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By G. H. Charlewood, J. W. McBean

"One hundred years after being developed, the diamond drill is still an essential tool in mineral exploration. The basic principle is unchanged, but the technique has been revolutionized, particularly in the past fifteen years. The cost of core drilling has not kept pace with the rising cost of living. The price of machinery, supplies and labour in drilling has doubled and trebled since 1946. Some of the techniques which have made it possible to hold the price line are described."

Jan 1, 1967

By V. G. Papangelakis, T. Clark, G. Kolliopoulos

Sustainability of the hydrometallurgical industry requires the development of processes for effective water recovery; if process water is recovered and recycled, fresh water intakes will be reduced. Forward osmosis (FO) is an innovative membrane process that promises to recover water from industrial process aqueous streams or seawater with less energy input compared to reverse osmosis (RO) and evaporation; the energy efficiency relies on the spontaneity of the process (no energy input required). The driving force of the process is the osmotic pressure gradient between a dilute feed solution (process water) and a concentrated draw solution. The draw solution is an engineered aqueous solution that contains a highly soluble chemical reagent that is able to osmotically "draw" only water from the dilute stream, through a semi-permeable membrane, leaving behind a small volume of concentrated brine. The draw solute is separated and recovered for reuse, leaving behind water. The main energy requirements of the FO process arise from the separation and the regeneration of the solute chemicals from the diluted draw solution. This work focuses on the evaluation of aqueous carbonated trimethylamine (TMAH:HCO3) as the draw solution and reports recent findings on the separation efficiency of TMA and CO2 from the solution.

Jan 1, 2015

By J. Ouellet

The design of hydrostatic liner for a deep potash mine shaft in Saskatchewan poses tremendous technological challenges. Technology has evolved to a point where one could consider a new innovative approach to hydrostatic liner design. But there is still a place for conventional technologies such as cast iron tubbings. As will be discussed in this paper, improvement to manufacturing process, installation procedures and even new materials can bring this technology to an excellent level of performance. With the spur of new projects in the potash industry of Saskatchewan, the authors worked in various shaft liner designs from the conceptual stage through to the construction phase. They were either directly leading the design work on some of these projects or acting as an external reviewer on others. Most of these shaft liner designs involved cast iron tubbing technology and ground freezing. The major challenge in sinking potash shafts in Saskatchewan is to go through a water-bearing ground formation under high pressure, known as the Blairmore or Manville fm. The only proven stabilizing technology for these formations is ground freezing. For a potash shaft, dry shaft conditions are highly desired, so a fully waterproof hydrostatic liner is required. All the existing potash mine shafts in Saskatchewan, except for two with composite steelconcrete lining, used the cast iron tubbing technology. Two new shaft tubbing liners have been constructed recently, one in the Athabasca Basin and one for a potash mine in Saskatchewan. When the authors began working on these new projects, what became quickly evident is that the technological knowhow for designing and constructing tubbing liners was no longer available within Canada and that the past construction methods used to sink tubbing lined shafts was obsolete. The tubbing liner for the shafts sunk in the sixties were designed either by German or British companies. In both of these countries only few tubbing lined shafts were sunk in last 40 years and the technology used in the sixties was not improved. There are only few countries where tubbing is routinely produced and installed: China, Russia, Ukraine and Poland. Out of these countries Poland is the one where this technology is the most advanced. The authors, working in close collaboration with engineers from Poland, attempted to rebuild this knowledge for the mining industry in Canada. This process involved thorough analysis of old technical reports, literature review and study of current polish design and construction practices as well as site visits of existing shafts. Through actual construction experience, some lessons were learned as well as ideas for improvements. In this paper, the authors will present a succinct review of design and procurement process. But, the practical aspects of the construction and installation methodology will be treated with more emphasis, more specifically the practice leading to good liner performance. Some of the poorly understood technical aspects of tubbing installation will be discussed more thoroughly and some currently accepted myths dispelled.

