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By Peter F. Pullen

The need to apply the latest available technology to develop better tools and methods to meet problems in the mining industry was recognized by six of Canada's leading mining companies. As a result, MIROC (Mining Industry Research Organization of Canada) was chartered to identify problem areas in Canadian mining and to have research carried out to develop the tools and equipment to meet these perceived needs. The initial activity of MIROC has been in the environmental field, with improved clothing and protective devices being developed by contractors. Work clothing for miners is now being field tested. Respiratory protection and a new personal light source combined in a new "space-age" helmet are about to be issued for testing. Further developmental work is being carried on to offer these units and probably other personal protective devices on an individual basis as well as in a combined package.

Jan 1, 1979

By V. S. Sastri, G. R. Doey, R. W. Revie

"Different forms of corrosion, the various corrosive environments encountered, the mining equipment subject to corrosion and the methods to control corrosion in the mining industry are briefly reviewed along with the savings that could be achieved by corrosion control. IntroductionCorrosive conditions in mines and metallurgical plants, lead to deterioration and wastage of equipment and of materials. The cost of corrosion in the mining industry can be significant, and measures to minimize corrosion must be taken to reduce this cost(l-3). Although the data in Table I are twenty years old they indicate the significance of corrosion costs in four industrialized countries. The costs of corrosion in the U.S. metallic ores sector and in the Canadian mining industry are presented in Tables 2 and 3, respectively. Significant savings in the mining industry can be achieved by using corrosion control methods. For example, corrosion in the Canadian mining industry in 1991 cost $1460 million of which $97 million was avoidable. Indirect costs of corrosion associated with plant shutdown, lowered efficiency of equipment and overdesign are additional to the direct costs cited here."

Jan 1, 1994

By William Petruk

Mineralogical investigations in connection with gold metallurgy are usually performed to find the reason for poor recoveries by cyanidation or by other leaching techniques. Poor recoveries most commonly are obtained when (I) native gold is encapsulated in an insoluble mineral as "invisible gold"; (2) native gold is coated with a precipitate; (3) gold-bearing products are insoluble in cyanide solutions; (4) carbonaceous material in the ore adsorbs gold; and (5) associated minerals decompose and consume cyanide. Samples of refractory material quite often have low gold tenors. It is difficult to find the gold-bearing minerals in such samples with an optical microscope because the probability of finding trace minerals in samples is small. The probability decreases with decreasing grain size of the gold-bearing mineral and with decreas¬ing gold tenor of the sample. Techniques have been developed to increase the success rate of finding gold grains; some are (1) concentrating heavy minerals; (2) preparing special polished sections; (3) searching with an image analyzer; and (4) dissolving associate silicate and sulphide minerals.

Jan 1, 1989

By Kosei Ishida

To achieve renovation work without noise, the authors developed techniques of manufacturing pre-cut interior finishing components for renovation work. In this paper, to achieve the system of pre-cut interior finishing components, the authors describe a measuring method of reinforced-concrete structure by 3D laser scanner and then describe a method of making a design of pre-cut interior finishing components with the polygon model. Using these two methods, the steps of manufacturing pre-cut interior finishing components consist of the following four steps: First, measure the building shape using a 3D laser scanner. Secondly, integrate a point cloud data and retrieve the markings on the floor. Then, create a polygon model of the building based on the point cloud data. Lastly, make a drywall design using a polygon model. To evaluate the technique feasibility of manufacturing pre-cut interior finishing components, the authors have conducted an experiment of the finishing interior work of the drywall. Using pre-cut interior finishing components, the authors have been able to achieve interior finishing work without noise.

Aug 1, 2013

By J. Gray, J. Peck

As the turn of the century approaches, traditional open pit mining methodologies and processes are being modified through the introduction and use of new technologies. As in other industries, the personal computer is dramatically changing the traditionally conservative mining industry by allowing mines of varying size and capacity to increase their productivity and efficiency through the use of easy to use, office software. Computer-based monitoring and control systems are also being used more frequently to measure and optimize, in real-time, the performances of operating equipment. When communicated to an end-user, this information can provide accurate and timely answers to questions of how much, where, when, and by whom. This capability forms the foundation of a more comprehensive, proactive management and planning facility where, ultimately, information acquired from the producing equipment will be used to optimize and control machine and human activities. As these technologies mature and become essential tools in a mine, they will eventually serve as the basis for more robotic and autonomous mining operations.

