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By R. L. Bruening, L. Navarro, R. M. Izatt, N. E. Izatt, S. R. Izatt

Green chemistry principles will be discussed, and examples will be given of the use of Molecular Recognition Technology (MRT) to selectively separate valuable metals such as rhenium and palladium from various copper refinery feed streams. Recovery of these metals has numerous advantages including (i) conservation of valuable resources, (ii) prevention of environmental damage, and (iii) elimination of capital and operating expenses due to re-processing or disposal of metal-bearing streams. INTRODUCTION Refining of copper ores has a long and successful story. The history of copper, one of the first metals mined in human history, illustrates the global challenges faced as a result of increased demand for major metals and for by-product specialty metals found with them in trace amounts (Izatt et al., 2014). Copper has valuable properties, which have sustained its use over the centuries. It is an ideal material for creation of novel materials. Some desirable properties of copper that have proved valuable in our high-technology society include suitability for alloying with many other metals; ease of joining by soldering and brazing; good combination of mechanical qualities; high resistance to corrosion; suitability for many artistic purposes; and, of great importance in the modern era, efficient and economic use as a conductor of electricity. Copper mining in the U.S.A. began in the late nineteenth century in Montana (Izatt et al., 2014). The estimated total amount of copper mined globally before 1800 is about 5 million tons, four times less than is mined in a single year today (Flanagan, 2018). Production of copper in the U.S.A. has remained fairly constant at about 1,300,000 to 1,400,000 metric tons per annum from 2013 to 2017. Specialty metals such as bismuth, rhenium, molybdenum, and others that have become essential in our 21st century technology, and precious metals such as silver, gold, and the platinum group metals (PGMs) are concentrated by geochemical processes in trace amounts in copper ores. These specialty and precious metals were discarded into tailings in early mining operations, since limited extractive technologies existed and uses for most of them were limited. Thus, economic benefits for recovering them were limited, primarily, to silver and gold. Today, copper processing is the main, and often the only, commercial source for certain of these elements (Izatt et al., 2014). For example, molybdenite (MoS2) is the predominant ore mineral of molybdenum mining (Pohl, 2011). Cu-Mo-Au porphyry ore deposits supply ~75% of the world’s copper, 50% of the molybdenum, nearly all of the rhenium, and 20% of the gold. Typical ore grades are 0.5–1.5% copper, 0.01–0.04% molybdenum, and <1.5 g/ton gold. Molybdenite is the primary source for rhenium, among the rarest of metals, which is an essential component of super alloys, such as turbine blades in the aerospace industry (Pohl, 2011). Most rhenium is obtained as a by-product of molybdenite from copper mines in Chile. The case of rhenium raises an important issue. Continued availability of rhenium, selectively concentrated in copper ores, depends on continued mining and processing of copper. Since the mining company’s main interest is typically in copper production, continued recovery of rhenium and other specialty elements present in the ore body is at risk. Dependence of specialty metal supply on continued mining of major metals exists in several additional cases including indium, gallium, selenium, tellurium, germanium and bismuth (Pohl, 2011). PGMs, on the other hand, are typically mined for their own value, which far exceeds that of associated base metals. However, copper ores often contain marketable amounts of platinum and palladium, making their separation of interest, if this can be done economically.

Jan 1, 2019

By G. Stokreef, B. R. Davis, M. Kadiyski, T. LeBel, Alvear Montenegro, R. Parra, V. Montenegro