Aug 1, 2013

By A. H. Lang

Introduction The recent uranium discovery at Theano point, lake Superior, is probably a rediscovery of the first reported Canadian uranium occurrence. A description of material from the original discovery was published in 1847 by J. L. LeConte, and many attempts have been made to relocate the deposit. Such attempts have in the past been unsuccessful because of vagueness in the original description of the locality. Besides being a prospect that seems to merit development work, the Camray discovery is important because it reaffirms the occurrence of pitchblende in the eastern part of the Precambrian shield. Much staking followed the announcement of the discovery, and some additional finds have been reported. Location The Camray discovery is at the shore of Theano point, lake Superior, about seventy miles north of Sault Ste. Marie (see Figure 1). It is in township 29, range XIV, district of Algoma. The showing is two miles from Highway No. 17, and is reached by a rough trail that leaves the highway at mileage 72.9 from Sault Ste. Marie. There are no towns of any size nearer than Sault Ste. Marie.

Jan 1, 1949

By K. Östcrdahl

We are developing a cost-saving and environmentally friendly process with low energy consumption to recover the metal content and recycle the acid from spent pickle baths. The metals are precipitated as metal fluorides, which can be turned into metal oxides and hydrofluoric acid by thermal hydrolysis. In the proposed process the solution is concentrated by nanofiltration and the metals are precipitated in a subsequent crystallization step. Different nanofiltration membranes have been evaluated in experimental batch tests. The membrane MPF-34 from Koch Membrane Systems offered both good flux and acceptable metal retention even after long periods of acid storage. The solubility of B-FeF3.3H20 has been measured at varying acid concentrations and at different temperatures. The solubility decreases with increasing hydrofluoric acid and nitric acid concentrations. This suggests that the crystallization process should be operated at high acid concentrations. The crystal growth rate of B-FeF3.3H2O is found to be quite low but increases significantly with temperature. This suggests that the crystallization process should be operated at higher temperatures (40 - 60°C). Within the project a pilot plant has been constructed where the spent pickle bath solution is concentrated by nanofiltration to the desired metal fluoride supersaturation, and B-FeF3.3H2O is crystallized in a 10 L continuous crystallizer.

Jan 1, 2006

By F. J. McMulkin

This paper, the 1965 Airey Memorial Lecture, reviews the world-wide technical advances in iron and steelmaking, and offers an appraisal of the new techniques which will be applied in the future. After a review of blast furnace operations, the continuous steelmaking process is described, and the resulting techniques of degassing and continuous casting are discussed at length. Pressure pouring, hot rolling, cold rolling and coating practices are also outlined, and considerable space is devoted to the direct reduction process. Finally, the application of the computer to steelmaking operations is discussed in some detail.

Jan 1, 1966

By A. Bowles

The process of accumulative roll bonding (ARB) has been applied to wrought magnesium alloy AZ31. Accumulative roll bonding results in severe plastic deformation of sheet material. In AZ31, this process leads to the refinement of the microstructure by dynamic recrystallization. The refinement of the microstructure results in an improvement in mechanical properties with potential for producing materials for superplastic forming. In this work AZ31 was bonded with up to 64 layers and the potential of roll cladding with aluminium was also investigated. The development of microstructure and the mechanical properties are reported here.

Jan 1, 2006

By D. M. Baird

"THE Island of Newfoundland lies on the extreme eastern edge of the continent of North America and at the extreme northeastern end of the Appalachian geological province. Its belonging to the Appalachian province is shown in the geological history of the region and in the rock types and structures.Geosynclinal sedimentation in early and middle Palaeozoic times was interrupted by Taconic and, more profoundly, by Acadian, mountain building activity. Mid-Palaeo-zoic intrusions range from masses of serpentinized ultrabasic rocks to granite batholiths. A Carboniferous overlay of continental and shallow, drying sea types covers the earlier developed complex. Local basins in these times were filled with products of the erosion of tl1e earlier rocks, and, locally, grew the right kind of vegetation to make thin, discontinuons seams and pockets of coal. Post-early Pennsylvanian history is one of erosion and pene-planation with renewal of movement along many of the older fault systems."

