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The Porphyry Gold Mine (150km NE of Kalgoorlie) was reopened in November 1983 with production commencing in April 1984. Original reserves quoted for the open pit were 822000 tonnes at 5.2 g/t Au based on wide spaced diamond drill holes. Close spaced grade control drilling has revealed some loss of tonnage and a significantly lower grade. In the area of the pit mined to 30 June 1985 this grade control reserve estimate contained 67% of the gold in the original ore reserve with the grade being 19% lower. It is anticipated that the final grade control reserve estimate will contain around 80-85% of the gold contained in the original reserve. There has been close agreement between the Mill Head grade (4.19 g/t Au) and the grade control predicted grade (4.2 g/t Au) confirming that dilution is not a major problem. After initial poor agreement (attributed to "lock-up" in the circuit) the bullion calculated head grade steadied out at 93% of the grade control prediction. This difference is considered to represent the geostatistical bias in the drill hole/crushed rock sampling. Gold recovery has been in the range 93-95% (compared with bullion calculated grade). The net result is that the recovered grade of ore mined to 30 June 1985 is 70% of the original ore reserve grade.

Jan 1, 1986

Kidston Gold Mines Limited (70 per cent Placer Pacific and 30 per cent Public Shareholders) has been mining the Wises Hill Pit since late-1984. The Wises Hill Deposit is a large low grade gold deposit and as such is highly sensitive to economic parameters. The uniformity of the orebody has allowed a bulk mining method to be used, with minimal dilution. Total reserves defined to-date are 64 160 OOOT at a grade of 1.60 g/t gold. Mineable reserves remaining as of January 1992 are 36 357 OOOT at a grade of 1.28 g/t gold.Mining investigations to reduce the impact of lower gold prices, the effect of decreasing headgrade and increasing mining costs have focused on wall steepening.

Jan 1, 1992

THE Company's smelting equipment consists of three blast furnaces, supplied with blast from two sets of vertical piston blowers, each capable of delivering 8000 cub. ft. of air per minute at a pressure of 60 oz. per sq. in. Each blower is belt-driven by a 1:30 h.p. motor. The maximum speed of the blowing engine is 35 r.p.m.No. 1, the largest of the three blast furnaces, has a crucible area of 49.5 sq. ft., and measures 11 ft. 6 in. x 5 ft. at the tuyeres.From tapping floor to feed floor measures 35 ft. 9 in., and holds, when full, 100 tons of charge. Blast enters through thirteen 3-m. tuyeres at 60-oz. pressure. Working normally, this furnace is capable of treating :300 tons of charge, exclusive of returned slag and coke, per 24: hours, with an output of 100 tons of lead. Tapped slag flows into a C.l. forehearth mounted on wheels, where any lead and matte is caught, and the slag overflows into a 3-ton cast-iron pot, in which it is drawn away by an electric locomotive and poured over the dump.

Jan 1, 1918

By M Hood, X S. L, W J. T Daniel, H Gurgenci

It is believed that disc cutter shape affects rock fracture and therefore cutter performance and cutter life. However, the current generation of disc cutters is made of hardened steel and these cutters wear rapidly and consequently they are unable to maintain their original shape in strong and abrasive rock. This wear problem could be reduced if the cutter was made from a harder material. Unfortunately as material hardness increases so does the propensity for brittle failure. In this study the optimum cutter shapes were identified by studying the mechanics of rock/tool interaction. The results showed that bevel and wedge cutters are better than cutters with dome and flat edges. A new cutter was designed, based on this result, using a harder material to increase the life by a factor of 20.

Jan 1, 1998

By M E. Malmstr÷m

Quantification of site-specific sulfide oxidation rates is crucial to accuracy of prediction of, for example, the environmental impact of a mine site. Sulfide oxidation reactions are reportedly increased by bacterial mediation; determination of abiotic and biotic weathering rates thus requires the establishment of sterile control samples. However, sterilisation often involves exposure of samples to extreme conditions that may alter the physical, chemical, or mineralogical characteristics of the tailings and hence affect element release rates. The impact of various sterilisation techniques, common and novel, on the element release rates from tailings from the Kristineberg site, northern Sweden, has been investigated. Batch weathering experiments indicated that the different methods of sterilisation (autoclaving, heat treatment, ethanol/heat treatment, application of antibiotics, rinsing with distilled water, and γ-radiation) did not greatly affect long-term element release rates. Long-term experiments (>30 days) are thus to be recommended for establishment of weathering rates. Sterilised and untreated control samples showed similar element release rates after ~100 days of experiments; possible explanations include that microbial oxidation is not important under our experimental conditions (Po2 = 0.2 atm, pH ~2.3, 22¦C, 0.01 M HNO3, no additional nutrients).