Jan 1, 1999

By M. H. Allan

"This paper presents the geographic and geological setting of Saskatchewan Power Corporation's Poplar River Mine in south-central Saskatchewan, about 8 miles from the U.S. border. Generally the mine, which is being expanded to four million tons per year, is in an extremely disturbed geological area with severe dewatering problems. The lignite coal, which is strip mined, is supplied directly to an electric power generating station by means of a 7-mile unit-train private railroad.A number of unique reclamation and socio-economic problems were encountered because of the proximity to the U.S. border and because of the lack of experience of the regulatory authorities in projects of this kind. These are described in some detail, as well as the performance of one of the largest draglines in Canada. IntroductionThe Saskatchewan Power Corporation is a publicly owned utility which has the franchise to supply electricity and natural gas to all customers within the boundaries of Saskatchewan.Saskatchewan is a province which can almost be divided in two: the populated southern portion, principally devoted to farming, and the northern portion which is mostly on the Precambrian Shield and consists of lakes, rocks and muskeg. This portion is largely uninhabited except for a number of small villages. However, in the last few years there has been considerable mineral exploration and development, notably for uranium. This has helped considerably in the diversification of the basic agricultural economy of the province.Saskatchewan consists of 251,700 square miles, 761 miles north to south and an average of 335 miles east to west. It has a population of approximately 960,000, giving a population density of four persons per square mile. The Saskatchewan Power Corporation supplies 357,249 electrical arid 221,378 natural gas customers."

Jan 1, 1982

By Deborah McCombe

"and Bill Roscoe, Consulting Geologist and Principal with Scott Wilson Roscoe Postle AssociatesMineral property valuations are carried out for a variety of reasons, such as mergers and acquisitions, non-arm’s length transactions, initial public offerings of stocks, support of audited financial statements, fairness opinions, determination of vendor considerations, litigation, expropriation, income tax matters and insurance claims.The CIMVal Committee was formed in 1999 to review and advise on approaches to the valuation of mineral properties. CIMVal is a special committee of CIM formed on the recommendation of the Mining Standards Task Force of the Toronto Stock Exchange and the Ontario Securities Commission.After solicitation of views and consultation with various interested parties, the CIMVal Draft Standards and Guidelines for Valuation of Mineral Properties were released for comment in February 2002 and were finalized in February 2003. CIMVal’s objective was for the standards to be used by the mining industry in general and to be adopted by Canadian securities regulators and Canadian stock exchanges. To that end, the standards contain many of the definitions and concepts of National Instrument 43-101, Standards of Disclosure for Mineral Projects, which came into force in February 2001.The intent of the CIMVal Standards and Guidelines is that mineral property valuations be carried out by appropriately qualified individuals and that all relevant information be fully disclosed. It consists of two parts: standards, which are mandatory in the valuation of mineral properties, and guidelines, which elaborate on the standards and provide guidance and recommendations for the valuation process and for reporting."

Jan 1, 2003

By H. Somekawa

The fracture toughness and deformation structures an AZ31 magnesium alloy processed by equal-channel-angular extrusion (ECAE) were investigated. The average grain sizes of as-ECAE and annealed-ECAE alloys were 4.0 and 16.3 µm, respectively. The plane-strain fracture toughness, Kip, in as-ECAE and annealed-ECAE were estimated to be 27.3 and 23.5 MPam1/2, respectively, by stretched zone analysis. The fracture toughness indicated higher value with grain refinement. From optical microstructural observations in samples after fracture toughness tests, although deformation twins were observed in annealed-ECAE, no deformation twins were observed in as-ECAE. From TEM observations, the dislocations on basal and non-basal planes were activated in as-ECAE. With grain refinement, the activations of dislocations on both basal and non-basal planes were possibly related to the reduction in formation of deformation twins in as-ECAE. In addition, in comparison with direct extruded process, ECAE process was more effective method to improve the fracture toughness in magnesium alloys.

Jan 1, 2006

By P. V. Barr, Y. -H. Li, A. P. Watkinson

Subsequent to a campaign of pilot-kiln trials of firing bio-oil and natural gas, scale-up to commercial lime kilns was made using an in-house mathematical kiln model. Both dry limestone and lime mud kilns of 3.5 m OD. by 100 m length were used for bio¬oil firing simulations. Comparisons were made against natural gas firing on the basis of specific firing rate, off-gas volume, energy consumption and overall lime quality. Model simulation results indicate that conversion from natural gas to bio-oil with no productivity loss will increase energy comsumption by about 7.5% and total off-gas volume by about 8%. Alternatively, a 6% decrease in productivity would be expected if off-gas volume is maintained constant. The calculations are sensitive to deviations in the lower heating value (LHV) used in the simulations. A 5% increase in the LHV of the bio-oil, which could result from a 3% decrease in the moisture content, reduces the energy penalty to 2% coupled with a slight reduction in off-gas volume.

