discussed. The use of primary/secondary type blasthole sequences in moderate to high stress situations is also discussed with several examples of the micro-seismic response to the stoping. Relatively erratic geology with high material strength contrasts is currently being mined with blasthole methods at Nickel Rim South. Although the mine is still in its? ?early? days, over 1 million tonnes has been extracted and some empirical experience is highlighted with potential longer term issues also being discussed.

Oct 1, 2010

By L. A. Homeniuk, R. Bonnar

"The Fond-du-Lac uranium deposit is located on the northern rim of the Athabasca Basin. The uranium mineralization is, for the most part, confined to the Athabasca Group, which is underlain by pre-Helikian metamorphic rocks of the Western Craton.The deposit is characterized by a remarkable train of mineralized glacial erratics which led to the original discovery. The mineralization is present as a ""high-grade"" core and a diffuse ""low-grade"" aureole. The ""high-grade"" core occurs as a stockwork of steeply dipping pitchblende veins which strike N 50°E. Hematite, siderite and secondary silicate are also abundant. The ""low-grade"" aureole contains uraniferous goethite, argillaceous material and rare carbon buttons. Recent alteration to coffinite has taken place along the margins of pre-existing ore minerals.The ""high-grade"" core is 390 m long and 10 to 40 m wide, and is surrounded by an irregularly shaped zone of ""low-grade"" mineralization with a similar length and a width of up to 350 m.Comparing the Fond-du-Lac deposit to other unconformity-type deposits, several important differences can be noted:1. Ninety per cent of the ore is above the unconformity, in the Athabasca sandstone.2. The deposit is not associated with underlying graphitic rocks or a major structure.3. The clay-rich alteration zone is not extensive around the Fond-du-Lac deposit.Although there are differences with other Athabasca unconformity-type deposits, the high-grade portion below the unconformity suggests a common origin.The ore deposit is postulated to have been formed from uranium-bearing solutions which entered the stockwork of fractures. Following the reduction in part of these solutions by pre-existing carbonaceous matter and pyrite and/or chemical reaction with pre-existing hematite, deposition continued as a result of decreasing temperature and pressure. Subsequently, minor supergene redistribution of the uranium has taken place."

Jan 1, 1982

By F. Gaul, H. R. Manouchehri, A. Mosser

"Mining is a major energy intensive industry that contributes in consuming about 7% of the total world’s energy in which almost half in comminution. The underlying trait that drives energy consumption upwards appears to be somewhat persistent due to increasing in population, demands and growth rate. High grade resources have been/being depleted; consequently, low grade, high competent and complex ores with complicated geological structure are brought into perspective. For efficient extraction of values from such resources comprehensive multistage mining and processing strategies must be taken into account. Different treatment technologies, including ore sorting, must be considered to improve resource efficiency and productivity while taking into account the reduction in energy and water consumptions and related sustainability issues.The implementation of sorting technology in mining industry has a long past and its impacts on improving the overall efficiency of both mining and milling have been proven. However, the lack of complete understanding of its potential combined with ore complexity and low capacity of sorting machines have prevented the large scale application in mining industry. The application of X-Ray transmission sorting at Mittersill Tungsten Mine in Austria is presented and discussed herein. A technoeconomic analysis of the technology has revealed a significant potential of adding value to the concentration process. The rough feasibility study has given a strong feed-back on profitability and short time payback of about 2 years for the investment. Except the economic benefits the technology has positive environmental impacts. The potential for saving energy and water is large. The rough calculations have revealed that the energy saving can be up of 840MWh/annum. Furthermore, the ongoing cooperation between Mittersill mine and the sorting manufacturer is a good example on how the development of more competitive products, and product offerings, can be made."

Jan 1, 2016

By R. S. Nichols

"During 1973 to 1978, Canadaka Mines Limited, a subsidiary of St. Joseph Explorations Ltd., undertook an extensive exploration and development program in the Cobalt area. This program resulted in the delineation of previously unknown stratigraphic units in the Archean volcanic sequence. During this time period, significant are controls related to area silver deposits were also identified.The Archean geology is comprised of a volcanic pile conformably overlain by sediments. The volcanics contain at least two felsic volcanic centres near the stratigraphic top of the pile. The bulk of the pile consists of mafic flows and interflow sediments. lnterflow sediments around silver are shoots contain mineralized halos of base metal sulphides. The halos exhibit lateral and vertical metal zoning with Cu, Pb and Zn mineralization decreasing away from an are shoot.Silver mineralization controls determined during the Canadaka program agree with the historically well established importance of Coleman sediments as well as Archean contacts for hosting silver deposits. The vertical extent of are shoots is typically 150to 250ft. A strong correlation was found to exist in the Cobalt area between Archean strike and the strike of are veins. Finally, al/ Cobalt area are deposits appear to be associated with a distinct volcanic pile at the top of a sequence of Archean flows."

Jan 1, 1988

By Zhang. L.