Jan 1, 2003

By J H. Kyle

Cyanide is a significant cost in gold processing, as well as an environmentally sensitive issue. It has been suggested that precipitation of cyanide from leach liquors as copper-iron-cyanide compounds such as Cu2Fe(CN)6 may account for part of the total cyanide consumption. This may be especially true for ores that are rich in both copper and iron minerals. Ammonia addition has been shown to decrease the cyanide consumption by copper. Cu2Fe(CN)6.xNH3 precipitates have also been postulated to form during conventional cyanide detoxification processes, using oxidants such as SO2/air, with ammonia arising as a breakdown product from the oxidation of free cyanide. The present work has examined the conditions under which such precipitates may form, particularly in gold plant process and detoxification liquors. Ammonia and pH were found to have a large effect on the extent of precipitation. The compounds that were formed were found to comprise mainly Cu2Fe(CN)6.7H2O, as well as a range of NH3-bearing variants. The stabilities of the various precipitates are important from an environmental perspective. The long-term stability of copper ferrocyanide precipitates in tailings dams may be a problem under alkaline conditions and when some free cyanide is present, elevating the measured total cyanide in solution significantly. Case studies including data from actual plants are also considered, and the importance of these effects is reaffirmed from these results.

Jan 1, 2000

By Q-c Li, G-l Gao

Cyanided tailings produced by gold processing operations may cause environmental problems, because they contain pollutants such as arsenic, sulfur and cyanide compounds. Moreover, tailings containing economic metals such as Au, Ag, Cu, Pb and Zn, are potentially valuable resources. In this article, cyanided tailings are catalytically oxidised by nitric acid in the presence of air or oxygen. The resulting solids may be leached to recover Au and Ag. The solution can be used to prepare ferric sulfate or iron pigment. Gases released in the reactions were recycled and reused by oxidation and absorption. All of these greatly improve metal recovery and the reuse prospects of cyanided tailings. Under the following conditions where the initial temperature of oxidation is 80¦C; initial concentration of nitric acid is 30 per cent (by weight); feed proportion (nitric acid to cyanide tailings mass ratio) is 3:1 and reaction time is two hours, the conversion ratio of cyanided tailings is 90.06 per cent. At the same time pyrite in the cyanided tailings is oxidised effectively, gold recovery is as high as 92.3 per cent and nitric acid loss per cycle is only five per cent because of NOx recovery.

Jan 1, 2007

Chlorination of organic matter by direct injection of chlorine gas or hypochlorite has been investigated metallurgically worldwide with little understanding of the basic chemistry of the passivation mechanisms in- volved. In this paper, chlorination of carbon is attributed to oxidation-reduc- tions, resulting in surface halogenation of graphitic or amorphous carbon. It is proposed that chlorine and carbon interact to form thin coatings of chioro-carbon complexes that block the adsorption of gold cyanide com- plexes, thus passivating the gold adsorption sites of carbonaceous matter. Analytical, spectrographic, microscopic and electron-optical methods have been applied to demonstrate the proposed mechanism of chlorine-carbon bonding, as well as to evaluate the advantages and limitations of chlorination in the pretreatment of refractory carbonaceous gold ores.

Jan 1, 1991

By M N. Ingham

X-ray fluorescence (XRF) spectrometry has always been considered to be a comparative method of analysis. Reference materials are required to calibrate the analytical system. This paper describes the use of a set of æsyntheticÆ oxide standards, made from commercially available high purity compounds, to calibrate a spectrometer for 21 major and minor oxides. The spectrometer software uses simple methods of background correction, and a fundamental parameter method of matrix correction. Sample preparation is by fusion in 66 per cent lithium tetraborate, 34 per cent lithium metaborate. The use of synthetic standards, made from traceable compounds, brings XRF significantly closer to being a primary rather than a comparative method. Reference materials were used to validate the method described and examples of accuracy for major constituents are given using ores and other minerals. This method has successfully been used to analyse a wide variety of minerals and ores, as validation data shows. A titanium process example clearly shows the benefits of highest accuracy analysis.