Jan 1, 2004

By J. H. Schloen

"One of the most important phases in Canada's relatively rapid development of its metal mining and refining industries was launched in 1928 when the directors of Noranda Mines Limited decided to establish an electrolytic copper refinery ""somewhere in Eastern Canada”. Noranda's president, J.Y. Murdoch, had already evolved the company's ""mine to market"" policy and was determined to prove the economic feasibility of refining Noranda copper in Canada. The time appeared to be ripe as buoyant business conditions continued into 1929. In addition, proven ore reserves at the Horne Mine in northwest Quebec had virtually tripled and the price of copper had reached a healthy 15 cents per pound. Letters Patent incorporating the company bearing the date February 6, 1929 had been granted by the Secretary of State in accordance with an application that specified a capital structure of $2 million divided into 20 000 shares with a value of $100 each. Noranda assumed 70% of the original investment in the proposed refinery, while the Nicholas Copper Company of New York (which later became Phelps Dodge Corporation) and British Metal Corporation Ltd. of London, England, each were responsible for 15%. Nicholas Copper Company agreed to supply the design and to supervise the construction of the refinery and British Metal Corporation would act as sales agent and market the refinery's products."

Jan 1, 1999

By T. R. Yu, D. B. Counter

"Kidd Creek Mines primarily employs sublevel blasthole stoping for underground mining operations. During pillar recovery in No.1 Mine and panel mining in No.2 Mine, the free standing fill exposures may reach a height of 100 m or more. Consequently, a competent consolidated rockfill has been required to fill the mined openings.Since 1976, a total of more than fifty stopes and pillars have been filled with over four million tonnes of backfill. Fill exposures, up to heights of 100 m, have stood up well after blasting adjacent to the backfill.The fill material consists of a graded aggregate, Portland cement and ground slag. Sand has been occasionally mixed in the fill material to serve as avoid filler. The aggregate is prepared in a fill crushing plant, transported underground through raises, and hauled to the filling stopes by conveyors in No. 1 Mine and by trucks in No.2 Mine.Two mixing methods are currently in use. No. I Mine utilizes the free fall of gravity; the fill materials are sprayed with cement slurry as the aggregate departs from the conveyor into a mixing culvert. The other is the use of a rotary mixer on a batch basis in No. 2 Mine.This paper describes the fill systems, filling operation s, and the backfill quality control practice, together with various testing results related to improving fill quality as well as reducing fill costs.IntroductionThe Kidd Creek minesite, located 27 km north o f the city centre of Timmins, Ontario, produces 4.5 million tonnes of copper, zinc, lead, and silver ores annually from its No. 1 and No.2 underground mining operations. Both mines employ a sublevel blasthole stoping method."

Jan 1, 1983

By S. K. Paul

"This paper briefly describes the underground crushing and conveying system at Sherritt Gordon Mines' Ruttan Mine. A series of three steel-cord belted conveyors, with a total length of 2J55 metres and a total vertical lift of 407 metres, convey the muck from the underground crushing station to the mill at the surface. The maximum size of the crushed rock is 6 in. All the conveyors are provided with numerous safety and fire suppression devices. IntroductionThe Ruttan Mine of Sherritt Gordon Mines Limited is located 20 km east of the town of Leaf Rapids, 760 km north of Winnipeg. The orebody is multilensed, with lens width varying from 6 to 45 m. Ore production started in 1973 with the opening of a 10,000-tpd open-pit mine. Initial development of the underground mine was started in 1972 with the driving of parallel conveyor and access declines at minus-2507o gradient to the I 220-m level, and then the access ramp was further extended to the 1160-m level. Exploration drifting was done on the 1280-m and 1160-m levels from the access ramp. The final development plan for the underground project was approved in January 1977, and full-scale development and constructionwere resumed.At present, Ruttan Mine is in a period of transition from open-pit to underground mining. Ore production is now coming from both operations. By mid-1980, open-pit production will cease and all production will come from the undergroundmine.The underground mining method at the Ruttan Mine is sublevel open stoping with delayed backfilling. The orebody is divided along strike into a series of 27-m-long stopes and 15-m pillars, both 60 m high."