Jan 1, 1960

By E. N. Gilje

"IntroductionDURING the past five years, over two miles of shaft sinking have been completed at Falconbridge. As sinking has continued, we have improved our equipment and technique with a resulting increase in efficiency. Throughout this period, all sinking has been done by contracting firms, under our direction and to our equipment specifications, with highly satisfactory results. Since 1949, Riddell shaft mucking machines have been successfully used in conjunction with the •benching method of sinking. Our most recent practice can best be illustrated by describing the method used in sinking No. 1 shaft at the Fecunis Lake mine.No. 1 Shaft, Fecunis Lake MineNo. 1 shaft, consisting of six compartments and measuring 13 ft. 11 l/2 in. by 19 ft. 9 3/8 in., outside timber (Figure 1), will be sunk to a depth of 4,170 feet. It was designed to accommodate two 10-ft.diam. Koepe hoists."

Jan 1, 1955

By Alan Rice

The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultrama?c igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on ?uid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other ?elds dealing with suspended loads in ?uids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By M. Niinae, F. Nakahara, T. Kawamoto, T. Suzuki

"MgO was chosen as an As(V) immobilization agent and a series of immobilization experiments was performed to obtain insights into the behavior of As(V)and MgO during leaching tests. Our experimental and modeling results demonstrated that As(V) immobilization by MgO consists of the following steps: (i) an increase in soil pH, (ii) desorption of As(V) from the soil, and (iii) the re-immobilization of As(V) by MgO/Mg(OH)2particles. Regarding the behavior of MgO, the modeling results showed that when the MgO dosage was 25 mg MgO/4g-drysoilor less, the majority of MgO was used to increase pH, and less than 1% of MgO was used to sorb As(V), which was consistent with the result of leaching tests showing that a high level of As(V) was leached at the MgO dosages. On the other hand, when the MgO dosage was above 25 mg MgO/4g-drysoil, the percentage of MgO used for As(V) sorption increased up to 35%, and correspondingly, the As(V) leaching level decreased to below 0.01 mg/L As at an MgO dosage of 75 mg MgO/4g-drysoil.INTRODUCTIONOne of the major arsenictransport pathways causing groundwater contamination is the migration of arsenicfrom artificially or naturally contaminated surface soils. Therefore, in this study, the immobilization of arsenate (As(V)) in soils was investigated using commercial-grade magnesium oxide (MgO) as a potential cost-effective measurement to prevent the occurrence of groundwater contamination with As(V).With respect to the use of MgO for remediating As(V)-contaminated environmental media, MgO has been used in several studies to remove As(V)from water(Yu et al., 2011; Jia et al., 2013; Tresintsi et al., 2014). Although these studies demonstrated that MgO effectively removes As(V)from water in water-MgO systems, the behavior of As(V)in water-soil-MgO systems has not been evaluated in the literature, and several questions remain to be answered to comprehensively evaluate the use of MgO as an As(V)immobilization agent in soils. For instance, as is well-documented in the literature(Ford, 2002; Lenoble et al., 2002; Zeng et al., 2008), iron oxy-hydroxide (FeOOH) is one of the important adsorbents for As(V)in both natural and engineered systems. Therefore, it is anticipated that the presence of FeOOH in soils significantly influences the behavior of As(V)in water-soil-MgO systems and consequently, the immobilization performance by MgO. Another important question to be answered is the behavior of MgO during the immobilization treatment. In our previous studies (Suzuki et al., 2013a, 2013b), commercial-grade MgO was demonstrated to effectively immobilize lead and fluoride, and the immobilization effectiveness was indicated to last more than 100 years against the exposure to acid rain (pH 4.0). However, these studies focused on the behavior of contaminants. As a result, little is known about the behavior of MgO during the immobilization treatment. The lack of understanding of the behavior of MgO during immobilization treatment is one of the main concerns leading to relatively low public confidence in immobilization treatments."