A drop tower and methodology were developed to study the impact of mineralogy on the flash combustion behaviour of copper concentrates. Reaction shaft conditions of a flash furnace were simulated using a drop tower reactor and different molar ratios of oxygen gas to sulphur in the feed. Five feeds were tested in the drop tower including pure minerals chalcopyrite and pyrite as well as two mineralogically distinct copper concentrates and a blend of the two. The behaviour of each of these five feeds were evaluated through analysis of the solid combustion products for elemental sulphur, mineralogy and particle size. Desulphurization curves for each of the feeds were produced. It is thought that the desulphurization behaviour of pure minerals can be used to estimate the behaviour of a concentrate and that a blending recipe could be developed, which can optimize the chemical and mineralogical inputs to the flash furnace and guide operations on the optimum furnace conditions. Overall, the drop tower has proven to be a useful tool for studying flash combustion processes. Experimental results suggest that mineralogy has a significant impact on the conditions required for the production of matte with consistent grade. This finding is especially significant for custom smelters, which may see several different blends in a day. INTRODUCTION Flash furnace smelting is a continuous feed, batch tap, pyrometallurgical process that is used to produce copper matte from copper sulphide concentrates. Dried concentrate(s), silica flux, and secondary materials are blended to a target chemical composition, typically given by the Cu/S ratio, before processing. This fine, dried feed is dispersed throughout the heated furnace reaction shaft with an O2-enriched reaction gas. The particles heat up in the shaft of the furnace, ignite and undergo reactions that pre-oxidize the iron sulphide and some of the impurities in the feed. Oxidation reactions in the shaft of the furnace desulphurize the feed and produce an SO2-containing off gas. The reacted particles fall into the furnace settler and separate into a Cu-rich matte and an iron-silicate slag, while the SO2-containing off gas is carried out of the furnace for heat and dust recovery, as well as H2SO4 production. Some concerns during operation of the furnace are dusting, over or under oxidation of the feed, and a stable flame.

Jan 1, 2019

By M. Moats

World copper refining tankhouse practices have been surveyed. This survey is a supplement to previous surveys that have been carried out in the 1987, 1991, 1995, 1999, 2001 and 2003. On a world basis, process technology trends include the further installation of automated electrode handling systems including permanent cathode systems, automatic anode preparation and cathode handling machines, section switches, fully automatic cranes and polymer concrete cells. General plant process control has increased with more automation of material handling in the copper refining tankhouse. The general trend for most greenfield copper refining projects remains in eastern Asia.

Jan 1, 2007

By Steven Dempsey

Overview What is Tubbing? A look at Cigar Lake Tubbing Design The Tubbing Installation Backwall Grouting

May 1, 2013

By Pavel Vasak

Microseismic monitoring is becoming standard practice in the Canadian mining industry, particularly as mines get deeper. Full-waveform microseismic systems allow the operator to distinguish the event source mechanism, e.g., blast, shear slip or stress-induced fracture. At mine sites that heave a microseismic system operator blasts are manually identified by comparing the event waveform traces to the morning blast logs. However, this procedure is not routinely done at sites where a system operator is not present and this can lead to misinterpretation of the data at a later stage, particularly where the interpretation is outsourced, often many years later. It is critical to improve the microseismic data quality and consistency for processing and interpretation with a reliable technique to filter out blasts and blast related seismicity. This paper presents the development and implementation of a simple blast identification and filtering routine. The routine was developed specifically for Vale?s Creighton Mine about a decade ago, but is made sufficiently general so that it can be used at any mine site with an ESG (Engineering Seismology Group Canada) based full-waveform microseismic systems. The routine is strictly a post-processing procedure developed for use with the Access database data structure used by ESG. The algorithm was tested at Creighton Mine and a success rate of 80 to 90% was achieved, when compared to manual blast picks.

Oct 1, 2010

By Juan Pablo Vielma

In this work we study how to incorporate risk control to the generation of ultimate pits when orebodies are modeled through a finite number of conditional simulations. To control risk we consider a chance constraint on the value of the ultimate pit. We incorporate this measure into the generation of ultimate pits by solving a stochastic programming version of the ultimate pit problem. We compare this stochastic programming problem to previous approaches such as generating the ultimate pit for each simulation and the hybrid pit approach introduced by Whittle and Bozorgebrahimi. We also study the effect of using different number of simulations in the generation and evaluation of ultimate pits.