Jan 1, 1980

By G. J. Reid, D. H. Stewart

"A diversity of structures and rock types in the Aft on pit has resulted in the occurrence of several different types of wall failure. Delivery of ore to the mill has not been affected and safety has not been compromised thanks to effective remedial 1V0rk and to a system of structural mapping, back analyses of failures, groundwater monitoring, and simple movement monitoring. Remedial measures have included artificial support, dewatering (including vacuum-assisted drainage), flattening of slopes and temporary buttressing. This paper describes six different wall failures at Afton and highlights the features of each. Examples given include rates of movement, extent and direction of movement, and piezometric responses. The practical, low-cost monitoring system was sufficient in one case to allow the prediction of date of failure. IntroductionThe Afton copper deposit is located 13 km west of Karnloops, British Columbia and has been mined for nine years out o f an expected eleven-year life. Open pit mining has reached 700 feet below sur face and is designed to proceed to 970 feet below surface by the time the pit is completed. The excavation is in a structurally and lithologically complex environment. Inevitably, some wall failures have occurred but these have been limited to small, manageable failures which have not compromised production or safety. To handle the failures it has been necessary to understand their nature. Of prim e concern has been the rate s of movement, but displacement vectors and hydrology have been monitored as well. The monitoring system is based on EDM surveys and on wire extensometers and plates set across cracks. Water levels have been read in standpipe piezometers. At Afton the emphasis has been on simple, practical, and inexpensive monitoring and because rock type s and structures play such a major role in any failure, detailed geologic al mapping is carried out."

Jan 1, 1988

By N. A. McPherson, P. C. Stevens, A. J. Rigby

"There has been a consistent move in recent years to continuously cast small billets while utilizing ceramic stream protection between tundish and mould. The need to have ceramic stream protection has developed from a need to improve billet surface quality by submerged pouring. The need to protect the ladle to tundish stream in conjunction with tundish to mould protection is explained.The continuous casting of thin slabs is at the development state and will require a great deal of ceramic development to ensure the economic viability of the project. An insight is given to the main problems.IntroductionDuring the early development period o f the continuous casting of steel in the late 1940s and 1950s, much of the work was carried out on small cross section products. For example, the continuous casting of 50 mm square billets was carried out on a production scale in the United Kingdom at Barrow. Slab casting was initiated on a production basis on 100 mm thick stainless steel slabs at Atlas Steel, Weiland, Ontario. In the case of slab casting the thickness increased gradually until it was similar to Slabbing Mill feedstock , i.e. in the range 200 mm to 250 mm , although stainless steel continued to be lower at around 185 mm thick.For billets , a significant proportion of steel is now cast at around 100 mm square which creates specific difficulties when casting with a submerged pour - mould powder practice. The move back to smaller cross sections is further emphasized by the current interest in "" Near Net Shape Casting"" . If this move continues, then significant development will be required to create the refractories used between tundish and mould in the continuous casting process.Two specific areas which will receive attention are; (I) the casting of small cross section billet s; and (2) the casting of thin slab."

Jan 1, 1990

By D. K. Sarkar, Ying Huang

"Superhydrophobic thin films were fabricated on aluminum alloy substrates by chemical etching followed by passivation with organic acid molecules; (ii) electrophoretic deposition (EPD) of functionalized ZnO nanoparticles and (iii) electrodeposition of organic-inorganic composite materials. The physical and compositional analyses of the deposited thin films were characterized by SEM, FTIR, XRD as well as contact angle goniometer. The contact angle and surface roughness of the superhydrophobic surfaces prepared by the chemical etching process were found to be 156° and 2.29 µm, (ii) by the EPD process were found to be 155° and 4.54 µm and (iii) by the electrodeposition process were found to be 159° and 7.11 µm, respectively.The corrosion properties were analyzed with both polarization and electrochemical impedance spectroscopy (EIS) in NaCl aqueous solutions. The results demonstrate that the superhydrophobic thin films on aluminum alloy substrates display better anti-corrosion behavior than the as-received aluminum substrate. The comparison of results pertaining to the compositional and corrosion properties of these thin films on aluminum will be discussed in this work.INTRODUCTIONSuperhydrophobicity is defined as a surface property which provides non-wetting characteristics with a water contact angle larger than 150°. It is observed that the creation of certain micro-nanoroughness structures promotes the entrapment of air in the spaces of the rough surface morphology. In addition, lowering the surface energy helps to reduce the affinity of water drops to the surface, thereby weakening the water-surface interaction. Recently, various fabrication methods for superhydrophobic surfaces have been explored (Sarkar, 2010, Huang, 2010, 2011, 2013, 2015a, 2015b), such as the sol-gel process (Brassard, 2011), plasma treatment (Marchand, 2013), chemical vapor deposition (Zheng, 2009), chemical etching (Saleema, 2011), electrodeposition (Ying, 2011) and electrophoretic deposition (EPD; Huang et al., 2015b)."