Jan 1, 2008

By M, C A. RosiFre, R C. Figueiredo e Silva

Jaspilites and underlying basalt contacts of the Archaean volcano- sedimentary Grpo Parß Group, Carajßs, host giant iron mineralisation in the ~100-km long, E-W trending Carajßs fold. Preliminary, unpublished geochronological data point to a Palaeoproterozoic mineralisation event. Geochemically, jaspilites are typical volcanogenic banded iron formations. Basalts exhibit evidence of spilitic seawater interaction. Iron-associated hydrothermal alteration of mafic rocks was induced by fluid infiltration in amygdales, with development of chlorite- and hematite-dominated zones. In the case of jaspilites, iron mineralisation encompasses: partial replacement of jaspilitic microcrystalline hematite by blasts of martitic magnetite; jasper recrystallisation, producing fine-grained, hematite-free granoblastic quartz; martite recrystallisation, forming lobate¦subhedral hematite; pervasive porosity development by quartz-chert leaching; incipient cavity filling by microlamellar hematite; and advanced filling by coarser, euhedral and comb-textured, tabular- shaped hematite.Peak hydrothermal ore textures indicate typical epithermal-crust conditions, supported by preliminary fluid-inclusion calculations at 160 - 200¦C. Such temperatures and extreme fluid-to-rock ratios during alteration must have exceeded the ambient metamorphic conditions, with the infiltrating fluid relatively hot and capable of leaching SiO2. Therefore, mineralisation developed over exhumed, Archaean, brittly deformed rocks, with mineral associations representative of very low- to low-grade metamorphism. Considering that chlorite (¦talc) abounds in mafic rocks; hydrothermal albite is developed; dolomite fills veins and vugs; the typical rare-earth-element (REE) pattern of jaspilites is significantly modified in higher-grade hard hematite ores (higher LREE); pyrite, copper sulfide minerals and rare gold occur in association with carbonate-quartz-rich alteration zones, it is suggested that an alkaline, H2O-Fe-CO2 mineralising fluid dominated, also containing species like S¦Cu¦Au. Peak-mineralising conditions are likely to have resulted from a single, evolving fluid, via incipient- through advanced-stage alteration phases. The porous, high-grade soft hematite-type ore (SH), rich in microlamellar and anhedral hematite, must have derived from interaction with this relatively hot SiO2-leaching fluid, whereas the high-grade massive hard hematite-type ore (MH) developed due to closer fluid-rock temperature equilibrium conditions, attained by mineral reactions, with relative increase in the Fe/Σcations ratios allowing the precipitation of subhedral-tabular hematite that partially cements the soft-hematite ore. SH and MH hematite ore types must thus reflect intermediate and high fluid:rock ratios, respectively. Since the N5 deposit is to date understood to contain the largest amount of the MH ore, its units are interpreted as the loci of the highest fluid:rock ratios in the district. Preliminary mineralogical information regarding the S11 deposit of the Serra Sul (south range) implies higher-temperature conditions. The near-equant grain size and the granoblastic intergrain relationship, coupled with the presence of riebeckite, augitic pyroxene and garnet, suggest hornfels textures. The data collected, though still relatively sparse, permit the speculation that the immense driving force for the Carajßs world-class iron deposits was a relatively shallow, igneous-related hydrothermal system. If such a model is correct, then the Carajßs Palaeoproterozoic iron deposits could represent an end-member of the iron oxide-copper-gold hydrothermal system in the province.