Jan 1, 2016

By Albert G. Zima

THE conservation of strategic materials during war rime gives rise to many problems not commonly encountered in times of peace. During normal times, when world trade is unrestricted, we are apt to become lavish to a point of extravagance in our use of those materials which, during rime of war, become scarce owing to inadequate transportation and production facilities or because the enemy may be in position to control sources of supply. It becomes necessary, then, to enforce rationing of available sup-plies, and in some cases, where such supplies are wholly inadequate, we find we must resort to the use of substitute materials. We are now confronted with such a problem to an extent never before experienced, with the result that many of the commodities upon which our civilization depended are now either shut off completely or, because of the heavy demand occasioned by war production, are not available in sufficient quantities to meet requirements predicated on peace-time standards and manufacturing methods. It has become necessary, therefore, to make many changes, some of them very drastic indeed, to enable us to carry on our war effort effectively. This? discussion will deal briefly with one phase of this problem, namely, the conservation of alloys required in the making of steels necessary for war production. In line with a request from the War Production Board, the Technical Committee on Alloy Steels of the American Iron and Steel Institute made a study of experimental steels embodying the !east amount of alloying constituents, with the objective in mind of substituting these steels wherever possible for the standard alloy steels used heretofore. This study embraced the following phases: (1) The availability of silicon and manganese; (2) The average quantity of alloying elements recoverable from scrap; (3) The effect of increases in manganese and silicon contents on the general properties of steel; ( 4) The elements and ranges of elements which might be used to duplicate the hardenability of the steels now in use; (5) The effect of combining several elements in small quantities upon the properties of steel at various hardness and strength levels; (6) A determination as to whether or not the steels selected would suffice for general application. Working on this basis, the Committee arranged for the manufacture of several heats of steels containing various combinations of different amounts of such elements as silicon, manganese, chromium, nickel, and molybdenum. The steels thus produced were compared by hardenability tests.

Jan 1, 1943

By R. G. K. Morrison

As mines grow deeper, the problem of ground control becomes one of increasing importance. The literature on the subject has grown extensively in the past few years, but is still far from conclusive. Detailed and precise observations are on record covering most phases of the problem, and control measures have progressed to the point where, in a large measure, they are effective. The success of methods to date must be attributed to the efforts which have been exerted to reduce convergence of stope walls and to the realization that a regular progression of stope faces approaching longwall has a beneficial effect. This paper attempts to explain the relationship between these two factors and the general problem of ground control. The problem at present lacks the co-ordination of the practical with the scientific outlook, but fortunately as time goes on there are indications that our scientific friends are becoming more interested and more familiar with the practical issues involved. Opinions vary widely regarding the mechanism of the problem and there are several schools of thought, two only of which will be discussed. One associates the incidence of rock-bursts with the stresses built up by a sagging hanging-wall, while the other takes the view that stresses primarily responsible for the sagging hanging-wall are also the cause of rock-bursts. The first group starts its reasoning from the convergence of the walls, probably the most conspicuous feature of deep mining, and works back to the conclusion that rock-bursts are in sorne way due to the breaking up of the sagging layers. The second group begins with the stress zone apparent around excavations at depth and follows mathematical conceptions based on certain assumptions which, in the absolute sense, are known to be inaccurate, but which are justified by the similarity between the conclusions reached and the results obtained in practice. This reasoning is followed to the point where rock-bursts result from the failure, under stress, of rock in situ, quite independent of wall convergence.

Jan 1, 1939

By J. Abrahams, A. Nesbitt

Over the past half-century, researchers have commented on the complexities of ion-exchange processes, but have been forced to use gross assumptions to simplify the associated mathematics sufficiently for mathematical models to be of practical use, given the available computational power. This paper reviews the development of increasingly complex models as computational power has increased over the past half-century, from the direct application of Fick's Law in 1947, through to today's models requiring finiteelement methods. The assumptions required for and the associated limitations of the various models are presented and the associated computational complexities are discussed. A case study is presented in which a continuous loss of capacity in an acid resin was observed over about sixty cycles of loading and elution. Resin poisoning does not explain this observation. This paper presents the capacity loss data, speculates on possible causes of the phenomenon, discusses why conventional kinetic and equilibrium mechanisms cannot explain it and concludes that the need to develop a more rigorous model is apparent. The significance of this observation is that standard tests done for a new resin application could significantly overestimate the commercial performance of the resin concerned, highlighting the importance of computer simulation in this field of process engineering.