Ordered intermetallic PtSb had been synthesized by arc-melted and then sintering treatment. The electro-oxidation of formic acid on PtSb was investigated at room temperature by cyclic voltammetry and chronoamperometry. The results are compared to those at a polycrystalline platinum electrode surface. It was found that PtSb intermetallic was catalytically more active than pure platinum according to the onset potential and current density. XRD and XPS technologies had been used to investigate the crystal structure and electron effect. We think formic acid decomposition on PtSb favors the reactive intermediate route and is not very much affected by the CO intermediate as compared to Pt.

Jan 1, 2005

By S. Shairp

Copper is an impurity as well as a necessary reagent in the processing of zinc sulfide concentrate at Hudson Bay Mining & Smelting Co., Limited's (HBMS) zinc pressure leach plant. Copper is present in the zinc concentrate as chalcopyrite, which consumes reagents necessary for zinc leaching. A small percentage of copper precipitates in the autoclaves, discharge lines, and flash tanks, requiring maintenance of the equipment and disposal of the solids. Copper also precipitates in the neutralization stages and is removed to low levels in a specific copper removal stage of purification. Yet some copper, as copper sulfate, is required, along with potassium antimony tartrate, in the final purification stage to improve cobalt removal from the zinc sulfate solution prior to electrowinning. The behaviour of copper experienced at HBMS's zinc pressure leach plant is discussed.

Jan 1, 2008

By Robert White

?Introduction of BMS?Paste fill generalities?Development through paste?Development through rock fill?Conclusion ?Brunswick mine is operated by Xstrata. The mine has been in operation since 1964 and produces around 10 000 tons per day of ore containing (in order) zinc, lead and silver? The ore body consists of close to ten sub-parallel massive sulfide lenses. The length of the ore body is 1200 m with a width of up to 200 m. From the surface, the ore body extends to a depth to 1200m ?There is 100 km of active drifts for a total 400 km ?The mine is divided by 7 levels and 23 actives sub levels

Feb 1, 2008

By J. Mizera, B. Adamczyk-Cieslak, K. J. Kurzydlowski, A. Dobkowska

"AZ31 is the one of the most popular magnesium alloy using in the modern industry. It is well known, that compared with steel, magnesium alloys posse better properties, such as light mass, high specific strength or thermal conductivity. It should be noted that their application is limited by poor corrosion resistance. In this work the corrosion behavior of AZ31 magnesium alloy as cast and after heat treatment were described with the use of testing in neutral salt spray atmosphere.To characterise corrosion resistance and describe layers built on the surface it was necessary to do the metallographic observations with the use of optical microscopy. After that influence of heat treatment for AZ31 corrosion resistance was examined. Measurements were conducted by electrochemical impedance spectroscopy (EIS) and by neutral salt spray tests in artificial atmosphere. Surface and cross section morphology after removal of corrosion products were observed with the use of scanning electron microscopy (SEM).The weight loss measurements show that there is no significant difference between alloys as cast and with following heat treatment.INTRODUCTIONMagnesium and magnesium alloys are popular in modern industry because of the low density and good formability. Magnesium alloys are described by few properties which have got significant influence for their application in transportation and electronics industries (Feliu & Liorente, 2015). Their wide application is limited by poor corrosion resistance. As it is well known Mg is one of the chemically most active metal. Corrosion resistance of Mg alloys depends on several factors, such as impurities, chemical composition or working conditions (Cheng, Qin, Wang, & Zhang, 2009). That all causes that there are many different ways to find well defined and good solution of magnesium alloys processing to improve their corrosion resistance.There are many different versions about the influence of aluminum on the corrosion resistance of magnesium alloy. It is known that intermetallic compounds such as Mg17Al12 due to ß-phase content plays the minor role for corrosion resistance. It is proved ß-phase acts as cathode and it has good ability to build passive layer in broad pH ranges. However it should be noted that mentioned behavior depend on size and distributions of ß-phase in the microstructure (Singh, Singh, & Das, 2015)."

Jan 1, 2016

By T. H. North, A. G. Glover, R. J. Pick

"Girth welding operations represent the rate-limiting step in pipeline construction. A joint industry-university program was set up to establish the field welding characteristics of large-diameter, high-strength line pipe.Theoretical work carried out at the University of Waterloo showed that pipe wall thickness and joint misalignment prior to welding has a marked influence on the lifting stresses acting on the root pass of girth welds. Pipe diameter and pipe ovality had negligible effects. Super-position of lifting and residual stress (caused by the fusion welding operation) highlighted regions of the weld bead most susceptible to hydrogen-induced cracking.The field welding characteristics of 1219-mm-diameter, 13.72-mm-wt Grade 483 line pipe were evaluated using a specially designed test rig. The principal test variables were lift height, delay time after root pass deposition, preheat temperature, pipe composition and joint misalignment prior to welding. For any given life, preheat and joint misalignment prior to welding had the most significant effect on cracking tendency.The output of this program has industrial significance and illustrates the beneficial features of university-industry collaboration.IntroductionField welding operations comprise the rate-limiting step during pipeline construction. Crack-free girth welds must be made in a wide range of weather conditions and consequently the field weldability of line pipe compositions directly affects pipeline integrity and construction economics.Pipe-laying practice comprises root bead deposition followed by a skidding operation involving lifting (or lowering) the pipe length onto skid s so that the next pipe length can be aligned prior to welding. Consider pipeline construction using 24.4-m lengths of 1219-mm-diameter , 13.72-mm-wt Grade 483 pipe weighing approximately 10,000 kg. Skidding involves loading a 3-mm-thick root bead by moving the free end of the pipe through vertical distances of up to 700 mm . The likelihood of cracking in these circumstances depends on the inherent crack susceptibility of the pipe composition employed, on the hydrogen content of the deposited weld metal and on how well the joint handles the external stressing caused byskidding."