Jan 1, 2005

By W J. Bruckard, M J. Vaisey

Ashton Mining Ltd (Ashton) and Lynas Corporation Ltd (Lynas) have established a joint venture partnership to develop and process rare earth oxides (REOÆs) from the Mt Weld deposit in Western Australia. The deposit is located in a deeply weathered volcanic carbonatite structure that contains approximately two million tonnes of rare earth oxides at an average grade of 20 per cent REO. As part of the 1999/2000 feasibility study currently being undertaken by Ashton and Lynas, an extensive laboratory beneficiation test program was undertaken by CSIRO Minerals on diamond drill core samples from the Mt Weld orebody. The aim was to develop a flowsheet, based primarily on flotation that could be confirmed at pilot plant scale. The target concentrate grade was 52 per cent REO with a REO recovery of at least 35 per cent. Two main ore types, nominated as CZ (limonitic siltstone) and LI (nodular limonitic ironstone) were identified for separate laboratory evaluation. The lower grade LI-type ore overlies the higher grade and more extensive CZ-type ore. The majority of the work was conducted on the CZ ore; only limited testing of the LI ore was undertaken. The latter contains a clay component that will present difficulties in processing due to its poor filtering and settling characteristics. Two processing options for treatment of CZ ore were presented for pilot plant consideration. One (Option 1) includes gravity concentration prior to flotation while the other (Option 2) includes finer grinding and four stages of open circuit cleaning. The benefits of each scheme are discussed in detail. Neither has been fully optimised and the definitive flowsheet is most likely to be a hybrid of the two schemes, incorporating the best features of each. Typical metallurgical results from each scheme were final concentrate grades of 49 per cent REO, 10-16 per cent Fe2O3 and 3.2-4.8 per cent CaO. REO recoveries were above 35 per cent in both cases. Features of the processes developed by CSIRO were the inclusion of a gravity concentration stage prior to flotation, a modified flotation reagent scheme, a change in the method of feed preparation, and incorporation of magnetic separation to upgrade final flotation concentrates. Metallurgical results obtained from flotation tests on LI ore were much poorer than those obtained for CZ ore. The best rougher/scavenger result, with the limited amount of testing so far completed, was an REO grade of 32 per cent with a recovery of 28 per cent. Further work is needed to develop a viable processing route for this ore type.

Jan 1, 2000

By D Schwab, R M. Tosdal

The Quesnell-Stikine arcs, in the Canadian Cordillera, are host to Triassic and Early Jurassic alkalic porphyry Cu-Au and calc-alkalic porphyry Cu-(Mo-Au) deposits formed outboard of ancestralNorth America in island-arc tectonic settings (McMillan, 1991). The majority of the alkalic porphyry Cu-Au deposits are products of a discrete magmatic event at the end of the Triassic, with a second and smaller event in the Early Jurassic (Mortensen, Ghosh and Ferri, 1995). Of the Triassic complexes, the Galore Creek alkalic intrusive suite is one of the largest and most silica-undersaturated intrusive complexes, and host to the most significant undeveloped alkalic porphyry Cu-Au resource in North America (Lang, Stanley and Thompson, 1995). Because of the common presence of feldspathoidal-bearing rocks in the complex (Enns et al, 1995), Galore Creek likely represents an end member example of the alkalic porphyry Cu-Au class. The Galore Creek alkalic Cu-Au-Ag porphyry district, located in NW British Columbia (Canada), contains 12 mineralised prospects (Enns et al, 1995; Micko et al, 2007; Schwab et al, in press) with a total measured and indicated resources of 785.7 Mt at 0.52 per cent Cu, 0.29 g/t Au and 4.87 g/t Ag (NovaGold Resources Inc, February, 2008). The Central Zone is the largest and best delineated. Other economically important mineralised centres include the South-West, Bountiful, West Fork and Junction deposits. The South-West Zone, the focus of this contribution, is a Cu-Au-Ag breccia-centred deposit with a measured and indicated resource of 69 Mt grading 0.42 per cent Cu, 0.69 g/t Au, 2.67 g/t Ag. Hosted in brecciated intrusive rocks, the South-West Zone is distinctly younger than the Central Zone and most of the other mineralised centres (Enns et al, 1995; Schwab et al, in press). The South-West Zone therefore preserves the late stages of hydrothermal evolution at Galore Creek. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Liu H, Chen S