Jan 1, 2005

By Lang Tao, Jun Wang, Wei Xiao, Wenqing Qin, Pan Cao, Guanzhou Qiu, Key Lab of Biohydrometallurgy of Ministry of Education, Central South University

"The effect of metal cations on the rutile flotation using styryl phosphoric acid (SPA) as the collector was investigated by micro-flotation test, bench scale flotation test, zeta-potential measurements and adsorption measurements. The micro-flotation results indicated that Fe (?) and Al (?) ions in low concentrations had obvious activation on the rutile flotation, and Pb (?) ions in low concentrations had smaller activation of rutile, but Fe (?), Al (?), Pb (?), Ca (?) and Mg (?) have strong inhibition of rutile flotation in high concentrations. The bench scale flotation results indicated ethylene diamine tetraacetic acid (EDTA), boracic acid, and sodium hexametaphospate can decrease the metal ions concentrations, and increase the recovery of rutile flotation. Adsorption measurements and zeta-potential measurements revealed that Fe (?), Al (?) and Pb (?) ions were adsorbed on the rutile surface, and had interaction with SPA. But when these ions concentration were over the largest adsorption capacity, residual metal ions could occur chemical reaction with SPA.INTRODUCTIONRutile is one of the favored minerals for production of titanium dioxide white pigment, primarily through the chloride manufacturing process (Stanaway 1994; Hou et al., 2013) However, the majority of rutile ores belong to refractory ores, while flotation is one of the most efficient methods to separate fine rutile from gangue (Dolbear et al., 1937). With the flotation development, many effective collectors were successfully applied in the oxide ore. Many reviews have indicated that organic phosphonic acid collectors showed good selectivity on oxide ores such as ilmenite and rutile (Bulatovic & Wyslouzil 1999; Liu & Peng 1999).It is inevitable that many types of metal cations are present in ore pulp. These metal cations significantly influence the flotation of minerals. Liu et al. (2015) showed that Ca2+ and Mg2+ could improve the floatability of spodumene at pH 12.5 and 10.0, respectively. The authors proposed that Ca2+ and Mg2+ ions readily form hydroxy complexes (CaOH(l) and MgOH(l)) and precipitates as (Ca(OH)2 and Mg(OH)2) in strongly alkaline solutions. Fan and Rowson (2000) investigated the effect of Pb(NO3)2 addition as an activator on ilmenite flotation and showed that it could improve ilmenite floatability. The addition of Pb(NO3)2 resulted in an increase of ilmenite zeta potential in both weakly alkaline and acidic aqueous solutions. Mehdilo, Irannajad, and Rezai (2015) studied three kinds of ilmenite of different origins and discovered that both Mg and V had a negative correlation with ilmenite flotation, while the Mn content seemed to correlate positively with flotation efficiency. A number of studies have also showed that Fe3+ can improve the floatability of ilmenite (Fan et al., 2009; Nuri, Mehdilo, & Irannajad, 2014)."

Jan 1, 2016

By Graham Sim

Agenda ?The Water Challenge ?Examples from Three Case Studies ?Mine Drainage, 99% recovery ?Mine Drainage, 80% recovery ?Road Dust Control ?Technology Development ? Conclusion Global water challenges Assuring sustainable quantity Improving water quality Reducing energy consumption

May 1, 2011

By Tapio Leskinen, Jouko Koskinen, Timo Nlltti, Lappalainen Seppo, Pentti Vanninen

"The Courier 300 on-stream analysis system manufactured by Outokumpu has now been in operation at five of the company's concentration plants long enough to give a reliable basis for closer examination of the benefits achieved in control of these processes. The first system was installed at the Pyhiisalmi mine at the end of 1967. Since November 1970, two analyzers have been in operation at Pyhiisalmi feeding the assay data to a process computer which controls the whole plant and does the optimization of the process. In October 1970 the Courier 300 analysis system was installed at S. T. O. LESKINEN J. KOSKINEN the Keretti concentrator of the Outokumpu mine, followed soon by installations at the Vihanti Mine in May 1971, at the new Vuonos mine in November J 971 and at t he Kotalahti mine in December 1971. Since installation of the Courier analysis systems, considerable improvements have been achieved in the control and the economy of the plants. Immediate knowledge of the changes in the process and the possibility for rapid action has resulted in evener production and higher capacity and recovery. The recovery has been increased most significantly at the Vihanti concentrator, which operates on a complex ore. Consumption of chemicals has been reduced at all concentrators. Due to the fact that process control and partly also bilance analysis are not achieved by conventional methods any more, it has been possible to reduce the personnel of the laboratories drastically. Two of the plants, viz. the Pyhiisalmi and the Vuonos concentrators, are computercontrolled. The Vuonos concentrator started operation in January 1972 under computer control from the very beginning. The Pyhiisalmi concentrator has been computer-controlled since 1970. The Courier 300 analysis system was described in detail at the AIME Centennial Annual Meeting (1971). In this paper, less attention is paid to the analysis system. Only the sampling system of the Courier 300 is described in more detail. In the development of sampling equipment, effective use has been made of the company's wide knowledge of the problems involved and the test field offered by its concentrators. The sampling equipment includes secondary samplers and six basically different types of primary samplers, with which most sampling situations can be managed."