Oct 1, 2009

By Caitlyn J. McKinley, Ahmad Ghahreman, Maziar E. Sauber

Ever-growing global needs for critical metals, such as rare earth elements (REE), and base metals, such as copper and nickel, and their environmental impact motivated the pursuit of sustainable flowsheets. Regeneration of hydrochloric acid in chloride-based leaching flowsheets as a critical unit operation is an example of such endeavours. This study presents an efficient hydrochloric acid regeneration method from a magnesium chloride solution waste by addition of sulphuric acid in relatively low temperatures. The effects of temperature, initial magnesium chloride concentration, amount of sulphuric acid added, and airflow are examined. Experimental work are focused on temperatures between 80 and 95°C, initial magnesium chloride concentrations of 2 to 5 M, 100% to 220% stoichiometric sulphuric acid additions, and airflows between 200 to 600 mL/min. The developed technology recovers hydrochloric acid at a high rate and concentration with a relatively small environmental footprint. INTRODUCTION The mining and metals sector is under increasing environmental and economic pressure to make more efficient use of chemical reagents and energy in the production process. This affects several areas of process and flowsheet design such as the selection of the most appropriate unit operations and the overall design of the process steps paying heed to sustainability. Owing to the inherent inefficiencies of physical and chemical processes used in the mining industry, there will be materials and streams generated that are not a desirable part of the envisaged flowsheet. Thus, methods are implemented to recover and recycle such effluents. If the recovery and recycling are not economical, then procedures are followed to neutralize and dispose these effluents. In many cases, these effluents are potential contaminants or hazardous materials, and their disposal should be looked at in a much larger context. The safe management of the contaminants and hazardous effluents is a daunting problem in the mining industry and is fraught with technological, economic, social, and political challenges.

Jan 1, 2019

By Jianping Zhang

QUESTIONS: ?? Is it more expensive to find an ounce of gold in Canada today than 50 yrs ago? ?? Did the Canadian gold industry find more gold than they mined? ?? What is the future sustainability of the Canadian gold industry? ANSWERS: ?? The gold discovery costs in real terms only increased slightly from 1946 to 2000. ?? Though the Canadian gold industry mined more gold than they discovered in the period, when undeveloped deposits are taken into account, the deficit was merely 12 million ounces. ?? The Canadian gold mining industry would be sustainable in the foreseeable future, particularly, given the overwhelming predicted promising gold market in the mid/long run.

May 1, 2006

By A. D. Akerman, D. D. Young, G. R. Baiden

The development and maintenance of underground roadways are increasingly important aspects of the modern mining process. With the trend toward automation and track-less mining, roadbeds capable of with standing increased wheel loading have proven necessary to maintain high vehicle speed and reduced maintenance costs. Concrete has been used successfully on some roadways in order to obtain the required characteristics. However, this solution usually involves unacceptable expense. The objective of the Road Router project was to create a drift floor profiling machine capable of cutting a smooth surface out of the existing rock floor of development drifts and ramps. This surface would provide a durable, high strength, low rolling resistance roadbed that would allow for reduced operating cycle times and lower maintenance costs of scoops and haulage trucks. The Road Router has the potential to offer an alternative to concrete with substantial cost savings.

Jan 1, 1997

By David F. Machuca-Mory

Modelling the geometry of a vein is a crucial step in resources estimation. The resulting models are used as mineralization domain boundaries and have a direct impact on the tonnage of estimated resources. Deterministic models are often built using time consuming wireframing techniques usually based on hand interpretation of the drillhole intercepts. Another approach consists in coding the drillhole samples by a function of their distance to the veins contacts. The coding is subsequently used for modelling the vein contacts away from drillholes. This is a more efficient approach and is able to provide a measure of tonnage uncertainty. The use of location-dependent variograms improves the modelling by incorporating local changes in the anisotropy of the vein structure. This combined approach results in more realistic vein models, particularly when the geometry of the vein has been are altered by folding, shearing and other structural processes. The approach is illustrated on a realistic case study.

Oct 1, 2009

By S. A. Beeson, C. Poole

"This paper reports on the development of selective flocculation processes for the direct recovery of KCl values from low-grade Canadian sylvinite and carnallite potash ores.Two reagent suites, consisting of either a non-selective cationic or selective non-ionic flocculant, together with the same selective anionic dispersant, were evaluated. Initial data from component mineral behaviour investigations, reagent adsorption studies and selective flocculation tests on a synthetic potash ore were used in the successful development of processes capable of recovering KCl values without the necessity for desliming to remove water-insolubles.Enhanced multi-stage treatment (involving redispersion and reflocculation) and subsequent floc recovery techniques (including sedimentation, hydrocyclones and froth flotation) were examined, and in all cases the influence of process parameters such as reagent dosages, conditioning times, solids concentration, particle size and other physical design criteria were investigated.The data reported clearly demonstrate the scale-up potential of these processes and possible applications in potash operations."