Natroalunite is one of colouring minerals in kaolin. In this investigation, natroalunite, on which Ca(II) was adsorbed, was flocculated by HPAM and kaolin was depressed in suspension. The adsorption of Ca(II) on the natroalunite surface was studied by zeta-potential measurement and Auger Electron Spectroscopy analysis. Ca(II) was adsorbed more on the natroalunite surface than on the kaolin surface. The mechanism of Ca(II) adsorption was considered to be chemical adsorption on natroalunite and to be physical adsorption on kaolin. It has been found that Na6P6O18 and Na2Si04 can strongly affect Ca(II) adsorption on the surface of kaolin, but weakly on the surface of natroalunite. The effects of degree of hydrolysis and the molecular weight of HPAM, the effect of pH and the effect of Ca(II) have been studied. The kaolin ore, containing SO3 1.05 per cent has been processed with this method. The products only containing S03 0.36 per cent and the weight ratio of concentrate 52.27 per cent were Obtained.

Jan 1, 1993

By Avraamides J, Ritchie I. M

Gold Tellurides are important sources of gold at Kalgoorlie, Western Australia, Cripple Creek, Colorado and Vatukoula, Fiji. Unlike free gold, the tellurides of gold are rather refractory and the usual treatment practice has been to oxidize the tellurides, either chemically or by roasting prior to cyanidation of the liberated free gold. There is a large measure of disagree- ment as to the actual cause of the refractory nature of gold tellurides. In order to investigate the leaching chemistry of gold telluride, a study was undertaken on the thermodynamics and kinetics of its dissolution using electrochemical methods. From this study suitable direct leaching condi- tions are suggested. In acidic chloride solutions gold telluride can be leached using iron(III) as the oxidant. At lower acid concentrations the reaction is controlled by the formation of a passivating film of H2TeO3. In alkaline solutions containing cyanide the rate of gold telluride dissolution increases with increasing pH and strength of oxidant. However, this can result in excessive consumption of cyanide in the presence of stronger oxidants.

Jan 1, 1991

By N Stockton

Some preliminary results on the secondary leaching of previously heap leached gold ore are presented. Alternative lixiviants for gold comprising chlorine, thiourea and thiosulphate were compared with cyanide using bottle roll tests. Chlorine was subsequently selected for column leaching tests. Column tests at 1.0, 0.1 and 0.01 gL-1 Cl2 at pH 2 were conducted. The results indicated that about 23 per cent of the gold was leached over 45 days using 1 gL-1 Cl2 at pH 2. The experiments conducted proved that the chlorine/chloride system has good potential for further extraction of gold and silver from the existing cyanide heap leach residues and a process for secondary leaching of gold has been proposed. Further testwork is recommended to extend conditions, sample types, and the duration of leaching period.

Jan 1, 2000

By J Pan

In this paper, the technology of producing fluxed pellets by using hydrated lime as binder instead of bentonite was carried out. The properties of the two types green balls (0.8 per cent bentonite and 2.0 per cent hydrated lime) were as follows: drop numbers of 4.8 - 5.0 times/0.5 m, compressive strength of 19.7 - 24.2 N/pellet and thermal shock temperature of 280° - 385°, respectively, under the same conditions of 1.5 per cent coke, 1.45 basicity and balling at 8.5 per cent moisture for 13 min in disc pelletiser. Comparing with bentonite as binder, the compressive strength of fired pellets with hydrated lime is elevated by 13.8 per cent and climbs up to 3113 N/pellet under the following conditions: preheating at 1050°C for ten minutes and fi ring at 1300°C for 15 min. In the mean time, the hydrated lime also improves the metallurgical performance of fired pellets. The reduction index was enhanced from 68.6 - 70.6 per cent, RDI+3.15+ increased from 90.1 to 98.8 per cent and reduction swelling index dropped from 22.4 - 7.4 per cent, respectively. The mineral compositions and microstructure of fi red pellets shows that the fired pellets containing 2.0 per cent possess more calcium ferrite and magnesium ferrite and compact microstructure, leading to the higher compressive strength.