Jan 1, 1973

By A Hitchen

A general outline is given for the determination of copper, nickel, cobalt, zinc, lead, cadmium, bismuth, manganese, uranium, molybdenum, vanadium, sulphate and fluoride by polarographic or amperometric methods in a variety of ores or metallurgical products. The detection of oxygen in gas mixtures by an amperometric method used as a safety device is also discussed. Introduction I N this paper, a general outline will be given of the polarographic and amperometric methods used for the chemical analysis of various ores and metallurgical products in the Chemical Analysis Section of the Extraction Metallurgy Division of the Mines Branch. The methods to be discussed will be confined to those based on the use of normal D.C. polarography and will not include those methods which utilize a cathode-ray, square wave, pulse or A.C. type of polarograph. For the sake of convenience, ? the polarographic methods will be discussed according to the type of supporting electrolyte employed, as the same electrolyte may serve to determine more than one element in more than one type of ore. Amperometric methods will be discussed according to the element to be determined rather than

Jan 1, 1965

By H. P. Dibbs

An account is given of the application of neutron activation analysis to the rapid, non-destructive determination of copper in minerals, using a 14-MeV neutron source. Elements that interfere in the determination of copper by this method are given, together with the errors in the estimation of copper that result from the presence of varying amounts of these elements. The possible use of a compact "sealed-tube" 14-MeV neutron generator for the field assay of copper in minerals is discussed.

Jan 1, 1970

By Antonio Segatori, Bjørn Holmedal, Kai Zhang, Trond Aukrust, Knut Marthinsen

"The visual appearance and mechanical properties of aluminium alloy extrusions are strongly dependent on the microstructure and texture of the extruded profiles, where the desired microstructure and texture may depend on the specific applications. In the present work, the evolution of deformation, as well as recrystallization textures during extrusion of AA6xxx aluminium alloys, have been experimentally and numerically investigated. Extrusion trials were performed in a laboratory extrusion set-up, which enabled immediate water-quenching of the profiles at the exit of the die, and thus the possibility to capture the deformation texture prior to post-extrusion recrystallization. The textures and their through-thickness variations were experimentally measured by the electron back-scatter diffraction technique (EBSD, and the deformation textures numerically modelled by coupling FEM flow simulations and crystal plasticity (CP) simulations. Different CP models as well as different choices of model parameters were employed and evaluated for texture predictions. With an appropriate choice of crystal plasticity model and model parameters, the deformation texture can mainly be predicted, although the accurate intensities are hard to reproduce. The corresponding recrystallization textures, either generated through spontaneous recrystallization of the extruded profiles or through post-extrusion annealing, are far more challenging to reproduce with available recrystallization models.INTRODUCTION Extrusion is a widely applied thermal-mechanical process to produce aluminium profiles. The properties of the profiles, for example mechanical, fatigue, fracture, corrosion as well surface appearance, are strongly dependent on the underlying microstructure and texture, and the requirements with respect to these aspects may vary with applications (Ralston et al., 2010; Dumoulin et al., 2012; Donati et al., 2013). Moreover, it is often a challenge to produce extrusions with a consistent and homogenous grain structure and texture along as well as through the cross section of the profiles. It is thus vital to understand and be able to predict (model) how different microstructures and textures are formed and how they evolve during and after extrusion, as basis for controlling the final appearance and properties of extruded profiles."

Jan 1, 2018