Jan 1, 2000

By Robert J. McCarthy

Many technologies have been adopted over the last half century for the haulage of material from open pit mining operations. Some of the technologies utilized include rail, off-highway trucks, conveyors, and slurry pipelines - each having its unique application and benefits. Over time, truck haulage has become the primary means of surface mine material movement, though recently it has been plagued by problems of tire shortages, high diesel fuel costs, labour shortages, and carbon emissions. This paper focuses on In-Pit Crushing and Conveying (IPCC) as a competitor to truck haulage which has the potential to solve many of these problems. An overview of the available technology is presented along with measures required to overcome perceptional if not physical barriers to implementing this technology in modern open pit mines.

May 1, 2011

By J. Gao

We present results from our investigation of the concept and practice of using surface-charged latex nanoparticles as building blocks for conductive membranes. Nanoparticles were synthesized by free-radical co-polymerization of two hydrophobic monomers, butyl acrylate (BA) and methyl methacrylate (MMA), a crosslinker, N, N&apos;- methylenebisacrylamide (BIS), and a charged monomer, sulfonate styrene sodium salt (NaSS), in water. The resultant nanospheres were characterized with static and dynamic laser light scattering. Thin films were cast from concentrated particle dispersions, followed by incubation at ?110 °C. Conductivity, water uptake and final charge content were measured. The membranes have higher conductivities than both amorphous films cast from sulfonated BA-MMA-Styrene copolymer chains and BA-BIS-MMA-NaSS gel films. TEM images and neutron scattering spectra confirm the particulate structure of the membranes.

Jan 1, 2005

By R. O. Burt, R. W. Bruce

"IntroductionGravity concentration, the separation of two or more minerals due to the difference in their relative specific gravity and usually in a fluid medium, is the oldest recorded form of mineral processing.The principles of gravity concentration were known to, and practiced by, the ancients and Hoover's commentary to De Re Meta/lied'' notes many early references.Over the centuries, as direct smelting ores became more and more uncommon, the mineral processing industry developed and along with it many varied methods of concentration. Gravity concentration declined rapidly in importance in the early twentieth century, and it is only in the last decade that its advantages are being re-evaluated.A significant proportion of ores are processed by gravity; a large proportion being in the iron and coal industries<'>, or in the treatment at very high volume of relatively coarse alluvial deposits. The tin dredges of South East Asia and Beach sand plants of Australia are prime examples.An indication of the broad application of gravity concentration is the variety of minerals presently recovered. A list is given in Table 1; this list is not exhaustive.Principle of Gravity ConcentrationGravity concentration methods separate minerals of different specific gravity by their relative movement in response to gravity and one or more other forces, the latter often being the resistance to motion offered by a viscous fluid, such as water or air.The relative movement of minerals to one another is achieved by a variety of methods. These are: separation in a fluid of intermediate density (heavy media separation); by stratification (such as in jigging); in a flowing fluid (cones, spirals, sluices etc.) and with a horizontal shear (shaking tables etc.)."

Jan 1, 1989

By Tim Bekhuys

Equator Principles ? Applies to projects > $10 million ? Voluntary agreement between 58+ EPFIs ? Categorized projects based on environmental risk, consequences ? Requirements for EA, EMP, use of safeguard policies, consultation ? IFC Performance Standards on Social and Environmental Sustainability ? Apply if the project is in a low or lower-middle income country ? Low-middle income countries defined by the World Bank Development Indicators Database