Jan 1, 2016

By Godfrey W. McDonald, Dennis E. Fredrickson

"Commercial coal mining has been recorded in Nova Scotia since 1863 and during this period an estimated 60,000,000 short tons of mine discard containing 10 1030% coal has been accumulated, Approximately 70% of these dumps are in the Cape Breton region and most are owned by the Cape Breton Development Corporation (CBDC), formerly DEVCO.The explosion of oil produced energy costs which created an increase in thermal coal demand as well as the desire to rehabilitate abandoned mine dumps encouraged coal reclamation. CBDC was receptive to a proposal from the Selminco Joint Venture and encouraged the building of the Princess Recovery Plant (1980) and The Summit Plant (1982).The mine dump contains scrap, waste rocks, coal and substantial quantities of fine shale. The scrap and oversize are removed and the remaining material slurried with water to a density of 1.45. The slurry is cycloned to separate the saleable thermal coal from the rejects which are returned to designated areas of the dump for contouring and revegetation.BackgroundThe recorded coal production in Nova Scotia from 1863 to 1980 was 390,000,000 short tons. This extraction was associated with an estimated 60,000,000 short tons of discarded material. This mining discard and coal washing plant reject are located in numerous, varying sized dumps throughout the mining areas. Approximately 70% of these dumps are in the Sydney coal field region of Nova Scotia. The coal content of these dumps varies from 10 to 30% coal with an average of 18%.Energy CostsThe explosion o f energy costs in the mid-1970s greatly increased the sale price of thermal coal which made recovery of coal from some of the dumps economical. The environmental benefit of these operations will be the rehabilitation of the dumps upon cessation of the coal reclamation operation."

Jan 1, 1983

By R. del Villar, A. R. Laplante

"This article presents four grinding simulation programs, written in Applesoft BASIC. The firs t two calculate residence time distributions (RT Ds) for open and closed loops mills. The third program calculates the select ion functions from the RTD, breakage function and particle size distribution (PSD) o f the feed and discharge. Two linear regression programs are also included to calculate the breakage function. These results are used in the fourth program to simulate continuous or batch grinding kinetics.The modelling approach presented is the size discrete, time continuous matrix formulation presented by Reid (1965) from concepts originally proposed by Epstein (1948). It is at the present time the most widely accepted phenomenological model of grinding kinetics and is standard textbook material (Austin et 01., 1982; Kelly and Spottiswood, 1982, p. 152). The concepts of RTDs and tracer testing originated from chemical engineering theory and practice, and are well presented in Leven spiel (2n d Ed . 1972 , Ch. 9) .Applesoft* was chosen because it is compatible with many micro computers. It is also one of the simplest and least powerful BASIC versions. Thus it can easily be adapted to other more complex BASIC versions.Open Loop Residence Time Distributions (Program RTDOPEN)As mixing, channelling, stagnation and short-circuiting all affect slurry motion in tumbling mills, transport characteristics are very complex an d cannot be derived from fundamental principles. Fortunately , as grinding follows first order kinetics, transport characteristics for the purpose of grinding simulation ca n be represented by the RTD of the slurry phase . It is normally determined using liquid tracers, as it has been demonstrated and is commonly accepted that in industrial ball mill s, the RTD of the so lid phase is particle size independent and equal to that of the liquid phase."