Jan 1, 1981

By D. Kao, J. Gogal, S. Humphrey, T. Byrne, M. Davoodi

"High total and dissolved uranium values were noted in the process water at the Cigar Lake Operation (CLO) during early production start-up period, whereas significant levels of dissolved uranium had not been observed previously at similar operations. The excess dissolved uranium resulted in higher demands on the water treatment plant, along with higher operating costs, environmental risks and some unrealized revenue potential. A species balance indicated that uranium was leaching into solution in the grinding, dewatering, and storage circuits under normal operating conditions. Jet boring, water recycle, ball milling, and the use of Pachuca tanks for ore storage results in a highly oxidative environment, which is favourable to leaching.This paper will outline the testwork performed to identify the conditions under which the uranium leaches into solution and to determine required conditions for uranium precipitation. Maximum uranium leaching was found to occur under normal operating conditions (pH ranging from 7.0 to 8.5); testwork indicated that both lowering and raising the pH can significantly reduce the uranium leaching. Analytical results combined with the batch scale testwork indicate that the uranium solubility is associated with carbonate species in the ore. Uranium precipitation was maximized at pH values greater than 10.5 or less than 6, corresponding well to carbonate leaching and precipitation values from literature. Higher precipitation efficiencies were noted at high pH ranges.As a result of this work, a pH control system has been implemented in the Pachuca storage vessels and thickener prior to water treatment plant on a trial basis. Caustic soda is recommended for pH control due to ease of operation, economic viability and material requirements and downstream constraints."

Jan 1, 2016

By J. Lu, M. Mohammadi, C. Pelletier, B. Wassink

Chemical reduction of selenate by chromous ions is proposed as a novel method to remove selenate from sulfate-bearing solutions Chromous ions were generated by electrochemical reduction of chromic ions using an electrochemical cell. The investigation was conducted in sulfate medium and under various concentrations of chromous ions (0.0062 to 0.05M), pH 1 to 2.2 and temperature 10 to 60°C. Selenate ions were rapidly reduced by chromous ions to hydrogen selenide. The overall reaction at a chromous/selenate molar ratio of 8 or higher can be expressed by the following reaction. At an initial chromous/selenate molar ratio below 8, the products are hydrogen selenide and elemental selenium. At a lower chromous/selenate molar ratio and pH, more elemental selenium and less hydrogen selenide are produced. The reduction kinetics is controlled by both chromous ion and hydrogen ions concentrations. The reaction rate is first order with respect to selenate, hydrogen ion and chromous ion concentrations. It was found that the selenate reduction rate with chromous is independent of the concentration of sulfate present in the solution. The general rate equation was proposed and the rate constant was calculated as k= 0.38 M-2s-1. An activation energy of 58.7 kJ/mol was obtained in the temperature range from 10 to 50°C. Nearly 100% of selenate can be reduced to H2Se from solution containing 17 ppm selenate in less than 30 minutes at pH 2.2 and 60°C. Various strategies have been tested to remove the produced H2Se from solution. INTRODUCTION Selenium in nature is mostly associated with metal sulfide minerals such as copper, iron, zinc, and lead sulfides (Zingaro & Cooper, 1974). The extraction of metals from ores has the potential for selenium contamination of ground and surface water which can pose an environmental and health concern. Therefore, selenium contamination in the receiving environment is a key issue for many industries (specifically copper industry) and the treatment of wastewater contaminated with selenium is a growing challenge. The effective removal of selenium from contaminated water is very important to support sustainability in the copper industry and the other industries with selenium pollution issues.

Jan 1, 2019

By Arash Habibi

The FMC Westvaco Trona Mine is located near Green River, Wyoming and has an annual production of 4.5 M tons. The underground mine has three active development panels and one longwall panel. The mining horizon is about 500 m below surface and strata liberate methane. Three surface-based blowing fans provide ventilation air. A ventilation survey and subsequent analysis was undertaken and a simulation model developed. Air heating during winter is essential to prevent freezing of pipelines and to lesser degree, for miner comfort. Air at all three intake shafts is heated using gas-fired heat exchangers. A strata heat study was conducted in one of the active panels to determine rock attributes. Tests included in-situ measurements of rock thermal conductivity and geothermal gradient. Continuously methane monitors have also been installed in an active development panel?s return drift. Ventsim ventilation software was used to aid the heat and contaminant simulation study. An exercise was also undertaken to gain some understanding of methane contaminant levels throughout the mine. It was further used to determine an adequate surface intake air heating rate and consequently the minimum natural gas consumption needed for winter intake air heating at the mine.

Aug 1, 2013