May 1, 2008

By A. Miura, R. Winarko, D. B. Dreisinger

Chalcopyrite leaching in acidic ferric sulfate media at ambient temperature exhibits slow kinetics and poor leaching efficiency, which is typically attributed to surface passivation. Recently, the presence of small amounts of iodide in the leaching media has been reported to significantly accelerate chalcopyrite dissolution. To further explore the behavior of chalcopyrite leaching in the presence of iodide, it is essential to determine the factors that control the leaching kinetics. In this study, we investigated the effect of initial solution potential, iodide concentration, particle size, and temperature on the kinetics of copper extraction from chalcopyrite. The key in the experimental setup was to minimize iodide loss by iodine evaporation and precipitation as cuprous iodide. The former was achieved by performing the leaching tests in fully sealed leaching systems. The latter was achieved by maintaining the solution potential higher than 420 mV (versus Ag/AgCl electrode), where formation of CuI precipitate is possible. The experimental results show that higher solution potential and higher iodide concentration had a pronounced positive effect on the rate of chalcopyrite dissolution. There was no effect associated with particle size, which might be due to the narrow size range tested. The positive effect of increasing temperature only manifested itself when the solution potential was sufficiently high. INTRODUCTION The main challenge of chalcopyrite leaching using ferric ions as the oxidant at ambient temperature is the slow kinetics and poor extraction. The reason for this leaching behavior has been attributed to passivation resulting from formation of insoluble passivating layers on chalcopyrite surfaces, which could be metal-deficient sulfides, elemental sulfur, polysulfides, and iron precipitates (Klauber, 2008). To overcome passivation, technologies using higher temperature and pressure have been developed to leach chalcopyrite concentrates, such as the CESL process (Mayhew, McCoy, Mean, & Woeller, 2013), FLSmidth Rapid Oxidative Leach (ROL) process (Mulligan et al., 2017), Galvanox (Dixon, Mayne, & Baxter, 2008), Albion process (Hourn, Turner, & Hourn, 2012), HydroCopper (Hyvärinen & Hämäläinen, 2005), TPOX (Dreisinger, 2006), and AAC/UBC process (Dreisinger, Dempsey, Steyl, Sole, & Gnoinski, 2003). Even though they are effective in accelerating copper leaching kinetics, those technologies typically have higher capital and operating costs associated with production of concentrates and application of autoclaves. This makes them unsuitable for treating low grade primary copper sulfide ores.

Jan 1, 2019

By Z. D. Hora

Several deposits of crystalline magnesite are known in southeast British Columbia. Deposits at Cross River and Marysville have been thoroughly explored, but as yet there has been no commercial production.

Jan 1, 1984

By Owen Owens, W. P. Armstrong

The process of arriving at the size and grade of: (a) a newly-discovered body of mineralization, (b) a potential ore resource, (c) an orebody proposed for mining, or (d) the ore reserves in a mine, requires fundamental geological, and geometrical determinations as well as physical and chemical analyses. This paper outlines geological and geometrical features considered critical, in the authors&apos; experience, in realistic reserve determination. These are discussed under the headings "The Four Cs". They include the Character, type or nature of the mineralization; the Continuity of various types of mineralization in the deposit; various key concerns in the Calculation besides the mathematics; and the Classification section which refers to basic considerations in classifying a mineral estimate. It is suggested that the responsibility for the calculation of a Resource or Reserve should be that of a geologist experienced in the ore type under review. Further, it should be the responsibility of the board of directors of the company owning the deposit to ensure that a sufficiently experienced person is chosen to carry out the process.

Jan 1, 1993

By C. Bissue, G. M. Castillo

Newmont’s Phoenix mine started production in March of 2006. Due to the extreme hardness of the ore, the mill has struggled to meet throughput projections. Grinding studies showed that optimizing the existing circuit would not achieve budgeted throughput. These studies also showed that the pebble crusher was being underutilized due to the inability of the SAG mill to break the rock. The concept was developed to supplement the feed to the existing pebble crusher with a secondary crusher. Models of this process looked favorable so a portable crusher was installed to test the process. The temporary crusher was successful at increasing the throughput by 7% and based on the operating data, plans are currently being developed to install a permanent secondary crushing system in front of the SAG mill. This paper will review the results from the test crusher and the flow sheet for the permanent secondary crusher.

Jan 1, 2012

By I. M. Gordon

"INTRODUCTIONThe Hollinger tailing disposal plant is situated about 1 1/4 miles south of the mill. The area available for tailing covers 620 acres and is roughly 1 ¼ miles long by ¾ mile wide.Tailing was first deposited on the northeast section of the present site. This section, 1 mile long by ~ mile wide, sloped from northeast to southwest, the slope amounting to 106 feet between the northeast corner and the low land to the south west. The low land was wet and a considerable area was covered with muskeg up to 17 feet deep. It was drained by a creek running across the property in a southwesterly direction. Later, when more ground was needed, the low lying mining claims adjacent to the south and west boundaries were acquired to allow for expansion of the plant. This entailed some extra difficulties and expense that would not have been necessary had the whole of the present site been acquired with the original purchase.At the conclusion of milling, May 7, 1968, the site contains nearly 56 million tons of tailing. The top of the deposit is from 70 to 90 feet above the original low lying ground along the northwest, west and south boundaries."

Jan 1, 1969