Jan 1, 1985

By So-Yeong Lee, Moosang Lee, Seung Hwan Ahn, Ho-Sang Sohn, Jongshin Chang

It is necessary to understand the characteristics, phase changes and chemical reactions of flue dusts introduced from a furnace to an off-gas line in order to achieve the stable operation and the improvement. This study is to develop the dust reaction model for chemical reactions of dusts in an uptake shaft of smelting furnace and a waste heat boiler. Phase equilibria and reaction paths in this system were determined by thermodynamic calculation with experimental and industrial data. The oxidation reaction rate of dusts was determined by the gas film mass transfer controlling. And the sulfation reaction rate was evaluated by the unreacted shrinking core model. Kinetic parameters were estimated by reference data including industrial ones. The present study with the developed model shows various effects of temperatures, dust particle sizes, and O2 gas partial pressures on dust reactions. INTRODUCTION The flue dusts from a copper smelting furnace move along a furnace off-gas stream into an uptake shaft and a waste heat boiler (WHB) and electrostatic precipitator(s). It is necessary to control the dust quality in order to stabilize the operation because the sticking behaviors differ depending on the phase of dusts. Phase changes of dusts are caused by chemical reactions at given conditions such as temperature and partial pressure of gases. Therefore, it is required to understand the phase changes and chemical reactions of dusts in order to perform the improvement and stable operation. The present study carried out the investigation to understand their fundamental knowledge. Especially, this study was focused on the kinetics of chemical reactions of flue dusts, developed the model. In particular, the scope of development and utilization of the model was defined as the uptake shaft of the Mitsubishi S furnace and the S-WHB radiation section in the Onsan smelter. Information needed for the modeling work referred to data from these processes.

Jan 1, 2019

By Brian Lewis

"IntroductionThe ion exchange process is classed as a purification and concentration stage. In the uranium industry it is used to separate, and recover uranium, from a solution produced in the leach and subsequent solid washing circuit, that contains uranium as well as some impurities. The final product from this circuit is a solution, containing uranium at a 15 to 25 fold increase in concentration, with a chemical composition suitable for the ""Precipitation"" circuit.The process is a reversible chemical ""ION"" exchange, between a solution, and solid phase, with the ""resin"" being the solid phase. Various chemical changes in the solution phase will permit the resin to remove uranium from a solution or have the uranium removed from the resin back into a solution phase. The former loads uranium onto the resin, and is called the ""adsorption cycle"", and the removal or stripping is known as the ""elution cycle"".Ion Exchange resin is a semi-rigid polystyrene spherical bead, approximately 10 to 30 mesh. It is used by placing the resin in a vessel, so that a porous bed of resin is formed, through which the solution may flow.There are many different types of vessels, and systems used to hold the resin, but it is not the intention of this chapter to describe them all, but to describe two methods used in Elliot Lake. These are the ""fixed bed"", and ""moving bed"" systems, the condition of the bed during normal operation signifies the name of the system.Chemical and Physical Characteristicslon Exchange ResinThe resin used is a strange base Anionic resin, semi-rigid, and spherical in shape. The size of the wet resin is approximately 9007o between 20 and 40 mesh. Physically the beads of resin are broken early, but some have lasted over 15 years and are still in use."

Jan 1, 1989

By H. E. Wilde

"Zinc has been used for many years as a galvanic coating for the protection of steel. Electrochemical measurements show that zinc actually overprotects steel. The corrosion rate of DQSK (drawing quality semi-killed) steel in air saturated salt water was determined as a Junction of applied cathodic potential. The resulting data indicate that at a critical cathodic over potential of - O. 725 Vsce an acceptably low corrosion rate of less than 1 mpy occurs. Using the developed criterion, alloys of Zn/X and AL/X were produced and evaluated in galvanic contact with steel in a standard laboratory test. The results indicate that Zn /Mn, Zn /Co, AI/Mg/Si and AI/Mg/Ge alloys offer excellent galvanic protection along with (a) no hydrogen evolution, and (b) improved dissolution life over Zn coatings.IntroductionZinc coated (galvanized) steel has been successfully used in applications where bare (or painted non-galvanized) steel would suffer corrosive attack. In general, galvanic coupling to zinc, as either an anode or a coating, is an effective means for combatting steel corrosion. Because of this, the use of galvanized steel has increased markedly, stimulated primarily by automobile manufacurers seeking to extend the corrosion warranties on automobiles(1).Although effective, zinc coatings are not without a number of drawbacks which warrant efforts to improve them. For example, because of the widely differing electrode potentials between zinc and steel ( - 1.05 Vsce and - 0.60 Vscc, respectively, in air saturated NaCl solutions), the zinc corrodes at a rapid rate to protect the steel. This is reflected in the limited lifetimes of galvanized unpainted siding. The basic electrochemistry controlling the situation is shown in Figure 1, for a system controlled by oxygen reduction. The zinc corrodes sacrificially to protect the steel, while cathodically polarizing the steel to a potential near that of zinc's open circuit anode potential."

Jan 1, 1990