Jul 11, 2011

To enable AN-FO .tòo' be used on an equal .weight basis wish Nitro Gl reerin.e expl3oòsives r smaller diameter bore holes became necessary With consequent modifications to drill steel and burden on holes, De't'onation of AN-FO "in small diameter holes proved successful' both with 'and without primer charges but some altorat-ions were required to. adopt Anolodeòr.s to the smaller -holes, Important factors in training all operators In the new charging method were the retention of imp-,cved, fragmentat'ion, avoidance of excel ive ove:break and keeping wall rock dilution 'to an absoluato mi. iArurle ò The ò successful storage of Ammonium 14t-rate in c"!ime.tic conditions 'with daily'.-' temperature fluctuationc above and below the critical' 90¦F, has. been "achieved,

Jan 1, 1964

By Y B. Kang, Y J. Park

Ti-added ultra-low carbon (ULC) steel is produced by adding Al and Ti during the secondary refining process to deoxidise molten steel and to bind C and N which are detrimental to the deep drawing quality of the steel product. However, the production of Ti-added ULC steel faces challenges, including submerged entry nozzle clogging and surface defects on cold rolled coils. The troubles were often attributed to ‘Al-Ti complex inclusions’ in the molten steel. However, the evolution of oxide inclusions including their stability has been still unclear. In the present study, the evolution of these inclusions in Ti-added ULC steel was investigated by phase diagram measurement, CALPHAD thermodynamic modelling, high-temperature stability test for the oxides, and observation of transient behaviour of oxide inclusions in the steel. The phase diagram of the Al-Ti-O system was elucidated with an emphasis on oxygen potential, which significantly controls the stability of the oxides. CALPHAD thermodynamic models and a self-consistent database were developed. The transient behaviour of Al-Ti complex inclusions in Ti-added ULC steel was observed in situ using a confocal scanning laser microscope. This was additionally validated by the new thermodynamic model. The equilibrium phases of the oxide inclusions were investigated using a high-temperature resistance furnace, and were analysed using a secondary electron microscope, energy dispersive spectrometer, and electron back-scattered diffraction. By considering the morphology and crystal structure of these inclusions, the evolution of Al-Ti oxide inclusions was elucidated. Various behaviour of Al-Ti inclusions and their influence on steel cleanliness are discussed.

Aug 21, 2024

By Rowe J

The case study is based on the largest ore deposit at Mt. Lyell; the Prince Lyell deposit, comprising a regular lensoid mass of dissemina- ted and vein pyrite-chalcopyrite mineralisation. Reserve estimation employs conventional techniques, based on diamond drill hole and relevant development sampling data. Probable ore reserves are estimated using the contouring (isoline) method an longitudinal projections for ore thickness and accumulation (m %Cu) at a '0.8% Cu' cutoff. Final stope and pillar res- erve estimates (proved ore) are derived from designed ring tonnages and contoured accumula- tion for individual mining units, following more intensive sampling. Systematic grade control procedures have been adopted and individual stopes and pillars reconciled against mill production. The proved ore estimates have been found to com- pare favourably with the reconciled production.

Jan 1, 1979

The sharp deterioration in Au~tralia'S ternn of trade in recent years and the accumulating national debt highlight the need for a restructuring of the economy which is highly dependent upon primary agricultural and mineral commodity exports (figure 1). Table I gives an indication of the value that can be added to raw material by mineral processing. Significantly higher value is added through downstream manufacturing. In 1987, the mining and rural sectors accounted for 47010 and 38010 respectively of total exports valued at $35,782 million (figure 2). The export contribution from minerals comprised $12,266 mil- lion from unprocessed ores and concentrates and $4,668 million from metals and processed minerals including some simple manufactures. Coal accounted for 450/s of total primary mineral exports. Iron ore and alumina are other important mineral exports, while gold and aluminium are major metal exports. (Figure 3) Australia's minerals are now traded in a much more competi- tive and oversupplied market in contrast to the 1960's and 1970's period which was characterised by increasing exports of largely unprocessed ores and concentrates. Since the early 1980's (I cI) resscd )ver~cas nutrkcts and km rununodlity liriccs ha~c hcen the product of excess capacity installed to satisfy a forecast high growth in demand which never eventuated due to the world reces- sion. During this period the emphasis on technology development was focussed on reducing costs through increased production effi- ciencies in order to maintain competitiveness.

Jan 1, 1988